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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,747 records · Page 97
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Magnetic and Dielectric Properties of Y{sub 3−x}Sm{sub x}Fe{sub 5}O{sub 12} (x = 0.0 to 3.0)

Single-phase polycrystalline samples of Y{sub 3−x}Sm{sub x}Fe{sub 5}O{sub 12} (x = 0.0–3.0) were prepared by using a solid-state reaction method. The lattice constant is found to increase from 12.372 Å for x = 0.0 to 12.524 Å for x=3.0. The substitution of Sm{sup 3+} at Y{sup 3+} site is confirmed from the red shift of Raman F{sub 2g} mode. Magnetization loops measured at room temperature and the analysis of initial magnetization curves show that saturation magnetization value decreases with an increase in Sm concentration due to the possible antiferromagnetic interaction. On the other hand, temperature variation of magnetization plots shows that all the samples exhibit ferrimagnetic transition with transition temperature in the range of 550 K for x = 0.0 to 573 K for x=3.0. The dielectric constant increases upon Sm substitution, and the analysis of impedance and dielectric spectra shows the contribution of both grains and grain boundaries.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1997

Solar-System Tests of Gravitational Theories

We are engaged in testing gravitational theory by means of observations of objects in the solar system. These tests include an examination of the Principle Of Equivalence (POE), the Shapiro delay, the advances of planetary perihelia, the possibility of a secular variation G in the "gravitational constant" G, and the rate of the de Sitter (geodetic) precession of the Earth-Moon system. These results are consistent with our preliminary results focusing on the contribution of Lunar Laser Ranging (LLR), which were presented at the seventh Marcel Grossmann meeting on general relativity. The largest improvement over previous results comes in the uncertainty for (eta): a factor of five better than our previous value. This improvement reflects the increasing strength of the LLR data. A similar analysis presented at the same meeting by a group at the Jet Propulsion Laboratory gave a similar result for (eta). Our value for (beta) represents our first such result determined simultaneously with the solar quadrupole moment from the dynamical data set. These results are being prepared for publication. We have shown how positions determined from different planetary ephemerides can be compared and how the combination of VLBI and pulse timing information can yield a direct tie between planetary and radio frames. We have continued to include new data in our analysis as they became available. Finally, we have made improvement in our analysis software (PEP) and ported it to a network of modern workstations from its former home on a "mainframe" computer.

Shapiro, Irwin↗
DOE OSTI2017

The frequency-dependent response of single aerosol particles to vapour phase oscillations and its application in measuring diffusion coefficients

A new method for measuring diffusion in the condensed phase of single aerosol particles is proposed and demonstrated. The technique is based on the frequency-dependent response of a binary particle to oscillations in the vapour phase of one of its chemical components. Here, we discuss how this physical situation allows for what would typically be a non-linear boundary value problem to be approximately reduced to a linear boundary value problem. For the case of aqueous aerosol particles, we investigate the accuracy of the closed-form analytical solution to this linear problem through a comparison with the numerical solution of the full problem. Then, using experimentally measured whispering gallery modes to track the frequency-dependent response of aqueous particles to relative humidity oscillations, we determine diffusion coefficients as a function of water activity. The measured diffusion coefficients are compared to previously reported values found using the two common experiments: (i) the analysis of the sorption/desorption of water from a particle after a step-wise change to the surrounding relative humidity and (ii) the isotopic exchange of water between a particle and the vapour phase. The technique presented here has two main strengths: first, when compared to the sorption/desorption experiment, it does not require the numerical evaluation of a boundary value problem during the fitting process as a closed-form expression is available. Second, when compared to the isotope exchange experiment, it does not require the use of labeled molecules. Therefore, the frequency-dependent experiment retains the advantages of these two commonly used methods but does not suffer from their drawbacks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

KEPLER MISSION STELLAR AND INSTRUMENT NOISE PROPERTIES REVISITED

An earlier study of the Kepler Mission noise properties on timescales of primary relevance to detection of exoplanet transits found that higher than expected noise followed, to a large extent, from the stars rather than instrument or data analysis performance. The earlier study over the first six quarters of Kepler data is extended to the full four years ultimately comprising the mission. Efforts to improve the pipeline data analysis have been successful in reducing noise levels modestly as evidenced by smaller values derived from the current data products. The new analyses of noise properties on transit timescales show significant changes in the component attributed to instrument and data analysis, with essentially no change in the inferred stellar noise. We also extend the analyses to timescales of several days, instead of several hours to better sample stellar noise that follows from magnetic activity. On the longer timescale there is a shift in stellar noise for solar-type stars to smaller values in comparison to solar values.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Numerical Analysis of Wave Characteristics in a Methane-Oxygen Rotating Detonation Engine

Results from the simulation of the U.S. Air Force Research Laboratory methane–oxygen rotating detonation rocket engine from four independent research groups with different flow solvers underpredicted primary detonation wave speeds by a significant margin as compared to experimental values. In a simulation performed by the authors, the average calculated speed of the detonation waves was roughly [Formula: see text] as compared to the experimentally measured value of [Formula: see text]. This paper presents a detailed analysis of the wave characteristics in this simulation to provide a more quantitative understanding of the underlying factors leading to this discrepancy. The results show that weaker counter-rotating shock waves have a significant impact on the behavior of the primary detonation waves. The wave speed of the primary detonation wave is reduced by [Formula: see text] due to collisions with the counter-rotating waves. The presence of these counter-rotating waves also has a strong influence on the flow conditions upstream of the primary detonation waves, as well as the engine heat release rate. In addition, the flow properties upstream of the detonation wave vary significantly in the radial direction. Finally, the subfilter turbulent viscosity is shown to vary radially and with proximity to detonation waves.

Engineering↗
DOE OSTI2020

Analysis of several high-resolution infrared bands of perdeutero-spiropentane, C5D8

Perdeutero-spiropentane (C5D8) has been synthesized and infrared spectra were taken from 400 to 4000 cm-1 at low sample pressures in a 22 meter multipass cell. The spectral resolution (0.0015 cm-1) reveals thousands of individual rovibrational transitions for several fundamental bands occurring in the spectral region of 500 to 1100 cm-1. C5D8 ground state constants reported in a previous study of a ?15 parallel band at 1054 cm-1 [1] were improved significantly in the present work by adding combination-differences derived from ?16 parallel and ?24 perpendicular band analyses. The larger data set at higher J values also allowed determination of the ground state K? = 2 splitting constant (?2? = 0.76(2) ×10-9 cm-1). For ?16, the band origin is 847.16933(5) cm-1 and changes in upper state rotational constants are ?A = –0.0013411(5) and ?B = –0.0002021(1) (in units of cm-1). Overlapping, and in Fermi resonance with ?16, is a second parallel band which, from Gaussian calculations at the anharmonic level, is assigned as the b2 combination ?8+?12, with band origin of 840.5434(1) and ?A = –0.0003500(7) and ?B = –0.0003502(1) cm-1. For ?24 analogous values are 556.41453(2) and ?A = –0.00032295(9) and ?B = –0.00016782(4) cm-1. The analyses also yields accurate values for the changes in both quartic and sextic centrifugal distortion constants and, for ?24, values for the l-doubling constants q+ and q-. Theoretical calculations of the rovibrational parameters aided in the analysis and the numerical values are in good agreement with experimental results.

Nibler, Joseph W.↗
NASA NTRS2005

Wavelengths, f-Values, and Cross Sections in the UV Spectra of Astrophysical, Atoms, Ions, and Molecules

Data analysis for Fe III was completed in 2004. The new spectra give wavelengths and some energy levels for Fe III that are at least an order of magnitude more accurate than values in the literature. However, the data set is missing - because they are outside the wavelength range that we can study at Imperial College or with ancillary FT spectroscopy measurements at NIST - important transitions that would allow all energy levels to be determined with improved accuracy. We are assessing collaborations at other labs. We have made test runs with a number of cathodes (pure metals and alloys) in the Penning discharge source and selected four iron group (3d) elements, Cr, Mn, Co, and Ni, for further measurements. Cathodes of pure Cr and Co and an alloy of Ni were found to be best. Mn has not nm stably yet, and other cathode geometries or alloys may need to be assessed. Optimum Penning discharge (PD) lamp conditions (buffer gas, gas pressure, and current/voltage) were established for Co, and investigations are underway for Cr and Ni. Definitive measurements for Co await purchase of new mirrors and photomultiplier tubes that will improve signal to noise ratio. Our plan for the next year is to continue evaluating cathodes and operating conditions through March 05, and then to begin definitive measurements. The UV wavelength measurements made at Imperial College with the unique UV FT spectrometer will be complemented by visible and near IR range measurements at NIST in June and/or July. Approximately one year from now, we intend to visit Lund University to collaborate on lifetime measurements that will allow our branching ration data to be used to determine f-values.

Raymond, John C.↗
DOE OSTI2016

Influence of protective actions on ingress-water mass in steam generator tube rupture of HTGR - 18479

Steam generator tube rupture(SGTR) accident is one characteristic accident of High Temperature Gas-Cooled Reactor (HTGR), which may cause a potential hazard to reactor system. Because the amount of water ingress into reactor core is related closely to the severity of the accident, the research on water-ingress is significant for the evaluation on inherent safety characteristics of HTGR. Both different accident scenario and the system design will have influence on the amount of the ingress-water under SGTR. In this paper, a pebble-bed high temperature gas cooled reactor is modeled by thermal-hydraulic system analysis code and the water-ingress transient under SGTR is simulated to study the influence of the protective action of emergency shutdown on the water ingress. The research indicates that the protective action has no obvious influence on the amount of the ingress-water within the current studied range. The amount of ingress-water is controlled below the design value to satisfy the demand of reactor safety. The analysis results will provide some support for the HTGR research. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2022

SCALE modeling of foil irradiations at WSU’s TRIGA with sensitivity/uncertainty analysis

We report the Washington State University TRIGA reactor was modeled in the SCALE system’s KENO neutron transport code. The model includes 119 fuel rods, a central boral control rod, 4 control blades, 5 irradiation ports, and 20 graphite reflector blocks within a rectangular aluminum grid box. The model accurately simulated the irradiation of depleted uranium and highly enriched uranium foils and predicted reaction rate ratios for 238 U(n,2n) 237 U / 238 U(n,γ) 239 U and 99 Mo / fission, which compared favorably to empirical values previously measured at Los Alamos. Finally, a sensitivity/uncertainty analysis was performed using the continuous-energy TSUNAMI-3D module of SCALE.

237Np↗
DOE OSTI2018

Effect of initial orientation on dynamic recrystallization of a zirconium alloy during hot deformation

Highlights: • The dynamic recrystallization process is enhanced by the operation of slip. • Continuous dynamic recrystallization is promoted by the rotation of grains. • Texture induced hardening hides the softening induced by dynamic recrystallization. - Abstract: The present study investigated the influence of the initial orientation on the dynamic recrystallization (DRX) behavior of a Zr-1Sn-0.3Nb alloy. A hot-rolled and annealed Zr sheet was compressed along two directions: along the normal direction so that the grains' -axis was nearly parallel to the loading direction (0° sample) and along the transverse direction so that the grains' -axis was nearly perpendicular to the loading direction (90° sample). The samples were compressed at 700 °C at a strain rate of 1 s{sup −1}. The microstructures at different strains were characterized by the electron backscatter diffraction (EBSD) technique, and conventional dislocation analysis using transmission electron microscope (TEM) was performed. A threshold value of grain orientation spread (GOS) equaled to 5° was used to distinguish the dynamically recrystallized grains from the deformed matrix. The results revealed that the DRX behavior strongly depended on the initial orientation. The Schmid factor analysis and TEM observation confirmed that pyramidal slip operated from the first stage of deformation in the 0° sample but not in the 90° sample. For the 0° sample, in the early and medium stages of deformation, due to the high stored energy caused by the operation of pyramidal slip, DDRX was mainly contributed to the formation of new fine grains. However, in the later stage of deformation, the DRX mechanism changed from DDRX to CDRX. In the 90° sample, although DDRX featured by grain boundary bulging occurred, the main DRX mechanism was CDRX in the whole deformation processing. Moreover, texture induced hardening in the early stage of deformation hides the softening induced by DDRX.

36 MATERIALS SCIENCE↗
NASA NTRS1990

Optimal design of control systems for prevention of aircraft flight departure

Control system design for general nonlinear flight dynamic models is considered through numerical simulation. The design is accomplished through a numerical optimizer coupled with analysis of flight dynamic equations. In the analysis, the general nonlinear flight dynamic equations with nonlinear aerodynamics are numerically integrated; and the dynamic characteristics needed in the optimization process are then identified from the dynamic response. To assure a reasonable solution, the initial input values of the design variables are estimated through a sensitivity analysis. To demonstrate the method, the pitch departure prevention for an F-16 configuration is demonstrated.

Lan, C. Edward↗
NASA NTRS2000

Analysis of the NASA White Sands Test Facility (WSTF) Test System for Friction-Ignition of Metallic Materials

Friction is a known ignition source for metals in oxygen-enriched atmospheres. The test system developed by the NASA White Sands Test Facility in response to ASTM G-94 has been used successfully to determine the relative ignition from friction of numerous metallic materials and metallic materials pairs. These results have been ranked in terms of a pressure-velocity product (PV) as measured under the prescribed test conditions. A high value of 4.1(exp 8) watts per square meter for Inconel MA 754 is used to imply resistance to friction ignition, whereas a low value of 1.04(exp 8) watts per square meter for stainless steel 304 is taken as indicating material susceptible to friction ignition. No attempt has been made to relate PV values to other material properties. This work reports the analysis of the WSTF friction-ignition test system for producing fundamental properties of metallic materials relating to ignition through friction. Three materials, aluminum, titanium, and nickel were tested in the WSTF frictional ignition instrument system under atmospheres of oxygen or nitrogen. Test conditions were modified to reach a steady state of operation, that is applied, the force was reduced and the rotational speed was reduced. Additional temperature measurements were made on the stator sample. The aluminum immediately galled on contact (reproducible) and the test was stopped. Titanium immediately ignited as a result of non-uniform contact of the stator and rotor. This was reproducible. A portion of the stator sampled burned, but the test continued. Temperature measurements on the stator were used to validate the mathematical model used for estimating the interface (stator/rotor) temperature. These interface temperature measurements and the associate thermal flux into the stator were used to distinguish material-phase transitions, chemical reaction, and mechanical work. The mechanical work was used to analyze surface asperities in the materials and to estimate a coefficient of fiction. The coefficient of fiction was analyzed in terms of material properties that is, hardness, Young's modulus and elasticity/plasticity of the material.

Shoffstall, Michael S.↗
NASA NTRS2009

New Flutter Analysis Technique for CFD-based Unsteady Aeroelasticity

This paper presents a flutter analysis technique for the transonic flight regime. The technique uses an iterative approach to determine the critical dynamic pressure for a given mach number. Unlike other CFD-based flutter analysis methods, each iteration solves for the critical dynamic pressure and uses this value in subsequent iterations until the value converges. This process reduces the iterations required to determine the critical dynamic pressure. To improve the accuracy of the analysis, the technique employs a known structural model, leaving only the aerodynamic model as the unknown. The aerodynamic model is estimated using unsteady aeroelastic CFD analysis combined with a parameter estimation routine. The technique executes as follows. The known structural model is represented as a finite element model. Modal analysis determines the frequencies and mode shapes for the structural model. At a given mach number and dynamic pressure, the unsteady CFD analysis is performed. The output time history of the surface pressure is converted to a nodal aerodynamic force vector. The forces are then normalized by the given dynamic pressure. A multi-input multi-output parameter estimation software, ERA, estimates the aerodynamic model through the use of time histories of nodal aerodynamic forces and structural deformations. The critical dynamic pressure is then calculated using the known structural model and the estimated aerodynamic model. This output is used as the dynamic pressure in subsequent iterations until the critical dynamic pressure is determined. This technique is demonstrated on the Aerostructures Test Wing-2 model at NASA's Dryden Flight Research Center.

Pak, Chan-gi↗
NASA NTRS1976

The passage of a distorted velocity field through a cascade of airfoils

An analysis has been developed to predict the unsteady force and moment generated by the passage of a timewise periodic total pressure distortion through an arbitrary cascade of airfoils. The mathematical formulation of this analysis is based on the assumption that the magnitudes of the timewise fluctuations of the variables which describe the flow field are small compared to their time average values. This assumption permits the development of a linear unsteady perturbation analysis about a steady flow field. In addition to this linearization assumption the fluid medium is assumed to be incompressible and inviscid. The mathematical development begins by decomposing the velocity field surrounding an infinite cascade of airfoils into its irrotational and rotational components. The rotational component is associated with an upstream unsteady total pressure distortion and is defined in terms of the vorticity field associated with the distortion pattern. The irrotational component is further decomposed into a steady and unsteady part. A combined analytical and numerical procedure has been developed to solve the field equations which govern the rotational and irrotational velocity fields. Results of this analysis show a strong influence of mean loading on the unsteady force generated by the passage of a one dimensional gust through a cascade of compressor blades.

Adamczyk, J. J.↗
NASA NTRS1986

Cosmic rays near the heliospheric current sheet. II - An ensemble approach to comparing theory and observation

A quantitative comparison is carried out between theoretical predictions and observations of the intensity of galactic cosmic rays near the interplanetary current sheet. Model calculations are compared with a statistical analysis of observations of galactic cosmic rays at the earth and the simultaneous position of the current sheet. Since the observations were made over a period of several years, the inclination of the current sheet varied considerably, and comparison with any one model calculation referring to a given inclination would not be appropriate. An ensemble of different current sheet inclinations are used to generate expected values with the model in order to make the analysis of the computations approximate the method used to analyze the data. Agreement is found between theory and observation at energies of the order of a few GeV.

Jokipii, J. R.↗
DOE OSTI2021

Big Adaptive Rotor Phase I (Final Report)

The Big Adaptive Rotor (BAR) project was initiate by DOE in 2018 with the goal of identifying novel technologies that can enable large (>100m) blades for low specific power (SP) turbines. Five distinct tasks were completed to achieve this goal: 1. Assess trends, impacts, and value of low-SP turbines, 2. Wind turbine blade cost reduction roadmap study, 3. Research and Development (R&D) opportunity screening, 4. Detailed design and analysis, and 5. Low-cost carbon fiber. These tasks were completed by the national lab team consisting of Sandia National Laboratories (SNL), the National Renewable Energy Laboratory (NREL), and Lawrence Berkeley National Laboratory (LBNL). The objective of Task 1 was to assess the historical trends of low-SP of onshore deployments, and to assess the impact and value of low-SP turbines. Analysis under this task showed that there is significant value for low-SP turbines, especially in markets where there is a higher saturation of wind energy on the grid. This has to do with the fact that low-SP turbines have increased capacity factors, and can contribute more reliable energy to the grid, even in lower wind conditions. This bodes well as higher renewable scenarios are likely in the coming years. Task 2 was a detailed analysis on the logistical challenges of deploying very large (>100m) onshore blade. This work was completed by experts at DNV-GL. The report looked at various ways to get around the current transportation constraints which are estimated to be around 75m in length. The report concluded that there are viable solutions to this issue including: segmented blades (which the industry is already pursuing), lighter than air (LTA) transportation, on-site manufacturing, and controlled bending of blades on rail. The final option was recommended for further analysis and study by DOE and the national labs because keeping a single piece blade reduces manufacturing and operations and maintenance (O&M) costs. Task 3 focused on identifying novel concepts that are capable of enabling a cost effective 5MW 206m rotor for onshore deployment. The findings from the first two tasks were considered in the analysis, in that the concepts identified must be able to overcome the transportation logistics challenges. Around 20 concepts were identified and evaluated by experts within the industry. Additionally, science and engineering challenges were identified for each concept. Based on these evaluations six concepts were deemed the most impactful and were selected for further analysis in Task 4. The concepts were: highly flexible rail transportable blades, downwind rotors, distributed aerodynamic control (DAC) devices, inflatable blade, bi-wing blade, and 4/5 bladed rotors. Task 4 conducted detailed design, optimization, and analysis on the selected BAR concepts. A modeling gaps analysis was conducted, and modeling improvements were implemented that allowed for the study and design of the novel concepts. The BAR team established a set of baseline designs by which to compare the selected designs through a technoeconomic analysis. It was found that the highly flexible rail transportable blade, the downwind rotor, and the DAC devices have the most promise to deliver the BAR targets. A Phase II for BAR has been proposed to further mature these concepts and address the open science and engineering challenges identified in Task 3. Task 5 conducted research on optimized carbon fiber materials that were used throughout the BAR Phase I project. Overall, the BAR project has identified low-SP turbines as important to continued LCOE reductions for onshore turbines. Furthermore, the project has identified viable solutions to the technical and logistical challenges to realizing these goals. The most promising technologies that were identified in Phase I of the project will be further matured and de-risked in Phase II of the BAR project.

17 WIND ENERGY↗
NASA NTRS1951

Combustion Instability in an Acid-Heptane Rocket with a Pressurized-Gas Propellant Pumping System

Results of experimental measurements of low-frequency combustion instability of a 300-pound thrust acid-heptane rocket engine were compared to the trends predicted by an analysis of combustion instability in a rocket engine with a pressurized-gas propellant pumping system. The simplified analysis, which assumes a monopropellant model, was based on the concept of a combustion the delay occurring from the moment of propellant injection to the moment of propellant combustion. This combustion time delay was experimentally measured; the experimental values were of approximately half the magnitude predicted by the analysis. The pressure-fluctuation frequency for a rocket engine with a characteristic length of 100 inches and operated at a combustion-chamber pressure of 280 pounds per square inch absolute was 38 cycles per second; the analysis indicated. a frequency of 37 cycles per second. Increasing combustion-chamber characteristic length decreased the pressure-fluctuation frequency, in conformity to the analysis. Increasing the chamber operating pressure or increasing the injector pressure drop increased the frequency. These latter two effects are contrary to the analysis; the discrepancies are attributed to the conflict between the assumptions made to simplify the analysis and the experimental conditions. Oxidant-fuel ratio had no apparent effect on the experimentally measured pressure-fluctuation frequency for acid-heptane ratios from 3.0 to 7.0. The frequencies decreased with increased amplitude of the combustion-chamber pressure variations. The analysis indicated that if the combustion time delay were sufficiently short, low-frequency combustion instability would be eliminated.

Tischler, Adelbert O.↗
DOE OSTI2025

Coal to Carbon Fiber (C2CF) Continuous Processing for High Value Composites (Final Report)

Coal tar is a condensed and recovered by-product of the coking of metallurgical coal for steel production. The heaviest fraction of distilled coal tar is an isotropic pitch largely used as a binder in the manufacturing of carbonaceous electrodes for primary aluminum smelting and in electric arc furnaces. Coal tar pitch offers high carbon yield upon carbonization. In this project, a process to convert the domestically sourced isotropic coal tar pitch, containing very low particulates (QI = 0.32 wt.%), to form flow-domain mesophase pitch amenable for melt spinning into precursor (green) fibers for carbon fiber, was developed and optimized. The final reproducible processing developed is reviewed in this report, along with several characterizations of the mesophase pitch. A final definition of the characteristics of a ‘spinnable’ mesophase pitch is presented. With this mesophase pitch, reproducible and stable multifilament melt spinning was developed, producing green fiber tows with filament diameters of approximately 20 m. The multifilament melt spinning was the most challenging aspect of the project and required the most effort. The best practices learned from this project for melt spinning are reviewed in this report. Once spun, the green fibers were oxidatively stabilized, carbonized and graphitized under inert gas atmosphere to form the final carbon fibers. Given the relatively high softening point of the mesophase pitch, no issues of interfilament fusion were observed during batch oxidation, and subsequent batch carbonization and graphitization went smoothly in all cases. An ~ 80 wt.% conversion of the green fiber mass to final carbon fiber was achieved. After graphitization, the carbon fibers showed high tensile moduli (most were ~ 600 GPa, or 87 Msi) consistent with commercially-available high-performance pitch-based carbon fiber. However, tensile strength and strain to failure were comparatively low. Further work to reduce defects in and on the fiber surfaces would increase these properties. SEM imaging of the graphitic fiber textures is presented herein. Rudimentary composites were fabricated from the carbon fibers and characterized showing similar modulus to baseline composites fabricated with commercial carbon fiber. Finally, a basic economic analysis was done showing the potential to increase the value of the isotropic coal tar pitch by up to 13.6 to 136 times based on a carbon fiber value of $\$$5/lb to $\$$50/lb, respectively. Moreover, the site case study suggests that the coal tar from the single integrated steel mill could supply production of up to 16 kt/yr of carbon fiber. Finally, a technological gap analysis was done which shed light on remaining technical challenges. These challenges included: recovery and utilization of condensates from the mesophase pitch processing, further advancing and increasing stability of the multifilament melt spinning processing, optimization of the oxidation processing, defect reduction for increased carbon fiber strength, and the development of a weaving process towards carbon fiber fabrics. To maximize the coal value chain, the primary objectives of this project were to (a) develop and scale efficient processing technology for producing melt-spinnable mesophase pitch from isotropic coal tar pitch, (b) clarify and simplify tedious continuous fiber processing technologies (particularly multifilament melt spinning of mesophase pitch) towards the efficient production of high performance carbon fiber, and (c) demonstrate and characterize representative composite parts derived from the final carbon fiber. Immense progress was made on all 3 objectives and is detailed in this report.

01 COAL, LIGNITE, AND PEAT↗