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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Antisolvent‐Mediated Air Quench for High‐Efficiency Air‐Processed Carbon‐Based Planar Perovskite Solar Cells

Perovskite solar cells (PSCs) have becoma a leading low‐cost photovoltaic technology, achieving power conversion efficiencies (PCEs) of up to 26.1%. However, their commercialization is hindered by stability issues and the need for controlled processing environments. Carbon‐electrode‐based PSCs (C‐PSCs) offer enhanced stability and cost‐effectiveness compared to traditional metal‐electrode PSCs, i.e., Au and Ag. However, processing challenges persist, particularly in air conditions where moisture sensitivity poses a significant hurdle. Herein, a novel air processing technique is presented for planar C‐PSCs that incorporates antisolvent vapors, such as chlorobenzene, into a controlled air‐quenching process. This method effectively mitigates moisture‐induced instability, resulting in champion PCEs exceeding 20% and robust stability under ambient conditions. The approach retains 80% of initial efficiency after 30 h of operation at maximum power point without encapsulation. This antisolvent‐mediated air‐quenching technique represents a significant advancement in the scalable production of C‐PSCs, paving the way for future large‐scale deployment.

14 SOLAR ENERGY↗
NASA NTRS2017

AIRS-Only Product in Giovanni for Exploring Up-to-Date AIRS Observation and Comparing with AIRS+AMSU Product

The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) has been the home of processing, archiving, and distribution services for the Atmospheric Infrared Sounder (AIRS) mission since its launch in 2002 for global observations of the atmospheric state. Giovanni, a Web-based application developed by the GES DISC, provides a simple and intuitive way to visualize, analyze, and access vast amounts of Earth science remote sensing data without having to download the data. Most important AIRS variables, including temperature and humidity profiles, outgoing longwave radiation, cloud properties, and trace gases, are available in Giovanni. AIRS is an instrument suite comprised of a hyperspectral infrared instrument (AIRS) and two multichannel microwave instruments, the Advanced Microwave Sounding Unit (AMSU) and the Humidity Sounder for Brazil (HSB). As HSB ceased operation in the very early stages of the AIRS mission, the AIRS project operates two parallel retrieval algorithms: one using both IR and MW measurements (AIRS+AMSU) and the other using only IR measurements (AIRS-only), which covers most of the mission duration. The AIRS+AMSU product is better quality, and the variables in Giovanni are from this product. However, generation of the AIRS+AMSU product has been suspended since the AMSU instrument anomaly occurred in late September 2016. To continue exploring up-to-date AIRS observations, the same set of variables from the AIRS-only product have been added to Giovanni by the GES DSIC. This will also support comparison of AIRS-only with AIRS+AMSU retrievals. In this presentation, we demonstrate the visualization of the AIRS-only product and plots/statistics of comparison with AIRS+AMSU product using Giovanni.

AIRS↗
NASA NTRS2015

Technology Candidates for Air-to-Air and Air-to-Ground Data Exchange

Technology Candidates for Air-to-Air and Air-to-Ground Data Exchange is a two-year research effort to visualize the U. S. aviation industry at a point 50 years in the future, and to define potential communication solutions to meet those future data exchange needs. The research team, led by XCELAR, was tasked with identifying future National Airspace System (NAS) scenarios, determining requirements and functions (including gaps), investigating technical and business issues for air, ground, & air-to-ground interactions, and reporting on the results. The project was conducted under technical direction from NASA and in collaboration with XCELAR's partner, National Institute of Aerospace, and NASA technical representatives. Parallel efforts were initiated to define the information exchange functional needs of the future NAS, and specific communication link technologies to potentially serve those needs. Those efforts converged with the mapping of each identified future NAS function to potential enabling communication solutions; those solutions were then compared with, and ranked relative to, each other on a technical basis in a structured analysis process. The technical solutions emerging from that process were then assessed from a business case perspective to determine their viability from a real-world adoption and deployment standpoint. The results of that analysis produced a proposed set of future solutions and most promising candidate technologies. Gap analyses were conducted at two points in the process, the first examining technical factors, and the second as part of the business case analysis. In each case, no gaps or unmet needs were identified in applying the solutions evaluated to the requirements identified. The future communication solutions identified in the research comprise both specific link technologies and two enabling technologies that apply to most or all specific links. As a result, the research resulted in a new analysis approach, viewing the underlying architecture of ground-air and air-air communications as a whole, rather than as simple "link to function" paired solutions. For the business case analysis, a number of "reference architectures" were developed for both the future technologies and the current systems, based on three typical configurations of current aircraft. Current and future costs were assigned, and various comparisons made between the current and future architectures. In general, it was assumed that if a future architecture offers lower cost than the current typical architecture, while delivering equivalent or better performance, it is likely that the future solution will gain industry acceptance. Conversely, future architectures presenting higher costs than their current counterparts must present a compelling benefit case in other areas or risk a lack of industry acceptance. The business case analysis consistently indicated lower costs for the proposed future architectures, and in most cases, significantly so. The proposed future solutions were found to offer significantly greater functionality, flexibility, and growth potential over time, at lower cost, than current systems. This was true for overall, fleet-wide equipage for domestic and oceanic air carriers, as well as for single, General Aviation (GA) aircraft. The overall research results indicate that all identified requirements can be met by the proposed solutions with significant capacity for future growth. Results also illustrate that the majority of the future communication needs can be met using currently allocated aviation RF spectrum, if used in more effective ways than it is today. A combination of such optimized aviation-specific links and commercial communication systems meets all identified needs for the 50-year future and beyond, with the caveat that a new, overall function will be needed to manage all information exchange, individual links, security, cost, and other factors. This function was labeled "Delivery Manager" (DM) within this research. DM employs a distributed client/server architecture, for both airborne and ground communications architectures. Final research results included identifying the most promising candidate technologies for the future system, conclusions and recommendations, and identifying areas where further research should be considered.

Communications↗
DOE OSTI2021

Emissions in short-gated ns/ps/fs-LIBS for fuel-to-air ratio measurements in methane-air flames

A study of short-gated 10 nanosecond (ns), 100 picosecond (ps), and 100 femtosecond (fs) laser induced breakdown spectroscopy (LIBS) was conducted for fuel-to-air ratio (FAR) measurements in an atmospheric Hencken flame. The intent of the work is to understand which emission lines are available near the optical range in each pulse width regime and which emission ratios may be favorable for generating equivalence ratio calibration curves. The emission spectra in the range of 550–800 nm for ns-LIBS and ps-LIBS are mostly similar with slightly elevated atomic oxygen lines by ps-LIBS. Spectra from fs-LIBS show the lowest continuum background and prominent individual atomic lines, though have significantly weaker ionic emission from nitrogen. A qualitative explanation based on assumed local thermodynamic equilibrium and electron temperatures calculated by the N I I ( 565 n m ) and N I I ( 594 n m ) emissions is presented. In studying line emission ratios for FAR calculation, it is found that H α <#comment/> ( 656 n m ) / N I I ( 568 n m ) is best for FAR measurements with ns-LIBS and remains viable for ps-LIBS, while H α <#comment/> ( 656 n m ) / O I ( 777 n m ) is optimal for the ps-LIBS and fs-LIBS cases. Due to low continuum background and short time delay for spectra collection, fs-LIBS is very promising for high-speed FAR measurements using short-gated LIBS.

Gragston, Mark (ORCID:0000000324698995)↗
NASA NTRS2020

Washington Health & Air Quality: Quantifying Air Quality Parameters and Validating Air Pollution Sources Impacting the Health of Puget Sound Residents Through the Use of NASA and ESA Remote Sensing Data

In the Puget Sound region of Washington, high levels of air pollutants put residents’ health at risk by increasing their likelihood of developing critical respiratory conditions. This project used remotely-sensed data to investigate aerosol optical depth (AOD) from NASA satellite sensors including the Terra and Aqua MODerate Resolution Imaging Spectroradiometer (MODIS) and European Space Agency Copernicus Sentinel-5 Precursor TROPOspheric Monitoring Instrument (TROPOMI). The team visualized the most recent data in Google Earth Engine (GEE) API to display air pollution trends in Washington State, which will support the Puget Sound Clean Air Agency’s (PSCAA) decision-making processes. The team performed linear regressions using the Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm to form a relationship between ground-level microscopic particles (PM2.5) and AOD in the Puget Sound region, validating the relationship using concentration readings taken from Environmental Protection Agency (EPA) air quality monitors. The team utilized estimated PM2.5 and other satellite data to produce a web-based tool and to evaluate the effectiveness of using such a tool for near real-time air quality monitoring within a particular region. The team found that the tool provides useful supplementary data that fills in the gaps of the PSCAA’s air monitoring network.

Health & Air Quality↗
NASA NTRS2020

Washington Health & Air Quality: Quantifying Air Quality Parameters and Validating Air Pollution Sources Impacting the Health of Puget Sound Residents Through the Use of NASA and ESA Remote Sensing Data

In the Puget Sound region of Washington, high levels of air pollutants put residents’ health at risk by increasing their likelihood of developing critical respiratory conditions. This project used remotely-sensed data to investigate aerosol optical depth (AOD) from NASA satellite sensors including the Terra and Aqua MODerate resolution Imaging Spectroradiometer (MODIS) and European Space Agency Copernicus Sentinel-5 Precursor TROPOspheric Monitoring Instrument (TROPOMI). The team visualized the most recent data in Google Earth Engine (GEE) API to display air pollution trends from Northern California to British Columbia, which will support the Puget Sound Clean Air Agency’s (PSCAA) decision-making processes. The team performed linear regressions using the Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm to form a relationship between ground-level microscopic particles (PM2.5) and AOD in the Puget Sound region, validating the relationship using concentration readings taken from Environmental Protection Agency (EPA) air quality monitors. The team utilized estimated PM2.5 and other satellite data to produce a web-based tool and to evaluate the effectiveness of using such a tool for near real-time air quality monitoring within a particular region. The team found that the tool provides useful supplementary data that fills in the gaps of the PSCAA’s air monitoring network.

Health & Air Quality↗
NASA NTRS2023

San Joaquin Valley Health & Air Quality: Evaluating the Overlap of Social Vulnerabilities and Air Quality in the San Joaquin Valley Air Pollution Control District

Little Manila Rising (LMR) is a nonprofit in Stockton, California that has been increasingly concerned by the air pollution in their city and the neighboring San Joaquin Valley (SJV). Geographical factors, climate conditions, and anthropogenic activities, such as agriculture burning and vehicle emissions, contribute to the high levels of air pollution in this region. To visualize the distribution of air pollution and social disparities across the SJV, LMR partnered with NASA DEVELOP. The DEVELOP team used Terra and Aqua MODIS, Sentinel-5P TROPOMI, and CALIPSO CALIOP to observe Aerosol Optical Depth (AOD), Nitrogen Dioxide (NO 2 ), and the vertical distribution of pollutants at varying pollution levels, respectively. Additionally, Suomi-NPP VIIRS provided active fire data. By leveraging NASA Earth observations along with sociodemographic and public health data, the DEVELOP team created maps identifying the areas experiencing the highest vulnerabilities and disparities in pollution exposure. The team found that AOD was slightly higher in agricultural regions, while NO 2 was consistently higher along transportation corridors and urban areas. Wildfires dominated the type of detected active fires, and there was high correlation (R 2 = 0.6924) between active fires and burn permits in agricultural tracts. Furthermore, the team identified both high AOD vulnerability and high NO 2 vulnerability in census tracts in South Stockton, an area that has been historically redlined and disinvested in, and where LMR resides. There was also a moderate correlation between air quality reported from the satellites and in-situ ground monitors. These results will support LMR’s organizing strategies for stricter enforcement of air pollution regulations and increased public health equity for community members.

Agricultural Fires↗
DOE OSTI2018

A lithium–oxygen battery with a long cycle life in an air-like atmosphere [Lithium-oxygen batteries with long cycle life in a realistic air atmosphere]

Lithium-air batteries are considered to be a potential alternative to lithium-ion batteries for transportation applications, owing to their high theoretical specific energy. So far, however, such systems have been largely restricted to pure oxygen environments (lithium oxygen batteries) and have a limited cycle life owing to side reactions involving the cathode, anode and electrolyte. In the presence of nitrogen, carbon dioxide and water vapour, these side reactions can become even more complex. Moreover, because of the need to store oxygen, the volumetric energy densities of lithium-oxygen systems may be too small for practical applications. Here we report a system comprising a lithium carbonate-based protected anode, a molybdenum disulfide cathode and an ionic liquid/di methyl sulfoxide electrolyte that operates as a lithium-air battery in a simulated air atmosphere with a long cycle life of up to 700 cycles. We perform computational studies to provide insight into the operation of the system in this environment. Furthermore this demonstration of a lithium-oxygen battery with a long cycle life in an air-like atmosphere is an important step towards the development of this field beyond lithium-ion technology, with a possibility to obtain much higher specific energy densities than for conventional lithium ion batteries.

25 ENERGY STORAGE↗
NASA NTRS1987

A two-dimensional air-to-air combat game - Toward an air-combat advisory system

Air-to-air combat is modeled as a discrete differential game, and by constraining the game to searching for the best guidance laws from the sets of those considered for each opponent, feedback and outcome charts are obtained which can be used to turn one of the automatic opponents into an intelligent opponent against a human pilot. A one-on-one two-dimensional fully automatic, or manned versus automatic, air-to-air combat game has been designed which includes both attack and evasion alternatives for both aircraft. Guidance law selection occurs by flooding the initial-condition space with four simulated fights for each initial condition, depicting the various attack/evasion strategies for the two opponents, and recording the outcomes. For each initial condition, the minimax method from differential games is employed to determine the best choice from the available strategies.

Neuman, Frank↗
NASA NTRS1952

Flame Speeds of Methane-Air, Propane-Air, and Ethylene-Air Mixtures at Low Initial Temperatures

Flame speeds were determined for methane-air, propane-air, and ethylene-air mixtures at -73 C and for methane-air mixtures at -132 C. The data extend the curves of maximum flame speed against initial mixture temperature previously established for the range from room temperature to 344 C. Empirical equations for maximum flame speed u(cm/ sec) as a function of initial mixture temperature T(sub O) were determined to be as follows: for methane, for T(sub O) from 141 to 615 K, u = 8 + 0.000160 T(sub O)(exp 2.11); for propane, for T(sub O) from 200 to 616 K, u = 10 + 0.000342 T(sub O)(exp 2.00); for ethylene, for T(sub O) from 200 to 617 K, u = 10 + 0.00259 T(sub O)(exp 1.74). Relative flame speeds at low initial temperatures were predicted within approximately 20 percent by either the thermal theory as presented by Semenov or by the diffusion theory of Tanford and Pease. The same order was found previously for high initial temperatures. The low-temperature data were also found to extend the linear correlations between maximum flame speed and calculated equilibrium active-radical concentrations, which were established by the previously reported high-temperature data.

Dugger, Gordon L↗
NASA NTRS1976

Emissions of an AVCO Lycoming 0-320-DIAD air cooled light aircraft engine as a function of fuel-air ratio, timing, and air temperature and humidity

A carbureted aircraft engine was operated over a range of test conditions to establish the exhaust levels over the EPA seven-mode emissions cycle. Baseline (full rich production limit) exhaust emissions at an induction air temperature of 59 F and near zero relative humidity were 90 percent of the EPA standard for HC, 35 percent for NOx, and 161 percent for CO. Changes in ignition timing around the standard 25 deg BTDC from 30 deg BTDC to 20 deg BTDC had little effect on the exhaust emissions. Retarding the timing to 15 deg BTDC increased both the HC and CO emissions and decreased NOx emissions. HC and CO emissions decreased as the carburetor was leaned out, while NOx emissions increased. The EPA emission standards were marginally achieved at two leanout conditions. Variations in the quantity of cooling air flow over the engine had no effect on exhaust emissions. Temperature-humidity effects at the higher values of air temperature and relative humidity tested indicated that the HC and CO emissions increased significantly, while the NOx emissions decreased.

Meng, P. R.↗
NASA NTRS1952

Effect of Initial Mixture Temperature on Flame Speed of Methane-Air, Propane-Air, and Ethylene-Air Mixtures

Flame speeds based on the outer edge of the shadow cast by the laminar Bunsen cone were determined as functions of composition for methane-air mixtures at initial mixture temperatures ranging from -132 degrees to 342 degrees c and for propane-air and ethylene-air mixtures at initial mixture temperatures ranging from -73 degrees to 344 degrees c. The data showed that maximum flame speed increased with temperature at an increasing rate. The percentage change in flame speed with change in initial temperature for the three fuels followed the decreasing order, methane, propane, and ethylene. Empirical equations were determined for maximum flame speed as a function of initial temperature over the temperature range covered for each fuel. The observed effect of temperature on flame speed for each of the fuels was reasonably well predicted by either the thermal theory as presented by Semenov or the square-root law of Tanford and Pease.

Dugger, Gordon L↗