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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,729 records · Page 96

Process modifications for improved carbon fiber composites: Alleviation of the electrical hazards problem

Attempts to alleviate carbon-fiber-composite electrical hazards during airplane crash fires through fiber gasification are described. Thermogravimetric and differential scanning calorimetric experiments found several catalysts that caused fibers to combust when composites were exposed to test fires. Composites were tested in the 'Burn-Bang' apparatus and in high voltage electrical detection grid apparatus. In a standard three minute burn test modified composites released no fibers, while state-of-the-art composites released several hundred fiber fragments. Expected service life with and without catalytic modification was studied and electron microscopy and X-ray microanalysis furnished physical appearance and chemical composition data. An acrylic acid polymer fiber coating was developed that wet the carbon fiber surface uniformly with the catalyst, providing a marked contrast with the uneven coats obtained by solution-dipping.

Ramohalli, K.↗

Infrared Imagery of Shuttle (IRIS). Task 1, summary report

The feasibility of remote, high-resolution infrared imagery of the Shuttle Orbiter lower surface during entry to obtain accurate measurements of aerodynamic heat transfer was demonstrated. Using available technology, such images can be taken from an existing aircraft/telescope system (the C141 AIRO) with minimum modification or addition of systems. Images with a spatial resolution of 1 m or better and a temperature resolution of 2.5% between temperatures of 800 and 1900 K can be obtained. Data reconstruction techniques can provide a geometrically and radiometrically corrected array on addressable magnetic tape ready for display by NASA.

Chocol, C. J.↗

Design of a natural laminar flow wing for a transonic corporate transport

Two- and three-dimensional computational methods were used to design a wing for a transonic corporate transport that had significant runs of laminar flow on both upper and lower wing surfaces at the cruise condition. The airfoil was derived from a low-speed laminar-flow section. The contour was systematically modified based on results from a two-dimensional transonic code to give favorable pressure gradients to 50-percent chord on the upper surface and 65-percent chord on the lower surface. Three-dimensional transonic codes were used to determine the wing twist and to evaluate the aerodynamic characteristics of the complete configuration at various flight conditions. A leading-edge modification for improved stall characteristics was also designed. The theoretical pressure distributions for the final airfoil correlated well with results from wind-tunnel tests.

Campbell, R. L.↗

Vortex ring bubbles

Toroidal bubbles with circulation are studied numerically and by means of a physically motivated model equation. Two series of computations are performed by a boundary-integral method. One set shows the starting motion of an initially spherical bubble as a gravitationally driven liquid jet penetrates through the bubble from below causing a toroidal geometry to develop. The jet becomes broader as surface tension increases and fails to penetrate if surface tension is too large. The dimensionless circulation that develops is not very dependent on the surface tension. The second series of computations starts from a toroidal geometry, with circulation determined from the earlier series, and follows the motion of the rising and spreading vortex ring. Some modifications to the boundary-integral formulation were devised to handle the multiply connected geometry. The computations uncovered some unexpected rapid oscillations of the ring radius. These oscillations and the spreading of the ring are explained by the model equation which provides a more general description of vortex ring bubbles than previously available.

Lundgren, T. S.↗

A user guide for the EMTAC-MZ CFD code

The computer code (EMTAC-MZ) was applied to investigate the flow field over a variety of very complex three-dimensional (3-D) configurations across the Mach number range (subsonic, transonic, supersonic, and hypersonic flow). In the code, a finite volume, multizone implementation of high accuracy, total variation diminishing (TVD) formulation (based on Roe's scheme) is used to solve the unsteady Euler equations. In the supersonic regions of the flow, an infinitely large time step and a space-marching scheme is employed. A finite time step and a relaxation or 3-D approximate factorization method is used in subsonic flow regions. The multizone technique allows very complicated configurations to be modeled without geometry modifications, and can easily handle combined internal and external flow problems. An elliptic grid generation package is built into the EMTAC-MZ code. To generate the computational grid, only the surface geometry data are required. Results obtained for a variety of configurations, such as fighter-like configurations (F-14, AVSTOL), flow through inlet, multi-bodies (shuttle with external tank and SRBs), are reported and shown to be in good agreement with available experimental data.

Szema, Kuo-Yen↗

The elimination of dead center in the controls of airplanes with thick sections

In several instances where control flaps are placed in the trailing edges of thick sections, it has appeared that a dead center (slackness or lack of control) exists about the neutral position. The condition was also experienced in the rudder action of the XB1A observation airplane. Examination of smoke pictures of the airflow around struts and airfoils indicates what may be the cause of the phenomenon. The streamwise airflow about the thick fin does not follow the surface of the rudder, and consequently the rudder can be moved between the boundaries of the intervening turbulent zone without developing an aerodynamic force. In order to alleviate this condition, a modification was designed and built for the XB1A. The modified rudder was intended to remedy the condition by thickening the section sufficiently to fill in the zone of turbulent flow and thus eliminate the dead center. The positive results of flight tests are given.

Carroll, Thomas↗

Unsteady panel method for flows with multiple bodies moving along various paths

A potential flow based three-dimensional panel method was modified to treat time-dependent conditions in which several submerged bodies can move within the fluid along different trajectories. This modification was accomplished by formulating the momentary solution in an inertial frame of reference, attached to the undisturbed stationary fluid. Consequently, the numerical interpretation of the multiple-body, solid-surface boundary condition and the viscous wake rollup was considerably simplified. The usteady capability of this code was calibrated and validated by comparing computed results with closed-form analytical results available for an airfoil, which was impulsively set into a constant speed forward motion. To demonstrate the multicomponent capability, computations were made for two wings following closely intersecting paths (i.e., simulations aimed at avoiding mid-air collisions) and for a flowfield with relative rotation (i.e., the case of a helicopter rotor rotating relative to the fuselage). Computed results for the cases were compared to experimental data, when such data was available.

Richardson, Thomas F.↗

Mach Number Effects on Turbine Blade Transition Length Prediction

The effect of a Mach number correction on a model for predicting the length of transition was investigated. The transition length decreases as the turbulent spot production rate increases. Much of the data for predicting the spot production rate comes from low speed flow experiments. Recent data and analysis showed that the spot production rate is affected by Mach number. The degree of agreement between analysis and data for turbine blade heat transfer without film cooling is strongly dependent of accurately predicting the length of transition. Consequently, turbine blade heat transfer data sets were used to validate a transition length turbulence model. A method for modifying models for the length of transition to account for Mach number effects is presented. The modification was made to two transition length models. The modified models were incorporated into the two-dimensional Navier-Stokes code, RVCQ3D. Comparisons were made between predicted and measured midspan surface heat transfer for stator and rotor turbine blades. The results showed that accounting for Mach number effects significantly improved the agreement with the experimental data.

Boyle, R. J.↗

CAPRI (Computational Analysis PRogramming Interface): A Solid Modeling Based Infra-Structure for Engineering Analysis and Design Simulations

CAPRI is a CAD-vendor neutral application programming interface designed for the construction of analysis and design systems. By allowing access to the geometry from within all modules (grid generators, solvers and post-processors) such tasks as meshing on the actual surfaces, node enrichment by solvers and defining which mesh faces are boundaries (for the solver and visualization system) become simpler. The overall reliance on file 'standards' is minimized. This 'Geometry Centric' approach makes multi-physics (multi-disciplinary) analysis codes much easier to build. By using the shared (coupled) surface as the foundation, CAPRI provides a single call to interpolate grid-node based data from the surface discretization in one volume to another. Finally, design systems are possible where the results can be brought back into the CAD system (and therefore manufactured) because all geometry construction and modification are performed using the CAD system's geometry kernel.

Haimes, Robert↗

MIR Measurements of Atmospheric Water Vapor Profiles

Three subjects related to atmospheric water vapor profiling using the 183.3 GHz absorption line are discussed in this paper. First, data acquired by an airborne millimeter-wave imaging radiometer (MIR) over ocean surface in the western Pacific are used to estimate three-dimensional (3-D) distribution of atmospheric water vapor. The instrument's radiometric measurements with mixed vertical and horizontal polarizations require modifications to the retrieval algorithm used in the past. It is demonstrated that, after the modifications, the new algorithm can provide adequate retrieval of water vapor profiles, even though the measured data are of mixed polarizations. Next, the retrieved profiles, in terms of water vapor mixing ratio rho (g/kg), are compared with those measured in near concurrence by dropsondes from a research aircraft in the western Pacific and by a ground-based Raman lidar at Wallops Island, Virginia. The ratio of the standard deviation to the mean rho is found to be 0.12 at 0.25 km altitude and gradually degraded to 0.67 at the highest altitude of the retrieval of 10.25 km. Finally, the effect of the "initial guess" relative humidity profile on the final retrieved product is analyzed with respect to the condition for the convergent retrieval. It is found that the effect is minimal if the initial profile is not unrealistically different from the true one. If the initial profile is very different from the true one, the final retrieved product could be subject to a substantial error. Tightening of the convergent condition in the retrieval helped reduce magnitude of the error, but not remove it totally. It is concluded that an initial profile based on climatology is likely to provide most reliable retrieval results.

Wang, J. R.↗

Turbulence Modeling for the Simulation of Transition in Wall Shear Flows

Our research involves study of the behavior of k-epsilon turbulence models for simulation of bypass-level transition over flat surfaces and turbine blades. One facet of the research has been to assess the performance of a multitude of k-epsilon models in what we call "natural transition", i.e. no modifications to the k-e models. The study has been to ascertain what features in the dynamics of the model affect the start and end of the transition. Some of the findings are in keeping with those reported by others (e.g. ERCOFTAC). A second facet of the research has been to develop and benchmark a new multi-time scale k-epsilon model (MTS) for use in simulating bypass-level transition. This model has certain features of the published MTS models by Hanjalic, Launder, and Schiestel, and by Kim and his coworkers. The major new feature of our MTS model is that it can be used to compute wall shear flows as a low-turbulence Reynolds number type of model, i.e. there is no required partition with patching a one-equation k model in the near-wall region to a two-equation k-epsilon model in the outer part of the flow. Our MTS model has been studied extensively to understand its dynamics in predicting the onset of transition and the end-stage of the transition. Results to date indicate that it far superior to the standard unmodified k-epsilon models. The effects of protracted pressure gradients on the model behavior are currently being investigated.

Crawford, Michael E.↗

Thermal Performance of Spandrel Assemblies in Glazed Wall Systems: Laboratory Test Design – Challenges and Test Results

Accurate thermal performance calculation procedures for opaque spandrel areas in curtain wall and window wall systems are essential for rating systems when comparing spandrel systems. However, there is a lack of consensus in thermal modeling needed for accurately characterizing heat transfer through spandrel assemblies due to the complex arrangement of materials and structural components. Several studies indicate that conventional 2D thermal simulations may overestimate R-values by 30% compared to physical testing and 3D simulations. Detailed simulations and well-curated laboratory test data are necessary to build confidence in simulation models, which will later be used to develop correlations to improve widely used conventional 2D thermal simulations. This study aims to experimentally test heat transfer through various spandrel assemblies to validate 3D simulation models. Also, the challenges of conducting a thorough testing design along with the solutions would be documented. The team developed a design for testing spandrel assemblies, making appropriate modifications to the existing heat, air, and moisture (HAM) chamber to accommodate the testing needs. Two moveable baffles were designed and fabricated to guide airflow direction parallel to the test article surface. The data acquisition capabilities in the chamber were upgraded to add more than two hundred sensors to the climate and indoor side of the chamber. The goal is to provide a quality dataset for validating complex 3D modeling simulations, which will be used to develop improved thermal simulation techniques that more accurately represent the thermal behavior of spandrel assemblies and their integration within the building envelope. This paper will summarize the results for the boundary conditions of the testing and the temperature variation across different locations of the spandrel assemblies.

Kunwar, Niraj [ORNL] (ORCID:0000000263457652)↗

Modeling of Turbulent Boundary Layer Surface Pressure Fluctuation Auto and Cross Spectra - Verification and Adjustments Based on TU-144LL Data

The literature on turbulent boundary layer pressure fluctuations provides several empirical models which were compared to the measured TU-144 data. The Efimtsov model showed the best agreement. Adjustments were made to improve its agreement further, consisting of the addition of a broad band peak in the mid frequencies, and a minor modification to the high frequency rolloff. The adjusted Efimtsov predicted and measured results are compared for both subsonic and supersonic flight conditions. Measurements in the forward and middle portions of the fuselage have better agreement with the model than those from the aft portion. For High Speed Civil Transport supersonic cruise, interior levels predicted by use of this model are expected to increase by 1-3 dB due to the adjustments to the Efimtsov model. The space-time cross-correlations and cross-spectra of the fluctuating surface pressure were also investigated. This analysis is an important ingredient in structural acoustic models of aircraft interior noise. Once again the measured data were compared to the predicted levels from the Efimtsov model.

Rackl, Robert↗

Deterioration and modification of the biosphere leading to irreversible climatic change of the global ecosystem

The level, intensity, nature and impact of man's activities upon weather and climatic changes are explored. It is shown that industrialization leads to increased CO2 levels, atmospheric dust content and land surfaces changes. This in turn causes global climatic interactions which results in a general cooling trend. Global cooperation is advocated to stem environmental degradation and weather pattern interruption by the use of corrective mechanisms.

Source record↗

Enhanced performance and stability of electrochromic device based on poly (3-methylthiophene) using 2-thiophenecarboxylic acid as interfacial modifier

Highlights: • The PMeT film covalently bonded to ITO electrode was prepared using ThCA as modifier. • The adsorption force between the PMeT film and ITO electrode was enhanced. • The ECD based on PMeT-ITO exhibited better electrochromic stability. - Abstract: In this paper, we modified the surface of Indium tin oxide (ITO) electrode with 2-thiophenecarboxylic acid (ThCA), and then prepared the poly (3-methylthiophene) (PMeT) film covalently bonded to ITO electrode (PMeT-ITO) by electrochemical polymerization. It was found that interfacial modification enhanced the adsorption force between PMeT and ITO substrate, PMeT-ITO exhibited better stability. Moreover, we successfully fabricated the electrochromic device (ECD) by using PMeT films on ITO substrate. The results of cycling tests showed that the optical contrast of ECD based on PMeT-ITO was kept almost the same after recycling 66 times. Compared with ECD based on PMeT physically adsorbed on bare ITO substrate (PD-PMeT), the ECD based on PMeT-ITO possessed good electrochromic stability in the 150 cycles. This demonstrated that the interaction between PMeT and ITO substrate became stronger by chemical bonding approach, improving the cyclic stability of ECD.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Use of a neutralizing antibody helps identify structural features critical for binding of Clostridium difficile toxin TcdA to the host cell surface

Clostridium difficile is a clinically significant pathogen that causes mild-to-severe (and often recurrent) colon infections. Disease symptoms stem from the activities of two large, multidomain toxins known as TcdA and TcdB. The toxins can bind, enter, and perturb host cell function through a multistep mechanism of receptor binding, endocytosis, pore formation, autoproteolysis, and glucosyltransferase-mediated modification of host substrates. Monoclonal antibodies that neutralize toxin activity provide a survival benefit in preclinical animal models and prevent recurrent infections in human clinical trials. However, the molecular mechanisms involved in these neutralizing activities are unclear. To this end, we performed structural studies on a neutralizing monoclonal antibody, PA50, a humanized mAb with both potent and broad-spectrum neutralizing activity, in complex with TcdA. Electron microscopy imaging and multiangle light-scattering analysis revealed that PA50 binds multiple sites on the TcdA C-terminal combined repetitive oligopeptides (CROPs) domain. A crystal structure of two PA50 Fabs bound to a segment of the TcdA CROPs helped define a conserved epitope that is distinct from previously identified carbohydrate-binding sites. Binding of TcdA to the host cell surface was directly blocked by either PA50 mAb or Fab and suggested that receptor blockade is the mechanism by which PA50 neutralizes TcdA. These findings highlight the importance of the CROPs C terminus in cell-surface binding and a role for neutralizing antibodies in defining structural features critical to a pathogen's mechanism of action. We conclude that PA50 protects host cells by blocking the binding of TcdA to cell surfaces.

59 BASIC BIOLOGICAL SCIENCES↗

Effects of Anionic Polymer Modification of Dye‐Sensitized Niobate Photocatalysts on Solar‐Driven Z‐Scheme Overall Water Splitting

Pt‐intercalated calcium niobate nanosheets (Pt/HCa 2 Nb 3 O 10 ) sensitized by a Ru(II) complex dye are good photocatalysts for producing H 2 from aqueous solutions containing I − as a reversible electron donor. These materials are applicable to Z‐scheme overall water splitting in combination with a WO 3 ‐based O 2 ‐evolving photocatalyst under simulated sunlight. In this work, the effects of anionic polymer modification of the dye‐sensitized nanosheets are examined by adsorbing sodium poly(styrenesulfonate) (PSS), sodium polyacrylate, sodium polymethacrylate (PMA), or sodium poly(4‐styrenesulfonic‐ co ‐maleic acid) onto the dye‐sensitized nanosheet surface. For half‐cell H 2 ‐evolution reaction in the presence of NaI, all of the polymers have a positive impact on the activity under visible light at lower light intensity, whereas only PMA is effective under high light‐intensity condition. For Z‐scheme overall water splitting with PtO x /H‐Cs‐WO 3 , PSS and PMA give almost the same solar‐to‐hydrogen energy conversion efficiencies (0.12% ± 0.01%) under optimized conditions. However, PMA operates better than PSS at relatively low and high NaI concentrations, which are in general disadvantageous for the H 2 ‐ and O 2 ‐evolving components of the Z‐scheme, respectively.

Energy & Fuels↗

Machine learning prediction and experimental verification of Pt-modified nitride catalysts for ethanol reforming with reduced precious metal loading

Ethanol is the smallest molecule containing C–O, C–C, C–H, and O–H bonds present in biomass-derived oxygenates. The development of inexpensive and selective catalysts for ethanol reforming is important towards the renewable generation of hydrogen from biomass. Transition metal nitrides (TMN) are interesting catalyst support materials that can effectively reduce precious metal loading for the catalysis of ethanol and other oxygenates. Herein theoretical and experimental methods were used to probe platinum-modified molybdenum nitride (Pt/Mo 2 N) surfaces for ethanol reforming. Computations using density-functional theory and machine learning predicted monolayer Pt/Mo 2 N to be highly active and selective for ethanol reforming. Temperature-programmed desorption (TPD) experiments verified that ethanol primarily underwent decomposition on Mo 2 N, and the reaction pathway shifted to reforming on Pt/Mo 2 N surfaces. Additionally, high-resolution electron energy loss spectroscopy (HREELS) results further indicated that while Mo2N decomposed the ethoxy intermediate by cleaving C–C, C–O, and C–H bonds, Pt-modification preserved the C–O bond, resulting in ethanol reforming.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗