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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,765 records · Page 98
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Revisiting the role of Zr doping in Ni-rich layered cathodes for lithium-ion batteries

We report the realization of high performance Ni-rich layered cathodes remains a challenge because of the multiple degradation factors that concurrently operate during battery cycling. In particular, depletion of oxygen charge and consequent lattice oxygen instability at deep charge state accelerate the subsequent chemomechanical degradation mechanisms. Among the proposed methodologies, doping has proven to be effective in enhancing the cathode cycle life by stabilizing the layered structure. Herein, we achieved the electrochemically stabilized Ni-rich LiNi 0.92 Co 0.04 Mn 0.04 O 2 through Zr doping, resulting in a 15% increase of the capacity retention after 100 cycles. In-depth investigations are conducted to unveil the effects of Zr doping on the layered cathode, and in particular, the critical role of Zr doping on the lattice oxygen stability is systematically studied. By combining state-of-the-art magnetometer characterization, X-ray analysis, and first-principles calculation, we reveal that Zr doping positively contributes the to lattice oxygen stability by alleviating the oxygen charge loss at deep charge, thereby improving the cathode electrochemical reversibility. Our findings provide an insight into the Zr doping mechanism and help to design the Ni-rich layered oxides for future applications.

25 ENERGY STORAGE↗
DOE OSTI2012

Function of phloem-borne information macromolecules in integrating plant growth & development

Studies on higher plants have revealed the operation of cell-to-cell and long-distance communication networks that mediate the transport of information macromolecules, such as proteins and RNA. Based on the findings from this DOE-funded project and results from other groups, it is now well established that the enucleate sieve tube system of the angiosperms contains a complex set of proteins including RNA binding proteins as well as a unique population of RNA molecules, comprised of both mRNA and small RNA species. Hetero-grafting experiments demonstrated that delivery of such RNA molecules, into the scion, is highly correlated with changes in developmental phenotypes. Furthermore, over the course of this project, our studies showed that plasmodesmata and the phloem are intimately involved in the local and systemic spread of sequence-specific signals that underlie gene silencing in plants. Major advances were also made in elucidating the underlying mechanisms that operate to mediate the selective entry and exit of proteins and RNA into and out of the phloem translocation stream. Our pioneering studies identified the first plant protein with the capacity to both bind specifically to small RNA molecules (si-RNA) and mediate in the cell-to-cell movement of such siRNA. Importantly, studies conducted with support from this DOE program also yielded a detailed characterization of the first phloem-mobile RNP complex isolated from pumpkin, namely the CmRBP50-RNP complex. This RNP complex was shown to bind, in a sequence-specific manner, to a set of transcripts encoding for transcription factors. The remarkable stability of this CmRBP50-RNP complex allows for long-distance delivery of bound transcripts from mature leaves into developing tissues and organs. Knowledge gained from this project can be used to exert control over the long-distance signaling networks used by plants to integrate their physiological and developmental programs at a whole plant level. Eventually, this information will aid in the engineering of elite plant lines with optimal traits for plant growth under non-ideal conditions, enhanced biomass and/or seed yield, and directed carbon allocation for efficient and sustainable biofuels production.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS2004

Development and Evaluation of an Airborne Separation Assurance System for Autonomous Aircraft Operations

NASA Langley Research Center is developing an Autonomous Operations Planner (AOP) that functions as an Airborne Separation Assurance System for autonomous flight operations. This development effort supports NASA s Distributed Air-Ground Traffic Management (DAG-TM) operational concept, designed to significantly increase capacity of the national airspace system, while maintaining safety. Autonomous aircraft pilots use the AOP to maintain traffic separation from other autonomous aircraft and managed aircraft flying under today's Instrument Flight Rules, while maintaining traffic flow management constraints assigned by Air Traffic Service Providers. AOP is designed to facilitate eventual implementation through careful modeling of its operational environment, interfaces with other aircraft systems and data links, and conformance with established flight deck conventions and human factors guidelines. AOP uses currently available or anticipated data exchanged over modeled Arinc 429 data buses and an Automatic Dependent Surveillance Broadcast 1090 MHz link. It provides pilots with conflict detection, prevention, and resolution functions and works with the Flight Management System to maintain assigned traffic flow management constraints. The AOP design has been enhanced over the course of several experiments conducted at NASA Langley and is being prepared for an upcoming Joint Air/Ground Simulation with NASA Ames Research Center.

Barhydt, Richard↗
NASA NTRS2010

Large Scale Covariability in the Aerosol-SST-Precipitation Relation: A Satellite Perspective

Although large scale aerosol effects on precipitation have attracted increasing attention in recent years, significant uncertainties still remain in the current understanding of'such effects. One of the factors contributing to these uncertainties is the availability of aerosol data sets that are sufficiently long, stable, and comprehensive to be used for climate analysis. Such data sets are crucial for any long-term studies that are needed to demonstrate the statistical significance of large scale aerosol effects on precipitation when compared to the effects from other climate factors, such as remote or local sea surface temperature (SST) variability (ENSO. etc.). A longterm consistent aerosol product that complements the existing MODIS and AVHRR aerosol products is therefore needed to minimize aerosol data uncertainty issues for such Studies. The SeaWiFS instrument was primarily designed to measure ocean color, and it has been the mayor source for providing a comprehensive global data set of such measurements since its launch in 1997. Besides being used in this capacity, however, the well-calibrated set of radiances measured in the wavelength range from the visible (0.41 m) to the near infrared (0.87 m) is also well suited to creating long-term climate data records of aerosols. Recently, a new 13-year SeaWiFS aerosol optical depth dataset has been developed that expands its capacity to be used for such atmospheric studies. This SeaWiFS aerosol product provides us with an unprecedented opportunity to examine the covariability of aerosol, SST and precipitation on both a regional and global scale. We also use concurrent independent SST (NOAA Optimum Interpolation, OI, SST V2) and precipitation (GPCP V2) datasets for this study. We will present and discuss results from this study over several aerosol hot spot regions ( -,North Atlantic. South Atlantic, Western Pacific, Indian Ocean etc.) during the SeaWIFS data period (1997 -- current) from this study will be presented and discussed. These results will highlight the value and impact of this unique product to climate studies

Hsu, N. Christina↗
NASA NTRS2012

Quantum Limits of Space-to-Ground Optical Communications

For a pure loss channel, the ultimate capacity can be achieved with classical coherent states (i.e., ideal laser light): (1) Capacity-achieving receiver (measurement) is yet to be determined. (2) Heterodyne detection approaches the ultimate capacity at high mean photon numbers. (3) Photon-counting approaches the ultimate capacity at low mean photon numbers. A number of current technology limits drive the achievable performance of free-space communication links. Approaching fundamental limits in the bandwidth-limited regime: (1) Heterodyne detection with high-order coherent-state modulation approaches ultimate limits. SOA improvements to laser phase noise, adaptive optics systems for atmospheric transmission would help. (2) High-order intensity modulation and photon-counting can approach heterodyne detection within approximately a factor of 2. This may have advantages over coherent detection in the presence of turbulence. Approaching fundamental limits in the photon-limited regime (1) Low-duty cycle binary coherent-state modulation (OOK, PPM) approaches ultimate limits. SOA improvements to laser extinction ratio, receiver dark noise, jitter, and blocking would help. (2) In some link geometries (near field links) number-state transmission could improve over coherent-state transmission

laser communications↗
DOE OSTI2012

Studying Salmonellae and Yersiniae Host–Pathogen Interactions Using Integrated ‘Omics and Modeling

Salmonella and Yersinia are two distantly related genera containing species with wide host-range specificity and pathogenic capacity. The metabolic complexity of these organisms facilitates robust lifestyles both outside of and within animal hosts. Using a pathogen-centric systems biology approach, we are combining a multi-omics (transcriptomics, proteomics, metabolomics) strategy to define properties of these pathogens under a variety of conditions including those that mimic the environments encountered during pathogenesis. These high-dimensional omics datasets are being integrated in selected ways to improve genome annotations, discover novel virulence-related factors, and model growth under infectious states. We will review the evolving technological approaches toward understanding complex microbial life through multi-omic measurements and integration, while highlighting some of our most recent successes in this area.

Ansong, Charles K.↗
DOE OSTI2018

Chemical Evolution in Silicon–Graphite Composite Anodes Investigated by Vibrational Spectroscopy

Silicon–graphite composites are under development for the next generation of high-capacity lithium-ion anodes, and vibrational spectroscopy is a powerful tool to identify the different mechanisms that contribute to performance loss. With alloy anodes, the underlying causes of cell failure are significantly different in half-cells with lithium metal counter electrodes compared to full cells with standard cathodes. However, most studies which take advantage of vibrational spectroscopy have only examined half-cells. In this work, a combination of FTIR and Raman spectroscopy describes several factors that lead to degradation in full pouch cells with LiNi 0.5 Mn 0.3 Co 0.2 O 2 (NMC532) cathodes. The spectroscopic signatures evolve after longer term cycling compared to the initial formation cycles. Several side-reactions that consume lithium ions have clear FTIR signatures, and comparison to a library of reference compounds facilitates identification. Raman microspectroscopy combined with mapping shows that the composite anodes are not homogeneous but segregate into graphite-rich and silicon-rich phases. Lithiation does not proceed uniformly either. A basis analysis of Raman maps identifies electrochemically inactive regions of the anodes. In conclusion, the spectroscopic results presented here emphasize the importance of improving electrode processing and SEI stability to enable practical composite anodes with high silicon loadings.

25 ENERGY STORAGE↗
DOE OSTI2012

Assessing the Control Systems Capacity for Demand Response in California Industries

California's electricity markets are moving toward dynamic pricing models, such as real-time pricing, within the next few years, which could have a significant impact on an industrial facility's cost of energy use during the times of peak use. Adequate controls and automated systems that provide industrial facility managers real-time energy use and cost information are necessary for successful implementation of a comprehensive electricity strategy; however, little is known about the current control capacity of California industries. To address this gap, Lawrence Berkeley National Laboratory, in close collaboration with California industrial trade associations, conducted a survey to determine the current state of controls technologies in California industries. This study identifies sectors that have the technical capability to implement Demand Response (DR) and Automated Demand Response (Auto-DR). In an effort to assist policy makers and industry in meeting the challenges of real-time pricing, facility operational and organizational factors were taken into consideration to generate recommendations on which sectors Demand Response efforts should be focused.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2019

Optimizing Polymer-Grafted Amidoxime-based Adsorbents for Uranium Uptake from Seawater

This Final Report for Project 14-6789: “Optimizing Polymer- Grafted Amidoxime-based Adsorbents for Uranium Uptake from Seawater” consists of three independent parts focused on (i) polymer design optimization, (ii) effect of environmental factors on uranium adsorption, and (iii) effect of flow rate on uranium uptake. The polymer design section focuses on the study of polymer graft-chain conformation through neutron reflectometry and the influence of conformation on adsorbent performance. The environmental effects section was divided into four subcategories: (1) investigating the impact of aqueous ions on uranium adsorption and the development of an object oriented modeling framework for analysis of aqueous adsorption modeling; (2) analyzing and predicting adsorption capacities as a function of temperature; (3) developing a multi-scale paradigm by coupling aqueous adsorption modeling with molecular level models to predict competitive adsorption between vanadium and uranium at various pH values; (4) investigating the effect of competing adsorbates on uranium adsorption capacity and the possibility of uranium recovery from desalination brine reject. The final section is concerned with determining the effect of current velocity on uranium uptake by developing an understanding of the relationship between mass transfer kinetics and flow rate.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS1988

Constraints on the microwave opacity of gaseous methane and water vapor in the Jovian atmosphere

Gaseous NH3's microwave absorption in the Jovian atmosphere appears too great to be due to a solar abundance of this gas. The additional capacity of microwave absorption is presently sought in measurements of the microwave absorption of CH4 and H2O under simulated Jovian conditions at 2.25 GHz, 8.5 GHz, 21.7 GHz; due to large error bars, measurements represent upper limits on the microwave opacity generated by H2O and CH4. The results obtained are consistent with theoretical expressions for microwave opacity in a Jovian atmosphere at the specified frequencies. The presence of an NH3 abundance exceeding the solar level by a factor of 1.5 is indicated by test results.

Jenkins, Jon M.↗
NASA NTRS2011

Research and Technology Development to Advance Environmental Monitoring, Food Systems, and Habitat Design for Exploration Beyond Low Earth Orbit

Exploration missions will carry crews far beyond the relatively safe environs of cis-lunar space. Such trips will have little or no opportunity for resupply or rapid aborts and will be of a duration that far exceeds our experience to date. The challenges this imposes on the requirements of systems that monitor the life support and provide food and shelter for the crew are the focus of much research within the Human Research Program. Making all of these technologies robust and reliable enough for multi-year missions with little or no ability to run for home calls for a thorough understanding of the risks and impacts of failure. The way we currently monitor for microbial contamination of water, air, and surfaces, by sampling and growing cultures on nutrient media, must be reconsidered for exploration missions which have limited capacity for consumables. Likewise, the shelf life of food must be increased so that the nutrients required to keep the crewmembers healthy do not degrade over the life of the mission. Improved formulations, preservation, packaging, and storage technologies are all being investigated for ways slow this process or replace stowed food with key food items grown fresh in situ. Ensuring that the mass and volume of a spacecraft are used to maximum efficiency calls for infusing human factors into the design from its inception to increase efficiency, improve performance, and retain robustness toward operational realities. Integrating the human system with the spacecraft systems is the focus of many lines of investigation.

Sullivan, Thomas A.↗
NASA NTRS1999

Combined effects of space flight factors and radiation on humans

The probability that a dose of ionizing radiation kills a cell is about 10,000 times the probability that the cell will be transformed to malignancy. On the other hand, the number of cells killed required to significantly impact health is about 10,000 times the number that must be transformed to cause a late malignancy. If these two risks, cell killing and malignant transformation, are about equal, then the risk that occurs during a mission is more significant than the risk that occurs after a mission. The latent period for acute irradiation effects (cell killing) is about 2-4 weeks; the latent period for malignancy is 10-20 years. If these statements are approximately true, then the impact of cell killing on health in the low-gravity environment of space flight should be examined to establish an estimate of risk. The objective of this study is to synthesize data and conclusions from three areas of space biology and environmental health to arrive at rational risk assessment for radiations received by spacecraft crews: (1) the increased physiological demands of the space flight environment; (2) the effects of the space flight environment on physiological systems; and (3) the effects of radiation on physiological systems. One physiological system has been chosen: the immune response and its components, consisting of myeloid and lymphoid proliferative cell compartments. Best-case and worst-case scenarios are considered. In the worst case, a doubling of immune-function demand, accompanied by a halving of immune capacity, would reduce the endangering dose to a crew member to around 1 Gy.

Non-NASA Center↗
DOE OSTI2018

Detrimental Effects of Chemical Crossover from the Lithium Anode to Cathode in Rechargeable Lithium Metal Batteries

The interfacial stability is one of the crucial factors affecting long-term cyclability of lithium (Li) metal batteries (LMBs). While cross contamination (such as Mn+2 crossover from cathode to contaminate graphite anode) phenomena has been well studied in Li ion batteries (LIBs), the similar phenomena has rarely been studied in LMBs. Here, we systematically investigated the cathode failure triggered by the chemical crossover between the electrode pair in rechargeable LMBs. In strong contrast to LIBs, the cathode in LMBs suffers more significant and irreversible capacity fade during cycling and its capacity cannot be fully recovered even when Li metal anode has been replaced in the successive cycling. In-depth characterizations of the cathode surface reveal severe CEI deterioration related to the accumulation of highly resistive polymeric components and lithium fluoride. The soluble decomposition products generated by extensive salt-anion decomposition at Li metal surface can diffuse toward cathode side and result in severe deterioration of cathode as well asseparator surfaces. A polydopamine coated separator with selective Li-ion permeability has been developed to mitigate the detrimental chemical crossover and enhance the cathode stability.

Lee, Hongkyung↗
DOE OSTI2017

Report on the Economic Optimization of a Demonstration Case for a Static N-R HES Configuration using RAVEN

The synthetic time history generation algorithm in RAVEN has been extensively tested and used to perform qualitative assessments of the statistical characteristics of the net demand vs. demand for different values of the penetration of wind generation. Reported results highlight the need to consider the impact of variable renewable on the electricity net demand profile, due to the increase in its volatility with increased wind penetration. This analysis provides a strong foundation for the modeling and simulation needs expressed under the "Nuclear-Renewable Hybrid Energy Systems" (NRHES) project. Following this confirmative analysis the entire stochastic optimization framework has been tested in a demo case. The case chosen is an optimization driven by profitability for a system composed by a nuclear plant and a hydrogen production industrial process. This type of economical analysis is aimed to assess the capability of a hybrid system to penetrate the current energy market. In this sense it differs from the approach suggested under NRHES, where a cost minimization approach is suggested. This analysis is instead aimed to show the flexibility of the developed framework, e.g. for the evaluation of retrofitting projects of already existing plants. The system considered is subject to variable prices of electricity, which are simulated using the algorithm for the production of synthetic time histories. The physical system is considered without inertia so that it can be replaced by dispatching rules based on the highest marginal profit. Two optimization problems have been considered, for the first the size of the nuclear power plant is fixed and the optimization variable is the capacity of the hydrogen production plant. For the second, both plant sizes are optimization parameters while the overall capital expenditure is caped. The economical figures of merits considered are the Internal Rate of Return (IRR) and/or Profitability Index (PI) for the first one (since no cap is placed on the investment size) and Net Present Value (NPV) and/or IRR for the second one where the capital expenditure is constrained. Economic input data concerning capital costs, size-scaling factors, and operational costs for both plants have been collected from literature in order to achieve a simulation as realistic as possible. More work will be needed to obtain even more realistic numbers, possibly from industrial partners, and considering market elasticity for the hydrogen market. In order to perform the optimization of the cases described above, the economical external RAVEN module (CashFlow) for financial analysis has been improved in flexibility and generality. Some improvements have also been made to the optimization algorithm for a more efficient treatment of the boundary constrains. In conclusion three major results have been obtained: a) collection of the economical parameters characterizing the nuclear power plants and hydrogen production plants, b) extension of the financial analysis module (CashFlow) to drive the calculation of all needed cash flow streams and c) the testing of the full framework in a nearly final configuration.

97 MATHEMATICS AND COMPUTING↗
NASA NTRS1921

The calculated performance of airplanes equipped with supercharging engines

In part one of this report are presented the theoretical performance curves of an airplane engine equipped with a supercharging compressor. In predicting the gross power of a supercharging engine, the writer uses temperature and pressure correction factors based on experiments made at the Bureau of Standards (NACA report nos. 45 and 46). Means for estimating the temperature rise in the compressor are outlined. Part two of this report presents an estimation of the performance curves of an airplane fitted with a supercharging engine. A supercharging installation suitable for commercial use is described, and it is shown that with the use of the compressor a great saving in fuel and a considerable increase in carrying capacity can be effected simultaneously. In an appendix the writer derives a theoretical formula for the correction of the thrust coefficient of an airscrew to offset the added resistance of the airplane due to the slip-stream effect.

Kemble, E C↗
NASA NTRS2012

Simulated Single Tooth Bending of High Temperature Alloys

Future unmanned space missions will require mechanisms to operate at extreme conditions in order to be successful. In some of these mechanisms, very high gear reductions will be needed to permit very small motors to drive other components at low rotational speed with high output torque. Therefore gearing components are required that can meet the mission requirements. In mechanisms such as this, bending fatigue strength capacity of the gears is very important. The bending fatigue capacity of a high temperature, nickel-based alloy, typically used for turbine disks in gas turbine engines and two tool steel materials with high vanadium content, were compared to that of a typical aerospace alloy-AISI 9310. Test specimens were fabricated by electro-discharge machining without post machining processing. Tests were run at 24 and at 490 C. As test temperature increased from 24 to 490 C the bending fatigue strength was reduced by a factor of five.

Handschuh, Robert, F.↗
DOE OSTI2015

A new role of SNAI2 in postlactational involution of the mammary gland links it to luminal breast cancer development

Breast cancer is a major cause of mortality in women. The transcription factor SNAI2 has been implicated in the pathogenesis of several types of cancer, including breast cancer of basal origin. Here we show that SNAI2 is also important in the development of breast cancer of luminal origin in MMTV-ErbB2 mice. SNAI2 deficiency leads to longer latency and fewer luminal tumors, both of these being characteristics of pretumoral origin. These effects were associated with reduced proliferation and a decreased ability to generate mammospheres in normal mammary glands. However, the capacity to metastasize was not modified. Under conditions of increased ERBB2 oncogenic activity after pregnancy plus SNAI2 deficiency, both pretumoral defects-latency and tumor load-were compensated. However, the incidence of lung metastases was dramatically reduced. Furthermore, SNAI2 was required for proper postlactational involution of the breast. At 3 days post lactational involution, the mammary glands of Snai2-deficient mice exhibited lower levels of pSTAT3 and higher levels of pAKT1, resulting in decreased apoptosis. Abundant noninvoluted ducts were still present at 30 days post lactation, with a greater number of residual ERBB2+ cells. These results suggest that this defect in involution leads to an increase in the number of susceptible target cells for transformation, to the recovery of the capacity to generate mammospheres and to an increase in the number of tumors. In conclusion, our work demonstrates the participation of SNAI2 in the pathogenesis of luminal breast cancer, and reveals an unexpected connection between the processes of postlactational involution and breast tumorigenesis in Snai2-null mutant mice.

60 APPLIED LIFE SCIENCES↗