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DOE OSTI2023

Next Generation Durable, Cost Effective, Energy Efficient Tubular SOFC (Final Scientific/Technical Report)

The overall objective of this project is to develop and optimize a YSZ electrolyte-based solid oxide fuel cell (SOFC) technology for low cost, low temperature (~ 650°C), and high energy efficiency operation. The developed technology will be implemented and demonstrated in a high efficiency 2~3kW SOFC with applicability to sub-MW systems. A summary of significant accomplishments is provided below. Key accomplishments: 1. Improved fundamental cell technology demonstrated at single tube and system scale. Improved power output by 54% while operating at the normal temperature of 750°C. And improved power output by 33% while operating at 650°C, 100°C lower than normal temperature. 2. SPS patented internal recycle arrangement was developed and extended to operate on LPG fuel directly in a compact, high-efficiency (> 40%) system. 3. System testing was conducted to prove the long-term durability of cell improvements. Demonstrated over 8000 hours of operation at 0.21 %/1000 hrs degradation. 4. A large-scale, 2.5kW net power system demonstration was completed, which demonstrated 40% net efficiency over 1000 hours. 5. System design and cost analysis of a 1MW system utilizing a 2.5kW bundle was completed. Cost optimization of the bundle showed a reduction of nearly 80% is possible from $\$$5,790/kW to $\$$1250/kW. This lower cost is considered viable for SPS commercialization.

03 NATURAL GAS↗

DOE OSTI2023

Life-Cycle Analysis of Potentially Longer Life Expectancy CdTe PV Modules

Research on PV module longevity shows that with lower degradation rates and better encapsulation, PV modules can significantly outlast their current life expectancy of 25-30 years. The focus of this study is on alternative CdTe PV module back-contact and encapsulation materials that show the potential of increasing module operation lives from 30 to 40 and 50 years. Life-cycle-analyis shows that some alternative materials may slightly increase cradle-to-gate environmental impacts per m2 of module, but increased operational life more than counterbalances such impacts. The life-cycle carbn footprint of systems operating under average US insolation conditions of 1800 kWh/m2/yr is reduced from 10 gCO2eq/kWh to 6 gCO2eq/kWh when the operation life increases from 30 to 50 yrs. Similar reductions are noted for all life-cycle impact indicators, whereas the EROI of the considered system increases from 67 to 177 as life increases from 30 to 50 yrs.

14 SOLAR ENERGY↗

DOE OSTI2022

Machine-learning from Pseudomonas putida KT2440 transcriptomes reveals its transcriptional regulatory network

Bacterial gene expression is orchestrated by numerous transcription factors (TFs). Elucidating how gene expression is regulated is fundamental to understanding bacterial physiology and engineering it for practical use. In this study, a machine-learning approach was applied to uncover the genome-scale transcriptional regulatory network (TRN) in Pseudomonas putida KT2440, an important organism for bioproduction. We performed independent component analysis of a compendium of 321 high-quality gene expression profiles, which were previously published or newly generated in this study. We identified 84 groups of independently modulated genes (iModulons) that explain 75.7% of the total variance in the compendium. With these iModulons, we (i) expand our understanding of the regulatory functions of 39 iModulon associated TFs (e.g., HexR, Zur) by systematic comparison with 1993 previously reported TF-gene interactions; (ii) outline transcriptional changes after the transition from the exponential growth to stationary phases; (iii) capture group of genes required for utilizing diverse carbon sources and increased stationary response with slower growth rates; (iv) unveil multiple evolutionary strategies of transcriptome reallocation to achieve fast growth rates; and (v) define an osmotic stimulon, which includes the Type VI secretion system, as coordination of multiple iModulon activity changes. Taken together, this study provides the first quantitative genome-scale TRN for P. putida KT2440 and a basis for a comprehensive understanding of its complex transcriptome changes in a variety of physiological states.

09 BIOMASS FUELS↗

DOE OSTI2017

NuSTAR Hard X-Ray Observation of the Gamma-Ray Binary Candidate HESS J1832–093

We present a hard X-ray observation of the TeV gamma-ray binary candidate HESS J1832−093, which is coincident with the supernova remnant G22.7−0.2, using the Nuclear Spectroscopic Telescope Array. Non-thermal X-ray emission from XMMU J183245−0921539, the X-ray source associated with HESS J1832−093, is detected up to ∼30 keV and is well-described by an absorbed power-law model with a best-fit photon index Γ=1.5±0.1. A re-analysis of archival Chandra and XMM-Newton data finds that the long-term X-ray flux increase of XMMU J183245−0921539 is 50{sub −20}{sup +40}% (90% C.L.), much less than previously reported. A search for a pulsar spin period or binary orbit modulation yields no significant signal to a pulse fraction limit of f{sub p}<19% in the range 4 ms < P<40 ks. No red noise is detected in the FFT power spectrum to suggest active accretion from a binary system. While further evidence is required, we argue that the X-ray and gamma-ray properties of XMMU J183245−0921539 are most consistent with a non-accreting binary generating synchrotron X-rays from particle acceleration in the shock formed as a result of the pulsar and stellar wind collision. We also report on three nearby hard X-ray sources, one of which may be associated with diffuse emission from a fast-moving supernova fragment interacting with a dense molecular cloud.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS1990

Recent results from the InP homojunction cell module on the LIPS III spacecraft

The flight performance of the NASA Lewis Research Center's indium phosphide homojunction cell module on the LIPs III spacecraft is presented. Four n+-p diffused junction cells, an early product of an InP development program, were flown. The voltage range of the data prohibits determination of the open-circuit voltage or the maximum power point. However, analysis of the 32 months of short-circuit current data reveals a slight increase, not the 4 percent decrease expected from radiation tolerance studies. This increase may be due to continual cleaning of possible prelaunch dust contamination or changes in data acquisition system calibration. For all cells, the average short-circuit current remains below prelaunch values.

Brinker, David J.↗

NASA NTRS1991

Space architecture monograph series. Volume 4: Genesis 2: Advanced lunar outpost

This research and design study investigated advanced lunar habitats for astronauts and mission specialists on the Earth's moon. Design recommendations are based on environmental response to the lunar environment, human habitability (human factors and environmental behavior research), transportability (structural and materials system with least mass), constructability (minimizing extravehicular time), construction dependability and resilience, and suitability for NASA launch research missions in the 21st century. The recommended design uses lunar lava tubes, with construction being a combination of Space Station Freedom derived hard modules and light weight Kevlar laminate inflatable structures. The proposed habitat includes research labs and a biotron, crew quarters and crew support facility, mission control, health maintenance facility, maintenance work areas for psychological retreat, privacy, and comtemplation. Furniture, specialized equipment, and lighting are included in the analysis and design. Drawings include base master plans, construction sequencing, overall architectural configuration, detailed floor plans, sections and axonometrics, with interior perspectives.

Fieber, Joseph P.↗

NASA NTRS1991

Thruster configurations for maneuvering heavy payloads

The Cargo Transfer Vehicle (CTV) will be required to perform six degree of freedom (6 DOF) maneuvers while carrying a wide range of payloads varying from 100,000 lbm to no payload. The current baseline design configuration for the CTV uses a forward propulsion module (FPM) mounted in front of the payload with the CTV behind the payload so that the center of gravity (CG) of the combined stack is centered between the thruster sets. This allows for efficient rotations and translations of heavy payloads in all directions; however, the FPM is a costly item, so it is desirable to find design solutions that do not require the FPM. This presentation provides an overview of the analysis of the FPM requirements for the CTV. In this study, only the reaction control system (RCS) thruster configurations are considered for 6 DOF maneuvers of various CTV cargo configurations. An important output of this study are the viable alternative thruster configurations that eliminate the need for the FPM. Initial results were derived using analytical techniques and simulation analysis tools. Results from the preliminary analysis were validated using our 6 DOF simulation.

Tsugawa, Roy K.↗

NASA NTRS2001

Overview of the NCC

A multi-disciplinary design/analysis tool for combustion systems is critical for optimizing the low-emission, high-performance combustor design process. Based on discussions between then NASA Lewis Research Center and the jet engine companies, an industry-government team was formed in early 1995 to develop the National Combustion Code (NCC), which is an integrated system of computer codes for the design and analysis of combustion systems. NCC has advanced features that address the need to meet designer's requirements such as "assured accuracy", "fast turnaround", and "acceptable cost". The NCC development team is comprised of Allison Engine Company (Allison), CFD Research Corporation (CFDRC), GE Aircraft Engines (GEAE), NASA Glenn Research Center (LeRC), and Pratt & Whitney (P&W). The "unstructured mesh" capability and "parallel computing" are fundamental features of NCC from its inception. The NCC system is composed of a set of "elements" which includes grid generator, main flow solver, turbulence module, turbulence and chemistry interaction module, chemistry module, spray module, radiation heat transfer module, data visualization module, and a post-processor for evaluating engine performance parameters. Each element may have contributions from several team members. Such a multi-source multi-element system needs to be integrated in a way that facilitates inter-module data communication, flexibility in module selection, and ease of integration. The development of the NCC beta version was essentially completed in June 1998. Technical details of the NCC elements are given in the Reference List. Elements such as the baseline flow solver, turbulence module, and the chemistry module, have been extensively validated; and their parallel performance on large-scale parallel systems has been evaluated and optimized. However the scalar PDF module and the Spray module, as well as their coupling with the baseline flow solver, were developed in a small-scale distributed computing environment. As a result, the validation of the NCC beta version as a whole was quite limited. Current effort has been focused on the validation of the integrated code and the evaluation/optimization of its overall performance on large-scale parallel systems.

Liu, Nan-Suey↗

NASA NTRS2021

Application of a new X-ray reflection model to V1223 Sagittarii

In intermediate polars (IPs), the intrinsic thermal emissions from white dwarfs (WDs) have typically been studied. Few reports have analysed X-ray reflections from WDs. We recently developed an elaborate IP-reflection spectral model. Herein, we report the first application of a reflection model with an IP thermal model to the spectra of the brightest typical IP V1223 Sagittarii observed by the Suzaku and Nuclear Spectroscopic Telescope Array satellites. The model reasonably reproduces the spectra within the range of 5–78 keV and estimates the WD mass as 0.92 ± 0.02 Mꙩ. The WD mass estimated by the proposed model is consistent with that measured using an active galactic nucleus reflection model and a partial covering absorption model. However, the choice of incorrect parameter values, such as an unsuitable fitting energy band and an incorrect metal abundance, was found to introduce systematic errors (e.g. ≲0.2 Mꙩ in the WD mass) in the WD mass measurement. Our spin-phase-resolved analysis resulted in discoveries regarding the modulations of the equivalent width of the fluorescent iron K α line and the angle between the post-shock accretion column and the line of sight (viewing angle). The viewing angle anticorrelates approximately with the X-ray flux and has average and semi-amplitude values of 55° and 7°, respectively, which points towards two WD spin axis angles from the line of sight of 55° and 7°, respectively. Both estimated spin axis angles are different from the reported system inclination of 24°.

Takayuki Hayashi↗

DOE OSTI2023

NETL Direct Air Capture Center

In 2022 Congress authorized the $25M National Energy Technology Laboratory Direct Air Capture Center. The facility will be specifically targeted at accelerating the commercialization of technologies beyond the conceptual stage which have not yet reached full pilot-scale (TRL 3 to 6). The ability to operate over a wide range of conditions will help the developers to understand how their technologies respond in different climates, from summer to winter and arid to tropical. NETL recognizes that DAC technology is still early in its evolution, and a wide variety of highly varied technologies are being explored. The Center will be designed with substantial flexibility to accommodate the rapidly evolving technological landscape. Testing systems at three scales will be included: lab-scale systems designed to examine the long-term stability of DAC materials, bench-scale module testing systems capable of probing flow dynamics, and small pilot-scale skid rooms able to test prototype DAC units under a wide variety of climate conditions. The NETL DAC Center will feature dedicated engineering, technician, scientific and logistical support for experimental system design, installation, operation of experiments, and interpretation of results for projects including but not limited to kinetics of absorption/desorption, thermal duty, and post-mortem elemental characterization to understand degradation. The NETL DAC Center projects will also have access to dedicated process modeling and analysis to evaluate the technoeconomic aspects of new technologies. NETL’s Systems Engineering and Analysis (SEA) team, the Carbon Capture Simulation Initiative (CCSI), and the Institute for the Design of Advanced Energy Systems (IDAES) are all potential collaborators with NETL’s testing partners from industry, academia, and other research institutions. NETL also has world class capabilities in device scale modeling (i.e., MFIX) that will be available to help design more efficient contactors and optimize unique internal configurations that can be realized by advanced manufacturing. The talk will cover the design and capabilities of the center, the planned availability, and feedback will be solicited from the audience on DAC testing needs.

Luebke, David↗

DOE OSTI2023

Accelerating commercialization of direct air capture technology

Luebke, David↗

DOE OSTI2025

Demonstration of an Automated System for Vertical Profiles of Volatile Organic Compounds

Volatile organic compounds (VOCs) play important roles throughout the atmosphere, many of which are altitude dependent. This highlights the need for easily deployable devices to sample VOCs across different atmospheric layers. To address this, we present the design and initial application of a Time Resolved Automated Volatile organIc compounds Sampling system (TRAVIS). VOCs are collected on sorbent tubes, which are subsequently analyzed by a thermal desorption gas chromatography mass spectrometry pipeline. TRAVIS leverages a piezoelectric pump with an integrated pressure sensor for precise (0.1% flow rate relative standard deviation) and accurate (−3 ± 2% error in VOC quantitation) measurements. Via deployment on a tethered balloon system over an agricultural area, TRAVIS is used to show consistent vertically resolved VOC concentrations in a well-mixed (i.e., turbulent) atmosphere (e.g., 5% relative standard deviation for isoprene) and vertically dependent concentrations for a stratified atmosphere (e.g., prior to boundary layer development). Furthermore, we also show VOC information from an intermittent plume via both targeted and untargeted analysis, highlighting future applications for spurious events in agriculture, air quality monitoring, and environmental impact. Overall, the development of TRAVIS represents a lightweight, accurate, sensitive, and precise VOC sampling module for the scientific community.

Aerosols↗

DOE OSTI2021

A metabolic modeling platform for the computation of microbial ecosystems in time and space (COMETS)

Genome-scale stoichiometric modeling of metabolism has become a standard systems biology tool for modeling cellular physiology and growth. Extensions of this approach are emerging as a valuable avenue for predicting, understanding and designing microbial communities. Computation of microbial ecosystems in time and space (COMETS) extends dynamic flux balance analysis to generate simulations of multiple microbial species in molecularly complex and spatially structured environments. Here we describe how to best use and apply the most recent version of COMETS, which incorporates a more accurate biophysical model of microbial biomass expansion upon growth, evolutionary dynamics and extracellular enzyme activity modules. In addition to a command-line option, COMETS includes user-friendly Python and MATLAB interfaces compatible with the well-established COBRA models and methods, as well as comprehensive documentation and tutorials. Overall, this protocol provides a detailed guideline for installing, testing and applying COMETS to different scenarios, generating simulations that take from a few minutes to several days to run, with broad applicability to microbial communities across biomes and scales.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2017

Feedback control design for non-inductively sustained scenarios in NSTX-U using TRANSP

This paper examines a method for real-time control of non-inductively sustained scenarios in NSTX-U by using TRANSP, a time-dependent integrated modeling code for prediction and interpretive analysis of tokamak experimental data, as a simulator. The actuators considered for control in this work are the six neutral beam sources and the plasma boundary shape. To understand the response of the plasma current, stored energy, and central safety factor to these actuators and to enable systematic design of control algorithms, simulations were run in which the actuators were modulated and a linearized dynamic response model was generated. A multi-variable model-based control scheme that accounts for the coupling and slow dynamics of the system while mitigating the effect of actuator limitations was designed and simulated. Simulations show that modest changes in the outer gap and heating power can improve the response time of the system, reject perturbations, and track target values of the controlled values.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2020

A Complex Interplay between Nitric Oxide, Quorum Sensing, and the Unique Secondary Metabolite Tundrenone Constitutes the Hypoxia Response in Methylobacter

Methylobacter species, members of the Methylococcales, have recently emerged as some of the globally widespread, cosmopolitan species that play a key role in the environmental consumption of methane across gradients of dioxygen tensions. In this work, we approached the question of howMethylobacter copes with hypoxia, via laboratory manipulation. Through comparative transcriptomics of cultures grown under high dioxygen partial pressure versus cultures exposed to hypoxia, we identified a gene cluster encoding a hybrid cluster protein along with sensing and regulatory functions. Through mutant analysis, we demonstrated that this gene cluster is involved in the hypoxia stress response. Through additional transcriptomic analyses, we uncovered a complex interconnection between the NO-mediated stress response, quorum sensing, the secondary metabolite tundrenone, and methanol dehydrogenase functions. This novel and complex hypoxia stress response system is so far unique to Methylobacter species, and it may play a role in the environmental fitness of these organisms and in their cosmopolitan environmental distribution.Here, we describe a novel and complex hypoxia response system in a methanotrophic bacterium that involves modules of central carbon metabolism, denitrification, quorum sensing, and a secondary metabolite, tundrenone. This intricate stress response system, so far unique to Methylobacter species, may be responsible for the persistence and activity of these species across gradients of dioxygen tensions and for the cosmopolitan distribution of these organisms in freshwater and soil environments in the Northern Hemisphere, including the fast-melting permafrosts.

59 BASIC BIOLOGICAL SCIENCES↗

NASA NTRS2009

Spacecraft Internal Acoustic Environment Modeling

Acoustic modeling can be used to identify key noise sources, determine/analyze sub-allocated requirements, keep track of the accumulation of minor noise sources, and to predict vehicle noise levels at various stages in vehicle development, first with estimates of noise sources, later with experimental data. In FY09, the physical mockup developed in FY08, with interior geometric shape similar to Orion CM (Crew Module) IML (Interior Mode Line), was used to validate SEA (Statistical Energy Analysis) acoustic model development with realistic ventilation fan sources. The sound power levels of these sources were unknown a priori, as opposed to previous studies that RSS (Reference Sound Source) with known sound power level was used. The modeling results were evaluated based on comparisons to measurements of sound pressure levels over a wide frequency range, including the frequency range where SEA gives good results. Sound intensity measurement was performed over a rectangular-shaped grid system enclosing the ventilation fan source. Sound intensities were measured at the top, front, back, right, and left surfaces of the and system. Sound intensity at the bottom surface was not measured, but sound blocking material was placed tinder the bottom surface to reflect most of the incident sound energy back to the remaining measured surfaces. Integrating measured sound intensities over measured surfaces renders estimated sound power of the source. The reverberation time T6o of the mockup interior had been modified to match reverberation levels of ISS US Lab interior for speech frequency bands, i.e., 0.5k, 1k, 2k, 4 kHz, by attaching appropriately sized Thinsulate sound absorption material to the interior wall of the mockup. Sound absorption of Thinsulate was modeled in three methods: Sabine equation with measured mockup interior reverberation time T60, layup model based on past impedance tube testing, and layup model plus air absorption correction. The evaluation/validation was carried out by acquiring octave band microphone data simultaneously at ten fixed locations throughout the mockup. SPLs (Sound Pressure Levels) predicted by our SEA model match well with measurements for our CM mockup, with a more complicated shape. Additionally in FY09, background NC noise (Noise Criterion) simulation and MRT (Modified Rhyme Test) were developed and performed in the mockup to determine the maximum noise level in CM habitable volume for fair crew voice communications. Numerous demonstrations of simulated noise environment in the mockup and associated SIL (Speech Interference Level) via MRT were performed for various communities, including members from NASA and Orion prime-/sub-contractors. Also, a new HSIR (Human-Systems Integration Requirement) for limiting pre- and post-landing SIL was proposed.

Chu, SShao-sheng R.↗

NASA NTRS2018

NASA's GEOS Composition Model Assessment of PM2.5 During Wildfires: Inferring the Impact of PM2.5 Exposure on Adverse Respiratory & Cardiovascular Conditions

Particulate matter pollution is a mixture of solid and liquid droplets floating in the air that can lead to reduced air quality and increased adverse health impact. Fine particulate matter (PM2.5) can be emitted into the air from anthropogenic sources such as the burning of fossil fuels, motor vehicles, and powerplant emissions. Exposure to PM2.5 can aggravate pre-existing respiratory and cardiovascular conditions. When PM2.5 is inhaled it can cause damage to the lungs such as reduced lung function and shortness of breath. After being inhaled PM2.5 can enter the bloodstream and cause harm to the heart. One major natural source of PM2.5 exposure is from wildfire smoke. The particulates within the smoke from the wildfires can spread from the initial source region, potentially impacting communities both near and far. During and after wildfire events, PM2.5 levels can exceed the WHO air quality guidelines (10 m.g/m^3 annual mean; 25 m.g/m^3 daily mean), becoming hazardous to an individual's health. Global models can be used to simulate the emission and transport of these particulates and subsequently they can be valuable to air quality forecasting in highly polluted areas. The NASA Goddard Earth Observing System (GEOS) Composition Forecast (GEOS-CF) system has been used to produce near-real time air quality forecasts of atmospheric composition at a high global resolution of 25x25 km2. The GEOS-CF system utilizes the GEOS weather forecast model coupled with GEOS-Chem (version 11) chemistry module to provide analyses and forecasts of various toxic air pollutants, including PM2.5. The GEOS-CF simulated high levels of PM2.5 (40 m.g/m^3 to 250 m.g/m^3 ), exceeding the WHO guidelines, during multiple recent regional and global wildfire seasons, including the 2017 Washington State and Northern and Southern California wildfire seasons. Furthermore, the GEOS-CF simulated PM2.5 applied to a human health assessment model, BenMAP (The Environmental Benefits Mapping and Analysis Program, version 1.3), estimates the impact on adverse respiratory health conditions due to PM2.5 exposure from wildfires. The GEOS-CF predicted PM2.5 during the wildfire season with the corresponding BenMAP results provides an assessment of the human health impact of PM2.5 exposure.

Saunders, Emily↗

DOE OSTI2023

Comprehensive Efficiency Analysis of Seven-Switch Current-Source Inverter Based on Voltage-Boost Function and Genetic Algorithm

This paper investigates the voltage-boost features of the emerging seven-switch current-source inverter (H7-CSI) to improve the efficiency of the CSI-based motor drive system. The switching transient and power loss model of the H7-CSI topology during voltage-boost operation are analyzed in detail. The effects of the boost function on the switching and conduction loss of the H7-CSI topology are investigated. A genetic algorithm has been introduced that makes it possible to optimize the H7-CSI’s modulation index to minimize its power loss. Experimental results for the H7-CSI unit show that this optimization can reduce the power loss by 10.6%.

42 ENGINEERING↗