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NASA NTRS2000

Measurement of the Heat Capacity of He-II Under a Heat Current Near the Lambda Transition

We present preliminary measurements of the heat capacity of superfluid helium-4 under an applied heat current near the lambda transition. The calorimeter is a standard cylindrical thermal conductivity cell with a 0.6 mm gap between two copper endplates. The sidewall is made of stainless steel. A heat current density in the range of 1 to 4 microW/sq cm is applied through the helium sample while a pulse method is used to measure the heat capacity. Temperature changes are recorded with high-resolution thermometers (HRTs) located on the top and bottom endplates. Corrections are made to the readings of the HRTs to account for the Kapitza boundary resistance and the anomalous Kapitza boundary resistance. After the corrections, both the top and the bottom HRTs. give the same heat capacity values. The heat capacity is found to be much larger than the prediction of recent theories. We also plotted our data on a scaled plot to test the prediction of scaling by the theories. The result and its interpretation will be presented. The cell height was deliberately made to be thin to reduce the effects of gravity. Nonetheless, gravity is expected to have significant effects on the heat capacity data in the temperature range of our measurement. A space experiment would remove this unwanted gravity effect and allow the true physics to be examined. Moreover, in the absence of gravity, a deeper cell can be used allowing HRTs to be mounted on to the sidewall providing direct measurements of the helium temperature, unaffected by the anomalous Kapitza boundary resistance.

Harter, Alexa W.↗

NASA NTRS2000

A 3-D Magnetic Analysis of a Linear Alternator For a Stirling Power System

The NASA Glenn Research Center and the Department of Energy (DOE) are developing advanced radioisotope Stirling convertors, under contract with Stirling Technology Company (STC), for space applications. Of critical importance to the successful development of the Stirling convertor for space power applications is the development of a lightweight and highly efficient linear alternator. This paper presents a 3-D finite element method (FEM) approach for evaluating Stirling convertor linear alternators. Preliminary correlations with open-circuit voltage measurements provide an encouraging level of confidence in the model. Spatial plots of magnetic field strength (H) are presented in the region of the exciting permanent magnets. These plots identify regions of high H, where at elevated temperature and under electrical load, the potential to alter the magnetic moment of the magnets exists. This implies the need for further testing and analysis.

Geng, Steven M.↗

NASA NTRS2000

Test Cases for a Clipped Delta Wing with Pitching and Trailing-Edge Control Surface Oscillations

Steady and unsteady measured pressures for a Clipped Delta Wing (CDW) undergoing pitching oscillations and trailing-edge control surface oscillations have been presented . From the several hundred compiled data points, 22 static cases, 12 pitching-oscillation cases, and 12 control-surface-oscillation cases have been proposed for Computational Test Cases to illustrate the trends with Mach number, reduced frequency, and angle of attack. The planform for this wing was derived by simplifying the planform of a proposed design for a supersonic transport which is described as the Boeing 2707-300. The strake was deleted, the resulting planform was approximated by a trapezoid with an unswept trailing edge, and the twist and camber were removed. In order to facilitate pressure instrumentation, the thickness was increased to 6 percent from the typical 2.5 to 3 percent for the supersonic transport. The airfoil is thus a symmetrical circular arc section with t/c = 0.06. A wing of similar planform but with a thinner airfoil of t/c = 0.03 was used in the flutter investigations, and the buffet and stall flutter investigation . Flutter results are also reported both for the 3 per cent thick simplified wing and for a more complex SST model. One of the consequences of the increased thickness of the clipped delta wing is that transonic effects are enhanced for Mach numbers near one. They are significantly stronger than would be the case for the thinner wing. Also, with the combination of high leading edge sweep of 50.5, and the sharp leading edge, a leading edge vortex forms on the wing at relatively low angles of attack, on the order of three degrees. The Appendix discusses some of the vortex flow effects. In addition, a shock develops over the aft portion of the wing at transonic speeds such that at some angles of attack, there is both a leading edge vortex and a shock wave on the wing. Such cases are a computational challenge. Some previous applications of this data set have been for the evaluation of an aerodynamic panel method and for evaluation of a Navier-Stokes capability. Linear theory and panel method results are also presented, which demonstrated the need for inclusion of transonic effects. Flutter calculations for the related wing with t/c=O.O3 are given. In this report several Test Cases are selected to illustrate trends for a variety of different conditions with emphasis on transonic flow effects. An overview of the model and tests are given, and the standard formulary for these data is listed. For each type of data, a sample table and a sample plot of the measured pressures are presented. A complete tabulation and plotting of the Test Cases is given. Only the static pressures and the 1st harmonic real and imaginary parts of the pressures are available. All of the data for the test are included in a microfiche document in the original report and are available in electronic file form. The Test Cases are also available as separate electronic files.

Bennett, Robert M.↗

NASA NTRS2001

Using Automation to Improve the Flight Software Testing Process

One of the critical phases in the development of a spacecraft attitude control system (ACS) is the testing of its flight software. The testing (and test verification) of ACS flight software requires a mix of skills involving software, attitude control, data manipulation, and analysis. The process of analyzing and verifying flight software test results often creates a bottleneck which dictates the speed at which flight software verification can be conducted. In the development of the Microwave Anisotropy Probe (MAP) spacecraft ACS subsystem, an integrated design environment was used that included a MAP high fidelity (HiFi) simulation, a central database of spacecraft parameters, a script language for numeric and string processing, and plotting capability. In this integrated environment, it was possible to automate many of the steps involved in flight software testing, making the entire process more efficient and thorough than on previous missions. In this paper, we will compare the testing process used on MAP to that used on previous missions. The software tools that were developed to automate testing and test verification will be discussed, including the ability to import and process test data, synchronize test data and automatically generate HiFi script files used for test verification, and an automated capability for generating comparison plots. A summary of the perceived benefits of applying these test methods on MAP will be given. Finally, the paper will conclude with a discussion of re-use of the tools and techniques presented, and the ongoing effort to apply them to flight software testing of the Triana spacecraft ACS subsystem.

ODonnell, James R., Jr.↗

NASA NTRS2000

Computations of Boiling in Microgravity

The absence (or reduction) of gravity, can lead to major changes in boiling heat transfer. On Earth, convection has a major effect on the heat distribution ahead of an evaporation front, and buoyancy determines the motion of the growing bubbles. In microgravity, convection and buoyancy are absent or greatly reduced and the dynamics of the growing vapor bubbles can change in a fundamental way. In particular, the lack of redistribution of heat can lead to a large superheat and explosive growth of bubbles once they form. While considerable efforts have been devoted to examining boiling experimentally, including the effect of microgravity, theoretical and computational work have been limited. Here, the growth of boiling bubbles is studied by direct numerical simulations where the flow field is fully resolved and the effects of inertia, viscosity, surface deformation, heat conduction and convection, as well as the phase change, are fully accounted for. Boiling involves both fluid flow and heat transfer and thus requires the solution of the Navier-Stokes and the energy equations. The numerical method is based on writing one set of governing transport equations which is valid in both the liquid and vapor phases. This local, single-field formulation incorporates the effect of the interface in the governing equations as source terms acting only at the interface. These sources account for surface tension and latent heat in the equations for conservation of momentum and energy as well as mass transfer across the interface due to phase change. The single-field formulation naturally incorporates the correct mass, momentum and energy balances across the interface. Integration of the conservation equations across the interface directly yields the jump conditions derived in the local instant formulation for two-phase systems. In the numerical implementation, the conservation equations for the whole computational domain (both vapor and liquid) are solved using a stationary grid and the phase boundary is followed by a moving unstructured two-dimensional grid. While two-dimensional simulations have been used for preliminary studies and to examine the resolution requirement, the focus is on fully three-dimensional simulations. The numerical methodology, including the parallelization and grid refinement strategy is discussed, and preliminary results shown. For buoyancy driven flow, the heat transfer is in good agreement with experimental correlations. The changes when gravity is turned off and/or fluid shear is added are discussed, as well as the difference between simulations of a layer freely releasing bubbles versus simulations using only one wavelength initial perturbation. Figure 1 shows the early stages of the formation of a three-dimensional bubble from a thin vapor layer. The boundary conditions are periodic in the x and y direction, the bottom is a hot and the top allows a free outflow. The jagged edge of the surface close to the bottom of the computational domain is due to some of the surface elements being on the other side of the domain and some elements not plotted by our plotting routine. In the second figure, we show the temperature distribution through two perpendicular planes.

Tryggvason, G.↗

NASA NTRS1994

The Influence of Sound Cues on the Maintenance of Temporal Organization in the Sprague-Dawley Rat

Temporal organization is a fundamental property of living matter. From single cells to complex animals including man, most physiological systems undergo daily periodic changes in concert with environmental cues (e.g., light, temperature etc.). It is known that pulsed Environmental synchronizers, zeitgebers, (e.g. light) can modify rhythm parameters. Rhythm stability is a necessary requirement for most animal experiments. The extent to which sound can influence the circadian system of laboratory rats is poorly understood. This has implications to animal habitats in the novel environments of the Space-Laboratory or Space Station. A series of three white noise (88+/-0.82 db) zeitgeber experiments were conducted (n=6/experiment).The sound cue was introduced in the circadian free-running phase (DD-NQ) and in one additional case sound was added to the usual photoperiod (12L:12D) to determine masking effects. Circadian rhythm parameters of drinking frequency, feeding frequency, and gross locomotor activity were continuously monitored. Data analysis for these studies included macroscopic and microscopic methods. Raster plots to visually detect entrainment versus free-running period, were plotted for each animal, for all three parameters, during all sound perturbation tested. These data were processed through a series of detrending (robust locally weighted regression analyses) and complex demodulation analyses. In summary, these findings show that periodic "white" noise "influences" the rats circadian system but does not "entrain" the feeding, drinking or locomotor activity rhythms.

Winget, C. M.↗

NASA NTRS2001

Using Automation to Improve the Flight Software Testing Process

One of the critical phases in the development of a spacecraft attitude control system (ACS) is the testing of its flight software. The testing (and test verification) of ACS flight software requires a mix of skills involving software, knowledge of attitude control, and attitude control hardware, data manipulation, and analysis. The process of analyzing and verifying flight software test results often creates a bottleneck which dictates the speed at which flight software verification can be conducted. In the development of the Microwave Anisotropy Probe (MAP) spacecraft ACS subsystem, an integrated design environment was used that included a MAP high fidelity (HiFi) simulation, a central database of spacecraft parameters, a script language for numeric and string processing, and plotting capability. In this integrated environment, it was possible to automate many of the steps involved in flight software testing, making the entire process more efficient and thorough than on previous missions. In this paper, we will compare the testing process used on MAP to that used on other missions. The software tools that were developed to automate testing and test verification will be discussed, including the ability to import and process test data, synchronize test data and automatically generate HiFi script files used for test verification, and an automated capability for generating comparison plots. A summary of the benefits of applying these test methods on MAP will be given. Finally, the paper will conclude with a discussion of re-use of the tools and techniques presented, and the ongoing effort to apply them to flight software testing of the Triana spacecraft ACS subsystem.

ODonnell, James R., Jr.↗

NASA NTRS2001

A 3-D Magnetic Analysis of a Stirling Convertor Linear Alternator Under Load

The NASA Glenn Research Center (GRC), the Department of Energy (DOE), and the Stirling Technology Company (STC) are developing Stirling convertors for Stirling Radioisotope Power Systems (SRPS) to provide electrical power for future NASA deep space missions. STC is developing the 55-We Technology Demonstration Convertor (TDC) under contract to DOE. Of critical importance to the successful development of the Stirling convertor for space power applications is the development of a lightweight and highly efficient linear alternator. This paper presents a 3-dimensional finite element method (FEM) approach for evaluating Stirling convertor linear alternators. The model extends a magnetostatic analysis previously reported at the 35th Intersociety Energy Conversion Engineering Conference (IECEC) to include the effects of the load current. STC's 55-We linear alternator design was selected to validate the model. Spatial plots of magnetic field strength (H) are presented in the region of the exciting permanent magnets. The margin for permanent magnet demagnetization is calculated at the expected magnet operating temperature for the near earth environment and for various average magnet temperatures. These thermal conditions were selected to represent a worst-case condition for the planned deep space missions. This paper presents plots that identify regions of high H where the potential to alter the magnetic moment of the magnets exists.

Geng, Steven M.↗

NASA NTRS2001

Organization of P, S, and Fe Inclusions in a Freshwater Magnetococcus

Magnetotactic bacteria are a heterogeneous group of motile, mainly aquatic procaryotes that align and swim along geomagnetic field lines. They are of interest to astrobiologists because of the magnetite crystals found in the Mars meteorite ALH84001 which share many characteristics with the magnetite produced intracellularly by magnetotactic bacteria. These bacteria are diverse morphologically, physiologically and phylogenetically, sharing a few key characteristics: 1) the presence of intracellular membrane-bound magnetic crystals (magnetosomes), usually but not always arranged in chains; 2) motility by means of flagella; and 3) microaerophillic or anaerobic physiology. The bilophotrichous (having two flagella bundles) magnetotactic cocci (MC) are ubiquitous in aquatic habitats but have proven extremely difficult to cultivate. Because only several marine strains have been isolated and grown in axenic culture, little is known about the physiology and the biogeochemical roles of the MC. We studied the composition and distribution of intracellular structures in an uncultured MC, designated ARB-1. To do this, a combination of light microscopy, environmental scanning electron microscopy (ESEM), transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDS) were used. Cells of ARB-1 were separated from sediments collected from Baldwin Lake (Los Angeles Arboretum, Arcadia, CA). They are large spherical to oblate spheroidal Gram-negative cells, ranging from 1 to 4 micrometers along the maximum dimension, which is perpendicular to the direction of swimming. Cells have two large phosphorus-containing inclusions that comprise a large percentage of the cell volume. Many smaller sulfur inclusions are located at the convex end of the cell. Most of the cellular Fe is present in the magnetosomes. These may be arranged as a clump at the concave end of the cell, near the two flagella bundles, or as chains, or as both a clump and chains. The magnetosomes were identified as magnetite (Fe3O4) by selected area electron diffraction (SAED) and high resolution TEM. We saw a trend between cell size and organization of the magnetosomes. Smaller, more spherical cells were more likely to have chains than were larger, more oblate cells. This may indicate different populations of cells, or it may be attributed to variations in cell growth cycle. The size distribution (length) of magnetosomes in chains was similar to that of magnetosomes in clusters, except that there was a larger size range for clustered magnetosomes. Magnetosomes from ARB-1 cells average 82 nm in length. If plotted on a graph of length as a function of aspect ratio, they fall within the single domain region of the plot. If compared with the size distributions of magnetite from ALH84001 and magnetosomes from the cultured magnetotactic vibrio MV-1, the magnetites produced by ARB-1 cells are, on average, larger and have a wider range of aspect ratio. ARB-1 cells have a specific organization of the P, S, and Fe inclusions. The P inclusions always occupy the majority of the cell volume and separate the S inclusions from the disorganized clumps of magnetosomes and the flagella bundles. The P inclusions may contain polyphosphate, which could play several roles in motility, adaptation to stress, growth and division, buoyancy, and energy. The S inclusions might be a way to store S, a potential energy source, when the cells move from sulfide to oxygen zones. The consistency of P, S, and Fe organization in ARB-1 cells suggests that these inclusions have some specific and interactive functions.

Cox, Lea↗

NASA NTRS2001

Diurnal and Seasonal Cold Lands Signatures in SSM/I-scale Microwave Radiometry of the North Slope of Alaska

In this paper, we explore scaling and data assimilation-related issues associated with utilizing passive microwave satellite observations of Cold Lands-in this case, the climatologically and ecologically sensitive arctic tundra. Our approach expands on our earlier work using a one-year dataset from the Radiobrightness Energy Balance Experiment-3 (REBEX-3). REBEX-3 featured a tower-based SSM/I (Special Sensor Microwave/Imager) simulator deployed on the North Slope of Alaska in 1994-95. Two findings are significant here. First, a comparison of tower and satellite signatures at 19 and 37 GHz strongly suggested that the North Slope is radiometrically homogeneous for spatial scales up to SSM/I footprints (approximately 25 km), an unusual and valuable characteristic for monitoring and retrieving land surface conditions. And second, at the plot scale, signatures of snow/no-snow and freeze/thaw transitions were identifiable for tussock tundra land cover, so that even snow-free frozen tundra could be unambiguously distinguished from tundra covered with dry snow, another unusual and valuable characteristic. We present results from analyzing satellite brightness signatures of selected North Slope pixels corresponding to instrumented sites along a transect from the Brooks Range to the Arctic Ocean. A custom EASE (Equal Area Scalable Earth)-Grid processor was used to extract SSMJI data for every orbit with observations of this region during the 1994-95 year. The resulting high temporal-resolution (4-8 points/day), gridded data were then analyzed for evidence of the same diurnal and seasonal signatures seen at the plot scale (through micrometeorological and/or brightness data). Differences between satellite and tower brightness observations are quantified for various conditions at the REBEX-3 site. Such differences from the less-frequent and/or larger-scale satellite observations represent a form of input 'noise' in data assimilation applications. For the other sites, the performance of snow/no-snow and freeze/thaw discriminators vs. ground truth represents an opportunity to gauge the homogeneity of other pixels.

Kim, Edward J.↗

NASA NTRS2001

Durability and Damage Development in Woven Ceramic Matrix Composites

Damage development in woven SiC/SiNC ceramic matrix composites (CMC's) under tensile and cyclic loading both at room and elevated temperatures have been investigated for the exhaust nozzle of high-efficient turbine engines. The ultimate strength, failure strain, proportional limit and modulus data at a temperature range of 23 to 1250 C are generated. The tensile strength of SiC/SiNC woven composites have been observed to increase with increased temperatures up to 1000 C. The stress/strain plot shows a pseudo-yield point at 25 percent of the failure strain (epsilon(sub r)) which indicates damage initiation in the form of matrix cracking. The evolution of damage beyond 0.25 epsilon(sub f), both at room and elevated temperature comprises multiple matrix cracking, interfacial debonding, and fiber pullout. Although the nature of the stress/strain plot shows damage-tolerant behavior under static loading both at room and elevated temperature, the life expectancy of SiC/SiNC composites degrades significantly under cyclic loading at elevated temperature. This is mostly due to the interactions of fatigue damage caused by the mechanically induced plastic strain and the damage developed by the creep strain. The in situ damage evolutions are monitored by acoustic event parameters, ultrasonic C-scan and stiffness degradation. Rate equations for modulus degradation and fatigue life prediction of ceramic matrix composites both at room and elevated temperatures are developed. These rate equations are observed to show reasonable agreement with experimental results.

Haque, A.↗

NASA NTRS2002

COSP for Windows: Strategies for Rapid Analyses of Cyclic Oxidation Behavior

COSP is a publicly available computer program that models the cyclic oxidation weight gain and spallation process. Inputs to the model include the selection of an oxidation growth law and a spalling geometry, plus oxide phase, growth rate, spall constant, and cycle duration parameters. Output includes weight change, the amounts of retained and spalled oxide, the total oxygen and metal consumed, and the terminal rates of weight loss and metal consumption. The present version is Windows based and can accordingly be operated conveniently while other applications remain open for importing experimental weight change data, storing model output data, or plotting model curves. Point-and-click operating features include multiple drop-down menus for input parameters, data importing, and quick, on-screen plots showing one selection of the six output parameters for up to 10 models. A run summary text lists various characteristic parameters that are helpful in describing cyclic behavior, such as the maximum weight change, the number of cycles to reach the maximum weight gain or zero weight change, the ratio of these, and the final rate of weight loss. The program includes save and print options as well as a help file. Families of model curves readily show the sensitivity to various input parameters. The cyclic behaviors of nickel aluminide (NiAl) and a complex superalloy are shown to be properly fitted by model curves. However, caution is always advised regarding the uniqueness claimed for any specific set of input parameters,

Smialek, James L.↗

NASA NTRS2001

Nutrient Stress Detection in Corn, Using Neural Networks and AVIRIS Hyperspectral Imagery

The US Department of Agriculture (USDA) Agricultural Research Service (ARS) Variable Rate (VRAT) Nitrogen Application site in Shelton, Nebraska, represents a well-documented, corn-growing quarter section. The USDA VRAT site is used to systematically study nutrient stress in corn by varying sub-plot application of fertilizer. The field has four replicates of five blocks that vary by nitrogen treatment from 0-kg/ha to 200-kg/ha in 50-kg/ha increments. The treatment blocks are set out in a randomized, complete block design. Typically, the VRAT is planted in a ridge till, monoculture corn and is watered by a central pivot irrigation system on a three-day period. Since water stress can increase spectral reflectance from corn leaves, it is important that the N-application plots be adequately watered so that only nutrient-related stress will predominate. A figure shows imagery of the USDA VRAT site with the fertilizer amounts for each block shown. Low-altitude Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) hyperspectral imagery was acquired over the Shelton, Nebraska, VRAT site on July 22, 1999. The overflight produced 3-meter pixels with 224 spectral bands. Ground personnel supported the mission with measurements at the time of the overflight. The image data was pre-processed at JPL before being sent out to an investigator. The data arrived radiometrically corrected, allowing ready application of an atmospheric correction procedure. The Atmosphere Removal Program (ATREM) was used to perform an atmospheric correction. The AVIRIS imagery after ATREM correction was output as relative reflectance. This relative reflectance file was scaled by an empirical line procedure to provide reflectances that matched closely those measured in the field.

Estep, Lee↗

NASA NTRS1997

Stray Light Analysis

Based on a Small Business Innovation Research contract from the Jet Propulsion Laboratory, TracePro is state-of-the-art interactive software created by Lambda Research Corporation to detect stray light in optical systems. An image can be ruined by incidental light in an optical system. To maintain image excellence from an optical system, stray light must be detected and eliminated. TracePro accounts for absorption, specular reflection and refraction, scattering and aperture diffraction of light. Output from the software consists of spatial irradiance plots and angular radiance plots. Results can be viewed as contour maps or as ray histories in tabular form. TracePro is adept at modeling solids such as lenses, baffles, light pipes, integrating spheres, non-imaging concentrators, and complete illumination systems. The firm's customer base includes Lockheed Martin, Samsung Electronics and other manufacturing, optical, aerospace, and educational companies worldwide.

Source record↗

NASA NTRS2000

DMSP SSJ4 Data Restoration, Classification, and On-Line Data Access

Compress and clean raw data file for permanent storage We have identified various error conditions/types and developed algorithms to get rid of these errors/noises, including the more complicated noise in the newer data sets. (status = 100% complete). Internet access of compacted raw data. It is now possible to access the raw data via our web site, http://www.jhuapl.edu/Aurora/index.html. The software to read and plot the compacted raw data is also available from the same web site. The users can now download the raw data, read, plot, or manipulate the data as they wish on their own computer. The users are able to access the cleaned data sets. Internet access of the color spectrograms. This task has also been completed. It is now possible to access the spectrograms from the web site mentioned above. Improve the particle precipitation region classification. The algorithm for doing this task has been developed and implemented. As a result, the accuracies improved. Now the web site routinely distributes the results of applying the new algorithm to the cleaned data set. Mark the classification region on the spectrograms. The software to mark the classification region in the spectrograms has been completed. This is also available from our web site.

Wing, Simon↗

NASA NTRS2002

Indirect Field Measurement of Wine-Grape Vineyard Canopy Leaf Area Index

Leaf area index (LAI) indirect measurements were made at 12 study plots in California's Napa Valley commercial wine-grape vineyards with a LI-COR LI-2000 Plant Canopy Analyzer (PCA). The plots encompassed different trellis systems, biological varieties, and planting densities. LAI ranged from 0.5 - 2.25 sq m leaf area/ sq m ground area according to direct (defoliation) measurements. Indirect LAI reported by the PCA was significantly related to direct LAI (r(exp 2) = 0.78, p less than 001). However, the PCA tended to underestimate direct LAI by about a factor of two. Narrowing the instrument's conical field of view from 148 deg to 56 deg served to increase readings by approximately 30%. The PCA offers a convenient way to discern relative differences in vineyard canopy density. Calibration by direct measurement (defoliation) is recommended in cases where absolute LAI is desired. Calibration equations provided herein may be inverted to retrieve actual vineyard LAI from PCA readings.

Johnson, Lee F.↗

NASA NTRS2002

Surface Radiation Budget and Climate Classification

The surface radiation budget of a region is strongly tied to its climate. An 8-yr climatology of surface radiation budget components for 2.5 deg over the earth is examined in order to learn how the regional climate and surface radiation are related. The yearly cycles of a few individual regions were studied by plotting monthly mean net longwave flux as a function of net shortwave flux at the surface. These plots show trajectories that are characteristic of the climate class. The behavior of the trajectories of surface radiation and their relation to the regional climate can be understood with simple conceptual models for many cases. From an examination of these trajectories, a set of parameters is developed, such as mean net longwave flux and range of net shortwave flux, which distinguish various climate classes on the basis of the surface radiation. These criteria are applied to produce a map of regional climate classes based on surface radiation, similar to those of Koeppen or Trewartha and Horn, which were based on vegetation, temperature, and precipitation. The current maps can be used to explore the relationships between surface radiation and regional climate.

Smith, G. Louis↗

NASA NTRS2002

Application of Powder Diffraction Methods to the Analysis of the Atomic Structure of Nanocrystals: The Concept of the Apparent Lattice Parameter (ALP)

The applicability of standard methods of elaboration of powder diffraction data for determination of the structure of nano-size crystallites is analysed. Based on our theoretical calculations of powder diffraction data we show, that the assumption of the infinite crystal lattice for nanocrystals smaller than 20 nm in size is not justified. Application of conventional tools developed for elaboration of powder diffraction data, like the Rietveld method, may lead to erroneous interpretation of the experimental results. An alternate evaluation of diffraction data of nanoparticles, based on the so-called 'apparent lattice parameter' (alp) is introduced. We assume a model of nanocrystal having a grain core with well-defined crystal structure, surrounded by a surface shell with the atomic structure similar to that of the core but being under a strain (compressive or tensile). The two structural components, the core and the shell, form essentially a composite crystal with interfering, inseparable diffraction properties. Because the structure of such a nanocrystal is not uniform, it defies the basic definitions of an unambiguous crystallographic phase. Consequently, a set of lattice parameters used for characterization of simple crystal phases is insufficient for a proper description of the complex structure of nanocrystals. We developed a method of evaluation of powder diffraction data of nanocrystals, which refers to a core-shell model and is based on the 'apparent lattice parameter' methodology. For a given diffraction pattem, the alp values are calculated for every individual Bragg reflection. For nanocrystals the alp values depend on the diffraction vector Q. By modeling different a0tomic structures of nanocrystals and calculating theoretically corresponding diffraction patterns using the Debye functions we showed, that alp-Q plots show characteristic shapes which can be used for evaluation of the atomic structure of the core-shell system. We show, that using a simple model of a nanocrystal with spherical shape and centro-symmetric strain at the surface shell we obtain theoretical alp-Q values which match very well the alp-Q plots determined experimentally for Sic, GaN, and diamond nanopowders. The theoretical models are defined by the lattice parameter of the grain core, thickness of the surface shell, and the magnitude and distribution of the strain field in the surface shell. According to our calculations, the part of the diffraction pattern measured at relatively low diffraction vectors Q (below 10/angstrom) provides information on the surface strain, whle determination of the lattice parameters in the grain core requires measurements at large Q-values (above 15 - 20/angstrom).

Palosz, B.↗