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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Assessing the Adhesion of Nanofibrous PVDF-HFP as Passive Thermal Control Coatings for the Extraterrestrial Storage of Cryogenic Propellants

Cryogenic propellant passive thermal management techniques in space are essential complements to active thermal management methods, helping reduce absolute dependence on the latter. Particularly, materials with superior optical properties (high solar reflectance and infrared emittance) would be beneficial for passive thermal control to reject most of the incident solar radiation and enhance thermal emission from the storage tank, leading to self-cooling. We developed a nanofibrous, porous passive thermal control material by electrospinning polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) co-polymer onto an aluminum foil substrate. The material exhibits a very high solar reflectance (>99%) and infrared emittance (~86%) when characterized in the ultraviolet-visible-near infrared and mid-infrared wavelengths. This study focuses on the adhesion of the nanofibrous PVDF-HFP to the substrate. We incorporated in-lab fabricated and commercial adhesives, under normal room conditions, between the nanofibers and the aluminum foil substrate to improve their adhesion. Some samples were also exposed to space-like conditions – vacuum and thermal cycling, to investigate their effects on the strengths of adhesives. Subsequently, adhesion peel tests were conducted on all the samples to assess the peel strengths of the bonds. Peel test strengths after space environment conditioning of the adhesives were generally higher than those observed in the pristine, unaged samples. The results are discussed in this study.

Chieloka Ibekwe

In-Space Demonstration of Spray-on Solar White Paint

Discs coated with spray-on solar white and two similar thermal control coatings were flown in low earth orbit for roughly five hours. While in orbit, the coated discs were exposed to direct sunlight and to deep space for short intervals. Measurements of disc temperatures showed that the spray-on solar white coating had the lowest absorption of sunlight. Numerical modeling was used to infer that spray-on solar white had a solar absorptance between 0.02 and 0.04 and a thermal emittance between 0.93 and 0.99, both of which are consistent with terrestrial laboratory measurements.

Solar White

Investigating Dual Electrospinning as a Means of Enhancing Passive Thermal Control Coatings for Cryogenic Propellant Storage in Extraterrestrial Environments

Passive thermal control is necessary as space exploration becomes increasingly widespread. Materials with superior optical properties (high solar reflectance and infrared emittance) are critical for passive thermal control because they can reject most of the incident solar radiation and promote thermal emission from cryogenic propellant storage tanks, enabling the extraterrestrial storage of cryogens. We have demonstrated in previous studies that electrospun nanofibers exhibit exceptional optical properties, offering significant benefits for passive radiative cooling in space. Particularly, electrospun polyvinylidene fluoride-co-hexafluoropropylene PVDF-HFP nanofibers demonstrate exceptionally high solar reflectance (>99%) and strong thermal emittance (measured at ~300 K). However, they exhibit nanostructural changes in the presence of atomic oxygen, which is prevalent in Low Earth Orbit. This study focuses on creating a unique blend of polymeric (PVDF-HFP) and ceramic-based (silica) nanofibers by leveraging the chemical stability and atomic oxygen resistance of silica, using the dual electrospinning manufacturing method. This approach aims to preserve the structural properties of the polymeric counterpart without compromising its optical performance, thereby providing an innovative method for manufacturing environmentally resilient passive thermal control nanofibers with desirable optical and thermal control functionalities for extraterrestrial storage of cryogenic propellants.

Chieloka Ibekwe

Application of Energy-efficient Electromagnetic Melt-Processing for the Upcycling of Recycled Polyphenylene Sulfide into Multifunctional Segregated Nanocomposites

Polyphenylene sulfide (PPS) is widely used in structural and functional composites because of its thermal stability, chemical resistance, and mechanical strength. As circular manufacturing becomes increasingly important, extending the service life of recycled PPS (rPPS) is essential. However, conventional high-temperature reprocessing accelerates thermo-oxidative degradation, reducing recycled composite performance. This study proposes a rapid and potentially energy-saving upcycling strategy for rPPS using electromagnetic (EM) melt-processing to form segregated carbon nanotube (CNT) networks and produce EM-responsive nanocomposites. The aim was to determine whether CNT-assisted EM heating could reduce polymer degradation while improving multifunctional properties at ultralow filler loadings. rPPS micropellets were coated with CNTs by ball milling to create conductive shells, then compacted into green bodies (GBs) and selectively melted by rapid EM irradiation. Structural, electrical, mechanical, rheological, and electromagnetic interference (EMI) shielding properties were evaluated. Electrical percolation occurred at an ultralow CNT loading of 0.08 wt%, with conductivity reaching (1.24 ± 0.74) × 10 -5 S⋅m -1 at 0.1 wt%. At this concentration, tensile strength and modulus increased by 72% and 99%, respectively. At ~ 0.7 mm thickness, X-band EMI shielding effectiveness reached 6 dB for GBs and 3 dB after EM processing. This shows that EM melt-processing upcycles rPPS into high-performance multifunctional nanocomposites with minimum thermal degradation.

recycled

Surprisingly Enriched CO and CH4 in Halley-type Comet 13P/Olbers: Clues to Its Interstellar Heritage

The native ice composition of Halley-type Comet 13P/Olbers (hereafter 13P) was measured post-perihelion, on UT 2024 August 16 using iSHELL, the 1–5 μm cross-dispersed, high-resolution facility spectrograph at the NASA InfraRed Telescope Facility. At that time, the heliocentric distance (Rh) of 13P was 1.37 au and the geocentric distance (Δ) was 1.99 au. Using a slit that delivered spectral resolving power RP λ/Δλ 4.5 × 104, two instrument settings targeted rovibrational emissions of seven parent molecules released into the coma through sublimation of ices in the nucleus. These settings provided broad and contiguous or nearly contiguous spectral coverage, one simultaneously measuring H2O, CO, and OCS, and the other simultaneously measuring CH4, C2H6, CH3OH, and H2CO. Meaningful abundances were obtained for all seven species. Our study revealed substantial enrichments of CO and CH4, the two most volatile species systematically targeted at IR wavelengths in comets. Relative to their respective mean abundance ratios among measured comets from the Oort cloud reservoir, CO in 13P was enriched by a factor of about six and CH4 was enriched by a factor of about three. Together with near-average abundances measured for CH3OH and C2H6, this suggests large endowments of CO and CH4 on interstellar grains, yet it could indicate inhibited surface chemistry on the pre-cometary grains subsequently contained in the nucleus or 13P. Assuming that this represents the primordial composition of 13P, it could reflect very low temperatures in its natal environment (∼10 K or lower).

Michael A Disanti

Evaluation of Long-Term Storage Stability and Operational Efficiency of Rapid Cycle Amine Adsorbents

With the recent incorporation of Mars Extravehicular Activity (EVA) into the 2025 NASA roadmap, Rapid Cycle Amine (RCA) technology advancement within the Exploration Extravehicular Mobility Unit (xEMU) applies to both the upcoming Lunar Artemis missions and future human exploration of Mars. The incorporation of commercial spacesuit vendors to service NASA’s crewed-space programs since 2021 has increased the demand for regenerable, RCA-based carbon dioxide (CO2) and humidity control adsorbents. The regenerable RCA subunit is the most advanced, long-term solution for CO2 removal and humidity control, enabling both lunar and Martian EVAs. The adsorbent selected for use within the RCA unit must exhibit sufficient storage stability and operational efficiency for prolonged missions. As XploSafe worked to simultaneously develop both a recirculating sub-atmospheric test rig and adsorbents for the RCA system within the xEMU, several novel adsorbents were evaluated for long-term storage stability in support of future extended-duration missions. The chosen materials were periodically evaluated by nuclear magnetic resonance (NMR) spectroscopy, thermal desorption-coupled with gas chromatography/mass spectrometry (TD-GC/MS), and CO2 adsorption to assess long-term storage efficacy across various environmental storage conditions. NMR spectroscopy was utilized by extracting the active CO2 adsorbing chemical from the solid support with deuterated solvent and comparing the spectra over time for degradation and change. The solid adsorbents were also analyzed via TD-GC/MS to reveal any potential off-gassing chemicals over time. Additionally, XploSafe’s breakthrough test rig was utilized to dose the solid adsorbents with a 585 BTU/h metabolic rate flow-equivalent CO2 stream and monitored for 0–99% CO2 breakthrough. The performance metrics from the breakthrough analysis were compared over the storage study duration for CO2 removal and humidity control. Xplo-SA9T was evaluated for 24 months, whereas two additional adsorbent variants, MMPA-Sorbent and LPEI-Sorbent, were each evaluated for 12 months.

John R Tidwell

Performance Results of a Digital Test Signal Generator

Performance results of a digital test signal-generator hardware-demonstration unit are reported. Capabilities available include baseband and intermediate frequency (IF) spectrum generation, for which test results are provided. Repeatability in the setting of a given signal-to-noise ratio (SNR) when a baseband or an IF spectrum is being generated ranges from 0.01 dB at high SNR's or high data rates to 0.3 dB at low data rates or low SNR's. Baseband symbol SNR and carrier SNR (P c /N o ) accuracies of 0.1 dB were verified with the built-in statistics circuitry. At low SNR's that accuracy remains to be fully verified. These results were confirmed with measurements from a demodulator synchronizer assembly for the baseband spectrum generation, and with a digital receiver (Pioneer 10 receiver) for the IF spectrum generation.

B O Gutierrez-Luaces

Computation of Optimal Interplanetary Low-Thrust Trajectories With Bounded Thrust Magnitude By Means of the Generalized Newton-Raphson Method

The generalized Newton-Raphson method, an iterative procedure for solving nonlinear operator equations, has been extended in application to variational problems with bounded control variables. A minimum fuel interplanetary low thrust orbital transfer problem is worked out in detail to demonstrate the practical aspects of the algorithm as well as its computational effectiveness. The control variables are the thrust magnitude, limited from zero to some prescribed maximum value, and the thrust steering angle.

Computation

Propulsion and Power Generation

This document comprises material presented during one session of the Manned Planetary Mission Technology Conference, Lewis Research Center, May 21, 22, and 23, 1963. In order to expedite release to the conferees, the papers are being published with minimum editing and retyping of the original manuscripts. Thus the usual NASA format and style have been compromised. The purpose of the conference was to explore the possibilities and problems of manned planetary space flight. The results and contemplations of the individual papers should in no sense be regarded as a part of NASA plans and programs.

F L Williams

Advancing the Oxygen Generation Assembly Design to Increase Reliability and Reduce Costs for a Future Long Duration Mission

The state-of-the-art Oxygen Generation Assembly (OGA) has been reliably producing breathing oxygen for the crew aboard the International Space Station (ISS) for over eight years. Lessons learned from operating the ISS OGA have led to proposing incremental improvements to advance the baseline design for use in a future long duration mission. These improvements are intended to reduce system weight, crew maintenance time and resupply mass from Earth while increasing reliability. The proposed improvements include replacing the cell stack membrane material, deleting the nitrogen purge equipment, replacing the hydrogen sensors, deleting the wastewater interface, replacing the hydrogen dome and redesigning the cell stack power supply. The development work to date will be discussed and forward work will be outlined. Additionally, a redesigned system architecture will be proposed.

Kevin C Takada

Control of an Axisymmetric Jet Using Vortex Generators

The results of an experimental investigation on the effect of vortex generators, in the form of small tabs at the nozzle exit on the evolution of a jet, are reported in this paper. Primarily tabs of triangular shape are considered, and the effect is studied up to a jet Mach number of 1.8. Each tab is found to produce a dominant pair of counter-rotating streamwise vortices having a sense of rotation opposite to that expected from the wrapping of the boundary layer. This results in an inward indentation of the mixing layer into the core of the jet. A triangular-shaped tab with its apex leaning downstream, referred to as a delta tab, is found to be the most effective in producing such vortices, with a consequential large influence on the overall jet evolution. Two delta tabs, spaced 180 deg apart, completely bifurcate the jet. Four delta tabs stretch the mixing layer into four 'fingers,' resulting in a significant increase in the jet mixing downstream. For six delta tabs the mixing layer distortion settles back to a three finger configuration through an interaction of the streamwise vortices. The tabs are found to be equally effective in jets with turbulent or laminar initial boundary layers. Two sources of streamwise vorticity are postulated for the flow under consideration. One is the upstream 'pressure hill,' generated by the tab, which constitutes the main contributor of vorticity to the dominant pair. Another is due to vortex filaments shed from the sides of the tab and reoriented downstream by the mean shear of the mixing layer. Depending on the orientation of the tab, the latter source can produce a vortex pair having a sense of rotation opposite to that of the dominant pair. In the case of the delta tab, vorticity from the two sources add, explaining the strong effect in that configuration.

Streamwise Vorticity

Electrodynamic Tethers. 1: Power Generator in LEO. 2: Thrust for Propulsion and Power Storage

An electrodynamic tether consists of a long insulated wire in space whose orbital motion cuts across lines of magnetic flux to produce an induce voltage that in typical low orbits averages about 200 v/km. Such a system should be capable of generating substantial electrical power, at the expense of IXB drag acting on its orbital energy. If a reverse current is driven against the induced voltage, the system should act as a motor producing IXB thrust. A reference system was designed, capable of generating 20 KW of power into an electrical load located anywhere along the wire at the expense of 2.6N (20,000 J/sec) drag on the wire. In an ideal system, the conversion between mechanical and electrical energy would reach 100% efficiency. In the actual system part of the 20 KW is lost to internal resistance of the wire, plasma and ionosphere, while the drag force is increased by residual air drag. The 20 KW PMG system as designed is estimated to provide 18.7 KW net power to the load at total drag loss of 20.4 KJ/sec, or an overall efficiency of 92%. Similar systems using heavier wire appear capable of producing power levels in excess of 1 Megawatt at voltages of 2-4 KV, with conversion efficiency between mechanical and electrical power better than 95%. The hollow cathode based system should be readily reversible from generator to motor operation by driving a reverse current using onboard power.

James E Mccoy

Americium-Fuelled Radioisotope Stirling Generator Elegant Breadboard

High power solutions for spacecraft are becoming increasingly sought after in the new era of space exploration, with energy intensive in-situ lunar surface exploration becoming a key part of the roadmap for major space agencies, as well as commercial companies. Nuclear power provides the most feasible solution to achieve continued operation through the long lunar night, and in extended periods in Permanently Shadowed Regions (PSRs). Americium-241 (241Am) is used as the fuel of choice in European Radioisotope Power Systems (RPS). The University of Leicester have developed a number of systems using this fuel type, including a 200 Wth heat source. Building on existing international partnerships, the University of Leicester is continuing to work with NASA Glenn Research Center (GRC) to maximise the electrical output that can be generated from the heat source by progressing the radioisotope-Stirling generator concept to elegant breadboard level, building on the long heritage of dynamic power conversion developments at NASA Glenn. Presented in the following conference paper is the next iteration of the Americium-fuelled Radioisotope Stirling Generator (Am-RSG) Elegant Breadboard, following on from a successful technology demonstration design conducted at NASA Glenn in early 2025. The design laid-out in this paper is a more flight-like version of the technology demonstrator, and is intended to pair with the next generation of Stirling convertor technology, the SunPower Robust Stirling Converter (SRSC). The SRSC is able to operate more efficiently at lower thermal power levels than the previous Advanced Stirling Convertor (ASC), making it more suitable for the 241Am system.

Lunar

Next-Generation Hard X-ray Missions: SuperHERO and HEROIX

High-energy X-ray observations have transformed our understanding of astrophysical systems where non-thermal processes dominate, from shock-accelerated particles in supernova remnants to relativistic jets and hot coronae in active galactic nuclei. NuSTAR’s pioneering focusing images of the hard X-ray sky have demonstrated the immense scientific potential of this band, while also highlighting how limited angular resolution constrains our ability to fully characterize complex physical processes in faint extended sources and resolving faint sources in crowded sky regions. In this presentation, I will discuss a pathway to overcome these challenges through NASA Marshall Space Flight Center’s replicated NiCo full-shell X-ray mirror technology. Specifically, I will discuss the SuperHERO hard X-ray telescope to achieve better than 10-arcsecond half-power diameter (HPD) angular resolution on a balloon flight observing the Crab Nebula, and the High EneRgy Observatory for Imaging X-rays (HEROIX) Medium-Class Mission concept to achieve an integrated effective area of 570 cm2 at 30 keV with 5 arcsec HPD angular resolution.

AGN

The Role of Disruptive Impacts on Ocean Generation and Longevity in Icy Moons

Among icy moons of the outer Solar System, subsurface water oceans and large collisions both seem to be common, but the impact of the latter on the presence and persistence of the former is unclear and has rarely been investigated. Here we interface a smoothed-particle hydrodynamics model to simulate collisions with a thermal-structural evolution model to simulate the evolution of moons pre-collision, post-collision and without a collision. Overall, even such large-scale collisions affect only the ocean thickness or longevity, and the presence or absence of an ocean is affected for only a part of a moon’s history. In reaccreted moons, the ocean survives the impact and becomes much thicker inside larger moons with radius near 1,000 km, whereas an ocean that would otherwise arise inside moons with radius near 500 km is absent because the collision promotes ice–rock differentiation. Our simulations have not yielded an ocean developed post-impact—whether directly via collisional or reaccretional heating or indirectly through tidal heating due to collision-induced orbital changes—in a moon that would otherwise have remained frozen. The ocean-enhancing effect is pronounced only for late disruptive impacts onto large, 1,000-km-class targets, which are unlikely in recent solar system history.

Marc Neveu