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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,783 records · Page 99

Design Considerations for Controlling Silicon Nanoparticle Nucleation and Growth in a Nonthermal Plasma

Controlling the nucleation and growth of nanoparticles in low temperature plasma systems is imperative for controlling nanoparticle size distributions; and for some applications such as deposition and etching in microelectronic processing, preventing particle contamination. In this work, silicon nanoparticle (NP) production from silane is used as a model system to investigate the nucleation process. Although the mechanisms responsible for silicon NP nucleation and growth have been studied, it is unclear how controllable system parameters (e.g., pressure, system geometry, and gas composition) can be used to inhibit or promote NP formation. For example, the transport of reactive silane species is expected to significantly affect the feed fraction of silane required to nucleate silicon NP (the nucleation onset fraction) due to losses at the reactor walls. In this work, NP mass density was determined as a function of system pressure, gas composition, and reactor diameter for a tubular flow-through radiofrequency (RF) plasma using Ar/H2/He/SiH4 gas mixtures. A quartz crystal microbalance (QCM) impactor was developed to measure the total aerosol mass density downstream of the plasma and thereby identify the nucleation onset and its dependence on process parameters. Finally, a reaction mechanism was developed and incorporated into a global plasma chemistry model to better understand the nucleation onset and NP growth.

36 MATERIALS SCIENCE↗

Review of Problems in Application of Supersonic Combustion

The problem of air-breathing engines capable of flying at very high Mach numbers is described briefly. Possible performance of supersonic combustion ramjets is outlined briefly and the supersonic combustion process is described. Two mechanisms of combustion are outlined: one is supersonic combustion controlled by convection process, and the second is controlled by diffusion. The parameters related to the combustion process are discussed in detail. Data and analyses of reaction rates and mixing phenomena are represented; the flame mechanism is discussed, and experimental results are presented.

Antonio Ferri↗

Effect of 316 stainless steel powder processing conditions on microstructure

One parameter that has both economic and performance effects in the manufacturing of steel parts is the powder feedstock used. 316 L steel powder can be produced through water atomization or gas atomization, where both the powder size and the atomization process determine the cost of powder feedstock. Gas atomized powder is spherical and has a lower oxygen content than water atomized powder, making it the preferred choice for performance, but comes at a higher financial cost. Here, in this study, various 316 L powder batches are characterized to understand physical properties and microstructural variations. Density and flowability were determined using gas pycnometry and Hall flow tests. Powder morphology and porosity were qualitatively analyzed via optical microscopy and scanning electron microscopy, Finally, transmission electron microscopy was used to determine changes in phases present. Spherical gas atomized powder of 30–100 μm contained Mn$-$Si rich oxides both on the surface and within the matrix. Meanwhile, irregular water atomized powder 30 μm in diameter contained silicon oxides without manganese. All powder particles contained a nickel rich cellular structure which was shown to support the formation of additional phases. While literature has observed general microstructural features across 316 L powder particles, transmission electron microscopy (TEM) in this study has identified variations in precipitation and cell structures. Information regarding morphology, flowability, density, and phase distributions can be applied to understand variations in part consolidation, which will in turn show which powder aspects are significant for production.

Chemical segregation↗

Modeling Riverine Dissolved and Particulate Organic Carbon Fluxes from Two Small Watersheds in the Northeastern United States

The coupled carbon (C) cycle across terrestrial and aquatic environments at the watershed scale has been identified as an important, but poorly constrained component of the global carbon budget. Here, we extended Soil and Water Assessment Tool (SWAT) with coupled riverine particulate organic carbon (POC) and dissolved organic carbon (DOC) modules (referred to as SWAT-C hereafter). Results show that SWAT-C reproduced daily POC and DOC fluxes well in two watersheds in the Northeastern United States. We found that SWAT-C tended to underestimate high flows and peak DOC and POC fluxes. Uncertainty analysis indicated flux uncertainties associated with POC and DOC simulation were larger than those for flow simulation. Sensitive parameters controlling POC and DOC biogeochemical processes were identified along with how these parameters influence mechanisms underlying C cycling. We anticipate that the tool developed and applied here will inform C related ecosystem services in watershed assessment and planning.

Dissolved organic carbon, Particulate organic carb↗

Learning Robust Marking Policies for Adaptive Mesh Refinement

Here in this work, we revisit the marking decisions made in the standard adaptive finite element method (AFEM). Experience shows that a naïve marking policy leads to inefficient use of computational resources for adaptive mesh refinement (AMR). Consequently, using AMR in practice often involves ad-hoc or time-consuming offline parameter tuning to set appropriate parameters for the marking subroutine. To address these practical concerns, we recast AMR as a Markov decision process in which refinement parameters can be selected on-the-fly at run time, without the need for pre-tuning by expert users. In this new paradigm, the refinement parameters are also chosen adaptively via a marking policy that can be optimized using methods from reinforcement learning. We use the Poisson equation to demonstrate our techniques on h- and hp-refinement benchmark problems, and our experiments suggest that superior marking policies remain undiscovered for many classical AFEM applications. Furthermore, an unexpected observation from this work is that marking policies trained on one family of PDEs are sometimes robust enough to perform well on problems far outside the training family. For illustration, we show that a simple hp-refinement policy trained on 2D domains with only a single re-entrant corner can be deployed on far more complicated 2D domains, and even 3D domains, without significant performance loss. For reproduction and broader adoption, we accompany this work with an open-source implementation of our methods.

97 MATHEMATICS AND COMPUTING↗

Determination of the natural convection coefficient in low-gravity

Fire safety is an important issue in the current space program; ignition in low-g needs to be studied. The reduction in the gravitational acceleration causes changes in the ignition process. This paper examines the effect of gravity on natural convection, which is one of the important parameters in the ignition process. The NASA-Lewis 2.2 Second Drop Tower provided the low-gravity environment for the experiments. A series of experiments was conducted to measure the temperature of a small copper plate which was heated by a high intensity lamp. These experiments verified that in low-gravity the plate temperature increased faster than in the corresponding 1-g cases, and that the natural convection coefficient rapidly decreased in the low-gravity environment.

Goldmeer, J.↗

Validation and Sensitivity Analysis of a 1-D Lake Model Across Global Lakes

Lakes have important influence on weather and climate from local to global scales. However, their prediction using numerical models is notoriously difficult because lakes are highly heterogeneous across the globe, but observations are sparse. In this study, we assessed the performance of a 1-D lake model in simulating the thermal structures of 58 lakes with diverse morphometric and geographic characteristics by following the phase 2a local lake protocol of the Inter-sectoral Impact Model Intercomparison Project (ISIMIP2a). After calibration, the root-mean-square errors (RMSE) were below 2 °C for 70% and 75% of the lakes for epilimnion and full-profile temperature simulations, with an average of 1.71 °C and 1.43 °C, respectively. The model performance mainly depended on lake shape rather than location, supporting the possibility of grouping model parameters by lake shape for global applications. Furthermore, through machine-learning based parameter sensitivity tests, we identified turbulent heat fluxes, wind-driven mixing and water transparency as the major processes controlling lake thermal and mixing regimes. Snow density was also important for modeling the ice phenology of high-latitude lakes. The relative influence of the key processes and the corresponding parameters mainly depended on lake latitude and depth. Turbulent heat fluxes showed a decreasing importance in affecting epilimnion temperature with increasing latitude. Wind-driven mixing was less influential to lake stratification for deeper lakes while the impact of light extinction, on the contrary, showed a positive correlation with depth. Our findings may guide improvements in 1-D lake model parameterizations to achieve higher fidelity in simulating global lake thermal dynamics.

54 ENVIRONMENTAL SCIENCES↗

Residual thermal stresses in a solid sphere cast from a thermosetting material

Expressions are developed for the residual thermal stresses in a solid sphere cast from a chemically hardening thermosetting material in a rigid spherical mold. The description of the heat generation rate and temperature variation is derived from a first-order chemical reaction. Solidification is described by the continuous transformation of the material from an inviscid liquidlike state into an elastic solid, with intermediate properties determined by the degree of chemical reaction. Residual stress components are obtained as functions of the parameters of the hardening process and the properties of the hardening material. Variation of the residual stresses with a nondimensionalized reaction rate parameter and the relative compressibility of the hardened material is discussed in detail.

Levitsky, M.↗

Three-Dimensional Finite Element Ablative Thermal Response and Thermostructural Design of Thermal Protection Systems

A finite element ablation and thermal response program is presented for simulation of three-dimensional transient thermostructural analysis. The three-dimensional governing differential equations and finite element formulation are summarized. A novel probabilistic design methodology for thermal protection systems is presented. The design methodology is an eight step process beginning with a parameter sensitivity study and is followed by a deterministic analysis whereby an optimum design can determined. The design process concludes with a Monte Carlo simulation where the probabilities of exceeding design specifications are estimated. The design methodology is demonstrated by applying the methodology to the carbon phenolic compression pads of the Crew Exploration Vehicle. The maximum allowed values of bondline temperature and tensile stress are used as the design specifications in this study.

Dec, John A.↗

Analysis of filter tuning techniques for sequential orbit determination

This paper examines filter tuning techniques for a sequential orbit determination (OD) covariance analysis. Recently, there has been a renewed interest in sequential OD, primarily due to the successful flight qualification of the Tracking and Data Relay Satellite System (TDRSS) Onboard Navigation System (TONS) using Doppler data extracted onboard the Extreme Ultraviolet Explorer (EUVE) spacecraft. TONS computes highly accurate orbit solutions onboard the spacecraft in realtime using a sequential filter. As the result of the successful TONS-EUVE flight qualification experiment, the Earth Observing System (EOS) AM-1 Project has selected TONS as the prime navigation system. In addition, sequential OD methods can be used successfully for ground OD. Whether data are processed onboard or on the ground, a sequential OD procedure is generally favored over a batch technique when a realtime automated OD system is desired. Recently, OD covariance analyses were performed for the TONS-EUVE and TONS-EOS missions using the sequential processing options of the Orbit Determination Error Analysis System (ODEAS). ODEAS is the primary covariance analysis system used by the Goddard Space Flight Center (GSFC) Flight Dynamics Division (FDD). The results of these analyses revealed a high sensitivity of the OD solutions to the state process noise filter tuning parameters. The covariance analysis results show that the state estimate error contributions from measurement-related error sources, especially those due to the random noise and satellite-to-satellite ionospheric refraction correction errors, increase rapidly as the state process noise increases. These results prompted an in-depth investigation of the role of the filter tuning parameters in sequential OD covariance analysis. This paper analyzes how the spacecraft state estimate errors due to dynamic and measurement-related error sources are affected by the process noise level used. This information is then used to establish guidelines for determining optimal filter tuning parameters in a given sequential OD scenario for both covariance analysis and actual OD. Comparisons are also made with corresponding definitive OD results available from the TONS-EUVE analysis.

Lee, T.↗

Repairing polycrystalline IN 100 using additive manufacturing (CRADA NFE-17-06791 Final Report)

The overall goal of this Manufacturing Demonstration Facility (MDF) technical collaboration project is to extend the use of the laser blown powder additive manufacturing process to enable the repair of polycrystalline high γ' Ni base super alloys, and to qualify the repaired parts for end use. The goal of phase 1 of this project was to evaluate the cracking susceptibility of Inconel 100 samples, and to identify parameters that would yield crack free repair deposits on representative geometries using a surrogate material as a substrate. A detailed design of experiments was performed in conjunction with thermomechanical modeling to determine processing conditions. A set of process parameters were identified which yielded minimal cracking. Further modeling was used to identify the preheat condition necessary to obtain crack free deposits. Following identification of the preheat, a furnace was integrated within the chamber of the blown powder Direct Energy Deposition (DED) system, and deposits were fabricated with on a preheated furnace. The results show that crack free deposits with dimensions 35x15x0.5 mm 3 can be fabricated. With this success obtained in phase 1 the goal of phase 2, if awarded, would be to fabricate the deposit on the actual IN 100 substrates develop heat treatment procedures and qualify the repair procedures.

36 MATERIALS SCIENCE↗

Differences Between OCO‐2 and GOME‐2 SIF Products From a Model‐Data Fusion Perspective

Space-borne retrievals of solar-induced chlorophyll fluorescence (SIF) over land surfaces have recently become a resource for studying and quantifying the broad scale dynamics of gross carbon uptake (gross primary productivity—GPP) across ecosystems. To prepare for the assimilation of SIF data in terrestrial biosphere models, we examine how differences between SIF products (due to differences in acquisition characteristics and processing chain) may affect the optimization of model parameters and the resultant GPP estimate. We compare recent daily mean SIF products (one from the Orbiting Carbon Observatory-2 [OCO-2] and two from the Global Ozone Monitoring Experiment–2 [GOME-2], GlobFluo [GF] and NASA-v28 [N28], missions), averaged at 0.5° × 0.5° spatial resolution and 16-day temporal resolution, at the biome level. Phase differences between these products are relatively small. A first-order correction of the difference in spectral sampling between the two instruments shows that OCO-2 and N28 are consistent in terms of magnitude and amplitude, while GF is twice as large as the others. Using a bias-blind toy data assimilation framework, we analyze how biases between SIF products, and between model and products, can be partially alleviated by optimizing the slope and intercept parameters of a linear GPP-SIF operator. As observation biases can transfer to biases in other optimized process-based parameters and to modeled carbon fluxes— thereby resulting in unidentified inaccurate parameter values—we argue that potential SIF biases should be treated cautiously in real-world experiments in order to achieve realistic and reliable future simulations.

Gross primary production↗

An Analytic Framework for Optimal Milling Parameter Selection

The selection of optimal parameters is an important step in machining process definition. This paper presents a decision analytic framework for completing this task. The approach is demonstrated for titanium milling. An influence diagram showing the decision situation, the corresponding uncertainties, and the value is presented. The optimization objective is the selection of machining parameters that minimize cost while considering uncertainty in tool life and stability. The uncertainties are characterized using a probability distribution taking into account all available information. The cost associated with tool failure and unstable cutting conditions is incorporated in the cost formulation. A process probability tree showing the uncertainties and the corresponding costs is constructed. The optimization results show a 90% reduction in machining cost as compared to tool manufacturer-recommended parameters. The proposed framework is normative and robust and can be applied for optimizing process parameters in conventional (such as milling and turning) and non-conventional (such as electric discharge machining, electro-chemical machining) processes. A discussion section regarding inference, experimental design, and risk aversion is included.

Karandikar, Jaydeep↗

Oxygen production System Models for Lunar ISRU

In-Situ Resource Utilization (ISRU) seeks to make human space exploration feasible; by using available resources from a planet or the moon to produce consumables, parts, and structures that otherwise would be brought from Earth. Producing these in situ reduces the mass of such that must be launched and doing so allows more payload mass' for each mission. The production of oxygen from lunar regolith, for life support and propellant, is one of the tasks being studied under ISRU. NASA is currently funding three processes that have shown technical merit for the production of oxygen from regolith: Molten Salt Electrolysis, Hydrogen Reduction of Ilmenite, and Carbothermal Reduction. The ISRU program is currently developing system models of, the , abovementioned processes to: (1) help NASA in the evaluation process to select the most cost-effective and efficient process for further prototype development, (2) identify key parameters, (3) optimize the oxygen production process, (4) provide estimates on energy and power requirements, mass and volume.of the system, oxygen production rate, mass of regolith required, mass of consumables, and other important parameters, and (5) integrate into the overall end-to-end ISRU system model, which could be integrated with mission architecture models. The oxygen production system model is divided into modules that represent unit operations (e.g., reactor, water electrolyzer, heat exchanger). Each module is modeled theoretically using Excel and Visual Basic for Applications (VBA), and will be validated using experimental data from on-going laboratory work. This modularity (plug-n-play) feature of each unit operation allows the use of the same model on different oxygen production systems simulations resulting in comparable results. In this presentation, preliminary results for mass, power, volume will be presented along with brief description of the oxygen production system model.

Santiago-Maldonado, Edgardo↗

Sparse regression for plasma physics

Many scientific problems can be formulated as sparse regression, i.e., regression onto a set of parameters when there is a desire or expectation that some of the parameters are exactly zero or do not substantially contribute. This includes many problems in signal and image processing, system identification, optimization, and parameter estimation methods such as Gaussian process regression. Sparsity facilitates exploring high-dimensional spaces while finding parsimonious and interpretable solutions. In the present work, we illustrate some of the important ways in which sparse regression appears in plasma physics and point out recent contributions and remaining challenges to solving these problems in this field. Further, a brief review is provided for the optimization problem and the state-of-the-art solvers, especially for constrained and high-dimensional sparse regression.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Development of an analytical transient evacuation model for the fairing jettison process

A general, lumped-parameter, control volume equation is developed to describe the rapid loss of pressure associated with a launch vehicle fairing jettison event in its initial phase. Beginning with a general mass conservation statement, a sonic constraint is applied to the expanding gap between receding fairing halves to produce a statement for transient density. This is related to fairing pressure by assuming the expansion may be described by a polytropic process. A generic, single-step, lateral fairing half separation case is created and explored for illustrative purposes.

Fairing depressurization↗

Development of an analytical transient evacuation model for the fairing jettison process

A general, lumped-parameter, control volume equation is developed to describe the rapid loss of pressure associated with a launch vehicle fairing jettison event in its initial phase. Beginning with a general mass conservation statement, a sonic constraint is applied to the expanding gap between receding fairing halves to produce a statement for transient density. This is related to fairing pressure by assuming the expansion may be described by a polytropic process. A generic, single-step, lateral fairing half separation case is created and explored for illustrative purposes.

fairing depressurization↗

Development of an Analytical Transient Evacuation Model for the Fairing Jettison Process

A general, lumped-parameter, control volume equation is developed to describe the rapid loss of pressure associated with a launch vehicle fairing jettison event in its initial phase. Beginning with a general mass conservation statement, a sonic constraint is applied to the expanding gap between receding fairing halves to produce a statement for transient density. This is related to fairing pressure by assuming the expansion may be described by a polytropic process. A generic, single-step, lateral fairing half separation case is created and explored for illustrative purposes.

fairing depressurization, jettison, venting↗