High-Performance Nitrogen-Doped Intermetallic PtNi Catalyst for the Oxygen Reduction Reaction
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30 DIRECT ENERGY CONVERSION↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Recent advances in biomass pretreatment using biphasic solvent systems
The complexity and recalcitrance of lignocellulosic biomass seriously hinder its subsequent conversion to liquid fuels. To achieve high-value utilization of lignocellulosic biomass, the physical–chemical barrier should be overcome through appropriate pretreatment techniques to improve the accessibility of cellulose for efficient enzymatic hydrolysis. With the rapid emergence of novel pretreatment solvents, biphasic solvent pretreatments represent a nascent and green pretreatment method that has shown outstanding advantages and broad application prospects in the biorefinery of lignocellulosic substrates due to its ability to provide economically viable biomass upgrading, the separation process for products in the solvent phase, and the reutilization of solvents. Herein, different types of biphasic solvents (e.g., 2-methyltetrahydrofuran, methyl isobutyl ketone, 1-butanol, phenoxyethanol, ionic liquids, and deep eutectic solvents) were reviewed systematically, including the fundamental designs of biphasic solvents for biomass pretreatment, their effect on the fractionation of individual biomass components (e.g., carbohydrate and lignin) and the enzymatic hydrolysis performance, and the coproduction of furan and hydroxymethylfurfural. Finally, the main pros and cons of these different biphasic solvent systems are summarized, and the future development direction is also proposed. Finally, this review can provide a reference for designing and selecting effective biphasic pretreatment methods for various types of lignocellulosic biomass.
09 BIOMASS FUELS↗
Bioenergy Research Centers
Multiple societal benefits underlie U.S. Department of Energy (DOE) research efforts to support a viable and sustainable domestic biofuel and bioproducts industry from nonfood lignocellulosic plant biomass. These benefits include ensuring future energy security, lowering greenhouse gases to mitigate climate impacts, diversifying the range of available biobased products, producing fewer toxic chemicals and byproducts, creating jobs in rural areas, and improving the trade balance. Cellulose—the most abundant biological material on Earth—is contained within plant cell walls in the form of long, tightly bound chains of sugars (polysaccharides) that can be converted into biofuels and bioproducts by microbes. Physically accessing these sugars, however, is difficult because the cellulose is embedded within a matrix of other polymers including hemicellulose and lignin, making it resistant to degradation. This resistance, called recalcitrance, along with a lack of efficient methods to convert lignocellulose to useful products are major impediments to the cost-effective production of biofuels and bioproducts from plant biomass. Innovation stemming from advanced biotechnology-based research is key to accelerating needed improvements in the sustainable production of lignocellulosic biomass, its deconstruction into sugars and lignin, and conversion.
09 BIOMASS FUELS↗
Feedstock-Conversion Interface Consortium: Failure Mode and Effects Analysis Summary Report (FY2022)
This report provides an overview of the development of failure modes and effects analysis (FMEA) and its implementation as a systematic criticality and risk assessment tool supporting a quality by design (QbD) approach for FCIC research. This report also provides a high-level overview of the results for the FMEA evaluation of two feedstock preprocessing system configurations: (1) generation of pine residue materials for high-temperature pyrolysis conversion and (2) generation of corn stover materials for low-temperature conversion using deacetylation and disc mechanical refining pretreatment for fermentation to hydrocarbons. For the results presented in this report, our FMEA interviews included two approaches. The first approach was to perform FMEA interviews for the entire system of unit operations giving a wholistic system level view. The second approach consisted of detailed interviews for each individual unit operation within the system allowing for a “deep dive” into the specific failures for the individual components within the configuration. These two approaches provide different resolutions of information. The FMEA results of this report were focused on failures associated with meeting critical quality attributes (CQAs) identified for the target conversion processes for each processed feedstock type. The information gathered through the FMEA interviews include estimations of risk scores for meeting each given CQA specification, identification of the impacts for not meeting a CQA specification, capturing causes associated with material attributes and process parameters for each failure, identification of current detection methods, and speculation of potential mitigation strategies for decreasing a failure’s risk score. The complete results of all FMEA interviews are provided in the Appendices of this report.
09 BIOMASS FUELS↗
Biological Moleculars: Have Most of Our Problems Already Been Solved?
Evolution has resulted in biological machinery that engineers have great reason to envy and at present can only poorly mimic. This is not just a curiosity as biological systems perform many functions that are desired industrial processes. Examples include photosynthesis, chemosynthesis, energy storage, low temperature chemical conversion, reproducible manufacture of chemical compounds, etc. The bases of biological machinery are the proteins and nucleic acids that comprise living organisms. Each molecule functions as a part of a biological machine. In many cases the molecule can be properly regarded as a stand alone machine of its own. Concepts and methods for harnessing the power of biological molecules exist but are often overlooked in the industrial world. Some are old and appear crude but are quite effective, e.g. the fermentation of grains and fruits. Currently, there is a revolution in progress regarding the harnessing biological processes. These include techniques such as genetic manipulation via polymerase chain reaction, forced evolution also known as evolution in a test tube, determination of molecular structure, and combinatorial chemistry. The following is a brief discussion on how these processes are performed and how they may relate to industrial and aerospace processes.
Downey, James P.↗
Issues that Drive Waste Management Technology Development for Space Missions
Waste management technologies for space life support systems are currently at low development levels. Manual compaction of waste in plastic bags and overboard disposal to earth return vehicles are the primary current waste management methods. Particularly on future missions, continuance of current waste management methods would tend to expose the crew to waste hazards, forfeit recoverable resources such as water, consume valuable crew time, contaminate planetary surfaces, and risk return to Earth of extraterrestrial life. Improvement of waste management capabilities is needed for adequate management of wastes. Improvements include recovery of water and other resources, conversion of waste to states harmless to humans, long-term containment of wastes, and disposal of waste. Current NASA requirements documents on waste management are generally not highly detailed. More detailed requirements are needed to guide the development of waste management technologies that will adequately manage waste. In addition to satisfying requirements, waste management technologies must also recover resources. Recovery of resources such as water and habitat volume can reduce mission cost. This paper explores the drivers for waste management technology development including requirements and resource recovery.
Fisher, John W.↗
Fission Surface Power Technology Development Testing at NASA's Early Flight Fission Test Facility
Fission surface power (FSP) systems could be used to provide power anytime, anywhere on the surface of the Moon or Mars. FSP systems could be used at polar locations, at locations away from the poles, or in permanently shaded regions, with excellent performance at all sites. A potential reference 40 kWe option has been devised that is cost-competitive with alternatives while providing more power for less mass anywhere on the lunar surface. The reference FSP system (FSPS) is also readily extensible for use on Mars. At Mars the system would be capable of operating through global dust storms and providing year-round power at any Martian latitude. Under the NASA Exploration Technology Development Program (ETDP), NASA and the Department of Energy (DOE) have begun technology development on Fission Surface Power (FSP). The primary customer for this technology is the NASA Constellation Program which is responsible for the development of surface systems to support human exploration on the moon and Mars. The objectives of the FSP technology project are: 1) Develop FSP concepts that meet expected surface power requirements at reasonable cost with added benefits over other options. 2) Establish a hardware-based technical foundation for FSP design concepts and reduce overall development risk. 3) Reduce the cost uncertainties for FSP and establish greater credibility for flight system cost estimates. 4) Generate the key products to allow Agency decision-makers to consider FSP as a viable option for flight development. To be mass efficient, FSP systems must operate at higher coolant temperatures and use different types of power conversion than typical terrestrial systems. The primary reason is the difficulty in rejecting excess heat to space. Although many options exist, NASA s current reference FSP system uses a fast spectrum, pumped-NaK cooled reactor coupled to a Stirling power conversion subsystem. The reference system uses technology with significant terrestrial heritage while still providing excellent performance on the surface of the moon or Mars. Recent testing at NASA s Early Flight Fission Test Facility (EFF-TF) has helped assess the viability of the reference FSP system, and has helped evaluate methods for system integration. In June, 2009, a representative pumped NaK loop (provided by Marshall Space Flight Center) was coupled to a Stirling power converter (provided by Glenn Research Center) and tested at various conditions representative of those that would be seen during actual FSP system operation. In all areas, performance of the integrated system exceeded project goals. High-temperature NaK pump testing has also been performed at the EFF-TF, as has testing of methods for providing long-duration NaK purity.
Houts. Michael G.↗
CSP Optical Facilities at the National Renewable Energy Laboratory
The concentrating Solar Power (CSP) Optical Facilities at NREL comprise unique optical tools and facilities for testing and characterizing concentrating solar optical components. These facilities are maintained to aid researchers and industry efforts to reduce market barriers, improve the performance, reduce the cost, and improve the lifetime and reliability of CSP materials, components, subsystems, and integrated concepts, where accurate and timely characterization methods are needed. To reach this goal, NREL is committed to collaborating in ongoing and projected research needs for industry, academia, and government entities, in the development and characterization of low-cost, high-performance reflector and absorber materials in addition to their components-a key element in the conversion of concentrated sunlight into energy. To accomplish this mission, the core laboratory includes the Advanced Optical Materials Laboratory, indoor and outdoor accelerated weather testing tools, "Distant Observer" for parabolic troughs, the High Flux Solar Furnace, and the ultra-accelerated weather testing tools. This equipment enables to rapidly respond to new challenges with novel solutions that align with the goals of the Solar Energy Technology Office (SETO) at the U.S. Department of Energy. The goal of this paper is to present the state-of art-optical facilities available at NREL that can help support the research needs of the CSP community. Therefore, we review here the different components of the CSP Optical Facilities at NREL and highlight their characteristics and importance for the CSP community.
accelerated weather testing↗
Understanding Manufacturing Scale-Up of Plasma Sprayed Zr Barrier Coatings on U-10Mo Fuels
The United States government is committed to further strengthening nuclear security and nonproliferation in order to reduce the threat of terrorists acquiring nuclear material. To meet this important mission, the US Department of Energy/National Nuclear Security Agency's Office of Material Management and Minimization (M{sup 3}) Reactor Conversion Program minimizes the use of highly enriched uranium (HEU) in civilian applications by working with governments and facilities around the world to convert research reactors to the use of non-weapons-usable low-enriched uranium (LEU) fuels. Each reactor converted not only eliminates the need for HEU at civilian sites, but also reduces the amount of HEU being manufactured, stored, and transported, where it is at its most vulnerable. In instances where suitable LEU fuels do not exist for particular reactors to convert, the M{sup 3} Reactor Conversion Program (CONVERT) contributes to the development of new LEU fuels. Currently, the M{sup 3} Reactor Conversion Program is committed to developing a high-density U-Mo LEU fuel that will be able to convert high performance research reactors while establishing an efficient and economic fabrication capability to make the fuel. To that end, Los Alamos National Laboratory (LANL) has been tasked with developing a method to affix a Zirconium fuel diffusion barrier via plasma spraying that will prevent a reaction between the U-Mo fuel and the aluminum cladding. This report discusses the transitions from development of the plasma spray deposition process to a scientific understanding of pseudo-production conditions and quantification of coating layer properties, characterization, reproducibility, etc. Understanding quality assurance and its applications to experiment work is non-trivial; statistical analysis of various measurement techniques not only improve quality, but will allow for scale up of manufacturing.
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
Solvent‐free enzymatic esterification of free fatty acids with glycerol for biodiesel application: Optimized using the Taguchi experimental method
Abstract Presence of free fatty acids along with glycerides poses a technical difficulty for biodiesel production. This work used a Taguchi L9 design to optimize the solvent‐free enzymatic process to result in the esterification of oleic acid with glycerol. Under optimal conditions the esterification reaction temperature of 60°C, enzyme dose of 5 wt%, glycerol: oleic acid molar ratio of 5:1, and reaction time of 3 h, a 75.235 ± 2.19% conversion of oleic acid to esters was achieved. With the addition of molecular sieves, the conversion increased to 86.73% ± 1.09%. However, using the parameters predicted by Taguchi design (60°C, 5 wt%, 5:1, and 4.5 h), 88.5% ± 1.11% of oleic acid could be converted to esters derivative. Diglycerides were the major product, and the reaction equilibrium was attained after 4 h. The immobilized enzyme could be used up to seven times with only a 10% reduction in the conversion. Thus, the process can efficiently reduce the free fatty acid content of oil to make it suitable for biodiesel production.
09 BIOMASS FUELS↗
Conversion of CO 2 from power plant into CaCO 3 nanoparticles
Carbon dioxide (CO 2 ), a main composition of flue gas, represents a significant and largely untapped carbon resource. Herein, mediated by glycine (Gly), we captured and converted CO 2 into CaCO 3 nanoparticles using real flue gas from a power plant, demonstrating for the first time the feasibility of using amino acid to convert CO 2 from power plant flue gasses. The method did not require extraneous energy and CaCO 3 nanoparticles with a size of ∼25 nm were obtained. Moreover, the potential toxicity of CO 2 -converted nanoparticles was investigated. It appeared that both the initial CO 2 loading and the carbamate percentage significantly influence the shape and size of the CaCO 3 particles. Our method was also proven effective for flue gas with varying CO 2 concentrations (4 %, 12 %, and 20 %). By tuning flue gas bubbling time and flow rate to achieve consistent CO 2 loading and carbamate levels, we produced CaCO 3 nanoparticles with similar shapes and sizes across all CO 2 concentrations studied. In addition, our data indicated that although real flue gas contains small amounts of gases like oxygen and CO, they insignificantly influence the shape and size of our nanoparticles but did impact the phase component of CaCO 3 . In conclusion, the toxicity experiments found that CaCO 3 nanoparticles produced from both real flue gas and simulated flue gas exhibited concentration- and time-dependent effects on cell viability.
36 MATERIALS SCIENCE↗
Data for Solvent-Free Enzymatic Esterification of Free Fatty Acids with Glycerol for Biodiesel Application: Optimized Using the Taguchi Experimental Method
Presence of free fatty acids along with glycerides poses a technical difficulty for biodiesel production. This work used a Taguchi L9 design to optimize the solvent-free enzymatic process to result in the esterification of oleic acid with glycerol. Under optimal conditions the esterification reaction temperature of 60°C, enzyme dose of 5 wt%, glycerol: oleic acid molar ratio of 5:1, and reaction time of 3 h, a 75.235 ± 2.19% conversion of oleic acid to esters was achieved. With the addition of molecular sieves, the conversion increased to 86.73% ± 1.09%. However, using the parameters predicted by Taguchi design (60°C, 5 wt%, 5:1, and 4.5 h), 88.5% ± 1.11% of oleic acid could be converted to esters derivative. Diglycerides were the major product, and the reaction equilibrium was attained after 4 h. The immobilized enzyme could be used up to seven times with only a 10% reduction in the conversion. Thus, the process can efficiently reduce the free fatty acid content of oil to make it suitable for biodiesel production.
Conversion↗
A Database for Propagation Models and Conversion to C++ Programming Language
The telecommunications system design engineer generally needs the quantification of effects of the propagation medium (definition of the propagation channel) to design an optimal communications system. To obtain the definition of the channel, the systems engineer generally has a few choices. A search of the relevant publications such as the IEEE Transactions, CCIR's, NASA propagation handbook, etc., may be conducted to find the desired channel values. This method may need excessive amounts of time and effort on the systems engineer's part and there is a possibility that the search may not even yield the needed results. To help the researcher and the systems engineers, it was recommended by the conference participants of NASA Propagation Experimenters (NAPEX) XV (London, Ontario, Canada, June 28 and 29, 1991) that a software should be produced that would contain propagation models and the necessary prediction methods of most propagation phenomena. Moreover, the software should be flexible enough for the user to make slight changes to the models without expending a substantial effort in programming. In the past few years, a software was produced to fit these requirements as best as could be done. The software was distributed to all NAPEX participants for evaluation and use, the participant reactions, suggestions etc., were gathered and were used to improve the subsequent releases of the software. The existing database program is in the Microsoft Excel application software and works fine within the guidelines of that environment, however, recently there have been some questions about the robustness and survivability of the Excel software in the ever changing (hopefully improving) world of software packages.
Kantak, Anil V.↗
Getting to Neutral: Options for Negative Carbon Emissions in California
This report is an assessment of negative emissions pathways - ones that physically remove CO 2 from the atmosphere - that can help California achieve carbon neutrality by 2045, or sooner. It integrates original research findings with current published research on three main pillars of negative emissions: natural and working lands, carbon capture from biomass conversion to fuels, and direct air capture. The focus and scope of this report is unique: it only addresses practices and technologies for removing carbon dioxide from the air. It also encompasses the entire breadth of strategies, from land management to the latest technological options, and it evaluates the cost of every step of the solution, from waste biomass collection to carbon dioxide transport and geologic storage. The methods are intended to be transparent; details of the calculations and underlying data are included in the report body and appendices. This study intentionally avoids any discussion of policies and does not include current incentives; it provides a range of options, tradeoffs and costs that can be used to inform future policies. The key finding of this report is that carbon neutrality is achievable.
29 ENERGY PLANNING, POLICY, AND ECONOMY↗
Design Criteria for X-CRV Honeycomb Panels: A Preliminary Study
The objective of this project is to perform the first step in developing structural design criteria for composite sandwich panels that are to be used in the aeroshell of the crew return vehicle (X-CRV). The preliminary concept includes a simplified method for assessing the allowable strength in the laminate material. Ultimately, it is intended that the design criteria be extended to address the global response of the vehicle. This task will require execution of a test program as outlined in the recommendation section of this report. The aeroshell of the X-CRV is comprised of composite sandwich panels consisting of fiberite face sheets and a phenolic honeycomb core. The function of the crew return vehicle is to enable the safe return of injured or ill crewpersons from space station, the evacuation of crew in case of emergency or the return of crew if an orbiter is not available. A significant objective of the X-CRV project is to demonstrate that this vehicle can be designed, built and operated at lower cost and at a significantly faster development time. Development time can be reduced by driving out issues in both structural design and manufacturing concurrently. This means that structural design and analysis progresses in conjunction with manufacturing and testing. Preliminary tests results on laminate coupons are presented in the report. Based on these results a method for detection material failure in the material is presented. In the long term, extrapolation of coupon data to large scale structures may be inadequate. Test coupons used to develop failure criteria at the material scale are typically small when compared to the overall structure. Their inherent small size indicates that the material failure criteria can be used to predict localized failure of the structure, however, it can not be used to predict failure for all failure modes. Some failure modes occur only when the structure or one of its sub-components are studied as a whole. Conversely, localized failure may not indicate failure of the structure as a whole and the amount of reserve capacity, if any, should be assessed. To develop a complete design criteria experimental studies of the sandwich panel are needed. Only then can a conservative and accurate design criteria be developed. This criteria should include effects of flaws and defects, and environmental factors such as temperature and moisture. Preliminary results presented in this report suggest that a simplified analysis can be used to predict the strength of a laminate. Testing for environmental effects have yet to be included in this work. The so called 'rogue flaw test' appears to be a promising method for assessing the effect of a defect in a laminate. This method fits in quite well with the philosophy of achieving a damage tolerant design.
Caccese, Vincent↗
CO 2 Activation with Manganese Tricarbonyl Complexes through an H–Atom Responsive Benzimidazole Ligand
Herein, we report the synthesis and characterization of two manganese tricarbonyl complexes, Mn I (HL)(CO) 3 Br (1 a-Br) and Mn I (MeL)(CO) 3 Br (1 b-Br) (where HL=2-(2’-pyridyl)benzimidazole; MeL=1-methyl-2-(2’-pyridy)benzimidazole) and assayed their electrocatalytic properties for CO 2 reduction. A redox-active pyridine benzimidazole ancillary ligand in complex 1 a-Br displayed unique hydrogen atom transfer ability to facilitate electrocatalytic CO 2 conversion at a markedly lower reduction potential than that observed for 1 b-Br. Notably, a one-electron reduction of 1 a-Br yields a structurally characterized H-bonded binuclear Mn(I) adduct (2 a’) rather than the typically observed Mn(0)-Mn(0) dimer, suggesting a novel method for CO 2 activation. Furthermore, combining advanced electrochemical, spectroscopic, and single crystal X-ray diffraction techniques, we demonstrate the use of an H-atom responsive ligand may reveal an alternative, low-energy pathway for CO 2 activation by an earth-abundant metal complex catalyst.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Chapter 4 - Pretreatment Technologies for Lignocellulosic Biomass Refineries
Pretreatment is a critical step in processing lignocellulosic biomass into biofuel and bioproducts and is considered the energy and cost center of the biomass conversion process. Although a large number of pretreatment technologies have been developed, not all the techniques are viable on a commercial scale at this stage. Moreover, the technology choice and process conditions depend highly on the type of biomass and the overall biorefinery scheme. This chapter provides an overview of different pretreatment methods, including their mechanism, important process parameters, current status, and challenges. The opportunities associated with new technologies and approaches are presented. Emphasis is placed on low-severity thermal pretreatment technologies. The chapter also provides a brief discussion of the challenges to achieving the economic viability of the technologies on a commercial scale.
BIOMASS FUELS↗
Experimental data based combinatorial kinetic simulations for predictions of synergistic catalyst mixtures
Physical mixtures of catalysts can sometimes show synergistic activity which exceeds the sum of the activities of the same amount of catalysts employed separately. However, identifying such synergistic mixtures is non-trivial. Not all mixtures display synergy, and the number of combinations that are possible (even for binary mixtures of equal portions) scales very rapidly, and thus they would be costly to screen experimentally. In this work, we show that it is possible to predict synergistic mixtures using combinatorial kinetic simulations based on experimental data collected on individual catalysts. The data was first collected for conditions-of-interest under low conversions (also called near differential conditions, such that each condition approximates a small volume in a non-differential conditions reactor) to build a library of kinetic models (one model for each catalyst). This data was then used for combinatorial kinetic simulations of non-differential reactor scale conversions, and successfully predicted the qualitative behavior of two synergistic physical mixtures. The capability was utilized in the present work in the context of converting CO, C 3 H 6 , and NO species in simulated car exhaust, but is a general approach. We provide equations to estimate the costs of the screening method as well as the combinatorial kinetics method and show that the costs of identifying synergistic physical mixtures become much lower with the combinatorial kinetics method even before ten catalysts of interest. The cost of using prediction by the combinatorial kinetics method continue to become lower (relative to screening) when more catalysts are added -- and even more so if mixtures beyond two components, or consideration of multiple catalyst ratios, is of interest.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗