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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Modeling the Behavior of Noble Metals During HLW Vitrification in the DM1200 Melter

The noble metals ruthenium (Ru), rhodium (Rh), and palladium (Pd) are present to various extents in defense and commercial high-level nuclear waste streams. Usually, their concentrations are higher in commercial waste. Ru, Rh, and Pd are sparingly soluble in silicate glass melts and they therefore form separate metal, oxide, or other phases. These phases are generally denser than the glass melt and tend to sediment to the bottom of the melter, where they form a "sludge" layer. Since the sludge layer has a higher electrical conductivity than the molten glass, accumulation of sludge can ultimately lead to electrical disruption of the operation of the melter. In addition, the sludge reduces the melt volume, which also changes the operational characteristics of the melter. The noble metals sludge is a highly viscous mixture of melt and noble metal phases. The concentration of noble metals in the sludge may be 10 to 100 times higher than that in the drained glass.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2026

Using Best Basis Inventory Data to Direct Strategies for Real Time Monitoring of Hanford High Level Waste – 26226

The potential to accelerate the processing of low- and high-level tank waste by applying real-time monitoring (RTM) of chemical and physical properties has prompted research into the suitability of multiple analytical methods for that purpose. The broad variety of waste stream properties and the large number of analytes of interest (as evidenced by Waste Acceptance Criteria (WAC) and Process Control Limit (PCL) lists) lead to an overwhelming set of possible analytical scenarios. This report describes the use of Best Basis Inventory (BBI) data to find the most relevant analytical targets for the specific case of monitoring the blending of High Level Waste from multiple tanks prior to introduction into a vitrification facility. Campaigns for blending this waste to minimize the risk of exceeding WACs and PCLs have been proposed. However, the predicted compositions of the blended materials do not incorporate any uncertainties that may be associated with the representativeness of the waste layer samples or the laboratory analyses that generated the BBI data. Also, they do not include any uncertainty associated with the precision of collecting highly specific fractions of the layers during a blending campaign or any inhomogeneities that may exist in those layers. Monte Carlo methods are used to apply uncertainties to the compositions of the individual layers specified in the campaign recipes. The resulting variations in the compositions of the blended materials allow estimation of the risks of exceeding WACs and PCLs for each campaign. A critical subset of WACs/PCLs – NOx, NaK, AlFeZr, and S – are especially at risk of being exceeded in multiple campaigns. These analytes should be the focus of instrument development. We also have extracted the expected solid/supernate distribution for these analytes, which establishes important performance criteria for individual analytical methods. The BBI data also permits an understanding of the different chemical forms in which the analytes appear. Thus, the need to establish instrumental sensitivity to these forms can be gainfully addressed. Although concentrating on one specific application – the blending of tank waste - this approach should be generalizable for the analysis of other possible RTM applications for waste processing.

Lascola, Robert [Savannah River National Laborator↗
DOE OSTI2016

A Paradigm Shift continued: An Application of Structured Decision Making for Sustainable Waste Management - 16486

Structured decision making presents an opportunity for DOE and others engaged in solving complex environmental and waste management problems to find solutions that are stakeholder engaged and cost effective. This approach represents a paradigm shift that was introduced in a series of papers and a panel session at the WM2015 Symposium. The advantages of structured decision making over less formal approaches to decision making include technical defensibility, traceability and transparency. Structured decision making also overcomes the limitations of misapplication of conservatism in modeling, addresses stakeholder concerns and competing objectives directly, and provides a formal method through which internal and external stakeholders are encouraged to collectively and carefully consider all relevant attributes of solving complex problems. The first requirement of this paradigm shift is a realization and recognition that the problems faced are inherently decision problems, and that there is a formal theory of decision analysis that can, and should, be used to support finding the best solutions. Structured decision making is, very simply, formalized common sense. The formalities include: framing the problem; identification of objectives and measures for valuing those objectives; costs or values associated with those objectives; management options or alternatives for taking action that are tied directly to the objectives; and, science-based models to evaluate the options. Decision analysis is used to evaluate objectives and choose management options by balancing probability and consequence. The science-based models are built probabilistically based on expectation and uncertainty, and costs and value judgments are used to fulfill addressing stakeholder concerns. Consequently, this approach avoids misplaced conservatism in science-based modeling and properly places values in the objectives component of a decision model. This approach honestly addresses uncertainty and value judgments and balances these competing components to find the most effective decision. A software framework program called Guided Interactive Statistical Decision Tools (GiSdT - pronounced 'gist') is used to support an application of this paradigm shift towards structured decision making. In this application objectives and management options for a waste disposal problem at the Los Alamos National Laboratory are identified, and features, events and processes are described and defined to form the basis of a conceptual site model. This establishes the decision model structure. Objectives are addressed through the three pillars of sustainability - economic, environmental, and social - and also address regulatory concerns or constraints. Management options include removal of waste to another location and engineering designs for leaving waste in place. Using structured decision making, the relationship between objectives, management options, and the conceptual site model is made clear, and leads to a comprehensive, defensible, transparent and traceable approach to effective decision making. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Summary of Consolidated Interim Storage Advantages and Disadvantages from an Integrated Systems Perspective from Prior Reports and Studies

The question of whether centralized storage of civilian spent nuclear fuel (SNF) should be part of the federal waste management system as an intermediate step before permanent disposal has been debated for more than four decades. Centralized storage facilities were included as a potential component of the U.S. spent fuel management system in the Nuclear Waste Policy Act of 1982 (NWPA), but these facilities were not identified as being essential. When the NWPA was passed, it was expected that a permanent repository would be available around the turn of the century to meet the commitments that were made to start accepting waste by that time. For a number of reasons, a permanent repository was not available at that stage. This report summarizes the advantages and disadvantages of including an ISF as part of an integrated waste management system that have been identified in numerous analyses of the impacts of a consolidated interim storage facility (ISF), previously discussed as monitored retrievable storage, the form of ISF authorized in the NWPA) by the U.S. Department of Energy (DOE) and independent groups. Storing SNF before disposal is a functional requirement for an integrated waste management system. As described below, the studies reviewed in this report have identified a range of benefits that could be obtained by adding a consolidated ISF to the waste management system, including (1) earlier acceptance of fuel by the federal government, (2) reduction in the number of unintended long-term storage sites, (3) added system flexibility and opportunity for better integration, and (4) near-term development and demonstration of institutional and technical infrastructures for large-scale management of SNF. At the same time, these studies have identified potential drawbacks to deployment of an ISF, including (1) potential adverse impacts on development of a repository, (2) additional transportation of SNF, and (3) a large upfront economic investment to establish the consolidated storage capability. In general, the studies that have considered the positive and negative impacts of consolidated storage most comprehensively have concluded that in light of these considerations, the benefits of including an ISF as part of an integrated waste management system can outweigh any real or perceived disadvantages.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2015

Melter Feed Reactions at T ≤ 700°C for Nuclear Waste Vitrification

To understand feed‐to‐glass conversion for the vitrification of nuclear waste, we investigated batch reactions and phase transitions in a simulated nuclear waste glass melter feed heated at 5 K/min up to 700°C using optical microscopy, scanning electron microscopy with energy‐dispersive X‐ray spectroscopy, and X‐ray diffraction. To determine the content and composition of leachable phases, we performed leaching tests; the leachates were analyzed by inductively coupled plasma atomic emission spectroscopy. By 400°C, gibbsite and sodium borates lost water and converted to amorphous phase, whereas other metallic hydroxides dehydrated to oxides. Between 400°C and 700°C, carbonates decomposed before 500°C; amorphous aluminum oxide and calcium oxide reacted with the sodium borate and formed the more durable amorphous borate phase along with intermediate crystalline products; above 500°C, quartz began to dissolve, and hematite started to convert to trevorite.

Xu, Kai↗
DOE OSTI2017

Identification and recovery of rare-earth permanent magnets from waste electrical and electronic equipment

Highlights: • Different WEEE were analyzed and the rare-earth permanent magnets were collected. • Chemical composition evolution of Nd-Fe-B alloys over the years is illustrated. • Loudspeakers from laptops and loudspeakers from flat TV contained Nd-Fe-B magnets. • The amount of Nd-Fe-B could double if the loudspeakers streams are included. - Abstract: Nd-Fe-B permanent magnets are a strategic material for a number of emerging technologies. They are a key component in the most energy efficient electric motors and generators, thus, they are vital for energy technologies, industrial applications and automation, and future forms of mobility. Rare earth elements (REEs) such as neodymium, dysprosium and praseodymium are also found in waste electrical and electronic equipment (WEEE) in volumes that grow with the technological evolution, and are marked as critical elements by the European Commission due to their high economic importance combined with significant supply risks. Recycling could be a good approach to compensate for the lack of rare earths (REs) on the market. However, less than 1% of REs are currently being recycled, mainly because of non-existing collection logistics, lack of information about the quantity of RE materials available for recycling and recycling-unfriendly product designs. To improve these lack of information, different waste streams of electrical and electronic equipment from an industrial recycling plant were analyzed in order to localize, identify and collect RE permanent magnets of the Nd-Fe-B type. This particular type of magnets were mainly found in hard disk drives (HDDs) from laptops and desktop computers, as well as in loudspeakers from compact products such as flat screen TVs, PC screens, and laptops. Since HDDs have been investigated thoroughly by many authors, this study focusses on other potential Nd-Fe-B resources in electronic waste. The study includes a systematic survey of the chemical composition of the Nd-Fe-B magnets found in the selected waste streams, which illustrates the evolution of the Nd-Fe-B alloys over the years. The study also provides an overview over the types of magnets integrated in different waste electric and electronic equipment.

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DOE OSTI2016

Crystallization of Sodium Phosphate Dodecahydrate and Re-crystallization to Natrophosphate in Simulated Hanford Nuclear Waste - 16188

The nuclear waste at the Hanford site near Richland, WA, has large concentrations of phosphate in the form of the phosphate ion, sodium phosphate dodecahydrate (Na{sub 3}PO{sub 4}.12H{sub 2}O.(1/4)NaOH) and natrophosphate (Na{sub 7}F(PO{sub 4}){sub 3}.19H{sub 2}O). Sodium phosphate dodecahydrate can form a gel and natrophosphate can crystallize large particles, complicating the processing of slurries of both salts. The gel is regarded as more problematic, so natrophosphate has historically been crystallized to prevent phosphate gelling. This study determined if natrophosphate crystals can grow to large size in short time periods (a few weeks), time periods relevant to short process shutdowns. Solutions of NaOH and NaAl(OH){sub 4} were blended at different ratios with stock solutions containing NaOH, NaF, and Na{sub 3}PO{sub 4} at 50 deg. C. The mixtures were allowed to cool to 22 deg. C, and the crystal growth was monitored by Polarized Light Microscopy (PLM) for 17 days. Four of the six blends investigated gelled rapidly due to Na{sub 3}PO{sub 4}.12H{sub 2}O.(1/4)NaOH precipitation. The gel slowly dissipated over time as the solids recrystallized into natrophosphate. In one case, the natrophosphate reached sizes of greater than 1000 microns in diameter in just 4 days. This rapid gelling and crystallization kinetics is important to engineers trying to manage nuclear wastes high in phosphates. Hanford tank farm engineers are developing sampling plans to support temperature and process control strategies for preventing the formation of solid phosphates. They are also developing methods of suspending large natrophosphate crystals. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Technical Gaps in Hanford High-Level Waste Solids Settling Behavior and Settling Time Evaluation for Direct Feed High-Level Waste (DFHLW) Operations

Settling of high-level waste (HLW) solids in process vessels is a key conceptual process step in providing HLW feed directly to the Hanford Waste Treatment and Immobilization Plant (WTP) HLW Vitrification Facility. Direct Feed High-Level Waste (DFHLW) is a potential approach to initiating HLW vitrification prior to completing of the WTP Pretreatment Facility. Settling would be used with subsequent supernatant decant to concentrate HLW feed. To support planning for DFHLW, Washington River Protection Solutions (WRPS) requested support from the Pacific Northwest National Laboratory to evaluate the current data set available to predict the time needed for HLW solids to settle, to identify gaps in the understanding and predictive capability of HLW solids waste settling times, and to provide scoping estimates of the potential settling time. Eight technical gaps were identified for predicting settling times and characteristics of the formed sediment layers including: Gap 1: In-Tank Settling Rates Faster than Settling of Laboratory Samples, Gap 2: Effect of Sludge Leaching/Washing on Predicted Settling Times, Gap 3: Predicting Waste Settling from Waste Chemistry (Waste Type), Gap 4: Predicting Waste Settling from Particle Size and Density Distributions (PSDDs), Gap 5: Insufficient Laboratory and In-Tank Settling Data to Represent Hanford Waste, Gap 6: Methods for Real-Time, In-Tank Tracking of Settling, Gap 7: Prediction of Sediment Erosion Resistance as a Function of Settling Time, and Gap 8: Prediction of Sediment Solids Content as a Function of Settling Time. In addition to the data gaps, an overarching observation of the settling rate and settled layer data is the significant variation in behavior. At similar solids concentrations, settling rates can vary by as much as 3 orders of magnitude depending on the source waste tank, and significantly different settling rates are noted between laboratory and in situ tests for the same waste tank. The range of average solids concentration in existing HLW sediment, which may have been quiescent for decades, can vary from less than 7 wt% to greater than 74 wt% solids. The shear strengths (or yield stresses) measured on laboratory samples range from less than 27 Pa to greater than 6400 Pa. These variations can challenge process planning for the application of a settle/decant process for DFHLW. This report describes the significance of the gaps to the settle/decant process and presents uncertainties by way of examples. Potential technical approaches for resolving these gaps are described and the estimated difficulty in resolving these gaps is evaluated. Based on the significance of the gap and the difficulty of resolution, recommendations are made to address specific gaps. Scoping estimates of the potential settling times for DFHLW solids have been made based on the existing data set with its associated gaps. Depending on the process vessel depth and final sediment concentration, substantial fractions of the scoping estimate results for settling times for characterized HLW exceed the 2-week period that has been previously assumed for process planning. There is also significant disparity, potentially greater than a factor of 5000 difference, in the estimated settling times depending on process vessel depth and final sediment solid concentration. This variation in results underscores the significance of the identified gaps and uncertainties with respect to process planning for utilizing settle/decant operations for DFHLW.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2012

Khazar Iodine Production Plant Site Remediation in Turkmenistan. NORM Contaminated Waste Repository Establishment - 12398

Radiation safety provisions for NORM contaminated areas are in use in a number of the former Soviet republics. Some of these areas were formed by absorbed radionuclides at the iodine and bromine extraction sites. As a rule, there are not any plant radiation monitoring systems nor appropriate services to ensure personnel, population and environmental radiation safety. The most hazardous sites are those which are situated in the Caspian Sea coastal zone. The bulk of the accumulated waste is represented by a loose mixture of sand and charcoal, which was basically used as the iodine extraction sorbent. The amounts of these wastes were estimated to be approximately 20,000 metric tons. The waste contamination is mainly composed of Ra-226 (U-238 decay series) and Ra-224, Ra-228 (Th-232 decay series). In 2009, the 'ECOMET-S', a Closed Joint-Stock Company from St. Petersburg, Russian Federation, was authorized by the Turkmenistan government to launch the rehabilitation project. The project includes D and D activities, contaminated areas remediation, collected wastes safe transportation to the repository and its disposal following repository closure. The work at the Khazar chemical plant started in September, 2010. Comprehensive radiological surveys to estimate the waste quantities were carried out in advance. In course of the rehabilitation work at the site of the Khazar chemical plant additional waste quantities (5,000 MT, 10,000 m{sup 3}) were discovered after the sludge was dumped and drained. Disposal volumes for this waste was not provided initially. The additional volume of the construction wastes was required in order to accommodate all the waste to be disposed. For the larger disposal volume the project design enterprise VNIPIET, offered to erect a second wall outside the existing one and this solution was adopted. As of May, 2011, 40,575 m{sup 3} of contaminated waste were collected and disposed safely. This volume represents 96.6% of the initial repository volume. Now work is underway to erect the second repository wall, which will allow housing of the additional 16,800 m{sup 3} The Khazar chemical plant territory restoration work is underway as well. (authors)

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DOE OSTI2024

Photooxidation of Polyolefins to Produce Materials with In-Chain Ketones and Improved Materials Properties

Herein, we report a selective photooxidation of commodity postconsumer polyolefins to produce polymers with in-chain ketones. The reaction does not involve the use of catalyst, metals, or expensive oxidants, and selectively introduces ketone functional groups. Under mild and operationally simple conditions, yields up to 1.23 mol % of in-chain ketones were achieved. Installation of in-chain ketones resulted in materials with improved adhesion of the materials and miscibility of mixed plastics relative to the unfunctionalized plastics. The introduction of ketone groups into the polymer backbone allows these materials to react with diamines, forming dynamic covalent polyolefin networks. This strategy allows for the upcycling of mixed plastic waste into reprocessable materials with enhanced performance properties compared to polyolefin blends. Mechanistic studies support the involvement of photoexcited nitroaromatics in consecutive hydrogen and oxygen atom transfer reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2012

Three novel PHEX gene mutations in four Chinese families with X-linked dominant hypophosphatemic rickets

Highlights: Black-Right-Pointing-Pointer In our study, all of the patients were of Han Chinese ethnicity, which were rarely reported. Black-Right-Pointing-Pointer We identified three novel PHEX gene mutations in four unrelated families with XLH. Black-Right-Pointing-Pointer We found that the relationship between the phenotype and genotype of the PHEX gene was not invariant. Black-Right-Pointing-Pointer We found that two PHEX gene sites, p.534 and p.731, were conserved. -- Abstract: Background: X-linked hypophosphatemia (XLH), the most common form of inherited rickets, is a dominant disorder that is characterized by renal phosphate wasting with hypophosphatemia, abnormal bone mineralization, short stature, and rachitic manifestations. The related gene with inactivating mutations associated with XLH has been identified as PHEX, which is a phosphate-regulating gene with homologies to endopeptidases on the X chromosome. In this study, a variety of PHEX mutations were identified in four Chinese families with XLH. Methods: We investigated four unrelated Chinese families who exhibited typical features of XLH by using PCR to analyze mutations that were then sequenced. The laboratory and radiological investigations were conducted simultaneously. Results: Three novel mutations were found in these four families: one frameshift mutation, c.2033dupT in exon 20, resulting in p.T679H; one nonsense mutation, c.1294A > T in exon 11, resulting in p.K432X; and one missense mutation, c.2192T > C in exon 22, resulting in p.F731S. Conclusions: We found that the PHEX gene mutations were responsible for XLH in these Chinese families. Our findings are useful for understanding the genetic basis of Chinese patients with XLH.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2016

Removal of TcO 4 - ions from solution: materials and future outlook

Technetium mainly forms during artificial nuclear fission; it exists primarily as TcO 4- in the nuclear waste, and is among the most hazardous radiation-derived contaminants because of its long half-life (t1/2 = 2.13 × 105 yrs) and environmental mobility. The high water solubility of TcO 4- (11.3 mol L -1 at 20°C) and its ability to readily migrate within the upper layer of Earth’s crust make it particularly hazardous. Several types of materials, namely resins, molecular complexes, layered double hydroxides, and pure inorganic and metal-organic materials, have been shown to be capable of capturing TcO 4- (or other oxoanions) from solution. In this review, we give a brief description about the types of materials that have been used to capture TcO 4- and closely related oxyanions so far and discuss the possibility of using metal-organic frameworks (MOFs) as next-generation ion-exchange materials for the stated application. In particular, with the advent of ultra-stable MOF materials, in conjunction with their chemical tunability, MOFs can be applied to capture these oxyanions under real-life conditions.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Evaluation of Gas Retention in Waste Simulants: Intermediate-Scale Column and Open-Channel-Depth Tests

Gas generation in Hanford’s radioactive waste storage tanks can lead to gas accumulation within the layer of settled solids (sludge) at the tank bottom. The gas, which may be hazardous and/or flammable, is formed principally by radiation-driven chemical reactions. Accumulation of these gases within the sludge increases the sludge-layer volume, which decreases the available tank volume for waste storage. Further, accumulation of large amounts of gas in the sludge can potentially result in a relatively rapid release of the accumulated gas if the sludge-layer density is reduced to less than that of the overlying sludge or that of the supernatant liquid. The potential for rapid release of large amounts of hazardous and/or flammable gases is a safety hazard that needs to be managed. Accordingly, a thorough understanding is needed of the circumstances that can lead to problematic gas accumulation in sludge layers. The Deep-Sludge Gas Release Event Project (DSGREP) is tasked with developing an improved understanding of these gas release events.

Gas retention↗
DOE OSTI2020

Reconfiguring Plant Metabolism for Biodegradable Plastic Production

For decades, plants have been the subject of genetic engineering to synthesize novel, value-added compounds. Polyhydroxyalkanoates (PHAs), a large class of biodegradable biopolymers naturally synthesized in eubacteria, are among the novel products that have been introduced to make use of plant acetyl-CoA metabolic pathways. It was hoped that renewable PHA production would help address environmental issues associated with the accumulation of nondegradable plastic wastes. However, after three decades of effort synthesizing PHAs, and in particular the simplest form polyhydroxybutyrate (PHB), and seeking to improve their production in plants, it has proven very difficult to reach a commercially profitable rate in a normally growing plant. This seems to be due to the growth defects associated with PHA production and accumulation in plant cells. Here, we review major breakthroughs that have been made in plant-based PHA synthesis using traditional genetic engineering approaches and discuss challenges that have been encountered. Then, from the point of view of plant synthetic biology, we provide perspectives on reprograming plant acetyl-CoA pathways for PHA production, with the goal of maximizing PHA yield while minimizing growth inhibition. Specifically, we suggest genetic elements that can be considered in genetic circuit design, approaches for nuclear genome and plastome modification, and the use of multiomics and mathematical modeling in understanding and restructuring plant metabolic pathways.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1965

Cork is used to make tooling patterns and molds

Sheet and waste cork are cemented together to provide a tooling pattern or mold. The cork form withstands moderately high temperatures under vacuum or pressure with minimum expansion, shrinkage, or distortion.

Hoffman, F. J.↗
NASA NTRS1972

Fuel cell powerplant operation in Apollo spacecraft.

Primary electrical power for loads in the Apollo Command and Service Modules is furnished by a system of three fuel cell powerplants. The powerplants convert cryogenic hydrogen and oxygen into direct current. Water formed in the fuel cell reactions is supplied to the spacecraft for crew use. Waste heat is rejected through a coolant loop to a spacecraft radiator. The ability of the fuel cell to meet its voltage-power requirements and to control its own operating temperature under the environmental extremes of launch, ascent, earth orbit, translunar flight, and lunar orbit was demonstrated on successively more difficult missions leading up to the first lunar landing.

Ching, A. C.↗
DOE OSTI2015

The future of RADCALC- the radioactive material and waste transportation software program - 15154

This paper provides a thorough review of RADCALC, the U.S. Department of Energy (DOE)-developed software tool to assist DOE sites in making radioactive material and waste packaging and transportation determinations in compliance with applicable Federal regulations and DOE Orders and Standards. There are more than 400 registered users of the RADCALC tool across the DOE complex. DOE has also authorized a limited number of users from certain universities and foreign countries. DOE periodically upgrades the software consistent with changing domestic and international requirements, as well as needs unique to DOE. Due to recent changes in regulatory requirements by the Department of Transportation (DOT), it is necessary that the current version of RADCALC should be updated in a timely manner. Prior to investing funds in software upgrades, DOE decided to evaluate the nature of changes required and level of operational support and looked for alternatives for meeting sites' operational needs. DOE formed a joint review team consisting of experts from Energy Facility Contractors Group (EFCOG) sites, commercial waste treatment facilities and the National Laboratories. This team evaluated the RADCALC software, commercially available software packages, and internal DOE site-developed programs against an established set of criteria. The team also reviewed and prioritized regulatory changes and user-recommended enhancements. Based on extensive review, the team recommended that DOE continue to support RADCALC noting that RADCALC is a cost-effective, technically robust tool that can perform complicated radioactive material shipping determinations. The tool promotes accuracy, consistency, and completeness between shipments by a single shipper, between shippers at a given site, and between sites. The isotopic coverage, decay algorithm and the range of calculations are without compare either within DOE or in industry in a tool of this kind. The team also recommended that DOE should actively promote RADCALC use throughout the DOE complex and consider cooperative arrangements with the Department of Defense or other government entities that may have similar needs. (authors)

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