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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,765 records · Page 98
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Synthesis and Characterization of Single Phase Metal Dodecaboride Solid Solutions: Zr 1-x Y x B 12 and Zr 1-x U x B 12

Single-phase metal dodecaboride solid solutions, Zr 0.5 Y 0.5 B 12 and Zr 0.5 U 0.5 B 12 , were arranged by arc melting from pure elements. The phase purity and composition were established by powder X-ray diffraction (PXRD), energy-dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), and 10 B and 11 B solid-state nuclear magnetic resonance (NMR) spectroscopy. The effects of carbon addition to Zr 1-x Y x B 12 were studied and it was found that carbon causes fast cooling and as a result rapid nucleation of grains, as well as “templating” and patterning effects of the surface morphology. The hardness of the Zr 0.5 Y 0.5 B 12 phase is 47.6 ± 1.7 GPa at 0.49 N load, which is ~17% higher than that of its parent compounds, ZrB 12 and YB 12 , with hardness values of 41.6 ± 2.6 and 37.5 ± 4.3 GPa, respectively. The hardness of Zr 0.5 U 0.5 B 12 is ~54% higher than that of its UB 12 parent. The dodecaborides were confirmed to be metallic by band structure calculations, diffuse reflectance UV–vis, and solid-state NMR spectroscopies. The nature of the dodecaboride colors—violet for ZrB 12 and blue for YB 12 —can be applied to charge-transfer. XPS indicates that the metals are in the following oxidation states: Y 3+ , Zr 4+ , and U$^{{5+}/^{6+}}$. The superconducting transition temperatures (T c ) of the dodecaborides were determined to be 4.5 and 6.0 K for YB 12 and ZrB 12 , respectively, as shown by resistivity and superconducting quantum interference device (SQUID) measurements. The T c of the Zr 0.5 Y 0.5 B 12 solid solution was suppressed to 2.5 K.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Suppressing Universal Cathode Crossover in High‐Energy Lithium Metal Batteries via a Versatile Interlayer Design**

Abstract The universal cathode crossover such as chemical and oxygen has been significantly overlooked in lithium metal batteries using high‐energy cathodes which leads to severe capacity degradation and raises serious safety concerns. Herein, a versatile and thin (≈25 μm) interlayer composed of multifunctional active sites was developed to simultaneously regulate the Li deposition process and suppress the cathode crossover. The as‐induced dual‐gradient solid‐electrolyte interphase combined with abundant lithiophilic sites enable stable Li stripping/plating process even under high current density of 10 mA cm −2 . Moreover, X‐ray photoelectron spectroscopy and synchrotron X‐ray experiments revealed that N‐rich framework and CoZn dual active sites can effectively mitigate the undesired cathode crossover, hence significantly minimizing Li corrosion. Therefore, assembled lithium metal cells using various high‐energy cathode materials including LiNi 0.7 Mn 0.2 Co 0.1 O 2 , Li 1.2 Co 0.1 Mn 0.55 Ni 0.15 O 2 , and sulfur demonstrate significantly improved cycling stability with high cathode loading.

Xie, Chuyi↗
DOE OSTI2023

Suppressing Universal Cathode Crossover in High‐Energy Lithium Metal Batteries via a Versatile Interlayer Design**

Abstract The universal cathode crossover such as chemical and oxygen has been significantly overlooked in lithium metal batteries using high‐energy cathodes which leads to severe capacity degradation and raises serious safety concerns. Herein, a versatile and thin (≈25 μm) interlayer composed of multifunctional active sites was developed to simultaneously regulate the Li deposition process and suppress the cathode crossover. The as‐induced dual‐gradient solid‐electrolyte interphase combined with abundant lithiophilic sites enable stable Li stripping/plating process even under high current density of 10 mA cm −2 . Moreover, X‐ray photoelectron spectroscopy and synchrotron X‐ray experiments revealed that N‐rich framework and CoZn dual active sites can effectively mitigate the undesired cathode crossover, hence significantly minimizing Li corrosion. Therefore, assembled lithium metal cells using various high‐energy cathode materials including LiNi 0.7 Mn 0.2 Co 0.1 O 2 , Li 1.2 Co 0.1 Mn 0.55 Ni 0.15 O 2 , and sulfur demonstrate significantly improved cycling stability with high cathode loading.

25 ENERGY STORAGE↗
DOE OSTI2017

Development of High Power Density Metal‐Supported Solid Oxide Fuel Cells

Abstract Symmetric‐structure metal‐supported solid oxide fuel cells (MS‐SOFCs) are fabricated by infiltrating catalysts on both anode and cathode side. Various aspects of the infiltration process are optimized. Performance is found to be sensitive to precursor dilution, catalyst loading, and catalyst calcining temperature. For an optimized cell with lanthanum strontium manganite (LSM) as cathode and Sm 0.2 Ce 0.8 O 2− δ mixed with Ni (SDCN) as anode, peak power densities of 0.44, 1.1, and 1.9 W cm −2 are achieved at 600, 700, and 800 °C, respectively. A fully symmetric MS‐SOFC with SDCN as both the anode and cathode sides achieves moderate peak power densities of 0.12, 0.37, and 0.76 W cm −2 at 600, 700, and 800 °C, respectively. A solvent‐based infiltration technique is also explored and found to be more effective than capillary forces alone but not as effective as vacuum infiltration.

Tucker, Michael C.↗
DOE OSTI2018

Mechanism-based constitutive modeling of ZEK100 magnesium alloy with crystal plasticity and in-situ HEXRD experiment

The constitutive behavior of a hexagonal close-packed (HCP) polycrystalline ZEK100 magnesium alloy was investigated here using combined high energy X-ray diffraction (HEXRD) from a synchrotron source and crystal plasticity modeling approach. The in-situ tensile test data coupled with the HEXRD enabled the tracking of the lattice strain evolution during deformation. The microscopic behavior represented by lattice strain and the macroscopic behavior represented by stress-strain curves were then used together as objective function to estimate the critical resolved shear stress (CRSS) and hardening parameters of available slip and deformation twin systems in the ZEK100 alloy. An enhanced predominant twinning reorientation (ePTR) scheme was proposed in the current work, and the ePTR parameters were determined for the first time by the use of basal plane peak intensity along loading direction measured from HEXRD. Two crystal plasticity models, the computationally efficient elastic-plastic self-consistent (EPSC) and crystal plasticity finite element (CPFE) models, were developed incorporating the deformation twinning for the HCP-structured metals. The determined constitutive parameters were further validated by comparing the predicted deformation texture with the measured one. The work provides a useful and computationally-efficient modeling scheme to understand the slip/twin induced deformation behaviors of the ZEK100 alloy in micro- and macro-scales.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Non-equilibrium reducing flame aerosol process to create supported high-entropy alloy nanoparticles

High-entropy alloy (HEA) nanomaterials provide opportunities and property combinations for energy and electronic applications, but their practical synthesis faces challenges of elemental immiscibility, metal reducibility, and particle aggregation during their synthesis. Herein, we report a broadly applicable non-equilibrium, scalable, and in-situ reducing flame aerosol process for synthesis of supported HEA nanoparticles. This versatile process can directly load a high concentration of 2 ~ 4 nm HEA nanoparticles on various 1- to 3-dimensional supports. Notably, simultaneous formation of HEA nanoparticles and a mesoporous silica support was successfully realized in a single step. Exploration of this process demonstrates the role of kinetics and entropy on decreasing alloy particle size and altering the reducibility of elements. We propose an entropy-induced reduction mechanism to incorporate oxidizable elements into HEAs, which extends the compositional space of HEA nanoparticles. As a representative catalytic application, we present a RuPdOsIrPt/graphene electrocatalyst with high activity and stability for hydrogen oxidation reaction. Our findings open horizons for high-performance HEA design and applications in diverse fields such as catalysis, electrochemistry, and sensing.

organic↗
DOE OSTI2018

A divertor scraper observation system for the Wendelstein 7-X stellarator

Two graphite divertor elements called scrapers have been installed on the Wendelstein 7-X stellarator in the throat of the magnetic island divertor. To diagnose one, we have designed, built, calibrated, and installed a new infrared/visible imaging endoscope system to enable detailed observations of the plasma interactions and heat loads at one of the scrapers and the nearby divertor surfaces. The new system uses a shuttered pinhole-protected pair of 90° off-axis 228 mm focal length aluminum parabolic mirrors, and two flat turning metal mirrors, to send light to a sapphire vacuum window 1.6 meters away, beyond which we have co-located telephoto lens-based infrared and visible cameras. The back-to-back off-axis parabolas serve to cancel out most aberrations, enabling the use of off-the-shelf commercial optics outside of the vessel. For the infrared, we use a 3-5 μm 1-megapixel FLIR SC8303HD camera and for the visible, a 5-megapixel CMOS PCO 5.5 edge camera. A short 1-m quartz pickoff fiber is used to send 200-1100 nm light to a compact spectrometer, also located in the same iron shield box as the cameras. The camera field of view covers the 700 mm length of the scraper, and includes locations monitored by thermocouples and Langmuir probes embedded in some of the scraper tiles. Predicted and actual optical test performances of the overall system are then compared.

47 OTHER INSTRUMENTATION↗
DOE OSTI2018

On the dynamic tensile strength of an FCC metal

The tensile response of ductile, polycrystalline metals is often accompanied by the formation of pores within the material, which coalesce and fail a plane within a metal. This large deformation process is broadly progressive, with a physical path consisting of nucleation, growth, coalescence, and failure, which occur individually over short periods of time. Thus distinct micro-mechanisms operate, each influenced by microstructure, loading path, and loading profile, which remains a significant challenge to represent and predict numerically at the macroscale. In a previous study, the influence of loading path on damage evolution in high-purity tantalum has been presented; in this paper, complimentary measurements are made on a pure, FCC copper. Samples were shock loaded to three different peak stresses using both symmetric impact, and two different composite flyer plate configurations, such that upon unloading, the three samples were subject to nearly identical tensile loading. The damage evolution in the soft-recovered copper samples was then quantified using optical metallography and electron-back-scatter diffraction. We shall compare metallurgical observations, velocimetry histories and simulations to discuss the dynamic failure mechanics observed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

CLASSY III. The Properties of Starburst-driven Warm Ionized Outflows

We report the results of analyses of galactic outflows in a sample of 45 low-redshift starburst galaxies in the COS Legacy Archive Spectroscopic SurveY (CLASSY), augmented by five additional similar starbursts with Cosmic Origins Spectrograph (COS) data. The outflows are traced by blueshifted absorption lines of metals spanning a wide range of ionization potential. The high quality and broad spectral coverage of CLASSY data enable us to disentangle the absorption due to the static interstellar medium (ISM) from that due to outflows. We further use different line multiplets and doublets to determine the covering fraction, column density, and ionization state as a function of velocity for each outflow. We measure the outflow's mean velocity and velocity width, and find that both correlate in a highly significant way with the star formation rate, galaxy mass, and circular velocity over ranges of four orders of magnitude for the first two properties. We also estimate outflow rates of metals, mass, momentum, and kinetic energy. We find that, at most, only about 20% of silicon created and ejected by supernovae in the starburst is carried out in the warm phase we observe. The outflows' mass-loading factor increases steeply and inversely with both circular and outflow velocity (log–log slope ~–1.6), and reaches ~10 for dwarf galaxies. We find that the outflows typically carry about 10%–100% of the momentum injected by massive stars and about 1%–20% of the kinetic energy. We show that these results place interesting constraints on, and new insights into, models and simulations of galactic winds.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Performance Comparison of LPG and Gasoline in an Engine Configured for EGR-Loop Catalytic Reforming

In prior work, the EGR loop catalytic reforming strategy developed by ORNL has been shown to provide a relative brake engine efficiency increase of more than 6% by minimizing the thermodynamic expense of the reforming processes, and in some cases achieving thermochemical recuperation (TCR), a form of waste heat recovery where waste heat is converted to usable chemical energy. In doing so, the EGR dilution limit was extended beyond 35% under stoichiometric conditions. In this investigation, a Microlith®-based metal-supported reforming catalyst (developed by Precision Combustion, Inc. (PCI)) was used to reform the parent fuel in a thermodynamically efficient manner into products rich in H2 and CO. We were able to expand the speed and load ranges relative to previous investigations: from 1,500 to 2,500 rpm, and from 2 to 14 bar break mean effective pressure (BMEP). Experiments were conducted to determine the effects of the H/C ratio of the fuel on H2 production and on the engine efficiency in order to compare E10 gasoline (H/C = 1.95) and liquified petroleum gas (LPG), comprised primarily of propane (H/C = 2.67). Additionally, the compression ratio of the engine was increased to ascertain whether further efficiency improvements could be realized based on a reduced knock propensity of the dilute EGR mixture with the reformed fuel. Both the gasoline and propane reforming strategies provided efficiency gains up to 1.85 percentage points and further efficiency improvements with the increased compression ratio were realized. The fuel specific effects of gasoline vs. LPG, the effect of engine operating condition on reforming, and knock limits of the reformed mixture are discussed in detail.

33 ADVANCED PROPULSION SYSTEMS↗
NASA NTRS1983

Friction and wear of iron in sulfuric acid

Elemental iron sliding on aluminum oxide in aerated sulfuric acid concentrations ranging from very dilute (0.000007 N; i.e., 4 ppm) to very concentrated (96 percent acid) was studied. Load and reciprocating sliding speeds were kept constant. With the most dilute acid of 0.7 to 0.0002 N, a complex corrosion product formed that was friable and often increased friction and wear. At concentrations of 0.001 N, metal losses were essentially by wear alone. Because no buildup of corrosion products occurred, this acid concentration became the standard from which to separate metal loss from direct corrosion and mechanical wear losses. When the acid concentration was increased to 5 percent, the high corrosion rate of iron in sulfuric acid strongly dominated the total wear loss. This strong corrosion increased to 30 percent acid, and decreased somewhat at 50 percent in accordance with expectations. However, the low corrosion of iron expected at acid concentrations of 65 to 96 percent was not observed in the wear area. It is apparent that the normal passivating film was being worn away and a galvanic cell established which rapidly attached to the wear area.

Rengstorff, G. W. P.↗
NASA NTRS1984

Support of Oil Lubrication by Bonded Coatings

A new generation of lubricating lacquers for treatment of metal surfaces has been developed. These new coatings have proved to be oil-compatible and are used in oil-lubricated systems. The oil lubrication is supported thereby through reduction of friction and increase of load-carrying capacity during boundary conditions. For difficult tribological systems, the problem-solving lubricating concept has proved to be the beneficial combination of lubricating oil and bonded coatings. A number of practical applications are presented.

Ruediger Holinski↗
NASA NTRS1988

Assembly Test Article (ATA)

The assembly test article (ATA) consisted of two live loaded redesigned solid rocket motor (RSRM) segments which were assembled and disassembled to simulate the actual flight segment stacking process. The test assembly joint was flight RSRM design, which included the J-joint insulation design and metal capture feature. The ATA test was performed mid-November through 24 December 1987, at Kennedy Space Center (KSC), Florida. The purpose of the test was: certification that vertical RSRM segment mating and separation could be accomplished without any damage; verification and modification of the procedures in the segment stacking/destacking documents; and certification of various GSE to be used for flight assembly and inspection. The RSRM vertical segment assembly/disassembly is possible without any damage to the insulation, metal parts, or seals. The insulation J-joint contact area was very close to the predicted values. Numerous deviations and changes to the planning documents were made to ensure the flight segments are effectively and correctly stacked. Various GSE were also certified for use on flight segments, and are discussed in detail.

Ricks, Glen A.↗
NASA NTRS1988

Strain measurement technique for elevated temperature tensile and creep testing of foil-gage metals

This paper describes a strain measurement technique suitable for elevated-temperature tensile and creep testing of foil-gage metals, using a modified commonly available mechanical extensometer in conjunction with a displacement transducer. The extensometer was modified by attaching to it a counterbalance (to reduce the effect of the extensometer weight on the total maximum test load) and by incorporating a conical tip/flat-edge design (to minimize induced stresses in the specimen resulting from extensometer attachment). Creep tests were performed on 0.102-mm-thick specimens of Ti-6Al-4V at temperatures of 427 and 538 C, at nominal applied stresses of 310.3 and 172.4 MPa, respectively. Examination of the resulting creep curves suggested that the strain measurement system provided actual creep strain values with good accuracy.

Blackburn, L. B.↗
NASA NTRS1989

Fracture of silicon carbide whisker reinforced aluminum

An attempt is made to apply standard fracture toughness testing procedures, developed for metals, to whisker reinforced metal matrix composites. Test were carried out on compact-tension, center-notched, and edge-notched specimens of silicon carbide whisker reinforced extruded 2124 aluminum plate (10 and twenty volume percent of whiskers), with the loading direction either parallel or perpendicular to the extrusion direction. None of the tests is found to give a valid fracture toughness according to the criteria of the ASTM Standard E-399.

Albritton, J. R.↗
DOE OSTI2021

Enhanced Guest@MOF Interaction via Stepwise Thermal Annealing: TCNQ@Cu 3 (BTC) 2

Confinement of guest molecules in porous materials such as metal organic frameworks (MOFs) promises to deliver emergent properties separate from those of the individual components. Understanding the confinement mechanism is therefore important for the development of new synthesis routes that adjust MOF properties for specific applications. In this work, we developed a new synthetic method to confine guest molecules into MOF pores through a stepwise thermal annealing process, wherein the confinement of 7,7,8,8-tetracyanoquinodimethane (TCNQ) guest molecules into Cu 3 (BTC) 2 (BTC = benzene-1,3,5-tricarboxylic acid) MOF host is used as an example of how novel materials can be created with new physical properties. The stepwise thermal annealing process includes 1) an activation process of pristine Cu 3 (BTC) 2 MOF to maximizes the TCNQ guest loading in the MOF host by effectively removing the residual solvents and 2) post-annealing of the TCNQ infiltrated MOF to enhances the interaction of the confined guest molecules with the MOF host. Obtained experimental results based on thermogravimetric analysis, N 2 gas adsorption, electron microscopy, X-ray diffraction and infrared absorption, combined with density functional theory calculations provide evidence that the use of a stepwise thermal annealing process yields enhancements in the guest loading, packing and interaction between the TCNQ guest and the MOF host. The new hybrid TCNQ@Cu 3 (BTC) 2 system is stable and shows no significant signs of structural degradation even after submersion in water. This is due to the presence of significantly stronger interactions of TCNQ with the frame-work metal ions compared to those of the water molecules competing for the same framework binding sites. It was also found that TCNQ@Cu 3 (BTC) 2 system maintains a significant CO 2 and CH 4 adsorption potential compared to the pristine MOF. The synthetic route developed in this work yields novel guest@MOF hybrid systems that will be useful for many MOF-based applications such as gas separations and chemical sensors performed under humid conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1992

Fatigue damage in cross-ply titanium metal matrix composites containing center holes

The development of fatigue damage in (0/90) sub SCS-6/TI-15-3 laminates containing center holes was studied. Stress levels required for crack initiation in the matrix were predicted using an effective strain parameter and compared to experimental results. Damage progression was monitored at various stages of fatigue loading. In general, a saturated state of damage consisting of matrix cracks and fiber matrix debonding was obtained which reduced the composite modulus. Matrix cracks were bridged by the 0 deg fibers. The fatigue limit (stress causing catastrophic fracture of the laminates) was also determined. The static and post fatigue residual strengths were accurately predicted using a three dimensional elastic-plastic finite element analysis. The matrix damage that occurred during fatigue loading significantly reduced the notched strength.

Bakuckas, J. G., Jr.↗
NASA NTRS2006

Effect of Reinforcement Architecture on Fracture of Selectively Reinforced Metallic Compact Tension Specimens

A computer-based parametric study of the effect of reinforcement architectures on fracture response of aluminum compact-tension (CT) specimens is performed. Eleven different reinforcement architectures consisting of rectangular and triangular cross-section reinforcements were evaluated. Reinforced specimens produced between 13 and 28 percent higher fracture load than achieved with the non-reinforced case. Reinforcements with blunt leading edges (rectangular reinforcements) exhibited superior performance relative to the triangular reinforcements with sharp leading edges. Relative to the rectangular reinforcements, the most important architectural feature was reinforcement thickness. At failure, the reinforcements carried between 58 and 85 percent of the load applied to the specimen, suggesting that there is considerable load transfer between the base material and the reinforcement.

Abada, Christopher H.↗