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At least 1,747 records · Page 97

Spatial variation of ozone depletion rates in the springtime Antarctic polar vortex

An area-mapping technique, designed to filter out synoptic perturbations of the Antarctic polar vortex such as distortion or displacement away from the pole, was applied to the Nimbus-7 TOMS (Total Ozone Mapping Spectrometer) data. This procedure reveals the detailed morphology of the temporal evolution of column O3. The results for the austral spring of 1987 suggest the existence of a relatively stable collar region enclosing an interior that is undergoing large variations. A simplified photochemical model of O3 loss and the temporal evolution of the area-mapped polar O3 are used to constrain the chlorine monoxide (ClO) concentrations in the springtime Antarctic vortex. The O3 loss rates could be larger than deduced here because of underestimates of total O3 by TOMS near the terminator.

Yung, Yuk L.↗

The stellar population structure of the galactic disk

The spatial structure of stellar populations with different chemical abundances in the Milky Way (MW) contains a wealth of information on Galactic evolution over cosmic time. We use data on 14,699 red-clump stars from the APOGEE survey, covering 4 kpc≲R≲15 kpc, to determine the structure of mono-abundance populations (MAPs)—stars in narrow bins in [α/Fe] and [Fe/H]—accounting for the complex effects of the APOGEE selection function and the spatially variable dust obscuration. We determine that all MAPs with enhanced [α/Fe] are centrally concentrated and are well-described as exponentials with a scale length of 2.2±0.2 kpc over the whole radial range of the disk. We discover that the surface-density profiles of low-[α/Fe] MAPs are complex: they do not monotonically decrease outwards, but rather display a peak radius ranging from ≈5 to ≈13 kpc at low [Fe/H]. The extensive radial coverage of the data allows us to measure radial trends in the thickness of each MAP. While high-[α/Fe] MAPs have constant scale heights, low-[α/Fe] MAPs flare. We confirm, now with high-precision abundances, previous results that each MAP contains only a single vertical scale height and that low-[Fe/H], low-[α/Fe] and high-[Fe/H], high-[α/Fe] MAPs have intermediate (h{sub Z}≈300--600 pc) scale heights that smoothly bridge the traditional thin- and thick-disk divide. That the high-[α/Fe], thick disk components do not flare is strong evidence against their thickness being caused by radial migration. The correspondence between the radial structure and chemical-enrichment age of stellar populations is clear confirmation of the inside-out growth of galactic disks. The details of these relations will constrain the variety of physical conditions under which stars form throughout the MW disk.

79 ASTRONOMY AND ASTROPHYSICS↗

InVEST Urban Development: Incorporating Earth Observation Data into the Integrated Valuation of Ecosystem Services and Tradeoffs (InVEST) Urban Flood Risk Mitigation Model Python API

Urban flooding poses as one of the biggest issues for cities today as its impacts are amplified by both climate change and urbanization. The Natural Capital Project’s Integrated Valuation of Ecosystem Services and Tradeoffs (InVEST) Urban Flood Risk Mitigation (UFRM) model, which benefits from its simplicity and robustness, is commonly used in NASA DEVELOP projects for disaster mitigation, urban planning, and environmental justice issues. While the InVEST UFRM model was able to produce the surface water runoff and retention map sufficient for the scopes of past projects, the model’s accuracy and spatial variability need improvement. Since the current InVEST UFRM model employs constant rainfall depth for all pixels in the area of interest (AOI), the model suffers from inaccurately estimating rainfall depth, runoff volume, and flood depth. Therefore, we adapted the model so that satellite-based precipitation raster datasets (i.e., Integrated Multi-satellitE Retrievals for Global Precipitation Measurement [GPM IMERG]) can be used instead of a single constant value. We simulated the flood events on August 21st and August 22nd, 2017, in Wyandotte County, Kansas using both our modified and the original InVEST UFRM model and then compared the results after incorporating rainfall raster into the model. Areas with developed land on the land use map predicted moderate to high flood volume in the original volume regardless of the actual amount of precipitation. The modified model considered the rainfall depth’s spatial variation achieving less overestimation of flood runoff and volume at low-to-moderate rainfall area.

Urban flooding↗

Modeling Methods for 3D Lightning Mapping from Space

Global lightning detection has advanced greatly over the past few decades both on ground and from orbit. Ground-based systems like the Lightning Mapping Array (LMA) excel at high-precision 3D reconstruction of local flashes, while spaceborne lightning sensors have much larger potential coverage but have been limited by coarser resolution and often rely on data from other instruments to determine flash location. The primary focus of this study is to examine the level of flash detail that can be expected from one or more low-Earth orbiting small satellites that combine VHF and optical measurements of lightning, which is a new mission concept called CubeSpark. The goal of CubeSpark is to map the 3D charge structure of thunderstorms at 1-2 km spatial resolution on a global scale, enabling a host of new atmospheric and space electricity studies. In order to maximize the potential data quality and minimize potential cost, flashes were simulated beneath single- and multi-satellite configurations. In the multi-satellite approach, RF detectors on each of the six satellites would measure the arrival times of impulsive VHF sources to collectively pinpoint their locations in 3D and reconstruct flashes with higher resolution than has been achieved from space. A single-station approach for 3D observation of lightning would follow the method of determining altitudes of strong VHF sources that produce trans-ionospheric pulse pairs (TIPPs) while relying on an on-board high-resolution optical day/night lightning mapper for approximate horizontal flash locations. Here we present preliminary results comparing the expected data fidelity and accuracy between these methods to inform potential satellite missions like CubeSpark.

lightning↗

Characterization of twin boundaries in an Fe–17.5Mn–0.56C twinning induced plasticity steel

A twinning-induced plasticity steel of composition Fe–17.5 wt.% Mn–0.56 wt.% C–1.39 wt.% Al–0.24 wt.% Si was analyzed for the purpose of characterizing the relationship between tensile strain and deformation twinning. Tensile samples achieved a maximum of 0.46 true strain at failure, and a maximum ultimate tensile strength of 1599 MPa. Electron backscatter diffraction (EBSD) analysis showed that the grain orientation rotated heavily to < 111 > parallel to the tensile axis above 0.3 true strain. Sigma 3 misorientations, as identified by EBSD orientation measurements, and using the image quality maps were used to quantify the number of twins present in the scanned areas of the samples. The image quality method yielded a distinct positive correlation between the twin area density and deformation, but the orientation measurements were unreliable in quantifying twin density in these structures. Quantitative analysis of the twin fraction is limited from orientation information because of the poor spatial resolution of EBSD in relation to the twin thickness. The EBSD orientation maps created for a thin foil sample showed some improvement in the resolution of the twins, but not enough to be significant. Measurements of the twins in the transmission electron microscopy micrographs yielded an average thickness of 23 nm, which is near the resolution capabilities of EBSD on this material for the instrumentation used. Electron channeling contrast imaging performed on one bulk tensile specimen of 0.34 true strain, using a method of controlled diffraction, yielded several images of twinning, dislocation structures and strain fields. A twin thickness of 66 nm was measured by the same method used for the transmission electron microscopy measurement. It is apparent that the results obtain by electron channeling contrast imaging were better than those by EBSD but did not capture all information on the twin boundaries such as was observed by transmission electron microscopy. - Highlights: • Performed tensile tests to assess mechanical performance of TWIP alloy • Analyzed tensile specimens using EBSD, TEM, and ECCI • EBSD showed that most twinning occurred at or near the < 111 >//TA orientation. • EBSD, TEM and ECCI were used to measure average twin density. • Compared spatial resolution of EBSD, ECCI and TEM for the instrumentation used.

36 MATERIALS SCIENCE↗

Imaging of the Li spatial distribution within V 2 O 5 cathode in a coin cell by neutron computed tomography

An understanding of Lithium (Li) spatial distribution within the electrodes of a Li-ion cell, during charge and discharge cycles, is essential to optimize the electrode parameters for increased performance under cycling. In this work, it is demonstrated that the spatial distribution of Li within Vanadium Pentoxide (V 2 O 5 ) electrodes of a small coin cell can be imaged by neutron computed tomography. The neutron attenuation data has been used to construct the three-dimensional Li spatial images. Specifically, it is shown that there is sufficient neutron imaging contrast between lithiated and delithiated regions of V 2 O 5 electrode making it possible to map Li distributions even in small electrodes with thicknesses <1 mm. The images reveal that the Li spatial distribution is inhomogeneous and a relatively higher C-rate leads to more non-uniform Li distribution after Li insertion. The non-uniform distribution suggests the limitation of Li diffusion within the electrode during the lithiation process under the relatively high cycling rates.

25 ENERGY STORAGE↗

Crack Imaging and Quantification in Aluminum Plates with Guided Wave Wavenumber Analysis Methods

Guided wavefield analysis methods for detection and quantification of crack damage in an aluminum plate are presented in this paper. New wavenumber components created by abrupt wave changes at the structural discontinuity are identified in the frequency-wavenumber spectra. It is shown that the new wavenumbers can be used to detect and characterize the crack dimensions. Two imaging based approaches, filter reconstructed imaging and spatial wavenumber imaging, are used to demonstrate how the cracks can be evaluated with wavenumber analysis. The filter reconstructed imaging is shown to be a rapid method to map the plate and any existing damage, but with less precision in estimating crack dimensions; while the spatial wavenumber imaging provides an intensity image of spatial wavenumber values with enhanced resolution of crack dimensions. These techniques are applied to simulated wavefield data, and the simulation based studies show that spatial wavenumber imaging method is able to distinguish cracks of different severities. Laboratory experimental validation is performed for a single crack case to confirm the methods' capabilities for imaging cracks in plates.

Yu, Lingyu↗

Utilization of GIS technology to support development of flow and contaminant fate and transport models at US DOE sites - 15457

U.S. Department of Energy (DOE) sites have accumulated years of data and millions of spatial and temporal records related to the hydrological cycle, contaminant transport, and parameters of remediation technologies. In addition, numerical models which use field monitoring data to help understand flow and transport produce gigabytes of computed spatial and temporal data for each computation node. There is a need therefore for an advanced spatial data structure that can be used to address the management, processing, and analysis of spatial and temporal numerical modeling data derived from multiple sources. This can be accomplished using a geo-database. The development of an ArcSDE geo-database facilitates the centralized storage, backup, accessibility, organization, and management of model configuration and computed simulation data, putting it into a structured, coherent, and logical computer-supported system. GIS data processing and automation would enable faster and hence more complex analyses of field test data. The Applied Research Center (ARC) at Florida International University (FIU) has provided analysis of flow and transport for several watersheds at DOE's Oak Ridge Reservation (ORR), including East Fork Poplar Creek (EFPC), Upper EFPC in the Y-12 National Security Complex area (Y-12 NSC) and White Oak Creek (WOC). Integrated surface and subsurface flow, fate and transport models were developed to provide analysis of contaminant patterns within each watershed. In addition, digital monitoring data available from the Oak Ridge Environmental Information System (OREIS) related to mercury (Hg) contamination and remediation within these watersheds was used for calibration and verification of the model. Experimental studies were also carried out which provided kinetic and equilibrium data about important parameters related to Hg transport, speciation and methylation/demethylation kinetics within the watershed. Geographic Information Systems (GIS) technology was employed to support the modeling work through storage and geo-processing of spatial and temporal data required by the models and to produce hydrogeological maps for visualization. An ArcGIS geo-database was developed for centralized storage and management of experimental and computed model data and its capabilities were extended over the years using tools such as ModelBuilder combined with Python scripting to automate repetitive tasks, perform statistical analyses and generate maps and reports. The hydrologic geo-database model developed possesses a structure that enables linkage with scalable hydrologic modeling tools/applications to model hydrologic systems, and in this case, enables the testing of the potential impacts of various remediation scenarios on the ORR watersheds. The ArcSDE geo-database can also be used to automate and simplify the process of calling stored GIS and time series data. This geo-database can serve as a tool for contaminant flow and transport analyses which require large amounts of high-quality spatial and temporal data in order to ensure reliability and validity of modeling results. The existing geo-database structure developed for the hydrological modeling at ORR was designed to be replicable for application at other DOE sites. An investigation of downloadable free/open source GIS software along with required security protocols to facilitate online querying of the database was also conducted to determine methods by which project-derived data can be more easily shared with other project stakeholders such as DOE personnel and site contractors. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Stellar and gaseous nuclear disks observed in nearby (U)LIRGs

We present near-infrared integral field spectroscopy of the central kiloparsec of 17 nearby luminous and ultra-luminous infrared galaxies undergoing major mergers. These observations were taken with OSIRIS assisted by the Keck I and II Adaptive Optics systems, providing spatial resolutions of a few tens of parsecs. The resulting kinematic maps reveal gas disks in at least 16 out of 19 nuclei and stellar disks in 11 out of 11 nuclei observed in these galaxy merger systems. In our late-stages mergers, these disks are young (stellar ages <30 Myr) and likely formed as gas disks that became unstable to star formation during the merger. On average, these disks have effective radii of a few hundred parsecs, masses between 10{sup 8} and 10{sup 10} M {sub ☉}, and v/σ between 1 and 5. These disks are similar to those created in high-resolution hydrodynamical simulations of gas-rich galaxy mergers, and favor short coalescence times for binary black holes. The few galaxies in our sample in earlier stages of mergers have disks that are larger (r {sub eff} ∼ 200-1800 pc) and are likely remnants of the galactic disks that have not yet been completely disrupted by the merger.

79 ASTRONOMY AND ASTROPHYSICS↗

Self-absorption correction on 2D X-ray fluorescence maps

Abstract X-ray fluorescence mapping (XRF) is a highly efficient and non-invasive technique for quantifying material composition with micro and nanoscale spatial resolutions. Quantitative XRF analysis, however, confronts challenges from the long-lasting problem called self-absorption. Moreover, correcting two-dimensional XRF mapping datasets is particularly difficult because it is an ill-posed inverse problem. Here we report a semi-empirical method that can effectively correct 2D XRF mapping data. The correction error is generally less than 10% from a comprehensive evaluation of the accuracy in various configurations. The proposed method was applied to quantify the composition distribution around the grain boundaries in an electrochemically corroded stainless steel sample. Highly localized Cr enrichment was found around the crack sites, which was invisible before the absorption correction.

36 MATERIALS SCIENCE↗

INTERPRETING THE SUBTLE SPECTRAL VARIATIONS OF THE 11.2 AND 12.7 μ m POLYCYCLIC AROMATIC HYDROCARBON BANDS

We report new properties of the 11 and 12.7 μ m emission complexes of polycyclic aromatic hydrocarbons (PAHs) by applying a Gaussian-based decomposition technique. Using high-resolution Spitzer Space Telescope data, we study in detail the spectral and spatial characteristics of the 11 and 12.7 μ m emission bands in maps of reflection nebulae NGC 7023 and NGC 2023 (north and south) and the star-forming region M17. Profile variations are observed in both the 11 and 12.7 μ m emission bands. We identify a neutral contribution to the traditional 11.0 μ m PAH band and a cationic contribution to the traditional 11.2 μ m band, the latter of which affects the PAH class of the 11.2 μ m emission in our sample. The peak variations of the 12.7 μ m complex are explained by the competition between two underlying blended components. The spatial distributions of these components link them to cations and neutrals. We conclude that the 12.7 μ m emission originates in both neutral and cationic PAHs, lending support to the use of the 12.7/11.2 intensity ratio as a charge proxy.

79 ASTRONOMY AND ASTROPHYSICS↗

Paradise: A Parallel Information System for EOSDIS

The Paradise project was begun-in 1993 in order to explore the application of the parallel and object-oriented database system technology developed as a part of the Gamma, Exodus. and Shore projects to the design and development of a scaleable, geo-spatial database system for storing both massive spatial and satellite image data sets. Paradise is based on an object-relational data model. In addition to the standard attribute types such as integers, floats, strings and time, Paradise also provides a set of and multimedia data types, designed to facilitate the storage and querying of complex spatial and multimedia data sets. An individual tuple can contain any combination of this rich set of data types. For example, in the EOSDIS context, a tuple might mix terrain and map data for an area along with the latest satellite weather photo of the area. The use of a geo-spatial metaphor simplifies the task of fusing disparate forms of data from multiple data sources including text, image, map, and video data sets.

DeWitt, David↗

Modeling Methods for 3D Lightning Mapping from Space

Global lightning detection has advanced greatly over the past few decades both on ground and from orbit. Ground-based systems like the Lightning Mapping Array (LMA) excel at high-precision 3D reconstruction of local flashes, while spaceborne lightning sensors have much larger potential coverage but are limited by coarser resolution and often rely on data from other instruments to determine 3D flash locations. CubeSpark is a new mission concept focused on combining these two methods in the form of six small satellites in low-Earth orbit. CubeSpark will combine RF and bispectral optical measurements of lightning in order to map the 3D structure of both individual flashes and their parent thunderstorms at 1-2 km spatial resolution on a global scale, enabling a host of new atmospheric, climate, and space electricity studies. The goal of this study is to assess the feasibility and expected resolution of lightning mapping via indivudal VHF sources using different methods and detector combinations. Flashes were simulated beneath orbital configurations consisting of 1-6 satellites, taking into account the complicated interactions with Earth's ionosphere. In the multi-satellite (>5) approach, RF detectors on each satellite measure the arrival times of impulsive VHF sources to collectively pinpoint their locations in 3D and reconstruct flashes with higher resolution than has been achieved from space. The same can process can be performed with 3-4 satellites by constraining sources' horizontal locations with onboard optical imagers. A 1-2 station approach follows the established method of determining the height of an RF source using the arrival time difference between direct RF waves and their reflections off the Earth's surface. Here we present preliminary results of the expected accuracy of these methods to inform potential satellite missions like CubeSpark.

Lightning↗

Synergistic Use of SMAP and OCO-2 Data in Assessing the Responses of Ecosystem Productivity to the 2018 U.S. Drought

Soil moisture and gross primary productivity (GPP) estimates from the Soil Moisture Active Passive (SMAP) and solar-induced chlorophyll fluorescence (SIF) from the Orbiting Carbon Observatory-2 (OCO-2) provide new opportunities for understanding the relationship between soil moisture and terrestrial photosynthesis over large regions. Here we explored the potential of the synergistic use of SMAP and OCO-2 based data for monitoring the responses of ecosystem productivity to drought. We used complementary observational information on root-zone soil moisture and GPP (9 km) from SMAP and fine-resolution SIF (0.05°; GOSIF) derived from OCO-2 SIF soundings. We compared the spatial pattern and temporal evolution of anomalies of these variables over the conterminous U.S. during the 2018 drought, and examined to what extent they could characterize the drought-induced variations of flux tower GPP and crop yield data. Our results showed that SMAP GPP and GOSIF could well capture the spatial extent and dynamics of drought indicated by the U.S. Drought Monitor maps and the SMAP root-zone soil moisture deficit. Over the U.S. Southwest, monthly anomalies of soil moisture showed significant positive correlations with those of SMAP GPP (R2=0.44, p<0.001) and GOSIF (R2=0.76, p<0.001), demonstrating strong water availability constraints on plant productivity across dryland ecosystems. We further found that SMAP GPP and GOSIF captured the impact of drought on tower GPP and crop yield. Our results suggest that synergistic use of SMAP and OCO-2 data products can reveal the drought evolution and its impact on ecosystem productivity and carbon uptake at multiple spatial and temporal scales, and demonstrate the value of SMAP and OCO-2 for studying ecosystem function, carbon cycling, and climate change.

Soil Moisture Active Passive↗

Snow-Cover Variability in North America in the 2000-2001 Winter as Determined from MODIS Snow Products

Moderate Resolution Imaging Spectroradiometer (MODIS) snow-cover maps have been available since September 13, 2000. These products, at 500-m spatial resolution, are available through the National Snow and Ice Data Center Distributed Active Archive Center in Boulder, Colorado. By the 2001-02 winter, 5-km climate-modeling grid (CMG) products will be available for presentation of global views of snow cover and for use in climate models. All MODIS snow-cover products are produced from automated algorithms that map snow in an objective manner. In this paper, we describe the MODIS snow products, and show snow maps from the fall of 2000 in North America.

Hall, Dorothy K.↗

Snow-Cover Variability in North America in the 2000-2001 Winter as Determined from MODIS Snow Products

Moderate Resolution Imaging Spectroradiometer (MODIS) snow-cover maps have been available since September 13, 2000. These products, at 500 m spatial resolution, are available through the National Snow and Ice Data Center Distributed Active Archive Center in Boulder, Colorado. By the 2001-02 winter, 5 km climate-modeling grid (CMG) products will be available for presentation of global views of snow cover and for use in climate models. All MODIS snow-cover products are produced from automated algorithms that map snow in an objective manner. In this paper, we describe the MODIS snow products, and show snow maps from the fall of 2000 in North America.

Hall, Dorothy K.↗

Robust Technique for Measuring and Simulating Silicon Wafer Quality Characteristics that Enable the Prediction of Solar Cell Electrical Performance of MEMC Silicon Wafer. Cooperative Research and Development Final Report, CRADA Number CRD-11-438

NREL and MEMC Electronic Materials are interested in developing a robust technique for monitoring material quality of mc-Si and mono-Si wafers -- a technique that can provide relevant data to accurately predict the performance of solar cells fabricated on them. Previous work, performed under two TSAs between NREL and MEMC, has established that dislocation clusters are the dominant performance-limiting factor in MEMC mc-Si solar cells. The work under this CRADA will go further in verifying these results on a larger data set, evaluate possibilities of faster method(s) for mapping dislocations in wafers/ingots, understanding dislocation generation during ingot casting, and helping MEMC to have an internal capability for basic characterization that will provide feedback needed for more accurate crystallization simulations. NREL has already developed dislocation mapping technique and developed a basic electronic model (called Network Model) that uses spatial distribution of dislocations to predict the cell performance. In this CRADA work, we will use these techniques to: (i) establish dislocation, grain size, and grain orientation distributions of the entire ingots (through appropriate DOE) and compare these with theoretical models developed by MEMC, (ii) determine concentrations of some relevant impurities in selected wafers, (iii) evaluate potential of using photoluminescence for dislocation mapping and identification of recombination centers, (iv) evaluate use of diode array analysis as a detailed characterization tool, and (v) establish dislocation mapping as a wafer-quality monitoring tool for commercial mc-Si production.

14 SOLAR ENERGY↗

Non-Destructive Study of Bulk Crystallinity and Elemental Composition of Natural Gold Single Crystal Samples by Energy-Resolved Neutron Imaging

Energy-resolved neutron imaging enables non-destructive analyses of bulk structure and elemental composition, which can be resolved with high spatial resolution at bright pulsed spallation neutron sources due to recent developments and improvements of neutron counting detectors. This technique, suitable for many applications, is demonstrated here with a specific study of ~5–10mm thick natural gold samples. Through the analysis of neutron absorption resonances the spatial distribution of palladium (with average elemental concentration of ~0.4 atom% and ~5 atom%) is mapped within the gold samples. At the same time, the analysis of coherent neutron scattering in the thermal and cold energy regimes reveals which samples have a single-crystalline bulk structure through the entire sample volume. A spatially resolved analysis is possible because neutron transmission spectra are measured simultaneously on each detector pixel in the epithermal, thermal and cold energy ranges. With a pixel size of 55μm and a detector-area of 512 by 512 pixels, a total of 262,144 neutron transmission spectra are measured concurrently. The results of our experiments indicate that high resolution energy-resolved neutron imaging is a very attractive analytical technique in cases where other conventional nondestructive methods are ineffective due to sample opacity.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗