Phase stability and cation partitioning in compositionally complex rare earth aluminates and aluminate‐zirconate mixtures
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Effect of X-Rays on the Mechanical Properties of Aluminized FEP Teflon(R)
Pieces of the multilayer insulation (MLI) that is integral to the thermal control of the Hubble Space Telescope (HST) have been returned by two servicing missions after 3.6 and 6.8 years in orbit. They reveal that the outer layer, which is made from 5 mil (0.13 mm)thick aluminized fluorinated ethylene propylene(FEP) Teflon(R), has become severely embrittled. Although possible agents of this embrittlement include electromagnetic radiation across the entire solar spectrum, trapped particle radiation, atomic oxygen, and thermal cycling, intensive investigations have not yielded unambiguous causes. Previous studies utilizing monoenergetic photons in the 69-1900 eV range did not cause significant embrittlement, even at much higher doses than were experienced by the HST MLI. Neither did x-rays in the 3 to 10 keV range generated in a modified electron beam evaporator. An antidotal aluminized FEP sample that was exposed to an intensive dose from unfiltered Mo x-ray radiation from a rotating anode generator, however, did show the requisite embrittlement. Thus, a study was undertaken to determine the effects of x-ray exposure on the embrittlement of aluminized FEP in hopes that it might elucidate the HST MLI degradation mechanism. Tensile specimens of aluminized 5 mil thick FEP were exposed to a constant fluence of unfiltered x-ray radiation from a Mo target whose maximum energy ranged from 20-60 kV. Other samples were annealed, thermally cycled (100x) between 77-333 K, or cycled and irradiated. Tensile tests and density measurements were then performed on the samples. Only the samples which had been irradiated had the drastically reduced elongation-to-break, characteristic of the HST samples. Thermal cycling may accelerate the embrittlement, but the effect was near the scatter in the measurements. Annealing and thermal cycling had no apparent effect. Only the samples which had been irradiated and annealed showed significant density increases, likely implicating polymer chain scission and annealing.
Gaier, James R.↗
Effect of X-Rays on the Mechanical Properties of Aluminized FEP Teflon(trademark)
Pieces of the multilayer insulation (MLI) that is integral to the thermal control of the Hubble Space Telescope (HST) have been returned by two servicing missions after 3.6 and 6.8 years in orbit. They reveal that the outer layer, which is made from 5 mil (0.13 mm) thick aluminized fluorinated ethylenepropylene (FEP) Teflon. has become severely embrittled. Although possible agents of this embrittlement include electromagnetic radiation across the entire solar spectrum, trapped particle radiation, atomic oxygen, and thermal cycling, intensive investigations have not yielded unambiguous causes. Previous studies utilizing monoenergetic photons in the 69-1900 eV range did not cause significant embrittlement, even at much higher doses than were experienced by the HST MLI. Neither did x-rays in the 3 to 10 keV range generated in a modified electron bean evaporator. An antidotal aluminized FEP sample that was exposed to an intensive dose from unfiltered Mo x-ray radiation from a rotating anode generator, however, did show the requisite embrittlement. Thus, a study was undertaken to determine the effects of x-ray exposure on the embrittlement of aluminized FEP in hopes that it might elucidate the HST MLI degradation mechanism. Tensile specimens of aluminized 5 mil thick FEP were exposed to a constant fluence of unfiltered x-ray radiation from a Mo target whose maximum energy ranged from 20-60 kV. Other samples were annealed, thermally cycled (100x) between 77-333 K, or cycled and irradiated. Tensile tests and density measurements were then performed on the samples. Only the samples which had been irradiated had the drastically reduced elongation-to-break, characteristic of the HST samples. Thermal cycling may accelerate the embrittlement, but the effect was near the scatter in the measurements. Annealing and thermal cycling had no apparent effect. Only the samples which had been irradiated and annealed showed significant density increases, likely implicating polymer chain scission and annealing.
Gaier, James R.↗
Kinetics of pack aluminization of nickel
The kinetics of pack aluminization of unalloyed nickel in packs of varying aluminum activity with various halide activators were studied. Surface compositions of the coatings as functions of time, temperature, and pack composition were obtained in order to establish the boundary conditions for diffusion in the system. The structure of the packs was also examined in order to clarify the mechanism of aluminum transport. The results indicate that the kinetics of pack aluminization are controlled jointly by gas diffusion in the pack and solid diffusion in the coating. Levine and Caves' model for gas diffusion was combined with calculations of rates of diffusion in the solid to formulate a more complete theory for the kinetics of pack aluminization.
Seigle, L. L.↗
Ion microprobe analyses of aluminous lunar glasses - A test of the 'rock type' hypothesis
Previous soil survey investigations found that there are natural groupings of glass compositions in lunar soils and that the average major element composition of some of these groupings is the same at widely separated lunar landing sites. This led soil survey enthusiasts to promote the hypothesis that the average composition of glass groupings represents the composition of primary lunar 'rock types'. In this investigation the trace element composition of numerous aluminous glass particles was determined by the ion microprobe method as a test of the above mentioned 'rock type' hypothesis. It was found that within any grouping of aluminous lunar glasses by major element content, there is considerable scatter in the refractory trace element content. In addition, aluminous glasses grouped by major elements were found to have different average trace element contents at different sites (Apollo 15, 16 and Luna 20). This evidence argues that natural groupings in glass compositions are determined by regolith processes and may not represent the composition of primary lunar 'rock types'.
Meyer, C., Jr.↗
The effect on the kinetics of pack aluminization of varying the activator
The effect on the kinetics of pack aluminization of nickel of varying the activator type was investigated using AlF3, NaF, NaCl and NaI as activators. The rate of aluminization was highest in packs activated with AlF3 and NaF, and lowest in those activated with NaCl and NaI. The results were in good accordance with predictions of the combined gas-solid diffusion theory of pack aluminization.
Gupta, B. K.↗
Thermal testing of aluminized Mylar
The effect of heat on aluminized Mylar film is summarized. A summary of the procedure used in testing the material, background information describing the physical properties of the material, and the experimental results of heating the material at various temperatures are included. It is revealed that aluminized Mylar film is thermally stable within the temperature range of 50 to 200 C. The information compiled will be used to determine if aluminized Mylar can be useful in space applications.
Lowe, D. L., II↗
Atomic Oxygen Durability of Aluminized Polymers
The atomic oxygen durability of aluminized polymers will be investigated. Such aluminized polymers are commonly used in space and specifically on the International Space Station. Recent data from in-space results indicates that vapor deposited aluminum coatings are highly defected with many small pin windows. However, electron microscopy to validate the size and aerial density of such defects remains to be demonstrated. The research project is planned to compare electron microscopy analysis of pristine and atomic oxygen exposed aluminized polyimide Kapton with the results of ground laboratory atomic oxygen erosion data, in-space results and computational Monte Carlo modeling to develop a self consistent understanding of the atomic oxygen degradation processes and effects.
Yang, Judith C.↗
Effect of Air and Vacuum Storage on the Degradation of X-Ray-Exposed Aluminized-Teflon Investigated
Metalized Teflon FEP (fluorinated ethylene propylene, DuPont), a common thermal control material, has been found to degrade in the low-Earth-orbit space environment. The aluminized-FEP (Al-FEP) exterior layer on the Hubble Space Telescope has become extremely embrittled, with extensive cracking occurring on all sides of the telescope. This embrittlement has been primarily attributed to radiation exposure (x-rays from solar flares, electron/proton radiation, and possibly near-ultraviolet radiation) combined with thermal cycling. Limited samples of FEP tested after long-term exposure to low Earth orbit on the Hubble Space Telescope and on the Long Duration Exposure Facility indicated that there might be continued degradation in tensile properties over time. An investigation was conducted at the NASA Glenn Research Center to evaluate the effect of air and vacuum storage on the mechanical properties of x-ray-exposed FEP. Aluminized-FEP (5-mil-thick) tensile samples were x-ray exposed with 15.3-kV copper xrays for 2 hr, reducing the percent elongation to failure by approximately 50 percent in comparison to that for pristine Al-FEP. X-ray-exposed samples were stored in air or under vacuum for various time periods to see the effect of storage on tensile properties. Tensile results indicated that samples stored in air had larger decreases in tensile properties than samples stored under vacuum had, as seen in the graph. Samples stored under vacuum (for up to 400 hr) showed no further decrease in tensile properties over time, whereas samples stored in air (for up to 900 hr) appeared to show decreases in tensile properties over time. X-ray-exposed samples stored in air developed a hazy appearance in the exposed area, as seen in the photographs. When the source of the haziness was evaluated using scanning electron microscopy and atomic force microscopy, it was found to reside at the Al/FEP interface as witnessed by an increased surface roughness of the aluminized side of the material and a dramatic decrease in the adhesion between the Al and FEP. Optical properties of air-stored irradiated samples showed an increase in the diffuse reflectance, which is consistent with observed roughening that was characterized by AFM. These findings indicate that air exposure helps degrade x-ray-irradiated FEP. These results indicate that proper sample handling and storage is necessary with space-retrieved materials and with those exposed to ground-based irradiation simulation exposures.
deGroh, Kim K.↗
Aluminized alloy boosts turbine blade life
Description of an aluminized alloy coating technique that involves first the application of a ductile, oxidation-resistant overlay, such as NiCrAl, which is then partially aluminized. The duplex protective system has performance advantages over conventional aluminide coatings in that it provides higher-temperature hot corrosion resistance over a longer service life.
Gedwill, M. A.↗
On the kinetics of pack aluminization
A theory of pack aluminization has been formulated by combining gaseous and solid-state diffusion rates. This theory relates the surface composition of the coating and therefore, in principle, the phase morphology and the growth rate of the coating, to pack operating parameters such as pack aluminum density, type of activator, temperature and others. Experimental data on the aluminization of unalloyed nickel in pure aluminum packs obtained to date are in good agreement with the predictions of the theory.
Gupta, B. K.↗
On the kinetics of the pack - Aluminization process
An investigation has been made of the aluminization of unalloyed Ni in fluoride-activated packs of varying Al activity. In packs of low Al activity, in which the ratio of Al to Ni was less than 50 at. pct, the specimen surface quickly came to equilibrium with the pack and remained close to equilibrium for the duration of normal coating runs. In these packs the kinetics of aluminization was controlled by diffusion in the solid. In packs of higher Al activity the surface of the specimen did not come to equilibrium with the pack and the kinetics of the process was governed by a combination of solid and gas diffusion rates. Under most conditions however, the surface composition was time-invariant and a steady-state appeared to exist at the pack-coating interface. By combining Levine and Caves' model for gaseous diffusion in pure-Al packs with calculations of solid diffusion rates some success has been achieved in explaining the results.
Sivakumar, R.↗
Experimental determination of the admittances of aluminized propellants by the impedance tube method
The adaptation of the impedance tube concept for the determination of the pressure coupled admittances and response functions of burning solid propellants is discussed. The results obtained in experiments with UTP-3001 and UTP-19360 aluminized propellants are presented. It is shown that the admittance Y remains constant during the quasi-steady burn period of a test, indicating constant driving of the gas phase disturbance by the burning solid propellant. The measured real part of the admittance is positive, indicating that the burning aluminized propellant is driving the gas phase oscillations. In addition, the measured high gas phase damping, provided by the aluminum oxide particles in the gas phase, suggests that the latter can significantly increase the damping in unstable solid rockets over the investigated frequency range. Finally, it is shown that the wave structure obtained by numerically solving the impedance tube wave equations which utilize the determined propellant admittance as an initial condition and the determined value of G to describe the gas phase losses is in excellent agreement with the measured wave structure.
Baum, J. D.↗
Aluminous mare basalts - New data from Apollo 14 coarse fines
Four aluminous mare basalt fragments selected from the Apollo 14 coarse fines collection are described: 14004,34 has an intergranular texture; 14160,103 and 14168,38 are granular; and 14256,10 is a fine-grained metabasalt. Pyroxene compositional trends vary among the fragments: in 14004,34 the trend is from ferroaugite to pyroxferrite; 14160,103 exhibits well-defined iron enrichment trends involving both pigeonite and augite; 14168,38 contains mostly pigeonite with minor augite; and pyroxene compositions in 14256,10 cluster in two distinct populations, high- and low-Ca. The igneous textures (except for 14256,10), the absence of discernible clasts, and low Ni compositions of metal grains lead to the conclusion that the fragments are pieces of pristine aluminous mare basalts. The marked differences in the REE patterns rule out a close genetic relation between any of the four basalts.
Warner, R. D.↗
Improved Aluminized Multilayer Insulation
In blanket of insulating material, layers of aluminized Mylar polyethylene terephthalate separated by spacers cause mutliple reflections of thermal radiation and impede passage of radiation through blanket. Insulating quality of blanket proportional to number of functional aluminized radiation-shield surfaces in assembly.
Tepper, Edward H.↗
Atomic oxygen undercutting of LDEF aluminized Kapton multilayer insulation
Atomic oxygen undercutting is a potential threat to vulnerable spacecraft materials which have been shielded with an atomic oxygen protective coating. This is due to atomic oxygen attack of oxidizable materials at the point of microscopic defects in the protective coatings which occur during fabrication and handling, or from micrometeoroid and debris bombardment in space. An aluminized Kapton multilayer insulation sample which was flown on the leading edge of the Long Duration Exposure Facility (LDEF) was used to study low Earth orbit (LEO) directed ram oxygen undercutting. Cracks in the aluminized coatings around the vent holes provided excellent locations for evaluation of atomic oxygen undercutting. The undercutting profiles were compared to Monte Carlo models which predict LEO ram atomic oxygen attack. The shape of the undercurrent profile was found to vary with crack width, which is proportional to the number of atomic oxygen atoms entering the crack. The resulting atomic oxygen undercut profiles which occurred on LDEF indicated wide undercut cavities in spite of the fixed ram orientation. Potential causes of the observed undercutting profiles will be presented. Implications of the undercutting profiles relevant to Space Station Freedom will also be discussed.
Degroh, Kim K.↗
Atomic oxygen undercutting of LDEF aluminized-Kapton multilayer insulation
Atomic oxygen undercutting is a potential threat to vulnerable spacecraft materials which have atomic oxygen protective coatings. Such undercutting is due to atomic oxygen attack of oxidizable materials at microscopic defects in the protective coatings. These defects occur during fabrication and handling, or from micrometeoroid and debris bombardment in space. An aluminized-polyimide Kapton multilayer insulation sample that was located on the leading edge of the Long Duration Exposure Facility (LDEF) was used to study low Earth orbit directed ram atomic oxygen undercutting. Cracks in the aluminized coatings located around vent holes provided excellent defect sites for evaluation of atomic oxygen undercutting. The experimentally observed undercutting profiles were compared to predictions from Monte Carlo models for normal incident ram atomic oxygen attack. The shape of the undercut profile was found to vary with crack width, which is proportional to the number of oxygen atoms entering the crack. The resulting profiles of atomic oxygen which occurred on LDEF indicated wide undercut cavities in spite of the fixed ram orientation. Potential causes of the observed undercutting are presented. Implications of the undercutting profiles relevant to the Space Station Freedom are also discussed.
Degroh, Kim K.↗
Ground Laboratory Soft X-Ray Durability Evaluation of Aluminized Teflon FEP Thermal Control Insulation
Metallized Teflon fluorinated ethylene propylene (FEP) thermal control insulation is mechanically degraded if exposed to a sufficient fluence of soft x-ray radiation. Soft x-ray photons (4-8 A in wavelength or 1.55 - 3.2 keV) emitted during solar flares have been proposed as a cause of mechanical properties degradation of aluminized Teflon FEP thermal control insulation on the Hubble Space Telescope (HST). Such degradation can be characterized by a reduction in elongation-to-failure of the Teflon FER Ground laboratory soft x-ray exposure tests of aluminized Teflon FEP were conducted to assess the degree of elongation degradation which would occur as a result of exposure to soft x-rays in the range of 3-10 keV. Tests results indicate that soft x-ray exposure in the 3-10 keV range, at mission fluence levels, does not alone cause the observed reduction in elongation of flight retrieved samples. The soft x-ray exposure facility design, mechanical properties degradation results and implications will be presented.
Banks, Bruce A.↗