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Scaling study of magnetic phase transition and critical behavior in Nd0.55Sr0.45Mn0.98Ga0.02O3 manganite

Highlights: • The sample of Nd{sub 0.55}Sr{sub 0.45}Mn{sub 0.98}Ga{sub 0.02}O{sub 3} was synthesized via a solid state reaction route. • The PM to FM phase transition of this sample is found to be of second-order. • The critical behaviors and scaling relation for Nd{sub 0.55}Sr{sub 0.45}Mn{sub 0.98}Ga{sub 0.02}O{sub 3} have also been investigated by modified Arrott plot and critical isotherm analysis. • The estimated critical exponents are close to the values for 3D-Ising model. - Abstract: Microscopic magnetic interactions and magnetism can be probed by studying the critical paramagnetic–ferromagnetic phase transition of magnetic materials. In this work, the critical behavior of the lightly Ga-doped manganites Nd{sub 0.55}Sr{sub 0.45}Mn{sub 0.98}Ga{sub 0.02}O{sub 3} (NSMGO) has been investigated. Scaling analysis reveals the critical exponents β = 0.308, γ = 1.197, and δ = 4.916, where their self-consistency and reliability are verified by the Widom scaling law and the scaling equation. These exponents indicate that the magnetic phase transition in NSMGO belongs to the anisotropic 3D-Ising universality class. Nevertheless, the asymptotic critical exponents β{sub eff} and γ{sub eff} are found to approach to the values of 3D-Heisenberg model, implying the existence of isotropic short-range magnetic interactions. We suggest that, although the Nd-based manganites possess a strong magnetocrystalline anisotropy, this effect can be partly averaged out in view of the present polycrystalline NSMGO. Therefore, in the asymptotic critical region, the phase transition reveals the crossover from the scaling of 3D-Ising toward 3D-Heisenberg universality class.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Analysis and design of three dimensional supersonic nozzles. Volume 3: A design technique for multiple nozzle configurations

An iteration procedure for optimum nozzle design with application to hypersonic aircraft is discussed. In the procedure, intial values of several of the design parameters are assumed from simplified approximate considerations and are then varied systematically in order to determine the value of each parameter which optimizes nozzle performance. Improvements in nozzle performance are obtained by perturbing the initially assumed values of the geometric parameters on the basis of a computer analysis.

Ferri, A.↗

A study of dirigibles for use in the Peruvian Selva Central Region

The potential for dirigibles as transports in the Selva Central region of Peru was evaluated by means of a mission and economic analysis. A total requirement to transport over 19 million tons (t) of agricultural produce, lumber, and meat was projected by the year 2004. A primary route involving zones for loading and delivering this cargo was identified. Although dirigibles are capable of short field operation, all existing airfields must be enlarged in width to allow for all conditions of wind and weather and to provide space for overnight mooring. A maintenance base and operations headquarters, complete with hangar and other service facilities would be required. The quantities of cargo to be carried establish requirements for fleets of dirigibles of various sizes and capacities. Cargo capacities of 5 to 100 tons were identified. Fleet sizes up to 106 dirigibles (in 20 t capacities) would be required. Dirigibles were assumed to be of the nonrigid type except in the 100 t category for which rigid characteristics were assumed. A method of determining dirigible costs was developed. The values derived were then applied to an economic analysis to determine initial investment and operating costs. It was found that larger dirigibles of approximately 20 t capacities or higher could offer significant cost benefits over airplanes, provided cruise speeds were higher than 100 km/hr.

Mayer, N. J.↗

On-Chip Spyhole Nanoelectrospray Ionization Mass Spectrometry for Sensitive Biomarker Detection in Small Volumes

A polyimide microfluidic chip with a microhole emitter (Ø 10–12 μm) created on top of a microchannel by scanning laser ablation has been designed for nanoelectrospray ionization (spyhole-nanoESI) to couple microfluidics with mass spectrometry. The spyhole-nanoESI showed higher sensitivity compared to standard ESI and microESI from the end of the microchannel. The limits of detection (LOD) for peptide with the spyhole-nanoESI MS reached 50 pM, which was 600 times lower than that with standard ESI. The present microchip emitter allows the analysis of small volumes of samples. As an example, a small cell lung cancer biomarker, neuron-specific enolase (NSE), was detected by monitoring the transition of its unique peptide with the spyhole-nanoESI MS/MS. NSE at 0.2 nM could be well identified with a signal to noise ratio (S/N) of 50, and thereby its LOD was estimated to be 12 pM. The potential application of the spyhole-nanoESI MS/MS in cancer diagnosis was further demonstrated with the successful detection of 2 nM NSE from 1 μL of human serum. Before the detection, the serum sample spiked with NSE was first depleted with immune spin column, then desalted by centrifugal filter device, and finally digested by trypsin, without any other complicated preparation steps. The concentration matched the real condition of clinical samples. In addition, the microchips can be disposable to avoid any cross contamination. The present technique provides a highly efficient way to couple microfluidics with MS, which brings additional values to various microfluidics and MS-based analysis. .

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Health Physics Parameter Analysis for the Mars 2020 Launch

This report describes research into three health physics parameters used by Launch Safety (LS) for which the appropriate value, distribution, or applicability came into question during preparation of the Mars 2020 LS analysis. These parameters and associated issues include the Dose and Dose Rate Effectiveness Factor (DDREF) and its use in health effects calculations, a methodology for translating projected contamination per unit area into dose to aquatic and terrestrial biota, and plutonium transfer factors for use in ingestion pathway consequence analyses.

61 RADIATION PROTECTION AND DOSIMETRY↗

Summary of Expedited Results from Samples Supporting Tank Closure Cesium Removal (TCCR) Batch 3

Savannah River Remediation (SRR) is currently operating the Tank Closure Cesium Removal (TCCR) process to remove 137 Cs from tank waste supernate using an ion exchange process. As part of that process, Savannah River National Laboratory (SRNL) receives and analyzes samples in support of the qualification of each batch to be processed. SRNL recently received supernate samples retrieved from Tank 10H as well as in-tank batch contact samples for characterization in support of qualifying Batch 3 for processing through the TCCR unit. SRNL received and characterized a set of dip samples collected from Tank 10H (one surface and one variable depth sample). No solids were observed in either sample and therefore the samples were combined, and a suite of analyses were performed on the composite sample. The density of the combined sample was 1.174 g/mL (0.18 %RSD), which was consistent with the measured sodium concentration of 3.54 M (0.08 %RSD). The 137Cs activity in the sample was 4.75E+07 dpm/mL (4.28 %RSD) and the total Cs concentration was calculated to be 1.54 mg/L (1.16E-05 M). The in-tank batch contact samples consist of 0.1 g of crystalline silicotitanate (CST) contained within a teabag device. Duplicate samples were submerged in Tank 10H supernate for a period of about 13 days, after which time they were retrieved and transferred to SRNL for analysis. At SRNL the CST was rinsed to remove excess salt solution and the CST was then air dried before being digested for analysis. Results of the analysis indicated a 137 Cs loading of 3.66E+10 ± 1.40E+09 dpm/g or 16.5 ± 0.63 Ci/kg CST . This value represents a bounding upper limit as it includes the addition of two sigma uncertainty from replicate analysis of the individual teabag samples as well as the addition of the small amount of 137 Cs activity measured in the rinse solutions. The above values are based on the air-dried mass of CST. Correcting to the true dry mass using a F-factor of 0.8191 results in a maximum loading of 20.2 ± 0.77 Ci/kg CST .

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Analysis of Delamination Growth from Matrix Cracks in Laminates Subjected to Bending Loads

A major source of delamination damage in laminated composite materials is from low-velocity impact. In thin composite laminates under point loads, matrix cracks develop first in the plies, and delaminations then grow from these cracks at the ply interfaces. The purpose of this study was to quantify the combined effects of bending and transverse shear loads on delamination initiation from matrix cracks. Graphite-epoxy laminates with 90 deg. plies on the outside were used to provide a two-dimensional simulation of the damage due to low-velocity impact. Three plate bending problems were considered: a 4-point bending, 3-point bending, and an end-clamped center-loaded plate. Under bending, a matrix crack will form on the tension side of the laminate, through the outer 90 deg. plies and parallel to the fibers. Delaminations will then grow in the interface between the cracked 90 deg. ply and the next adjacent ply. Laminate plate theory was used to derive simple equations relating the total strain energy release rate, G, associated with the delamination growth from a 90 deg. ply crack to the applied bending load and laminate stiffness properties. Three different lay-ups were tested and results compared. Test results verified that the delamination always formed at the interface between the cracked 90 deg. ply and the next adjacent ply. Calculated values for total G sub c from the analysis showed good agreement for all configurations. The analysis was able to predict the delamination onset load for the cases considered. The result indicated that the opening mode component (Mode I) for delamination growth from a matrix crack may be much larger than the component due to interlaminar shear (Mode II).

Murri, G. B.↗

Analysis of delamination growth from matrix cracks in laminates subjected to bending loads

A major source of delamination damage in laminated composite materials is from low-velocity impact. In thin composite laminates under point loads, matrix cracks develop first in the plies, and delaminations then grow from these cracks at the ply interfaces. The purpose of this study was to quantify the combined effects of bending and transverse shear loads on delamination initiation from matrix cracks. Graphite-epoxy laminates with 90 deg plies on the outside were used to provide a two-dimensional simulation of the damage due to low-velocity impact. Three plate bending problems were considered: a 4-point bending, 3-point bending, and an end-clamped center-loaded plate. Under bending, a matrix crack will form on the tension side of the laminate, through the outer 90 deg plies and parallel to the fibers. Delaminations will then grow in the interface between the cracked 90 deg ply and the next adjacent ply. Laminate plate theory was used to derive simple equations relating the total strain energy release rate, G, associated with the delamination growth from a 90 deg ply crack to the applied bending load and laminate stiffness properties. Three different lay-ups were tested and results compared. Test results verified that the delamination always formed at the interface between the cracked 90 deg ply and the next adjacent ply. Calculated values for total G sub c from the analysis showed good agreement for all configurations. The analysis was able to predict the delamination onset load for the cases considered. The result indicated that the opening mode component (Mode I) for delamination growth from a matrix crack may be much larger than the component due to interlaminar shear (Mode II).

Murri, Gretchen Bostaph↗

Lifetimes of Vibro-Rotational Levels in Excited Electronic States of Diatomic Hydrogen Isotopologues

The current situation in studies of lifetimes of excited rovibronic levels for the H{sub 2}, D{sub 2}, T{sub 2}, HD, HT, and DT molecules is analyzed. All measured lifetime values (792 entries for 618 different vibro-rotational levels of 33 electronic states) reported in 61 publications before April 2015 are compiled and listed in tabular format together with an annotated bibliography. Experimental data are only available for the H{sub 2}, HD, and D{sub 2} molecules. The data collected in the present work show fragmentariness of experimental data. For the vast majority of the levels, the lifetime values were reported in one paper only and up to now are without independent experimental verification. A complete bibliography of publications concerning semiempirical determination and nonempirical calculations of the lifetimes is presented. Numerical results obtained in the framework of these two approaches are listed only in cases when experimental data are available. For more than half of the levels, the differences between measured and calculated values are three times higher than experimental errors. These discrepancies show necessity of more precise experimental and nonempirical studies. For some 79 rovibronic levels, our analysis makes it possible to propose certain set of recommended lifetime values.

74 ATOMIC AND MOLECULAR PHYSICS↗

Numerical Evaluation of Mode 1 Stress Intensity Factor as a Function of Material Orientation For BX-265 Foam Insulation Material

Foam; a cellular material, is found all around us. Bone and cork are examples of biological cell materials. Many forms of man-made foam have found practical applications as insulating materials. NASA uses the BX-265 foam insulation material on the external tank (ET) for the Space Shuttle. This is a type of Spray-on Foam Insulation (SOFI), similar to the material used to insulate attics in residential construction. This foam material is a good insulator and is very lightweight, making it suitable for space applications. Breakup of segments of this foam insulation on the shuttle ET impacting the shuttle thermal protection tiles during liftoff is believed to have caused the space shuttle Columbia failure during re-entry. NASA engineers are very interested in understanding the processes that govern the breakup/fracture of this complex material from the shuttle ET. The foam is anisotropic in nature and the required stress and fracture mechanics analysis must include the effects of the direction dependence on material properties. Material testing at NASA MSFC has indicated that the foam can be modeled as a transversely isotropic material. As a first step toward understanding the fracture mechanics of this material, we present a general theoretical and numerical framework for computing stress intensity factors (SIFs), under mixed-mode loading conditions, taking into account the material anisotropy. We present mode I SIFs for middle tension - M(T) - test specimens, using 3D finite element stress analysis (ANSYS) and FRANC3D fracture analysis software, developed by the Cornel1 Fracture Group. Mode I SIF values are presented for a range of foam material orientations. Also, NASA has recorded the failure load for various M(T) specimens. For a linear analysis, the mode I SIF will scale with the far-field load. This allows us to numerically estimate the mode I fracture toughness for this material. The results represent a quantitative basis for evaluating the strength and fracture properties of anisotropic foam insulation material.

Knudsen, Erik↗

Strain-energy-release rate analysis of the end-notched flexure specimen using the finite-element method

Two-dimensional finite-element analysis of the end-notched flexure specimen was performed using 8-node isoparametric, parabolic elements to evaluate compliance and mode II strain energy release rates, G sub II. The G sub II values were computed using two different techniques: the virtural crack-closure technique (VCCT) and the rate of change of compliance with crack length (compliance derivative method). The analysis was performed for various crack-length-to-semi-span (a/L) ratios ranging from 0.2 to 0.9. Three material systems representing a wide range of material properties were analyzed. The compliance and strain energy release rates of the specimen calculated with the present finite-element analysis agree very well with beam theory equations including transverse shear. The G sub II values calculated using the compliance derivative method compared extremely well with those calculated using the VCCT. The G sub II values obtained by the compliance derivative method using the top or bottom beam deflections agreed closely with each other. The strain energy release rates from a plane-stress analysis were higher than the plane-strain values by only a small percentage, indicating that either assumption may be used in the analysis. The G sub II values for one material system calculated from the finite-element analysis agreed with one solution in the literature and disagreed with the other solution in the literature.

Salpekar, S. A.↗

Strain energy release rate analysis of the end-notched flexure specimen using the finite-element method

Two-dimensional finite-element analysis of the end-notched flexure specimen was performed using 8-node isoparametric, parabolic elements to evaluate compliance and mode II strain energy release rates, G sub II. The G sub II values were computed using two different techniques: the virtual crack-closure technique (VCCT) and the rate of change of compliance with crack length (compliance derivative method). The analysis was performed for various crack-length-to-semi-span (a/L) ratios ranging from 0.2 to 0.9. Three material systems representing a wide range of material properties were analyzed. The compliance and strain energy release rates of the specimen calculated with the present finite-element analysis agree very well with beam theory equations including transverse shear. The G sub II values calculated using the compliance derivative method compared extremely well with those calculated using the VCCT. The G sub II values obtained by the compliance derivative method using the top or bottom beam deflections agreed closely with each other. The strain energy release rates from a plane-stress analysis were higher than the plane-strain values by only a small percentage, indicating that either assumption may be used in the analysis. The G sub II values for one material system calculated from the finte-element analysis agreed with one solution in the literature and disagreed with the other solution in the literature.

Salpekar, S. A.↗

Toxicokinetics of benzo[a]pyrene in humans: Extensive metabolism as determined by UPLC-accelerator mass spectrometry following oral micro-dosing

Benzo[a]pyrene (BaP), produces tumors of skin, lung, liver, kidney and stomach in animals, enhances lung cancer in epidemiological studies and is a known human carcinogen. The EPA cancer slope risk factor for oral BaP exposure is 1 per mg/kg-day. The remarkable sensitivity (attomole 14C; precision 0.5-2% in biological samples) of accelerator mass spectrometry (AMS) makes possible [14C]-BaP dosing of humans with de minimus risk. A micro-dose of 46 ng (5 nCi), was given in 3 separate cycles to 5 human volunteers with a minimum 2 weeks between dosing. Blood was collected over 72 hours and BaP and BaP metabolites ([14C]-BaPeq) measured using AMS. [14C]-BaPeq appeared in plasma with an average Tmax of 75 minutes and Cmax 116-326 fM (29-82 fg/mL). Non-compartmental half-lives in plasma ranged from 30.7-114.2 hours and area under the curve values (AUC0-72 hr) 649-2060 fg x hr x mL-1. A two compartmental model yielded first-order rate constants (Ka, K12, K21, Kela and Kelß) of 0.92, 0.49, 0.12, 0.05 and 0.01 fg/hr, respectively. The T1/2a and T1/2ß were 1.14 and 89 hours, respectively. The actual interval between dosing was 20-420 days with no impact on a low intra-individual variation. No covalent [14C]-BaPeq-DNA adducts from peripheral blood mononuclear cells (PBMCs) were detected (LLOD of 10 fg [14C]-BaPeq adducts/mg DNA) 12-72 hours post-dosing negating the use of this cancer biomarker in risk assessment. We assert that the most relevant model for humans is humans. AMS and micro-dosing could be used to enhance the accuracy of pharmacokinetics and potentially risk assessments.

pharmacokinetcs, Polycyclic aromatic hydrocarbons↗

α-Particle Detection and Charge Transport Characteristics in the A 3 M 2 I 9 Defect Perovskites (A = Cs, Rb; M = Bi, Sb)

Here, we have investigated the defect perovskites A 3 M 2 I 9 (A = Cs, Rb; M = Bi, Sb) as materials for radiation detection. The phase purity of Bridgman-grown A 3 M 2 I 9 single crystals was confirmed via high-resolution synchrotron X-ray diffraction, while density functional theory calculations (DFT) show surprisingly dispersive bands in the out-of-plane direction for these layered materials, with low effective masses for both holes and electrons. Accordingly, each of the four A 3 M 2 I 9 defect perovskites showed response to 241 Am α-particle irradiation for hole and electron electrode configurations, a remarkable ambipolar response that resembles the 3D halide perovskites. The electron response spectra were used to estimate the mobility–lifetime product (μτ) e for electrons in these materials, with Rb 3 Bi 2 I 9 showing the lowest (μτ) e value of 1.7 × 10 – 6 cm 2 V –1 and Cs 3 Bi 2 I 9 the highest (μτ) e of 5.4 × 10 –5 cm 2 V –1 . The rise time of the α-particle-generated pulse was used to estimate the electron mobility μ e of the A 3 M 2 I 9 defect perovskites, which ranged from 0.32 cm 2 V –1 s–1 for Rb 3 Sb 2 I 9 to 4.3 cm 2 V –1 s –1 in Cs 3 Bi 2 I 9 . Similar analysis of the hole response spectra yielded (μτ) h values for each A 3 M 2 I 9 compound, with Cs 3 Bi 2 I 9 again showing the highest (μτ) h value of 1.8 × 10 –5 cm 2 V –1 , while Rb 3 Bi 2 I 9 showed the lowest (μτ) h with 2.0 × 10 –6 cm 2 V –1 . Rise time analysis gave hole mobilities ranging from 1.7 cm 2 V –1 s –1 for Cs 3 Bi 2 I 9 to 0.14 cm 2 V –1 s –1 for Cs 3 Sb 2 I 9 . Comparing the experimental electron and hole mobilities to the effective masses obtained from DFT calculations revealed sizable discrepancies, possibly indicating self-trapping of charge carriers due to electron–phonon interactions. The α-particle response of the A 3 M 2 I 9 defect perovskites demonstrates their potential as semiconductor radiation detectors, with Cs 3 Bi 2 I 9 and Cs 3 Sb 2 I 9 showing the most promise.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The tip of the red giant branch distances to type IA supernova host galaxies. III. NGC 4038/39 AND NGC 5584

We present the tip of the red giant branch (TRGB) distances to Type Ia supernova (SNe Ia) host galaxies NGC 4038/39 and NGC 5584. Based on the deep images constructed using archival Hubble Space Telescope data, we detect red giant branch stars in each galaxy. VI photometry of the resolved stars and corresponding I-band luminosity functions show the TRGB to be at I{sub TRGB}=27.67±0.05 for NGC 4038/39 and I{sub TRGB}=27.77±0.04 for NGC 5584. From these estimates, we determine the distance modulus to NGC 4038/39 to be (m−M){sub 0}=31.67±0.05 (random) ± 0.12 (systematic) (corresponding to a linear distance of 21.58±0.50±1.19 Mpc) and the distance modulus to NGC 5584 to be (m−M){sub 0}=31.76±0.04 (random) ± 0.12 (systematic) (corresponding to a linear distance of 22.49±0.41±1.24 Mpc). We derive a mean absolute maximum magnitude of SNe Ia of M{sub V}=−19.27±0.08 from the distance estimates of five SNe Ia (including two SNe in this study and three SNe Ia from our previous studies), and we derive a value of M{sub V}=−19.19±0.10 using three low-reddened SNe Ia among the five SNe Ia. With these estimates, we derive a value of the Hubble constant, H{sub 0}=69.8±2.6 (random) ± 3.9 (systematic) km s{sup −1} Mpc{sup −1} and 72.2 ± 3.3 (random) ± 4.0(systematic) km s{sup −1} Mpc{sup −1}, respectively. The value from the five SNe is similar to those from the cosmic microwave background analysis, and not much different within errors, from those of recent Cepheid calibrations of SNe Ia. The value from the three SNe is between the values from the two methods.

79 ASTRONOMY AND ASTROPHYSICS↗

Cosmology constraints from shear peak statistics in Dark Energy Survey Science Verification data

Shear peak statistics has gained a lot of attention recently as a practical alternative to the two point statistics for constraining cosmological parameters. We perform a shear peak statistics analysis of the Dark Energy Survey (DES) Science Verification (SV) data, using weak gravitational lensing measurements from a 139 deg$^2$ field. We measure the abundance of peaks identified in aperture mass maps, as a function of their signal-to-noise ratio, in the signal-to-noise range $0<\mathcal S / \mathcal N<4$. To predict the peak counts as a function of cosmological parameters we use a suite of $N$-body simulations spanning 158 models with varying $\Omega_{\rm m}$ and $\sigma_8$, fixing $w = -1$, $\Omega_{\rm b} = 0.04$, $h = 0.7$ and $n_s=1$, to which we have applied the DES SV mask and redshift distribution. In our fiducial analysis we measure $\sigma_{8}(\Omega_{\rm m}/0.3)^{0.6}=0.77 \pm 0.07$, after marginalising over the shear multiplicative bias and the error on the mean redshift of the galaxy sample. We introduce models of intrinsic alignments, blending, and source contamination by cluster members. These models indicate that peaks with $\mathcal S / \mathcal N>4$ would require significant corrections, which is why we do not include them in our analysis. We compare our results to the cosmological constraints from the two point analysis on the SV field and find them to be in good agreement in both the central value and its uncertainty. As a result, we discuss prospects for future peak statistics analysis with upcoming DES data.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Variations of characteristic time scales in rotating stratified turbulence using a large parametric numerical study

In this work, we study rotating stratified turbulence (RST) making use of numerical data stemming from a large parametric study varying the Reynolds, Froude and Rossby numbers, Re, Fr and Ro in a broad range of values. The computations are performed using periodic boundary conditions on grids of 10243 points, with no modeling of the small scales, no forcing and with large-scale random initial conditions for the velocity field only, and there are altogether 65 runs analyzed in this paper. The buoyancy Reynolds number defined as R B = ReFr 2 varies from negligible values to ≈ 105, approaching atmospheric or oceanic regimes. This preliminary analysis deals with the variation of characteristic time scales of RST with dimensionless parameters, focusing on the role played by the partition of energy between the kinetic and potential modes, as a key ingredient for modeling the dynamics of such flows. We find that neither rotation nor the ratio of the Brunt-Väisälä frequency to the inertial frequency seem to play a major role in the absence of forcing in the global dynamics of the small-scale kinetic and potential modes. Specifically, in these computations, mostly in regimes of wave turbulence, characteristic times based on the ratio of energy to dissipation of the velocity and temperature fluctuations, T V and T P , vary substantially with parameters. Their ratio γ=T V /T P follows roughly a bell-shaped curve in terms of Richardson number Ri. It reaches a plateau --on which time scales become comparable, γ≈0.6 -- when the turbulence has significantly strengthened, leading to numerous destabilization events together with a tendency towards an isotropization of the flow.

97 MATHEMATICS AND COMPUTING↗