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Results for “ABSORBERS (MATERIALS)”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Submillimeter and millimeter wave characterization of absorbing materials

Several microwave absorbers have been characterized in terms of transmittance and reflectance at frequencies between 35 GHz and 3 THz. The materials studied were a series of iron-loaded cast epoxy absorbers known as Eccosorb. Measurements show that reflectance and absorption coefficient increase with the iron density. A dramatic decrease, by as much as a factor of 2, in absorption coefficient was observed when the samples were cooled from ambient to cryogenic temperatures. A blackbody calibrator to be operated at liquid helium temperature was constructed using the measured optical constants for these absorbers. The measured absorption coefficient for cold Eccosorb CR-110 is within 20 percent of that reported recently by Peterson and Richards.

Hemmati, H.↗

Absorber Materials for Transition-Edge Sensor X-ray Microcalorimeters

Arrays of superconducting transition-edge sensors (TES) can provide high spatial and energy resolution necessary for x-ray astronomy. High quantum efficiency and uniformity of response can be achieved with a suitable absorber material, in which absorber x-ray stopping power, heat capacity, and thermal conductivity are relevant parameters. Here we compare these parameters for bismuth and gold. We have fabricated electroplated gold, electroplated gold/electroplated bismuth, and evaporated gold/evaporated bismuth 8x8 absorber arrays and find that a correlation exists between the residual resistance ratio (RRR) and thin film microstructure. This finding indicates that we can tailor absorber material conductivity via microstructure alteration, so as to permit absorber thermalization on timescales suitable for high energy resolution x-ray microcalorimetry. We show that by incorporating absorbers possessing large grain size, including electroplated gold and electroplated gold/electroplated bismuth, into our current Mo/Au TES, devices with tunable heat capacity and energy resolution of 2.3 eV (gold) and 2.1 eV (gold/bismuth) FWHM at 6 keV have been fabricated.

Brown, Ari-David↗

Magnetic field effects on microwave absorbing materials

The objective of this program was to gather information to formulate a microwave absorber that can work in the presence of strong constant direct current (DC) magnetic fields. The program was conducted in four steps. The first step was to investigate the electrical and magnetic properties of magnetic and ferrite microwave absorbers in the presence of strong magnetic fields. This included both experimental measurements and a literature survey of properties that may be applicable to finding an appropriate absorbing material. The second step was to identify those material properties that will produce desirable absorptive properties in the presence of intense magnetic fields and determine the range of magnetic field in which the absorbers remain effective. The third step was to establish ferrite absorber designs that will produce low reflection and adequate absorption in the presence of intense inhomogeneous static magnetic fields. The fourth and final step was to prepare and test samples of such magnetic microwave absorbers if such designs seem practical.

Goldberg, Ira↗

Measurements of the light-absorbing material inside cloud droplets and its effect on cloud albedo

Most of the measurements of light-absorbing aerosol particles made previously have been in non-cloudy air and therefore provide no insight into aerosol effects on cloud properties. Here, researchers describe an experiment designed to measure light absorption exclusively due to substances inside cloud droplets, compare the results to related light absorption measurements, and evaluate possible effects on the albedo of clouds. The results of this study validate those of Twomey and Cocks and show that the measured levels of light-absorbing material are negligible for the radiative properties of realistic clouds. For the measured clouds, which appear to have been moderately polluted, the amount of elemental carbon (EC) present was insufficient to affect albedo. Much higher contaminant levels or much larger droplets than those measured would be necessary to significantly alter the radiative properties. The effect of the concentrations of EC actually measured on the albedo of snow, however, would be much more pronounced since, in contrast to clouds, snowpacks are usually optically semi-infinite and have large particle sizes.

Twohy, C. H.↗

Broad line region clouds and the absorbing material in NGC 4151

A discussion is presented of the constraints imposed by X-ray, UV and optical observations on the absorbing material in the Seyfert 1.5 galaxy NGC 4151, comparing said observations with both photoionization model predictions of broad line region clouds and models of the narrow line region gas. The weakness of both semiforbidden C III 1909 and the broad component of H-alpha relative to C IV 1549, in conjunction with the absence of an absorption Balmer jump, indicate a broad line region ionization parameter that is greater in NGC 4151 than in QSO clouds by a factor of 30. The present calculations suggest that narrow line region clouds have a composition similar to extragalactic giant H II regions, with the H line spectrum showing that dust is mixed with narrow line region gas. It is hypothesized that broad line region clouds are likely to be in a radiatively driven wind, and it is shown that such clouds are opaque to radio emission.

Ferland, G. J.↗

A Novel, Real-Valued Genetic Algorithm for Optimizing Radar Absorbing Materials

A novel, real-valued Genetic Algorithm (GA) was designed and implemented to minimize the reflectivity and/or transmissivity of an arbitrary number of homogeneous, lossy dielectric or magnetic layers of arbitrary thickness positioned at either the center of an infinitely long rectangular waveguide, or adjacent to the perfectly conducting backplate of a semi-infinite, shorted-out rectangular waveguide. Evolutionary processes extract the optimal physioelectric constants falling within specified constraints which minimize reflection and/or transmission over the frequency band of interest. This GA extracted the unphysical dielectric and magnetic constants of three layers of fictitious material placed adjacent to the conducting backplate of a shorted-out waveguide such that the reflectivity of the configuration was 55 dB or less over the entire X-band. Examples of the optimization of realistic multi-layer absorbers are also presented. Although typical Genetic Algorithms require populations of many thousands in order to function properly and obtain correct results, verified correct results were obtained for all test cases using this GA with a population of only four.

Hall, John Michael↗

Hydrogen Absorbing Materials for Use as Radiation Shielding During Extended Space Flight Missions

Minimizing radiation exposure from the galactic cosmic ray (GCR) environment during extended space missions is particularly crucial to crew health and safety. Here, an ideal candidate for shielding would be pure solid or liquid hydrogen, a material that effectively fragments heavy ions into ones of lower mass and energy that are more easily attenuated. Unfortunately, utilizing pure hydrogen is not presently feasible. It is, however, known that the hydrogen content of other materials (for example, metal hydrides, palladium alloys, and organic compounds) can exceed that of pure solid hydrogen and thus merit consideration as shielding candidates. This presentation will discuss an ongoing effort to develop novel shielding from such materials in concert with a coordinated testing/evaluation and modeling effort.

Grugel, Richard N.↗

Absorbent Material

A superabsorbent fabric developed by Johnson Space Center and described in Tech Briefs was adapted by Honeywell and fabricated into special containment devices used on Navy "smart" torpedos. The superabsorbent fabric can sequester up to 400 times its own weight in water and protects the torpedo electronic controls from possible short circuiting by deepwater hull seepage.

Source record↗

A High Signal-To-Noise Ultraviolet Spectrum of NGC 7469: New Support for Reprocessing of Continuum Radiation

From 1996 June 10 to 1996 July 29, the International AGN Watch monitored the Seyfert 1 galaxy NGC 7469 using the International Ultraviolet Explorer, the Rossi X-Ray Timing Explorer, and a network of ground-based observatories. On 1996 June 18, in the midst of this intensive monitoring period, we obtained a high signal-to-noise snapshot of the UV spectrum from 1150 to 3300 A, using the Faint Object Spectrograph (FOS) on the Hubble Space Telescope. This spectrum allows us to disentangle the UV continuum more accurately from the broad wings of the emission lines, to identify clean continuum windows free of contaminating emission and absorption, and to deblend line complexes such as Ly(alpha) + N V, C IV + He II + O III], Si III] + C III], and Mg II + Fe II. Using the FOS spectrum as a template, we have fitted and extracted line and continuum fluxes from the IUE monitoring data. The cleaner continuum extractions c o n h the discovery of time delays between the different UV continuum bands by Wanders et al. Our new measurements show delays increasing with wavelength for continuum bands centered at 1485, 1740, and 1825 A, relative to 1315 A with delays of 0.09, 0.28, and 0.36 days, respectively. Like many other Seyfert I galaxies, the UV spectrum of NGC 7469 shows intrinsic, blue-shifted absorption in Ly(alpha), N V, and C IV. Soft X-ray absorption is also visible in archival ASCA X-ray spectra. The strength of the UV absorption, however, is not compatible with a single-zone model in which the same material absorbs both the UV and X-ray light. Similar to other Seyfert galaxies, such as NGC 3516, the UV-absorbing gas in NGC 7469 has a lower ionization parameter and column density than the X-ray-absorbing material. While the UV and X-ray absorption does not arise in the same material, the frequent occurrence of both associated UV absorption and X-ray warm absorbers in the same galaxies suggests that the gas supply for each has a common origin.

Kriss, Gerard A.↗

Black Carbon Absorption at the Global Scale Is Affected by Particle-Scale Diversity in Composition

Atmospheric black carbon (BC) exerts a strong, but uncertain, warming effect on the climate. BC that is coated with non-absorbing material absorbs more strongly than the same amount of BC in an uncoated particle, but the magnitude of this absorption enhancement (E(sub abs)) is not well constrained. Modelling studies and laboratory measurements have found stronger absorption enhancement than has been observed in the atmosphere. Here, using a particle-resolved aerosol model to simulate diverse BC populations, we show that absorption is overestimated by as much as a factor of two if diversity is neglected and population-averaged composition is assumed across all BC-containing particles. If, instead, composition diversity is resolved, we find E(sub abs) = 1 - 1.5 at low relative humidity, consistent with ambient observations. This study offers not only an explanation for the discrepancy between modelled and observed absorption enhancement, but also demonstrates how particle-scale simulations can be used to develop relationships for global-scale models.

Climate models↗

Method and apparatus for selectively annealing heterostructures using microwaves

The present invention discloses a process for selectively annealing heterostructures using microwaves. A heterostructure, comprised of a material having higher microwave absorption and a material having lower microwave absorption, is exposed to microwaves in the cavity. The higher microwave absorbing material absorbs the microwaves and selectively heats while the lower microwave absorbing material absorbs small amounts of microwaves and minimally heats. The higher microwave absorbing material is thereby annealed onto the less absorbing material which is thermally isolated.

Atwater, Harry A.↗

Method and apparatus for selectively annealing heterostructures using microwave

The present invention discloses a process for selectively annealing heterostructures using microwaves. A heterostructure, comprised of a material having higher microwave absorption and a material having lower microwave absorption, is exposed to microwaves in the cavity. The higher microwave absorbing material absorbs the microwaves and selectively heats while the lower microwave absorbing material absorbs small amounts of microwaves and minimally heats. The higher microwave absorbing material is thereby annealed onto the less absorbing material which is thermally isolated.

Atwater, Harry A.↗

Carbon dioxide concentration indicator

Device will provide visual indication of concentration of carbon dioxide. It consists of small amounts of absorbent material contained in semipermeable membrane and device to detect color changes. Material will absorb quantity of carbon dioxide proportional to carbon dioxide concentration in atmosphere. Amount of absorption is indicated by color change.

King, P. H.↗

Wipes, Coatings, and Patches for Detecting Hydrazines

Three color-indicating devices have been conceived as simple, rapid, inexpensive means of detecting hazardous liquid and gaseous substances in settings in which safety is of paramount concern and it would be too time-consuming or otherwise impractical to perform detection by use of such instruments as mass spectrometers. More specifically, these devices are designed for detecting hypergolic fuels (in particular, hydrazines) and hypergolic oxidizers in spacecraft settings, where occasional leakage of these substances in liquid or vapor form occurs and it is imperative to take early corrective action to minimize adverse health effects. With suitable redesign, including reformulation of their color indicator chemicals, these devices could be adapted to detection of other hazardous substances in terrestrial settings (e.g., industrial and military ones). One of the devices is a pad of a commercially available absorbent material doped with a color indicator. The absorbent material is made from 70 percent polyester and 30 percent nylon and can absorb about eight times its own weight of liquid. The color indicator is a mixture of conventional pH color indicator chemicals. Hydrazine and monomethyl hydrazine, which are basic, cause the color indicator to turn green. In the original intended application, the pad is wiped on a space suit that is suspected of having been exposed to leaking monomethyl hydrazine during a space walk, before the wearer returns to the interior of the spacecraft. If the wiped surface is contaminated with hydrazine, the pad turns green. In addition, the pad absorbs hydrazine from the wiped surface, thereby reducing or eliminating the hazard. Used pads, including ones that show contamination by hydrazine, can be stored in a sealed plastic bag for subsequent disposal. The second device, which has been proposed but not yet developed, would comprise a color indicator material in the form of either a coating on a space suit (or other protective garment) or a coating on a sheet that could be easily attached to and detached from the protective garment. The coating material would be a hydrogel doped with a suitable pH indicator. The hydrogel would also serve to maintain a level of moisture needed to support the chemical reaction mentioned in the next sentence. In addition to changing color to indicate the presence of any hypergolic fuel (which is basic) or hypergolic oxidizer (which is acidic) that might splash on the space suit, the pH indicator would also react with the hypergolic fuel or oxidizer and thereby bind it. The third device is a color dosimeter for detecting hydrazine liquid or vapor coming from microscopic leaks. This device is designed to satisfy several requirements specific to its original intended use in the auxiliary power unit of the space shuttle. These requirements include stability under vacuum, stability at moderate temperature, fast and irreversible change in color upon exposure to hydrazine, and visibility of the color change through polyimide tape.

Young, Rebecca↗

Two-photon or higher-order absorbing optical materials for generation of reactive species

Disclosed are highly efficient multiphoton absorbing compounds and methods of their use. The compounds generally include a bridge of pi-conjugated bonds connecting electron donating groups or electron accepting groups. The bridge may be substituted with a variety of substituents as well. Solubility, lipophilicity, absorption maxima and other characteristics of the compounds may be tailored by changing the electron donating groups or electron accepting groups, the substituents attached to or the length of the pi-conjugated bridge. Numerous photophysical and photochemical methods are enabled by converting these compounds to electronically excited states upon simultaneous absorption of at least two photons of radiation. The compounds have large two-photon or higher-order absorptivities such that upon absorption, one or more Lewis acidic species, Lewis basic species, radical species or ionic species are formed.

Cumpston, Brian↗

Two-photon or higher-order absorbing optical materials for generation of reactive species

Disclosed are highly efficient multiphoton absorbing compounds and methods of their use. The compounds generally include a bridge of pi-conjugated bonds connecting electron donating groups or electron accepting groups. The bridge may be substituted with a variety of substituents as well. Solubility, lipophilicity, absorption maxima and other characteristics of the compounds may be tailored by changing the electron donating groups or electron accepting groups, the substituents attached to or the length of the pi-conjugated bridge. Numerous photophysical and photochemical methods are enabled by converting these compounds to electronically excited states upon simultaneous absorption of at least two photons of radiation. The compounds have large two-photon or higher-order absorptivities such that upon absorption, one or more Lewis acidic species, Lewis basic species, radical species or ionic species are formed.

Cumpston, Brian↗