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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Intrinsic oxygen fugacity measurements of some Allende Type B inclusions

The intrinsic oxygen fugacities (IOFs) of two type B Ca-rich and Al-rich inclusions (CAI) from the Allende meteorite were measured using the solid-electrolyte double-cell IOF technique of Ulmer et al. (1976). The measurements were compared to calculated and experimentally extrapolated fO2 of type B phases. It was found that the IOFs of the type B are 6-8 orders of magnitude more oxidized (H2/H2O = 1-10) than the canonical solar nebular gas (H2/H2O = 100-2000). It is suggested that some local fO2 enhancing mechanism, such as dust or gas concentrations, or the release of oxygen-rich vapors during CAI volatilization in the type B inclusions was in operation at temperatures higher than 700 C.

Kozul, Jean M.↗

Electrochemical measurements and thermodynamic calculations of redox equilibria in pallasite meteorites - Implications for the eucrite parent body

The intrinsic oxygen fugacity (IOF) of olivine separates from the Salta, Springwater, and Eagle Station pallasites was measured between 850 and 1150 C using oxygen-specific solid zirconia electrolytes at 100,000 Pa. Thermodynamic calculations of redox equilibria involving equalibrium pallasite assemblages are in good agreement with the experimental results and provide a lower limit to pallasite redox stability; others involving disequilibrium assemblages, suggest that pallasites experienced localized, late-stage oxidation and reduction effects. Consideration of the redox buffer metal-olivine-orthopyroxene utilizing calculated Eucrite Parent Body (EPB) mantle phase compositions indicates that small redox gradients may have existed in the EPB. Such gradients may have produced strong compositional variation within the EPB. In addition, there is apparently significant redox heterogeneity in the source area of Eagle Station Trio pallasites and Bocaiuva iron meteorites.

Righter, Kevin↗

Micromechanics Modeling of Fracture in Nanocrystalline Metals

Nanocrystalline metals have very high theoretical strength, but suffer from a lack of ductility and toughness. Therefore, it is critical to understand the mechanisms of deformation and fracture of these materials before their full potential can be achieved. Because classical fracture mechanics is based on the comparison of computed fracture parameters, such as stress intlmsity factors, to their empirically determined critical values, it does not adequately describe the fundamental physics of fracture required to predict the behavior of nanocrystalline metals. Thus, micromechanics-based techniques must be considered to quanti@ the physical processes of deformation and fracture within nanocrystalline metals. This paper discusses hndamental physicsbased modeling strategies that may be useful for the prediction Iof deformation, crack formation and crack growth within nanocrystalline metals.

Glaessgen, E. H.↗

Summary of NACA/NASA Variable-Sweep Research and Development Leading to the F-111 (TFX)

On November 24, 1962, the United States ushered in a new era of aircraft development when the Department of Defense placed an initial development contract for the world's first supersonic variable-sweep aircraft - the F-111 or so-called TFX (tactical fighter-experimental). The multimission performance potential of this concept is made possible by virtue of the variable-sweep wing - a research development of the NASA and its predecessor, the NACA. With the wing swept forward into the maximum span position, the aircraft configuration is ideal for efficient subsonic flight. This provides long-range combat and ferry mission capability, short-field landing and take-off characteristics, and compatibility with naval aircraft carrier operation. With the wing swept back to about 650 of sweep, the aircraft has optimum supersonic performance to accomplish high-altitude supersonic bombing or interceptor missions. With the wing folded still further back, the aircraft provides low drag and low gust loads during supersonic flight "on the deck" (altitudes under 1000 feet). The concept of wing variable sweep, of course, is not new. Initial studies were conducted at Langley as early as 1945, and two subsonic variable-sweep prototypes (Bell X-5 and Grumman XF-IOF) were flown as early as 1951/52. These were subsonic aircraft, however, and the great advantage of variable sweep in improving supersonic flight efficiency could not be realized. Further~ the structures of these early aircraft were complicated by the necessity for translating the ~ing fore and aft to achieve satisfactory longitUdinal stability as the wing sweep was varied. Late in 1958 a research breakthrough at Langley provided the technology for designing a variable-sweep wing having satisfactory stability through a wide sweep angle range without the necessity for fore and aft translation of the wing. In this same period there evolved within the military services an urgent requirement for a versatile fighter-bomber that could fly efficiently at subsonic and supersonic speeds at high altitude and "on the deck". The application of variable sweep to this mission requirement then became obvious.

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