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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,747 records · Page 97
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Equations of motion of slung load systems with results for dual lift

General simulation equations are derived for the rigid body motion of slung load systems. These systems are viewed as consisting of several rigid bodies connected by straight-line cables or links. The suspension can be assumed to be elastic or inelastic, both cases being of interest in simulation and control studies. Equations for the general system are obtained via D'Alembert's principle and the introduction of generalized velocity coordinates. Three forms are obtained. Two of these generalize previous case-specific results for single helicopter systems with elastic or inelastic suspensions. The third is a new formulation for inelastic suspensions. It is derived from the elastic suspension equations by choosing the generalized coordinates so as to separate motion due to cable stretching from motion with invariant cable lengths. The result is computationally more efficient than the conventional formulation, and is readily integrated with the elastic suspension formulation and readily applied to the complex dual lift and multilift systems. Equations are derived for dual lift systems. Three proposed suspension arrangements can be integrated in a single equation set. The equations are given in terms of the natural vectors and matrices of three-dimensional rigid body mechanics and are tractable for both analysis and programming.

Cicolani, Luigi S.↗
NASA NTRS1990

West Antarctic Ice Sheet Initiative. Volume 1: Science and Implementation Plan

The Science and Implementation Plan of the West Antarctic Ice Sheet Initiative (WAIS) is described. The goal of this initiative is the prediction of the future behavior of this ice sheet and an assessment of its potential to collapse, rapidly raising global sea level. The multidisciplinary nature of WAIS reflects the complexity of the polar ice sheet environment. The project builds upon past and current polar studies in many fields and meshes with future programs of both the U.S. and other countries. Important tasks in each discipline are described and a coordinated schedule by which the majority of these tasks can be accomplished in 5 years is presented. The companion report (Volume 2) contains seven discipline review papers on the state of knowledge of Antarctica and opinions on how that knowledge must be increased to attain the WAIS goal.

Bindschadler, Robert A.↗
NASA NTRS2008

Small-Body Extensions for the Satellite Orbit Analysis Program (SOAP)

An extension to the SOAP software allows users to work with tri-axial ellipsoid-based representations of planetary bodies, primarily for working with small, natural satellites, asteroids, and comets. SOAP is a widely used tool for the visualization and analysis of space missions. The small body extension provides the same visualization and analysis constructs for use with small bodies. These constructs allow the user to characterize satellite path and instrument cover information for small bodies in both 3D display and numerical output formats. Tri-axial ellipsoids are geometric shapes the diameters of which are different in each of three principal x, y, and z dimensions. This construct provides a better approximation than using spheres or oblate spheroids (ellipsoids comprising two common equatorial diameters as a distinct polar diameter). However, the tri-axial ellipsoid is considerably more difficult to work with from a modeling perspective. In addition, the SOAP small-body extensions allow the user to actually employ a plate model for highly irregular surfaces. Both tri-axial ellipsoids and plate models can be assigned to coordinate frames, thus allowing for the modeling of arbitrary changes to body orientation. A variety of features have been extended to support tri-axial ellipsoids, including the computation and display of the spacecraft sub-orbital point, ground trace, instrument footprints, and swathes. Displays of 3D instrument volumes can be shown interacting with the ellipsoids. Longitude/latitude grids, contour plots, and texture maps can be displayed on the ellipsoids using a variety of projections. The distance along an arbitrary line of sight can be computed between the spacecraft and the ellipsoid, and the coordinates of that intersection can be plotted as a function of time. The small-body extension supports the same visual and analytical constructs that are supported for spheres and oblate spheroids in SOAP making the implementation of the more complex algorithms largely transparent to the user.

Carnright, Robert↗
NASA NTRS2016

A Cognitive Systems Engineering Approach to Developing HMI Requirements for New Technologies

This document examines the challenges inherent in designing and regulating to support human-automation interaction for new technologies that will deployed into complex systems. A key question for new technologies, is how work will be accomplished by the human and machine agents. This question has traditionally been framed as how functions should be allocated between humans and machines. Such framing misses the coordination and synchronization that is needed for the different human and machine roles in the system to accomplish their goals. Coordination and synchronization demands are driven by the underlying human-automation architecture of the new technology, which are typically not specified explicitly by the designers. The human machine interface (HMI) which is intended to facilitate human-machine interaction and cooperation, however, typically is defined explicitly and therefore serves as a proxy for human-automation cooperation requirements with respect to technical standards for technologies. Unfortunately, mismatches between the HMI and the coordination and synchronization demands of the underlying human-automation architecture, can lead to system breakdowns. A methodology is needed that both designers and regulators can utilize to evaluate the expected performance of a new technology given potential human-automation architectures. Three experiments were conducted to inform the minimum HMI requirements a detect and avoid system for unmanned aircraft systems (UAS). The results of the experiments provided empirical input to specific minimum operational performance standards that UAS manufacturers will have to meet in order to operate UAS in the National Airspace System (NAS). These studies represent a success story for how to objectively and systematically evaluate prototype technologies as part of the process for developing regulatory requirements. They also provide an opportunity to reflect on the lessons learned from a recent research effort in order to improve the methodology for defining technology requirements for regulators in the future. The biggest shortcoming of the presented research program was the absence of the explicit definition, generation and analysis of potential human-automation architectures. Failure to execute this step in the research process resulted in less efficient evaluation of the candidate prototypes technologies in addition to the complete absence of different approaches to human-automation cooperation. For example, all of the prototype technologies that were evaluated in the research program assumed a human-automation architecture that relied on serial processing from the automation to the human. While this type of human-automation architecture is typical across many different technologies and in many different domains, it ignores different architectures where humans and automation work in parallel. Defining potential human-automation architectures a priori also allows regulators to develop scenarios that will stress the performance boundaries of the technology during the evaluation phase. The importance of adding this step of generating and evaluating candidate human-automation architectures prior to formal empirical evaluation is discussed.

human systems integration↗
DOE OSTI2018

Thermally initiated disproportionation of manganese(II) bis(1-hydroxyethylidene)diphosphonate. Formation and properties of the lepidoid structure of manganese(II) (1-hydroxyethylidene)diphosphonate-2-hydroxyethaneaminium whiskers. Agronomical efficiency of the manganese(II) complex with (1-hydroxyethylidene)diphosphonic acid

The reaction of poorly soluble manganese(II) bis(1-hydroxyethylidene)diphosphonate tetrahydrate (Mn(H{sub 3}L){sub 2}•4H{sub 2}O) with 2-aminoethanol (H{sub 2}NCH{sub 2}CH{sub 2}OH) in an aqueous medium on heating to 70—80 оС causes the initial formation of soluble manganese(II) bis(1-hydroxyethylidene)diphosphonate tris(1-hydroxyethaneaminium) (Mn(H{sub 3}L)2• •3H{sub 2}NCH{sub 2}CH{sub 2}OH•4H{sub 2}O), which then disproportionates to slightly soluble manganese(II) (1-hydroxyethylidene)diphosphonate-2-hydroxyethaneaminium (MnH{sub 2}L•H{sub 2}NCH{sub 2}CH{sub 2}OH) and coordination polymer of 1-hydroxyethylidenediphosphonic acid with 2-aminoethanol containing no metal cations. In the course of the reaction, MnH{sub 2}L•H{sub 2}NCH{sub 2}CH{sub 2}OH precipitates as whiskers that are grouped into a leaf (lepidoid) structure. The latter was examined by IR spectroscopy, X-ray phase analysis, scanning electron microscopy, atomic force microscopy, optical microscopy, and thermal desorption of nitrogen. The starting and resulting manganese compounds refer to poorly soluble crystalline complexes. The presence of a 2-aminoethanol molecule in the final product leads to an increase in the solubility from 0.40 to 0.54 g in 100 mL of the solution. Poorly soluble MnH{sub 2}L•H{sub 2}NCH{sub 2}CH{sub 2}OH is easily converted to a soluble form by the treatment with 2-aminoethanol or 2-amino-2-(hydroxy- methyl)propane-1,3-diol (H{sub 2}NC(CH{sub 2}OH)3). The agronomical efficiency of a solution of the Mn(H{sub 3}L){sub 2}•3H{sub 2}NCH{sub 2}CH{sub 2}OH•4H{sub 2}O complex was studied on the cultures of white lupine Degas, spring wheat Ester, spring rape, and pea Stabil.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

ExaWorks: Workflows for Exascale

Exascale computers will offer transformative capabilities to combine data-driven and learning-based approaches with traditional simulation applications to accelerate scientific discovery and insight. These software combinations and integrations, however, are difficult to achieve due to challenges of coordination and deployment of heterogeneous software components on diverse and massive platforms. We present the ExaWorks project, which can address many of these challenges: ExaWorks is leading a co-design process to create a workflow Software Development Toolkit (SDK) consisting of a wide range of workflow management tools that can be composed and interoperate through common interfaces. We describe the initial set of tools and interfaces supported by the SDK, efforts to make them easier to apply to complex science challenges, and examples of their application to exemplar cases. Furthermore, we discuss how our project is working with the workflows community, large computing facilities as well as HPC platform vendors to sustainably address the requirements of workflows at the exascale.

97 MATHEMATICS AND COMPUTING↗
NASA NTRS1992

Coordinating space telescope operations in an integrated planning and scheduling architecture

The Heuristic Scheduling Testbed System (HSTS), a software architecture for integrated planning and scheduling, is discussed. The architecture has been applied to the problem of generating observation schedules for the Hubble Space Telescope. This problem is representative of the class of problems that can be addressed: their complexity lies in the interaction of resource allocation and auxiliary task expansion. The architecture deals with this interaction by viewing planning and scheduling as two complementary aspects of the more general process of constructing behaviors of a dynamical system. The principal components of the software architecture are described, indicating how to model the structure and dynamics of a system, how to represent schedules at multiple levels of abstraction in the temporal database, and how the problem solving machinery operates. A scheduler for the detailed management of Hubble Space Telescope operations that has been developed within HSTS is described. Experimental performance results are given that indicate the utility and practicality of the approach.

Muscettola, Nicola↗
DOE OSTI2022

Quantum Distributed Unit Commitment: An Application in Microgrids

The dawn of quantum computing brings on a revolution in the way combinatorially complex power system problems such as Unit Commitment are solved. The Unit Commitment problem complexity is expected to increase in the future because of the trend toward the increase of penetration of intermittent renewables. Even though quantum computing has proven effective for solving a host of problems, its applications for power systems’ problems have been rather limited. Here, in this paper, a quantum unit commitment is innovatively formulated and the quantum version of the decomposition and coordination alternate direction method of multipliers (ADMM) is established. The above is achieved by devising quantum algorithms and by exploiting the superposition and entanglement of quantum bits (qubits) for solving subproblems, which are then coordinated through ADMM to obtain feasible solutions. The main contributions of this paper include: 1) the innovative development of a quantum model for Unit Commitment; 2) development of decomposition and coordination-supported framework which paves the way for the utilization of limited quantum resources to potentially solve the large-scale discrete optimization problems; 3) devising the novel quantum distributed unit commitment (QDUC) to solve the problem in a larger scale than currently available quantum computers are capable of solving. The QDUC results are compared with those from its classical counterpart, which validate the efficacy of quantum computing.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2020

Butyltin Keggin Ion with a Rare Four-Coordinate Ca Center

Alkyltin clusters are exploited in nanolithography for the fabrication of microelectronics. The alkyltin Keggin family is unique among Keggin clusters across the periodic table; its members appear to favor the lower-symmetry β and γ isomers rather than the highly symmetrical α and ε isomers. Therefore, the alkyltin Keggin family may provide important fundamental information about the formation and isomerization of Keggin clusters. In this study, we have synthesized and structurally characterized a new butyltin Keggin cluster with a tetrahedral Ca 2+ center, fully formulated [(BuSn) 12 (CaO 4 )(OCH 3 ) 12 (O) 4 (OH) 8 ] 2+ (β-CaSn 12 ). The synthesis is a simple one-step process. Extensive solution characterization including electrospray ionization mass spectrometry, small-angle X-ray scattering, and multinuclear ( 1 H, 13 C, and 119 Sn) nuclear magnetic resonance shows β-CaSn 12 is essentially phase-pure and stable. This differs from the previously reported Na-centered analogues that always form a mixture of β and γ isomers, with facile interconversion. Therefore, this study has clarified prior confusion over complex spectroscopic and crystallographic characterization of the Na-centered analogues. Density functional theory calculations showed the following stability order: γ-CaSn 12 < γ-NaSn 12 < β-CaSn 12 < β-NaSn 12 . The β analogue is always more stable than the γ analogue, consistent with experiment. Notable outcomes of this study include a rare tetrahedral Ca coordination, a Na-free alkyltin cluster (important for microelectronics manufacturing), and a better understanding of Keggin families built of different metal cations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Mechanisms of Plutonium Redox Reactions in Nitric Acid Solutions

Plutonium (Pu) exhibits a complex redox behavior in acidic solutions due to its ability to adapt a wide range of oxidation states typically from +3 to +6 and the tendency for dynamic interconversion between the oxidation states that depends upon electrochemical potential, acid concentration and coordination environments. In particular, the accurate redox speciation of Pu in nitric acid solutions and mapping the interconversion between the various oxidation states mechanistically is challenging due to overlapping chemical and electrochemical reactions leading to significant experimental uncertainties. The last several decades have seen the extensive use of spectroscopic methods to identify and characterize Pu solution species in the various oxidation states. However, dynamic redox mobility of Pu has led to discrepancies among the relevant spectral databases for Pu in nitric acid solutions. This work utilizes a combination of voltammetry and controlled-potential in-situ vis–NIR spectroelectrochemistry to overcome these challenges, and map the interconversion between Pu species in +3, +4, and +6 oxidation states. This allowed elucidation of the mechanisms of the involved redox reactions and an in-depth understanding of the relative stability of the Pu oxidation states through mapping of the Pu redox processes as a function of redox potentials and nitric acid concentrations. The NIR-spectroelectrochemistry studies used to spectroscopically map the redox speciation of Pu as a function of oxidation potentials with varying HNO3 concentrations allows a new perspective into the plutonium redox transformations.

Chatterjee, Sayandev↗
DOE OSTI2018

Metastable silica high pressure polymorphs as structural proxies of deep Earth silicate melts

Modelling of processes involving deep Earth liquids requires information on their structures and compression mechanisms. However, knowledge of the local structures of silicates and silica (SiO 2 ) melts at deep mantle conditions and of their densification mechanisms is still limited. Here we report the synthesis and characterization of metastable high-pressure silica phases, coesite-IV and coesite-V, using in situ single-crystal X-ray diffraction and ab initio simulations. Their crystal structures are drastically different from any previously considered models, but explain well features of pair-distribution functions of highly densified silica glass and molten basalt at high pressure. Built of four, five-, and six-coordinated silicon, coesite-IV and coesite-V contain SiO 6 octahedra, which, at odds with 3 rd Pauling’s rule, are connected through common faces. Our results suggest that possible silicate liquids in Earth’s lower mantle may have complex structures making them more compressible than previously supposed.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Solvent control of charge transfer excited state relaxation pathways in [Fe(2,2'-bipyridine)(CN) 4 ] 2-

The excited state dynamics of solvated [Fe(bpy)(CN) 4 ] 2- , where bpy = 2,2'-bipyridine, show significant sensitivity to the solvent Lewis acidity. Using a combination of optical absorption and X-ray emission transient spectroscopies, we have previously shown that the metal to ligand charge transfer (MLCT) excited state of [Fe(bpy)(CN) 4 ] 2- has a 19 picosecond lifetime and no discernable contribution from metal centered (MC) states in weak Lewis acid solvents, such as dimethyl sulfoxide and acetonitrile. Here, in the present work, we use the same combination of spectroscopic techniques to measure the MLCT excited state relaxation dynamics of [Fe(bpy)(CN) 4 ] 2- in water, a strong Lewis acid solvent. The charge-transfer excited state is now found to decay in less than 100 femtoseconds, forming a quasi-stable metal centered excited state with a 13 picosecond lifetime. We find that this MC excited state has triplet ( 3 MC) character, unlike other reported six-coordinate Fe(II)-centered coordination compounds, which form MC quintet ( 5 MC) states. The solvent dependent changes in excited state non-radiative relaxation for [Fe(bpy)(CN) 4 ] 2- allows us to infer the influence of the solvent on the electronic structure of the complex. Lastly, the robust characterization of the dynamics and optical spectral signatures of the isolated 3 MC intermediate provides a strong foundation for identifying 3 MC intermediates in the electronic excited state relaxation mechanisms of similar Fe-centered systems being developed for solar applications.

14 SOLAR ENERGY↗
DOE OSTI2024

Optimal Managed Fast-Charging Model for Electric Vehicle Fleets with High Utilization and Multiple Charge-Acceptance Curves

A predictive control/scheduling optimization model is proposed for managed charging of an electric vehicle (EV) fleet - under time-of-use energy and demand prices, high vehicle utilization frequency (short dwell times), multiple charge- acceptance curves (configurable charging rates), and flexible vehicle demand. This context is particularly relevant for flight schools (small electric aircraft) or other commercial facilities where an EV fleet performs multiple operating and fast-charging sessions on the same day. The proposed model performs both the operational and charging scheduling of the vehicles, which is not typically done for residential managed charging and significantly increases problem complexity. The problem is formulated as a MILP model and a case study of a small fast-charging station is presented. Results demonstrate a significant reduction in operating cost, mainly from peak shaving during high demand price periods, achieved by coordinating the operation of different vehicles, chargers and charging rates.

ADVANCED PROPULSION SYSTEMS,ENERGY PLANNING, POLIC↗
DOE OSTI2025

Ultraselective sequestration of Li + and Mg 2+ from brines via a reusable polyoxoniobate-based ion sponge

Lithium (Li) and magnesium (Mg) are designated as critical mineral materials (CMM) due to their essential roles in clean energy technologies. However, extracting high-purity Li + from brine remains a formidable challenge owing to the presence of Mg 2+ , a physicochemical similar ion that often exists in excess. Here, we introduce a polyoxoniobate-based “Mg-PONb sponge” that enables ultraselective and rapid Li + /Mg 2+ separation across an exceptionally broad range of Mg/Li ratios (0.02 to 200.63). This framework achieves >99.9% Mg 2+ removal with negligible Li + loss in under 1 min, yielding Li + /Mg 2+ selectivity values exceeding 5000. The sponge demonstrates excellent recyclability, maintaining >99% Mg 2+ rejection and Li + permeability across five regeneration cycles without structural degradation. Mechanistic investigations reveal that selective Mg 2+ capture originates from strong coordination with terminal oxygens on the PONb cluster, driving rapid formation of porous Mg-PONb frameworks. This work presents a generalizable, scalable strategy for Li + /Mg 2+ separation and offers a sustainable path toward enhanced Li and Mg recovery from complex brine sources.

Chen, Linfeng [Lawrence Berkeley National Laborato↗
NASA NTRS1975

Numerical solutions for inviscid supersonic corner flows

Analytical solutions for inviscid supersonic corner flows are virtually nonexistent due to the complexity of the interference geometry. In view of this, numerical solutions for compressive-compressive and expansive-compressive corner flows are obtained. The governing equations are written in strong conservation-law form and are solved iteratively in nonorthogonal conical coordinates by use of a second-order, shock-capturing, finite-difference technique. The computed wave structure and surface pressure distributions are compared with high Reynolds number (Re greater than 2,500,000 ft) experimental data. The results clearly show that the wave structure in the corner is dominated by the inviscid field.

Shankar, V. S. V.↗
NASA NTRS1975

Numerical solutions for supersonic corner flow

Analytical solutions for inviscid supersonic corner flows are virtually nonexistent due to the complexity of the interference geometry. In view of this, numerical solutions for swept-compressive and swept-expansive corner flows are obtained. The governing equations are written in strong conservation-law form and are solved iteratively in nonorthogonal conical coordinates by use of a second-order, shock-capturing, finite-difference technique. The computed wave structure and surface pressure distributions are compared with high Reynolds number experimental data and show very good agreement. The results clearly show that supersonic corner flow at reasonably high Reynolds numbers including the effect of sweep is dominated by the inviscid field.

Shankar, V.↗
NASA NTRS1975

Fully unsteady subsonic and supersonic potential aerodynamics for complex aircraft configurations for flutter applications

A general theory for study, oscillatory or fully unsteady potential compressible aerodynamics around complex configurations is presented. Using the finite-element method to discretize the space problem, one obtains a set of differential-delay equations in time relating the potential to its normal derivative which is expressed in terms of the generalized coordinates of the structure. For oscillatory flow, the motion consists of sinusoidal oscillations around a steady, subsonic or supersonic flow. For fully unsteady flow, the motion is assumed to consist of constant subsonic or supersonic speed for time t or = 0 and of small perturbations around the steady state for time t 0.

Tseng, K.↗
NASA NTRS1978

The practical application of a finite difference method for analyzing transonic flow over oscillating airfoils and wings

Separating the velocity potential into steady and unsteady parts and linearizing the resulting unsteady equations for small disturbances was performed. The steady velocity potential was obtained first from the well known nonlinear equation for steady transonic flow. The unsteady velocity potential was then obtained from a linear differential equation in complex form with spatially varying coefficients. Since sinusoidal motion is assumed, the unsteady equation is independent of time. The results of an investigation into the relaxation-solution-instability problem was discussed. Concepts examined include variations in outer boundary conditions, a coordinate transformation so that the boundary condition at infinity may be applied to the outer boundaries of the finite difference region, and overlapping subregions. The general conclusion was that only a full direct solution in which all unknowns are obtained at the same time will avoid the solution instabilities of relaxation. An analysis of the one-dimensional form of the unsteady transonic equation was studied to evaluate errors between exact and finite difference solutions. Pressure distributions were presented for a low-aspect-ratio clipped delta wing at Mach number of 0.9 and for a moderate-aspect-ratio rectangular wing at a Mach number of 0.875.

Weatherill, W. H.↗