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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,747 records · Page 97

International Training to Promote Successful Environmental Remediation Projects - 18636

The International Atomic Energy Agency (IAEA) supports the efforts of its Member States to manage their nuclear and radiological liabilities, including radioactive waste management, decommissioning of facilities, and remediation of contaminated sites. As part of a project addressing Constraints in Decommissioning and Environmental Remediation (the CIDER Project), the IAEA is developing initiatives to further support capacity development specifically to promote implementation of safe, appropriate, and cost-effective environmental remediation (ER) projects. The IAEA sponsors numerous initiatives to provide its Member States training on important topics related to ER. It has become clear in recent years, however, that the existing training should be augmented with more in-depth training to provide for the development of the critical expertise needed to address significant ER challenges. ER projects typically are very complex, requiring the integration of numerous scientific and engineering disciplines, along with effective project planning and management. There are many examples of ER projects where considerable work has been completed, qualified technical staff are available, and adequate funding has been obtained, yet actual progress towards a final solution has been limited. In such cases, it appears that a key barrier is the lack of capacity to develop strategies, make fully informed decisions, plan for and manage activities, and implement successful ER actions. In light of the above, the IAEA has placed a priority on capacity development across the broad spectrum of ER project implementation. Efforts are underway to develop a new training program to develop capacity at the institutional and individual levels to equip course graduates to effectively integrate all areas of expertise in the planning and execution of ER projects. The target audience includes decision-makers; project managers, planners, and implementers; and academics. The core capabilities to be developed via this program include knowledge and skills related to: (1) radiation issues and radionuclide behavior; (2) health and safety protection principles and requirements; (3) identification, evaluation, and selection of ER technologies and approaches; (4) ongoing, constructive dialogue with stakeholders; (5) project planning, management, and communication; (6) cost estimation and funding development; and (7) implementation of appropriate site monitoring activities. The IAEA is collaborating with multiple organizations to develop and implement this training program, to leverage existing training programs and materials, and to coordinate on the development of sustainable training solutions. This paper will present the status of this initiative and work accomplished thus far. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Importance of river water recharge to the San Joaquin Valley groundwater system

Groundwater is not a sustainable resource, unless abstraction is balanced by recharge. Identifying the sources of recharge in a groundwater basin is critical for sustainable groundwater management. In this paper, we studied the importance of river water recharge to groundwater in the south-eastern San Joaquin Valley (24,000 km 2 , population 4 million). We combined dissolved noble gas concentrations, stable isotopes, tritium, and carbon-14 analyses to analyse the sources, mechanisms, and timescales of groundwater recharge. Area-representative groundwater sampling and numerical model input data enabled a stable isotope mass balance and quantitative estimates of river and local recharge. River recharge, identified by a lighter stable isotope signature, represents 47 ± 4% of modern groundwater in the San Joaquin Valley (recharged after 1950) but only 26 ± 4% of premodern groundwater (recharged before 1950). This implies that the importance of river water recharge in the San Joaquin valley has nearly doubled and is likely the result of a 40% increase in total recharge, caused by river water irrigation return flows and increased stream depletion and river recharge due to groundwater pumping. Compared with the large and long-duration capacity for water storage in the subsurface, storage of water in rivers is limited in time and volume, as evidenced by cold river recharge temperatures resulting from fast infiltration and recharge. Finally, groundwater banking of seasonal surface water flows and expansion of managed aquifer recharge practices therefore appear to be a natural and promising method for increasing the resilience of the San Joaquin Valley water supply system.

54 ENVIRONMENTAL SCIENCES↗

Machine Learning Derived Dynamic Operating Reserve Requirements in High-Renewable Power Systems

Accurately forecasting wind and solar power output poses challenges for deeply decarbonized electricity systems. Grid operators must commit resources to provide reserves to ensure reliable operations in the face of forecast errors, a process which can increase fuel consumption and emissions. We apply neural network-based machine learning to expand the usefulness of median point forecast data by creating probabilistic distributions of short-term uncertainty in demand, wind, and solar forecasts that adapt to prevailing grid conditions. Machine learning derived estimates of forecast errors compare favorably to estimates based on incumbent methods. Reserves derived from machine learning are usually smaller than values derived using incumbent methods, which enables fuel savings during most hours. Machine learning reserves are generally larger than incumbent reserves during times of higher forecast error, potentially improving system reliability. Performance is tested using multi-stage production simulation modeling of the California Independent System Operator (CAISO) system. Machine learning reserves provide production cost and greenhouse gas (GHG) emission reductions of approximately 0.3% relative to historical 2019 requirements. Savings in the 2030 timeframe are highly dependent on battery storage capacity. At lower levels of battery capacity, savings of 0.4% from machine learning reserves are shown. Significant quantities of battery storage are expected to be added to meet California's resource adequacy needs and GHG reduction targets. Addition of these batteries saturate reserve needs and results in minimal within-hour balancing costs in 2030.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Synthesis and physical properties of a new layered ferromagnet Cr 1.21 Te 2

Single crystals of a new layered compound, Cr 1.21 Te 2 , were synthesized via a vapor transport method. The crystal structure and physical properties were characterized by single crystal and powder x-ray diffraction, temperature- and field-dependent magnetization, zero-field heat capacity, and angle-resolved photoemission spectroscopy. Cr 1.21 Te 2 , containing two Cr sites, crystalizes in a trigonal structure with a space group P-3 (No. 147). The Cr site in the interstitial layer is partially occupied. Physical property characterizations indicate that Cr 1.21 Te 2 is metallic with hole pockets at the Fermi energy and undergoes a ferromagnetic phase transition at ~ 173 K. The magnetic moments align along the c axis in the ferromagnetic state. Based on low-temperature magnetization, the spin stiffness constant, D, and spin excitation gap, Δ , were estimated according to Bloch's law to be D = 94 ± 17 meV Å 2 and Δ = 0.45 ± 0.33 meV, suggesting its possible application as a low dimensional ferromagnet.

36 MATERIALS SCIENCE↗

Cost of Oil and Biomass Supply Shocks under Different Biofuel Supply Chain Configurations

This analysis estimates the cost of selected oil and biomass supply shocks for producers and consumers in the light-duty vehicle fuel market under various supply chain configurations using a mathematical programing model, BioTrans. The supply chain configurations differ by whether they include selected flexibility levers: multi-feedstock biorefineries; advanced biomass logistics; and the ability to adjust ethanol content of low-ethanol fuel blends, from E10 to E15 or E05. The simulated scenarios explore market responses to supply shocks including substitution between gasoline and ethanol, substitution between different sources of ethanol supply, biorefinery capacity additions or idling, and price adjustments. Welfare effects for the various market participants represented in BioTrans are summarized into a net shock cost measure. As oil accounts for a larger fraction of fuel by volume, its supply shocks are costlier than biomass supply shocks. Corn availability and the high cost of adding biorefinery capacity limit increases in ethanol use during gasoline price spikes. During shocks that imply sudden decreases in the price of gasoline, the renewable fuel standard (RFS) biofuel blending mandate limits the extent to which flexibility can be exercised to reduce ethanol use. The selected flexibility levers are most useful in response to cellulosic biomass supply shocks.

Uria Martinez, Rocio↗

Surface temperature variations as measured by the Heat Capacity Mapping Mission

The AEM-1 satellite, the Heat Capacity Mapping Mission, has acquired high-quality thermal infrared data at times of day especially suited for studying the earth's surface and the exchange of heat and moisture with the atmosphere. Selected imagery illustrates the considerable variability of surface temperature in and around cities, in the dry southwestern United States, in the Appalachian Mountains, and in agricultural areas. Through simplifying assumptions, an analytic experience is derived that relates day/night temperature differences to the near-surface layer (thermal inertia) and to meteorological factors. Analysis of the result suggests that, in arid regions, estimates of relative thermal inertia may be inferred, whereas, in agricultural areas, a hydrologic interpretation is possible.

Price, J. C.↗

The ELLIPSO (tm) system: Elliptical low orbits for mobile communications and other optimum system elements

On 5 Nov. 1990, Ellipsat filed with the FCC the first application to provide voice communication services via low earth orbiting (LEO) satellites. The proposed system, ELLIPSO, aims at achieving end-user costs comparable to those in the cellular industry. On 3 Jun. 1991 Ellipsat filed for the second complement of its system. Ellipsat was also the first company to propose combined position determination and mobile voice services via low-earth orbiting satellites. Ellipsat is still the only proponent of elliptical orbits for any commercial system in the United States. ELLIPSO uses a spectrum efficient combination of FDMA and CDMA techniques. Ellipsat's strategy is to tailor required capacity to user demand, reduce initial system costs and investment risks, and allow the provision of services at affordable end-user prices. ELLIPSO offers optimum features in all the components of its system, elliptical orbits, small satellites, integrated protocol and signalling system, integrated end-user electronics, novel marketing approach based on the cooperation with the tenets of mobile communications, end-user costs that are affordable, and a low risk approach as deployment is tailored to the growth of its customer base. The efficient design of the ELLIPSO constellation and system allows estimated end-user costs in the $.50 per minute range, five to six times less than any other system of comparable capability.

Castiel, David↗

Measurement-based performance profiles and dynamics of UDT over dedicated connections

Wide-area data transfers in high-performance computing and big data scenarios are increasingly being carried over dedicated network connections that provide high capacities at low loss rates. UDP-based transport protocols are expected to be particularly well-suited for such transfers but their performance is relatively unexplored over a wide range of connection lengths, compared to TCP over shared connections. We present extensive throughput measurements of UDP-based Data Transfer (UDT) over a suite of physical and emulated 10 Gbps connections. In sharp contrast to current UDT analytical models, these measurements indicate much more complex throughput dynamics that are sensitive to the connection modality, protocol parameters, and round-trip times. Lyapunov exponents estimated from the Poincare maps of UDT traces clearly indicate regions of instability and complex dynamics. We propose a simple model based on the ramp-up and sustainment regimes of a generic transport protocol, which qualitatively illustrates the dominant monotonicity and concavity properties of throughput profiles and relates them to Lyapunov exponents. These measurements and analytical results together enable us to comprehensively evaluate UDT performance and select parameters to achieve high throughput, and they also provide guidelines for designing effective transport protocols for dedicated connections.

Foster, Ian↗

Case Study of ISO/TS 6336-22 Micropitting Method: Preprint

ISO/TS 6336-22 (Calculation of load capacity of spur and helical gears — Part 22: Calculation of micropitting load capacity) is the ISO technical specification containing a proposal for a method to calculate the risk of micropitting in gear sets. It assesses micropitting risk through a safety factor which is calculated as the minimum specific film thickness in the contact zone divided by a permissible specific film thickness. A sliding parameter is used to adjust the film thickness in the contact zone to the region of highest sliding, which is where micropitting has been observed. The permissible specific film thickness is best determined through experience or testing, but there is an option to estimate it based on the lubricant’s failure load stage in FZG testing. This paper is a case study of how the method behaves when applied to several gear sets and applications that have experienced micropitting in the field.

gears↗

Case Study of ISO/TS 6336-22 Micropitting Calculation

ISO/TS 6336-22 (Calculation of load capacity of spur and helical gears - Part 22: Calculation of micropitting load capacity) is the ISO technical specification containing a proposal for a method to calculate the risk of micropitting in gear sets. It assesses micropitting risk through a safety factor which is calculated as the minimum specific film thickness in the contact zone divided by a permissible specific film thickness. A sliding parameter is used to adjust the film thickness in the contact zone to the region of highest sliding, which is where micropitting has been observed. The permissible specific film thickness is best determined through experience or testing, but there is an option to estimate it based on the lubricant’s failure load stage in FZG testing. This paper is a case study of how the method behaves when applied to several gear sets and applications that have experienced micropitting in the field.

ENGINEERING,WIND ENERGY↗

Automatic Generation of Chemical Mechanisms for Electrochemical Systems: Solid Electrolyte Interphase Formation in Lithium Batteries

Electrolytes in many lithium ion batteries decompose at the low potentials near the anode. The decomposition products form a layer termed the solid electrolyte interphase (SEI). The composition and growth of the SEI layer significantly affect both the capacity fade and safety of lithium ion batteries. However, SEI formation and growth kinetics are not well understood. In this work, we present an extension of the Reaction Mechanism Generator (RMG) software to automatically generate mechanisms for SEI formation. We extend RMG’s solvation correction framework to account for kinetic solvent effects and demonstrate the accuracy of our technique. We calculate thermochemical parameters for 252 species and rate coefficients for 69 reactions, most with associated solvation corrections. This and additional quantum chemistry data are used to extend RMG’s thermodynamic group additivity and solute parameter estimation schemes to handle lithiated species and add 14 new reaction families to RMG. RMG is additionally extended to simulate electrocatalytic systems. Lastly, we demonstrate RMG on the decomposition of acetonitrile and ethylene carbonate near a battery anode. Furthermore, while this framework does not yet resolve individual ions, as appropriate thermochemistry estimators are not available, and thus, cannot yet resolve more complex electrochemical pathways, RMG is able to generate reasonable pathways for SEI formation that match literature pathways and products. In particular, RMG identifies a new important reaction pathway that is not present in literature.

Chemical reactions↗

Assessing the system value of optimal load shifting

We analyze a competitive electricity market, where consumers exhibit optimal load shifting behavior to maximize utility and producers/suppliers maximize their profit under supply capacity constraints. The associated computationally tractable formulation can be used to inform market design or policy analysis in the context of increasing availability of the smart grid technologies that enable optimal load shifting. Through analytic and numeric assessment of the model, we assess the equilibrium value of optimal electricity load shifting, including how the value changes as more electricity consumers adopt associated technologies. For our illustrative numerical case, derived from the Current Trends scenario of the ERCOT Long Term System Assessment, the average energy arbitrage value per ERCOT customer of optimal load shifting technologies is estimated to be $3 for the 2031 scenario year. We assess the sensitivity of this result to the flexibility of load, along with its relationship to the deployment of renewables. Finally, the model presented can also be a starting point for designing system operation infrastructure that communicates with the devices that schedule loads in response to price signals.

24 POWER TRANSMISSION AND DISTRIBUTION↗

A Full-Featured User Friendly CO 2 -EOR and Sequestration Planning Software

A Full-Featured, User Friendly CO 2 -EOR and Sequestration Planning Software This project addressed the development of an integrated software solution that includes a graphical user interface, numerical simulation, visualization tools and optimization processes for reservoir simulation modeling of CO 2 -EOR. The objective was to assist the industry in the development of domestic energy resources by expanding the application of CO 2 -EOR technologies, and ultimately to maximize the CO 2 } sequestration capacity of the U.S. The software resulted in a field-ready application for the industry to address the current CO 2 -EOR technologies. The software has been made available to the public without restrictions and with user friendly operating documentation and tutorials. The software (executable only) can be downloaded from NITEC’s website at www.nitecllc.com. This integrated solution enables the design, optimization and operation of CO 2 -EOR processes for small and mid-sized operators, who currently cannot afford the expensive, time intensive solutions that the major oil companies enjoy. Based on one estimate, small oil fields comprise 30% of the of total economic resource potential for the application of CO 2 -EOR processes in the U.S. This corresponds to 21.7 billion barrels of incremental, technically recoverable oil using the current “best practices”, and 31.9 billion barrels using “next-generation” CO 2 -EOR techniques. The project included a Case Study of a prospective CO 2 -EOR candidate field in Wyoming by a small independent, Linc Energy Petroleum Wyoming, Inc. NITEC LLC has an established track record of developing innovative and user friendly software. The Principle Investigator is an experienced manager and engineer with expertise in software development, numerical techniques, and GUI applications. Unique, presently-proprietary NITEC technologies have been integrated into this application to further its ease of use and technical functionality.

54 ENVIRONMENTAL SCIENCES↗

Prices in Frequency Regulation Markets: Impacts of Natural Gas Prices and Variable Renewable Energy

Increasing wind and solar penetration and low natural gas prices have reduced electricity prices in competitive power markets in recent years, while also increasing the relative importance of ancillary services in balancing short-term net load variability. As a result, ancillary service markets are providing a valuable alternative revenue stream for many market participants. Yet the price dynamics in these markets are still not very well understood. In this work, we incorporate unit-level ancillary service offer prices and quantities into a production cost model and examine how prices for frequency regulation are impacted by relatively extreme perturbations of several system parameters. Initial offers are first estimated on the basis of limited available public data and are then iteratively calibrated against historic market outcomes. Through a case study of the PJM Interconnection, we find that doubling the natural gas price increases the average annual regulation price by 36%, while replacing all coal generation with natural gas decreases the average price by 42%. Increasing the wind penetration from 2% to 30% in isolation increases the average regulation price by 32%, while further doubling the regulation requirement results in an 84% increase. These price increases can be mitigated by introducing additional battery storage capacity or by increasing offer quantities from hydro and thermal units. Finally, we discuss a number of modeling challenges that are faced when incorporating ancillary services into traditional production cost models. These include poor data availability, inconsistent product definitions across markets, and complex market rules.

02 PETROLEUM↗

Impacts of Siting Considerations on Offshore Wind Technical Potential in the United States

We estimated the technical potential for the offshore wind (OSW) resource in the United States under two siting regimes to characterize the uncertainty pertaining to the local drivers of siting within a national context. We established Open Access and Limited Access regimes to represent upper and lower bounds on OSW deployment, respectively. These included spatial constraints such as technology depth limits, military use areas, protected areas, existing infrastructure, shipping lanes and more. The same spatial considerations are also considered in the Limited Access regime, but with additional buffers to existing infrastructure as well as a reduced capacity density assumption. Capacity density is the concentration of wind energy development for a given area specified in terms of megawatts (MW) per square kilometer (km 2 ). In the Open-Access regime we used a 5 MW/km 2 assumption, while in the Limited Access scenario we assumed 3 MW/km 2 . This difference reflects our intention for the Open-Access scenario to serve as an upper bound for OSW technical potential, with the Limited-Access scenario as a lower bound. We also applied three technology advancement scenarios to each of the siting regimes. The three technology scenarios (Conservative, Moderate, and Advanced) represent plausible improvements in turbine technology including increased rated power and higher hub heights.

17 WIND ENERGY↗

Examination of Factors Affecting the Cost and Performance of a Natural Gas Combined Cycle Equipped with Carbon Dioxide Capture

The purpose of this Technical Note is to report the findings of an examination of the effect of plausible deviations in select study assumptions on the reported cost and performance estimates for a power plant case drawn from NETL’s “Cost and Performance Baseline for Fossil Energy Plants Volume 1: Bituminous Coal and Natural Gas to Electricity” (known as the Fossil Energy Baseline). An F-Class NGCC power plant equipped with state-of-the-art, solvent-based, post-combustion carbon dioxide (CO2) capture (95 percent carbon capture rate)—designated as Case B31B.95—was selected for this work. This sensitivity analysis provides insight into the effects of parameter variations within and across selected categories—ambient conditions, construction cost, natural gas (NG) price, capacity factor, and finance—on the plant performance and capital and operating and maintenance (O&M) costs, and the subsequent impact on common figures of merit.

20 FOSSIL-FUELED POWER PLANTS↗

Crossing the Barriers: An Analysis of Land Access Barriers to Geothermal Development and Potential Improvement Scenarios

Developers have identified many non-technical barriers to geothermal power development, including access to land. Activities required for accessing land, such as environmental review and private and public leasing can take a considerable amount of time and can delay or prevent project development. This paper discusses the impacts to available geothermal resources and deployment caused by land access challenges, including tribal and cultural resources, environmentally sensitive areas, biological resources, land ownership, federal and state lease queues, and proximity to military installations. In this analysis, we identified challenges that have the potential to prevent development of identified and undiscovered hydrothermal geothermal resources. We found that an estimated 400 MW of identified geothermal resource potential and 4,000 MW of undiscovered geothermal resource potential were either unallowed for development or contained one or more significant barriers that could prevent development at the site. Potential improvement scenarios that could be employed to overcome these barriers include (1) providing continuous funding to the U.S. Forest Service (USFS) for processing geothermal leases and permit applications and (2) the creation of advanced environmental mitigation measures. The model results forecast that continuous funding to the USFS could result in deployment of an additional 80 MW of geothermal capacity by 2030 and 124 MW of geothermal capacity by 2050 when compared to the business-as-usual scenario. The creation of advanced environmental mitigation measures coupled with continuous funding to the USFS could result in deployment of an additional 97 MW of geothermal capacity by 2030 and 152 MW of geothermal capacity by 2050 when compared to the business-as-usual scenario. The small impact on potential deployment in these improvement scenarios suggests that these 4,400 MW have other barriers to development in addition to land access. In other words, simply making more resources available for development does not increase deployment; however, impacts to deployment could increase when coupled with other improvements (e.g., permitting, market and/or technology improvements).

15 GEOTHERMAL ENERGY↗