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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,711 records · Page 95
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Measured response of the equatorial thermospheric temperature to geomagnetic activity and solar flux changes

Fabry-Perot inteferometer determinations of thermospheric temperatures from 630.0-nm nightglow line-width measurements have been carried out for the period April-August 1983 from Arequipa, Peru (16.4-deg S, 71.5-deg W geographic; 4.4-deg S magnetic). The nightly variation of the thermospheric temperature T(n) measured on 62 nights is compared with MSIS model predictions and found to agree occasionally with the model but, on average, to exceed model predictions by about 180 K. The largest differences, 400-500 K, often occur during strongly increasing geomagnetic activity such as sudden commencements. The rapid increases in T(n) may result from energetic neutrals precipitating at low latitudes from the ring current or from energy carried to equatorial regions from high-latitude (auroral oval) heat sources by gravity waves and equatorward neutral winds.

Biondi, M. A.↗
NASA NTRS1986

Coupled stratospheric ozone and temperature responses to short-term changes in solar ultraviolet flux - An analysis of Nimbus 7 SBUV and SAMS data

Earlier studies of solar-induced variations in stratospheric parameters have been mainly concerned with observed ozone responses. In the present investigation, attention is given to temperature responses as well as ozone responses at low latitudes, taking into account 22 months of Nimbus 7 solar backscattered ultraviolet (SBUV) ozone and stratospheric and mesospheric sounder temperature data. A data description is provided, and cross-correlation and regression analyses are conducted. An extension is considered of an analytic model, which was derived by Frederick (1981) for the coupled behavior of ozone and temperature perturbations in the upper stratosphere and lower mesosphere. The extended model is applied to the results of the analyses. The obtained data provide statistical evidence for ozone and temperature responses to changes in solar ultraviolet flux on the time scale of the solar rotation period.

Hood, L. L.↗
DOE OSTI2019

Low temperature traps myosin motors of mammalian muscle in a refractory state that prevents activation

Myosin motors in the thick filament of resting striated (skeletal and cardiac) muscle are trapped in an OFF state, in which the motors are packed in helical tracks on the filament surface, inhibiting their interactions with actin and utilization of ATP. To investigate the structural changes induced in the thick filament of mammalian skeletal muscle by changes in temperature, we collected x-ray diffraction patterns from the fast skeletal muscle extensor digitorum longus of the mouse in the temperature range from near physiological (35°C) to 10°C, in which the maximal isometric force (T0) shows a threefold decrease. In resting muscle, x-ray reflections signaling the OFF state of the thick filament indicate that cooling produces a progressive disruption of the OFF state with motors moving away from the ordered helical tracks on the surface of the thick filament. We find that the number of myosin motors in the OFF state at 10°C is half of that at 35°C. At T0, changes in the x-ray signals that report the fraction and conformation of actin-attached motors can be explained if the threefold decrease in force associated with lowering temperature is due not only to a decrease in the force-generating transition in the actin-attached motors but also to a twofold decrease in the number of such motors. Thus, lowering the temperature reduces to the same extent the fraction of motors in the OFF state at rest and the fraction of motors attached to actin at T0, suggesting that motors that leave the OFF state accumulate in a disordered refractory state that makes them unavailable for interaction with actin upon stimulation. This regulatory effect of temperature on the thick filament of mammalian skeletal muscle could represent an energetically convenient mechanism for hibernating animals.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Random copolymer of poly(polyethylene glycol methyl ether)methacrylate as tunable transition temperature solid-solid phase change material for thermal energy storage

Polymer based phase change materials (PCM) for thermal energy storage (TES) applications have gained some attention recently due to their high stability and potential solid to solid phase transition. In this work, we are the first to utilize a simple copolymerization strategy for static tunability transition temperature (T t ) of polymeric PCM. The copolymerization between short and long side chain polyethylene glycol based methacrylate polymers was designed to tune T t with minimum impact on their energy density. Polarized optical microscope and x-ray techniques were also used to understand the relationship between crystal structure and T t of different copolymer composition which was discussed in the context. The solid to solid transition polymeric PCM were successfully developed with tunable T t ranged from 18 °C to 35 °C which is suitable toward building envelop applications.

14 SOLAR ENERGY↗
NASA NTRS2011

Atmospheric Composition Change: Climate-Chemistry Interactions

Chemically active climate compounds are either primary compounds such as methane (CH4), removed by oxidation in the atmosphere, or secondary compounds such as ozone (O3), sulfate and organic aerosols, formed and removed in the atmosphere. Man-induced climate-chemistry interaction is a two-way process: Emissions of pollutants change the atmospheric composition contributing to climate change through the aforementioned climate components, and climate change, through changes in temperature, dynamics, the hydrological cycle, atmospheric stability, and biosphere-atmosphere interactions, affects the atmospheric composition and oxidation processes in the troposphere. Here we present progress in our understanding of processes of importance for climate-chemistry interactions, and their contributions to changes in atmospheric composition and climate forcing. A key factor is the oxidation potential involving compounds such as O3 and the hydroxyl radical (OH). Reported studies represent both current and future changes. Reported results include new estimates of radiative forcing based on extensive model studies of chemically active climate compounds such as O3, and of particles inducing both direct and indirect effects. Through EU projects such as ACCENT, QUANTIFY, and the AEROCOM project, extensive studies on regional and sector-wise differences in the impact on atmospheric distribution are performed. Studies have shown that land-based emissions have a different effect on climate than ship and aircraft emissions, and different measures are needed to reduce the climate impact. Several areas where climate change can affect the tropospheric oxidation process and the chemical composition are identified. This can take place through enhanced stratospheric-tropospheric exchange of ozone, more frequent periods with stable conditions favouring pollution build up over industrial areas, enhanced temperature-induced biogenic emissions, methane releases from permafrost thawing, and enhanced concentration through reduced biospheric uptake. During the last 510 years, new observational data have been made available and used for model validation and the study of atmospheric processes. Although there are significant uncertainties in the modelling of composition changes, access to new observational data has improved modelling capability. Emission scenarios for the coming decades have a large uncertainty range, in particular with respect to regional trends, leading to a significant uncertainty range in estimated regional composition changes and climate impact.

Atmosphere climate chemistry↗
NASA NTRS2021

US Tropical Cyclone Activity in the 2030s Based on Projected Changes in Tropical Sea-Surface Temperature

We use a statistical tropical cyclone (TC) model, the North Atlantic Stochastic Hurricane Model (NASHM), in combination with sea-surface temperature (SST) projections from climate models, to estimate regional changes in US TC activity into the 2030s. NASHM is trained on historical variations in TC characteristics with two SST indices: global-tropical mean SST and the difference between tropical North-Atlantic (NA) SST and the rest of the global tropics, often referred to as “relative SST.” Testing confirms the model’s ability to reproduce historical US TC activity, as well as to make skillful predictions. When NASHM is driven by SST projections into the 2030s, overall NA annual TC counts increase, and the fractional increase is the greatest at the highest wind intensities. However, an eastward anomaly in mean TC tracks and an eastward shift in TC formation region result in a geographically-varied signal in US coastal activity. Florida’s Gulf coast is projected to see significant increases in TC activity, compared to the long-term historical mean, and these increases are fractionally greatest at the highest intensities. By contrast, the northwestern US Gulf and the US East Coast will see little change.

tropical cyclone (TC) model↗
DOE OSTI2017

Albedo feedbacks to future climate via climate change impacts on dryland biocrusts

Drylands represent the planet’s largest terrestrial biome and evidence suggests these landscapes have large potential for creating feedbacks to future climate. Recent studies also indicate that dryland ecosystems are responding markedly to climate change. Biological soil crusts (biocrusts) - soil surface communities of lichens, mosses, and/or cyanobacteria - comprise up to 70% of dryland cover and help govern fundamental ecosystem functions, including soil stabilization and carbon uptake. Drylands are expected to experience significant changes in temperature and precipitation regimes, and such alterations may impact biocrust communities by promoting rapid mortality of foundational species. In turn, biocrust community shifts affect land surface cover and roughness—changes that can dramatically alter albedo. We tested this hypothesis in a full-factorial warming (+4 °C above ambient) and altered precipitation (increased frequency of 1.2 mm monsoon-type watering events) experiment on the Colorado Plateau, USA. We quantified changes in shortwave albedo via multi-angle, solar-reflectance measurements. Warming and watering treatments each led to large increases in albedo (>30%). This increase was driven by biophysical factors related to treatment effects on cyanobacteria cover and soil surface roughness following treatment-induced moss and lichen mortality. A rise in dryland surface albedo may represent a previously unidentified feedback to future climate.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1998

Thermal Effects Modeling Developed for Smart Structures

Applying smart materials in aeropropulsion systems may improve the performance of aircraft engines through a variety of vibration, noise, and shape-control applications. To facilitate the experimental characterization of these smart structures, researchers have been focusing on developing analytical models to account for the coupled mechanical, electrical, and thermal response of these materials. One focus of current research efforts has been directed toward incorporating a comprehensive thermal analysis modeling capability. Typically, temperature affects the behavior of smart materials by three distinct mechanisms: Induction of thermal strains because of coefficient of thermal expansion mismatch 1. Pyroelectric effects on the piezoelectric elements; 2. Temperature-dependent changes in material properties; and 3. Previous analytical models only investigated the first two thermal effects mechanisms. However, since the material properties of piezoelectric materials generally vary greatly with temperature (see the graph), incorporating temperature-dependent material properties will significantly affect the structural deflections, sensory voltages, and stresses. Thus, the current analytical model captures thermal effects arising from all three mechanisms through thermopiezoelectric constitutive equations. These constitutive equations were incorporated into a layerwise laminate theory with the inherent capability to model both the active and sensory response of smart structures in thermal environments. Corresponding finite element equations were formulated and implemented for both the beam and plate elements to provide a comprehensive thermal effects modeling capability.

Lee, Ho-Jun↗
DOE OSTI2016

First-principles calculations of K-shell X-ray absorption spectra for warm dense nitrogen

X-ray absorption spectrum is a powerful tool for atomic structure detection on warm dense matter. Here, we perform first-principles molecular dynamics and X-ray absorption spectrum calculations on warm dense nitrogen along a Hugoniot curve. From the molecular dynamics trajectory, the detailed atomic structures are examined for each thermodynamical condition. The K-shell X-ray absorption spectrum is calculated, and its changes with temperature and pressure along the Hugoniot curve are discussed. The warm dense nitrogen systems may contain isolated nitrogen atoms, N{sub 2} molecules, and nitrogen clusters, which show quite different contributions to the total X-ray spectrum due to their different electron density of states. The changes of X-ray spectrum along the Hugoniot curve are caused by the different nitrogen structures induced by the temperature and the pressure. Some clear signatures on X-ray spectrum for different thermodynamical conditions are pointed out, which may provide useful data for future X-ray experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1984

Surface topographical changes measured by phase-locked interferometry

An electronic optical laser interferometer capable of resolving depth differences of as low as 30 A and planar displacements of 6000 A was constructed to examine surface profiles of bearing surfaces without physical contact. Topological chemical reactivity was determined by applying a drop of dilute alcoholic hydrochloric acid and measuring the profile of the solid surface before and after application of this probe. Scuffed bearing surfaces reacted much faster than virgin ones but that bearing surfaces exposed to lubricants containing an organic chloride reacted much more slowly. The reactivity of stainless steel plates, heated in a nitrogen atmosphere to different temperatures, were examined later at ambient temperature. The change of surface contour as a result of the probe reaction followed Arrhenius-type relation with respect to heat treatment temperature. The contact area of the plate of a ball/plate sliding elastohydrodynamic contact run on trimethylopropane triheptanoate with or without additives was optically profiled periodically. As scuffing was approached, the change of profile within the contact region changed much more rapidly by the acid probe and assumed a constant high value after scuffing. A nonetching metallurgical phase was found in the scuff mark, which was apparently responsible for the high reactivity.

Lauer, J. L.↗
DOE OSTI2021

Extraordinarily strong magneto-responsiveness in phase-separated LaFe 2 Si

Materials responding vigorously to minor variations of external stimuli with negligible hysteresis could revolutionize many of the energy technologies, including refrigeration, actuation, and sensing. Here, we report a combined experimental and theoretical study of a two-phase composite, naturally formed at the LaFe 2 Si stoichiometry, which exhibits a nearly anhysteretic, two-step first-order ferromagnetic-to-paramagnetic phase transformation with enhanced sensitivity to an external magnetic field. Other unusual properties include a large plateau-like positive magnetoresistance, magnetic-field-induced temperature and entropy changes occurring over a wide temperature range, and a Griffiths-like phase associated with short-range ferromagnetic clustering in the paramagnetic state. The heat capacity, magnetization, Mössbauer spectroscopy, and electrical resistivity, all exhibit characteristic, unusually sharp, first-order discontinuities even in magnetic fields as high as 100 kOe. We expect that similar phenomena could be designed in other mixed-phase systems, leading to novel functionalities, such as giant caloric effects in many yet undiscovered or/and underperforming intermetallic compounds.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Effect of Temperature and Hydrophilic Ratio on the Structure of Poly( N -vinylcaprolactam)- block -poly(dimethylsiloxane)- block -poly( N -vinylcaprolactam) Polymersomes

Nanosized polymeric vesicles (polymersomes) assembled from ABA triblock copolymers of poly(N-vinylcaprolactam)-poly(dimethylsiloxane)-poly(N-vinylcaprolactam) (PVCL–PDMS–PVCL) are a promising platform for biomedical applications, as the temperature-responsiveness of the PVCL blocks enables reversible vesicle shrinkage and permeability of the polymersome shell at elevated temperatures. Herein, we explore the effects of molecular weight, polymer block weight ratios, and temperature on the structure of these polymersomes via electron microscopy, dynamic light scattering, small angle neutron scattering (SANS), and all-atom molecular dynamics methods. We show that the shell structure and overall size of the polymersome can be tuned by varying the hydrophilic (PVCL) weight fraction of the polymer: at room temperature, polymers of smaller hydrophilic ratios form larger vesicles that have thinner shells, whereas polymers with higher PVCL content exhibit interchain aggregation of PVCL blocks within the polymersome shell above 50 °C. Model fitting and model-free analysis of the SANS data reveals that increasing the mass ratio of PVCL to the total copolymer weight from 0.3 to 0.56 reduces the temperature-induced change in vesicle diameter by a factor of 3, while simultaneously increasing the change in shell thickness by a factor of 1.5. Finally, by analysis of the shell structures and overall size of polymersomes with various PVCL weight ratios and those without temperature-dependent polymer components, we bring into focus the mechanism of temperature-triggered drug release reported in a previous study. This work provides new fundamental perspectives on temperature-responsive polymersomes and elucidates important structure–property relationships of their constituent polymers.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Emergence of Fermi arcs due to magnetic splitting in an antiferromagnet

The Fermi surface plays an important role in controlling the electronic, transport and thermodynamic properties of materials. As the Fermi surface consists of closed contours in the momentum space for well-defined energy bands, disconnected sections known as Fermi arcs can be signatures of unusual electronic states, such as a pseudogap. Another way to obtain Fermi arcs is to break either the time-reversal symmetry or the inversion symmetry of a three-dimensional Dirac semimetal, which results in formation of pairs of Weyl nodes that have opposite chirality, and their projections are connected by Fermi arcs at the bulk boundary. Here, we present experimental evidence that pairs of hole- and electron-like Fermi arcs emerge below the Neel temperature (TN) in the antiferromagnetic state of cubic NdBi due to a new magnetic splitting effect. The observed magnetic splitting is unusual, as it creates bands of opposing curvature, which change with temperature and follow the antiferromagnetic order parameter. This is different from previous theoretically considered and experimentally reported cases of magnetic splitting, such as traditional Zeeman and Rashba, in which the curvature of the bands is preserved. Therefore, our findings demonstrate a type of magnetic band splitting in the presence of a long-range antiferromagnetic order that is not readily explained by existing theoretical ideas.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Laser cooling of electron – ion plasma in the case of optimal scanning of the laser frequency

Laser cooling of ions of electron – ion plasma is studied under the action of spontaneous radiation pressure forces. It is shown that the use of a constant detuning of the laser frequency from the quantum transition frequency w0 in ions significantly limits the conditions under which the ions are cooled. To extend the range of initial temperatures of possible cooling of ions and to increase the cooling efficiency we suggest scanning the laser frequency detuning so that the cooling rate remained maximal in the process of changing the temperature of ions. In the case of an optimal detuning, we have found an asymptotic expression for the cooling rate and identified intervals of electron concentrations and temperatures, where cooling of ions is possible. (interaction of laser radiation with matter. laser plasma)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2019

Projected Changes in Daily Variability and Seasonal Cycle of Near-Surface Air Temperature over the Globe during the Twenty-First Century

Abstract Increases in atmospheric greenhouse gases will not only raise Earth’s temperature but may also change its variability and seasonal cycle. Here CMIP5 model data are analyzed to quantify these changes in surface air temperature (Tas) and investigate the underlying processes. The models capture well the mean Tas seasonal cycle and variability and their changes in reanalysis, which shows decreasing Tas seasonal amplitudes and variability over the Arctic and Southern Ocean from 1979 to 2017. Daily Tas variability and seasonal amplitude are projected to decrease in the twenty-first century at high latitudes (except for boreal summer when Tas variability increases) but increase at low latitudes. The day of the maximum or minimum Tas shows large delays over high-latitude oceans, while it changes little at low latitudes. These Tas changes at high latitudes are linked to the polar amplification of warming and sea ice loss, which cause larger warming in winter than summer due to extra heating from the ocean during the cold season. Reduced sea ice cover also decreases its ability to cause Tas variations, contributing to the decreased Tas variability at high latitudes. Over low–midlatitude oceans, larger increases in surface evaporation in winter than summer (due to strong winter winds, strengthened winter winds in the Southern Hemisphere, and increased winter surface humidity gradients over the Northern Hemisphere low latitudes), coupled with strong ocean mixing in winter, lead to smaller surface warming in winter than summer and thus increased seasonal amplitudes there. These changes result in narrower (wider) Tas distributions over the high (low) latitudes, which may have important implications for other related fields.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Integral Solution of Two-Region Solid–Liquid Phase Change in Annular Geometries and Application to Phase Change Materials–Air Heat Exchangers

A mathematical model based on the integral method is developed to solve the problem of conduction-controlled solid–liquid phase change in annular geometries with temperature gradients in both phases. The inner and outer boundaries of the annulus were subject to convective, constant temperature or adiabatic boundary conditions. The developed model was validated by comparison with control volume-based computational results using the temperature-transforming phase change model, and an excellent agreement was achieved. The model was used to conduct parametric studies on the effect of annuli geometry, thermophysical properties of the phase change materials (PCM), and thermal boundary conditions on the dynamics of phase change. For an initially liquid PCM, it was found that increasing the radii ratio increased the total solidification time. Also, increasing the Biot number at the cooled (heated) boundary and Stefan number of the solid (liquid) PCM, decreased (increased) the solidification time and resulted in a greater (smaller) solid volume fraction at steady state. The application of the developed method was demonstrated by design and analysis of a PCM–air heat exchanger for HVAC systems. The model can also be easily employed for design and optimization of annular PCM systems for all associated applications in a fraction of time needed for computational simulations.

Shabgard, Hamidreza↗
NASA NTRS1974

Control of skin blood flow, sweating, and heart rate - Role of skin vs. core temperature

A study was conducted to generate quantitative expressions for the influence of core temperature, skin temperature, and the rate of change of skin temperature on sweat rate, skin blood flow, and heart rate. A second goal of the study was to determine whether the use of esophageal temperature rather than the right atrial temperature as a measure of core temperature would lead to different conclusions about the control of measured effector variables.

Wyss, C. R.↗
NASA NTRS1981

Techniques for thermal sensitivity analysis

Techniques for computing the sensitivity of temperatures to changes in design variables needed for designing thermal protection systems are considered. It is shown that the choice of the most efficient technique depends on the ratio of number of temperature constraints to the number of design variables, as well as on the thermal analysis method employed. The analysis is specialized to the case of a structure modeled by finite elements, and an example of an insulation panel is used to demonstrate the techniques.

Haftka, R. T.↗