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Terrestrial Exospheric Dayside H-density Profile at 3 - 15 RE from UVIS/HDAC and TWINS Lyman-alpha Data Combined

Terrestrial ecliptic dayside observations of the exospheric Lyman-α column intensity between 3–15 Earth radii (RE) by UVIS/HDAC (UVIS – ultraviolet imaging spectrograph; HDAC – hydrogen-deuterium absorption cell) Lyman-α photometer at CASSINI have been analyzed to derive the neutral exospheric H-density profile at the Earth’s ecliptic dayside in this radial range. The data were measured during CASSINI’s swing-by maneuver at the Earth on 18 August 1999 and are published by Werner et al. (2004). In this study the dayside HDAC Lyman-α observations published by Werner et al. (2004) are compared to calculated Lyman-α intensities based on the 3D H-density model derived from TWINS (Two Wide-angle Imaging Neutral-atom Spectrometers) Lyman-α observations between 2008–2010 (Zoennchen et al., 2015). It was found that both Lyman-α profiles show a very similar radial dependence in particular between 3–8RE. Between 3.0–5.5RE impact distance Lyman-α observations of both TWINS and UVIS/HDAC exist at the ecliptic dayside. In this overlapping region the cross-calibration of the HDAC profile against the calculated TWINS profile was done, assuming that the exosphere there was similar for both due to comparable space weather conditions. As a result of the cross-calibration the conversion factor between counts per second and rayleigh, fc = 3.285 counts s−1R−1, is determined for these HDAC observations. Using this factor, the radial H-density profile for the Earth’s ecliptic dayside was derived from the UVIS/HDAC observations, which constrained the neutral H density there at 10RE to a value of 35 cm-3. Furthermore, a faster radial H-density decrease was found at distances above 8RE (≈r−2.37) compared to the lower distances of 3–7RE (≈r−2.37). This increased loss of neutral H above 8RE might indicate a higher rate of H ionization in the vicinity of the magnetopause at 9–11RE (near subsolar point) and beyond, because of increasing charge exchange interactions of exospheric H atoms with solar wind ions outside the magnetosphere.

Jochen H Zoennchen↗

Thermal Analysis, Compressibility, and Decomposition of Synthetic Bastnäsite-(La) to Lanthanum Oxyfluoride

Understanding basic material properties of rare earth element (REE) bearing minerals such as their phase stability and equations of state can assist in understanding how economically viable deposits might form. Bastnäsite is the most commonly mined REE bearing mineral. We synthesized the lanthanum-fluoride end member, bastnäsite-(La) (LaCO3F), and investigated its thermal behavior and decomposition products from 298 K to 1173 K under ambient pressure conditions through thermogravimetric analysis, differential scanning calorimetry, evolved gas analysis, and high temperature powder X-ray diffraction. We also investigated the compressibility of bastnäsite-(La) via single crystal X-ray diffraction in diamond anvil cells at an ambient temperature up to 11.3 GPa and from 4.9 GPa to 7.7 GPa up to 673 K. At ambient pressure, bastnäsite-(La) was stable up to 598 K in air, where it decomposed into CO2 and tetragonal γ-LaOF. Above 948 K, cubic α-LaOF is stable. High temperature X-ray diffraction data were used to fit the Fei thermal equation of state and the thermal expansion coefficient α(sub 298) for all three materials. Bastnäsite-(La) was fit from 298 K to 723 K with V(sub 0) = 439.82 Å(exp 3), α(sub 298) = 4.32 × 10(exp -5) K(exp -1), a(sub 0) = −1.68 × 10(exp -5) K(exp -1), a(sub 1) = 8.34 × 10(exp -8) K(exp -1), and a(sub 2) = 3.126 K(exp -1). Tetragonal γ-LaOF was fit from 723 K to 948 K with V(sub 0) = 96.51 Å(exp 3), α(sub 298) = 2.95×10(exp -4) K(exp -1), a(sub 0) = −2.41×10(exp -5) K(exp -1), a(sub 1) = 2.42×10(exp -7) K(exp -1), and a(sub 2) = 41.147 K(exp -1). Cubic α-LaOF was fit from 973 K to 1123 K with V(sub 0) = 190.71 Å(exp 3), α(sub 298) = −1.12×10(exp -5) K(exp -1), a(sub 0) = 2.36×10(exp -4) K(exp -1), a(sub 1) = −1.73 × 10(exp -7) K(exp -1), and a(sub 2) = −17.362 K(exp -1). An ambient temperature third order Birch–Murnaghan equation of state was fit with V(sub 0) = 439.82 Å(exp 3), K(sub 0) = 105 GPa, and K’ = 5.58.

Bastnäsite↗