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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2023

AMORE-Isoprene v1.0: A New Reduced Mechanism for Gas-Phase Isoprene Oxidation

Gas-phase oxidation of isoprene by ozone (O 3 ) and the hydroxyl (OH) and nitrate (NO 3 ) radicals significantly impacts tropospheric oxidant levels and secondary organic aerosol formation. The most comprehensive and up-to-date chemical mechanism for isoprene oxidation consists of several hundred species and over 800 reactions. Therefore, the computational expense of including the entire mechanism in large-scale atmospheric chemical transport models is usually prohibitive, and most models employ reduced isoprene mechanisms ranging in size from ∼ 10 to ∼ 200 species. We have developed a new reduced isoprene oxidation mechanism using a directed-graph path-based automated model reduction approach, with minimal manual adjustment of the output mechanism. The approach takes as inputs a full isoprene oxidation mechanism, the environmental parameter space, and a list of priority species which are protected from elimination during the reduction process. Our reduced mechanism, AMORE-Isoprene (where AMORE stands for Automated Model Reduction), consists of 12 species which are unique to the isoprene mechanism as well as 22 reactions. We demonstrate its performance in a box model in comparison with experimental data from the literature and other current isoprene oxidation mechanisms. AMORE-Isoprene's performance with respect to predicting the time evolution of isoprene oxidation products, including isoprene epoxydiols (IEPOX) and formaldehyde, is favorable compared with other similarly sized mechanisms. When AMORE-Isoprene is included in the Community Regional Atmospheric Chemistry Multiphase Mechanism 1.0 (CRACMM1AMORE) in the Community Multiscale Air Quality Model (CMAQ, v5.3.3), O 3 and formaldehyde agreement with Environmental Protection Agency (EPA) Air Quality System observations is improved. O 3 bias is reduced by 3.4 ppb under daytime conditions for O 3 concentrations over 50 ppb. Formaldehyde bias is reduced by 0.26 ppb on average for all formaldehyde measurements compared with the base CRACMM1. There was no significant change in computation time between CRACMM1AMORE and the base CRACMM. AMORE-Isoprene shows a 35 % improvement in agreement between simulated IEPOX concentrations and chamber data over the base CRACMM1 mechanism when compared in the Framework for 0-D Atmospheric Modeling (F0AM) box model framework. This work demonstrates a new highly reduced isoprene mechanism and shows the potential value of automated model reduction for complex reaction systems.

Automated Model Reduction↗
DOE OSTI2023

AMORE-Isoprene v1.0: a new reduced mechanism for gas-phase isoprene oxidation

Abstract. Gas-phase oxidation of isoprene by ozone (O3) and the hydroxyl (OH) and nitrate (NO3) radicals significantly impacts tropospheric oxidant levels and secondary organic aerosol formation. The most comprehensive and up-to-date chemical mechanism for isoprene oxidation consists of several hundred species and over 800 reactions. Therefore, the computational expense of including the entire mechanism in large-scale atmospheric chemical transport models is usually prohibitive, and most models employ reduced isoprene mechanisms ranging in size from ∼ 10 to ∼ 200 species. We have developed a new reduced isoprene oxidation mechanism using a directed-graph path-based automated model reduction approach, with minimal manual adjustment of the output mechanism. The approach takes as inputs a full isoprene oxidation mechanism, the environmental parameter space, and a list of priority species which are protected from elimination during the reduction process. Our reduced mechanism, AMORE-Isoprene (where AMORE stands for Automated Model Reduction), consists of 12 species which are unique to the isoprene mechanism as well as 22 reactions. We demonstrate its performance in a box model in comparison with experimental data from the literature and other current isoprene oxidation mechanisms. AMORE-Isoprene's performance with respect to predicting the time evolution of isoprene oxidation products, including isoprene epoxydiols (IEPOX) and formaldehyde, is favorable compared with other similarly sized mechanisms. When AMORE-Isoprene is included in the Community Regional Atmospheric Chemistry Multiphase Mechanism 1.0 (CRACMM1AMORE) in the Community Multiscale Air Quality Model (CMAQ, v5.3.3), O3 and formaldehyde agreement with Environmental Protection Agency (EPA) Air Quality System observations is improved. O3 bias is reduced by 3.4 ppb under daytime conditions for O3 concentrations over 50 ppb. Formaldehyde bias is reduced by 0.26 ppb on average for all formaldehyde measurements compared with the base CRACMM1. There was no significant change in computation time between CRACMM1AMORE and the base CRACMM. AMORE-Isoprene shows a 35 % improvement in agreement between simulated IEPOX concentrations and chamber data over the base CRACMM1 mechanism when compared in the Framework for 0-D Atmospheric Modeling (F0AM) box model framework. This work demonstrates a new highly reduced isoprene mechanism and shows the potential value of automated model reduction for complex reaction systems.

58 GEOSCIENCES↗
NASA NTRS1973

Resonances and librations of some Apollo and Amor asteroids with the Earth.

The orbital evolution of the Apollo asteroids 1620 Geographos and 1685 Toro and Amor asteroids 433 Eros, 1221 Amor, and 1627 Ivar are investigated by numerical integration. All these asteroids, with the exception of Geographos, exhibit systematic orbital couplings with the Earth during the time interval studied (1600-2350 A.D.). 1685 Toro is captured into libration once with Venus due to the 13.5 resonance, and once with the Earth due to the 8:5 resonance. Both librations are unstable because of the effect of the 13:8 near commensurability of the Venus-Earth system. 433 Eros exhibits no libration pattern; the regular variation of its orbital period is due to the beat-effect of the 4:7 resonance with the Earth.

Ip, W.-H.↗
NASA NTRS1989

Physical properties of Aten, Apollo and Amor asteroids

Data available on the physical properties of a group of planet-crossing asteroids, the Aten, Apollo, and Amor objects (AAAO) (include data on the taxonomy, mineralogical surface composition, diameter, rotation rate, shape, and surface texture) are presented together with the type of observations used for obtaining these data. These data show that the population of the AAAO is diverse in all of their physical characteristics. This diversity implies that the AAAO come from multiple sources and had different evolutionary histories.

Mcfadden, Lucy-Ann↗
NASA NTRS1993

Meteorites from recent amor-type orbits

We report here the discovery of a recent meteorite shower in Antarctica, the members of which have very high natural thermoluminescence levels. It is apparent from these data that the shower has been on Earth only a short time (approximately 1000 years) and the meteorite probably came to Earth through rapid (less than 10 exp 5 years) evolution from an orbit with perihelion greater than 1.1 AU, similar to Amor asteroids. Only a very small number of meteorites, including a few modern falls, appear to have had similar orbital histories.

Benoit, P. H.↗
NASA NTRS1977

Mining the Apollo and Amor asteroids

Earth-approaching asteroids could provide raw materials for space manufacturing. For certain asteroids the total energy per unit mass for the transfer of asteroidal resources to a manufacturing site in high earth orbit is comparable to that for lunar materials. For logistical reasons the cost may be many times less. Optical studies suggest that these asteroids have compositions corresponding to those of carbonaceous and ordinary chondrites, with some containing large quantities of iron and nickel; other are thought to contain carbon, nitrogen, and hydrogen, elements that appear to be lacking on the moon. The prospect that several new candidate asteroids will be discovered over the next few years increases the likelihood that a variety of asteroidal resource materials can be retrieved on low-energy missions.

Oleary, B.↗
NASA NTRS1989

Physical studies of Apollo-Amor asteroids - UBVRI photometry of 1036 Ganymed and 1627 Ivar

The 1036 Ganymed and 1627 Ivar photoelectric lightcurves presently discussed indicate in the former case a drastic lightcurve shape change, in conjunction with a significant increase of the synodic rotation period; a substantial change in viewing conditions during the apparition, and a complex interaction between these changes and the asteroid's irregular shape, are indicated by the change. In the latter asteroid's case, a prograde rotation rate is apparent in the observed decrease in synodic period. Both asteroids' phase curves exhibit deviations from the H-G magnitude system phase function at large phase angles.

Hahn, G.↗
NASA NTRS2011

Why Atens Enjoy Enhanced Accessibility For Human Space Flight

In the context of human space flight (HSF), the concept of near-Earth object (NEO) accessibility is highly subjective. Whether or not a particular NEO is accessible critically depends on mass, performance, and reliability of interplanetary HSF systems yet to be designed. Such systems would certainly include propulsion and crew life support with adequate shielding from both solar flares and galactic cosmic radiation. Equally critical architecture options are relevant to NEO accessibility. These options are also far from being determined and include the number of launches supporting an HSF mission, together with whether or not consumables are to be pre-emplaced at the destination. Until the unknowns of HSF to NEOs come into clearer focus, the notion of relative accessibility is of great utility. Imagine a group of NEOs, each with nearly equal HSF merit determined from their individual characteristics relating to crew safety, scientific return, resource utilization, and planetary defense. The more accessible members of this group are more likely to be explored first. A highly accessible NEO could conceivably be deferred in favor of a less accessible HSF destination because the latter is more accessible during a programmatically desirable launch compliant mission trajectory solutions detected in association with a specific NEO. The known NEO population is then surveyed to illustrate in which regions of heliocentric semi-major axis, eccentricity, and inclination (a, e, i) space NEOs with large n values are mapped. The (a, e, i) mapping is also formatted such that membership in each of four NEO orbit classifications, as defined below, is evident. Amors have orbits everywhere superior to (outside of) Earth's. An Amor is therefore defined to have perihelion between 1.017 astronomical units (AU) and the maximum NEO value of 1.3 AU. As of 0 hrs Universal Time on 1 January 2011 (UT epoch 2011.0), Amors numbered 2855 in the Jet Propulsion Laboratory (JPL) Small-Body Database (SBDB), comprising 37.7% of known NEOs. Apollos have orbits crossing Earth's with periods greater than Earth's. An Apollo is therefore defined to have perihelion less than 1.017 AU and a greater than 1.0 AU. As of 2011.0 UT, Apollos numbered 4080 in the SBDB, comprising 53.9% of known NEOs. Atens have orbits crossing Earth's with periods less than Earth's. An Aten is therefore defined to have aphelion greater than 0.983 AU and a less than 1.0 AU. As of 2011.0 UT, Atens numbered 618 in the SBDB, comprising 8.2% of known NEOs. Atiras have orbits everywhere inferior to (inside of) Earth's. An Atira is therefore defined to have aphelion less than 0.983 AU. As of 2011.0 UT, Atiras numbered 11 in the SBDB, comprising 0.1% of known NEOs. It is no surprise that the largest n values are chiefly associated with Apollos and Atens. Because these orbits cross Earth's, distance to be covered in a given round trip mission time delta-t can be far less than is possible for Amors or Atiras . This delta-t or the sum of mission propulsive impulse magnitudes delta-v can more frequently be minimized to enhance NHATS compliance for Apollos and Atens than is generally the case for Amors and Atiras. A less intuitive trend in NHATS results is that Atens nearly outnumber the more numerous Apollos among the most compliant NEOs as measured by n. This trend is completely out of proportion to the degree Atens are represented among the known NEO population. A theory based on geocentric NEO dynamics is presented by this paper to explain why Atens enjoy inherently greater accessibility than do Apollos. Another trend evident from mapping into (a, e, i) space is the dearth of known NEOs at low e when a < 1 AU. Underrepresentation of Atens and Atiras in the NEO catalog is at least in part attributable to observing exclusively from a perspective near Earth. Generally inferior Aten and Atira orbits are rarely, if ever, in Earth's night sky. Until a comprehensive NEO survey is conducted from an appropriateegion remote from Earth, the theory developed in this paper indicates a substantial fraction of the most accessible NEOs will remain unknown. season. Such a season is really yet another undetermined HSF architecture option. A launch season's duration will likely be measured in weeks, and it will be utilized at an indeterminate point almost certainly more than a decade in the future when HSF programmatic maturity is sufficient. Furthermore, current knowledge of the NEO population relevant to HSF is far from complete. In the 100-m-diameter class of greatest interest, only a few percent of the estimated NEO population is known [2, Figure 2.4]. Therefore, any known, lost, or fictitious NEO in a highly accessible orbit is a potential HSF destination of merit. Even if lost, fictitious, small, or hazardous, such a potential target (or another in a similar orbit) may ultimately prove to be an early HSF destination when the pertinent NEO population is more thoroughly catalogued and NEO orbits are more thoroughly maintained at high accuracy. This paper first reviews methodology and pertinent results from NASA-sponsored research performed in late 2010 and dubbed NEO HSF Accessible Targets Study (NHATS, pronounced as "gnats"). A useful accessibility metric developed during this study is n, the tally of NHATS-

Barbee, Brent↗
NASA NTRS2011

Methodology and Results of the Near-Earth Object (NEO) Human Space Flight (HSF) Accessible Targets Study (NHATS)

Near-Earth Asteroids (NEAs) have been identified by the current administration as potential destinations for human explorers during the mid-2020s. While the close proximity of these objects' orbits to Earth's orbit creates a risk of highly damaging or catastrophic impacts, it also makes some of these objects particularly accessible to spacecraft departing Earth, and this presents unique opportunities for solar system science and humanity's first ventures beyond cislunar space. Planning such ambitious missions first requires the selection of potentially accessible targets from the growing population of nearly 7,800 NEAs. To accomplish this, NASA is conducting the Near-Earth Object (NEO) Human Space Flight (HSF) Accessible Targets Study (NHATS). Phase I of the NHATS was executed during September of 2010, and Phase II was completed by early March of 2011. The study is ongoing because previously undetected NEAs are being discovered constantly, which has motivated an effort to automate the analysis algorithms in order to provide continuous monitoring of NEA accessibility. The NHATS analysis process consists of a trajectory filter and a minimum maximum estimated size criterion. The trajectory filter employs the method of embedded trajectory grids to compute all possible ballistic round-trip mission trajectories to every NEA in the Jet Propulsion Laboratory (JPL) Small-Body Database (SBDB) and stores all solutions that satisfy the trajectory filter criteria. An NEA must offer at least one qualifying trajectory solution to pass the trajectory filter. The Phase II NHATS filter criteria were purposely chosen to be highly inclusive, requiring Earth departure date between January 1st, 2015 and December 31st, 2040, total round-trip flight time <= 450 days, stay time at the NEA >= 8 days, Earth departure C(sub 3) energy <= 60 km(exp 2)/s(exp 2), total mission delta-v <= 12 km/s (including an Earth departure maneuver from a 400 km altitude circular parking orbit), and a maximum atmospheric re-entry speed of 12 km/s. After determining which NEAs offer at least one trajectory solution meeting the criteria, the estimated size constraint is then imposed whereby those NEAs may only be considered NHATS- qualifying NEAs if their maximum estimated size is >= 30 m. This corresponds to an absolute magnitude H <= 26.5 with an assumed albedo p = 0:05. The following is a brief high-level summary of the Phase II study results. Of the 7,665 NEAs in the SBDB as of February 3rd, 2011, 765 NEAs passed the trajectory filter and yielded a total of 79,157,604 trajectory solutions. The trajectory solutions for each NEA are post-processed into Pork Chop Contour (PCC) plots which show total mission delta-v as a function of Earth departure date and total mission duration. Although the PCC plots necessarily compress a very multi-dimensional design space into a two-dimensional plot, they permit rapid assessment of the breadth and quality of an NEA's available Earth departure season and clearly indicate the regions of the trajectory design space which warrant further analysis and optimization. The PCC plot for the NEA with the greatest number of NHATS-qualifying trajectory solutions, 2000 SG-344, is shown. Of the 765 NEAs which passed the Phase II trajectory filter, a total of 590 NEAs also satisfied the further constraint of maximum estimated size >= 30 m. The distributions of osculating heliocentric orbital semi-major axis (a), eccentricity (e), and inclination (i), for those 590 NEAs are shown. Note that the semi-latus rectum used is equal to alpha (1-e(exp 2)). To further our understanding of round-trip trajectory accessibility dynamics, it is instructive to examine the distribution of the NHATS-Qualifying NEAs according to orbit classification. NEAs are grouped into four orbit families: Atiras (aphelion < 0.983 AU), Atens (aphelion > 0.983 AU, alpha < 1.0 AU), Apollos (perihelion < 1.017 AU, alpha > 1.0 AU), and Amors (1.017 < perihelion < 1.3 AU). Of the 765 NEAhich satisfied the NHATS trajectory criteria, none are Atiras, 193 are Atens (31% of known Atens), 456 are Apollos (11% of known Apollos), and 116 are Amors (4% of known Amors). While Apollos comprise 60% of the NEAs which pass the NHATS trajectory filter and Atens comprise only 25%, the percentages according to orbit family are perhaps more relevant. Note that only 11% of known Apollos passed the trajectory filter while 31% of known Atens passed. These simple statistics alone strongly suggest that Aten orbits possess features which tend to enhance their round-trip trajectory accessibility as compared to Apollos or Amors. This is significant because Atens' orbits cause them to spend considerable time in Earth's daytime sky, making them difficult to discover and track using ground-based observing assets. In this paper we will detail the NHATS analysis algorithms, present and analyze all NHATS results to date, and discuss aspects of HSF mission architecture design for future NEA missions.

Barbee, Brent↗
NASA NTRS1989

Cratering of the terrestrial planets by Apollo objects

An asteroidal collision model and Monte Carlo program used for studies of the terrestrial meteorite flux, the steady-state number of Apollo-Amor objects, and the orbital distribution of both meteorites and Apollo-Amor objects is used to calculate absolute and relative cratering rates on the terrestrial planets. It is found that the 'best' estimates of the predicted asteroidal cratering rate are three times lower than estimates of the observed terrestrial cratering rate. If this is due to errors in the asteroidal production rate of Apollo-Amor objects, the predicted present-day cratering rate per unit area on Mars is four times that on earth, whereas that on Mercury is twice that on earth.

Wetherill, G. W.↗
NASA NTRS1979

Earth-crossing asteroids - Orbital classes, collision rates with earth, and origin

Asteroids that can intersect the orbit of the earth are discussed, which include Aten asteroids (semimajor axis (a) less than 1 AU, aphelion greater than 0.983 AU), Apollo asteroids (a greater than 1 AU, perihelion less than 1.017 AU), and Amor asteroids (perihelion distance between 1.017 and 1.3 AU). The principal sources of earth-crossing asteroids appear to be extinct comet nuclei and collision fragments from regions in the main asteroid belt. The total population of earth-crossers is estimated at 13,000, of which approximately 8% are Atens, 50% are Apollos, and 40% are Amors,and the present collision rate of such asteroids with the earth is estimated at about 3.5 objects, to absolute magnitude 18, per million years.

Shoemaker, E. M.↗
NASA NTRS1981

The diameter and albedo of 1943 Anteros

The results of broadband visual and infrared photometry of the Apollo-Amor asteroid 1943 Anteros during its 1980 apparition are reported. By means of a radiometric model, a diameter of 2.3 + or - 0.2 km and a visual geometric albedo of 0.13 + or - 0.03 is calculated. The albedo and reflectance spectrum of Anteros imply that it is a type S asteroid. Thus, Anteros may have a silicate surface similar to other Apollo-Amor asteroids as well as some stony-iron meteorites.

Veeder, G. J.↗
NASA NTRS1989

Radiometry of near-earth asteroids

Infrared photometry is reported for 22 Aten, Apollo, and Amor asteroids. Thermal models are used to derive the corresponding radiometric albedos and diameters. Several of these asteroids appear to have surfaces of relatively high thermal inertia due to the exposure of bare rock or a coarse regolith. The Apollo asteroid 3103, 1982 BB, is recognized as class E. The Jupiter-crossing Amor asteroid 3552, 1983 SA, is confirmed as class D, but low albedos remain rare for near-earth asteroids.

Veeder, G. J.↗
NASA NTRS1991

Near-Earth asteroids: Metals occurrence, extraction, and fabrication

Near-earth asteroids occur in three principle types of orbits: Amor, Apollo, and Aten. Amor asteroids make relatively close (within 0.3 AU) approaches to the earth's orbit, but do not actually overlap it. Apollo asteroids spend most of their time outside the earth's orbital path, but at some point of close approach to the sun, they cross the orbit of the earth. Aten asteroids are those whose orbits remain inside the earth's path for the majority of their time, with semi-major axes less than 0.1 AU. Near-earth orbit asteroids include: stones, stony-irons, irons, carbonaceous, and super-carbonaceous. Metals within these asteroids include: iron, nickel, cobalt, the platinum group, aluminum, titanium, and others. Focus is on the extraction of ferrous and platinum group metals from the stony-iron asteroids, and the iron asteroids. Extraction of the metal fraction can be accomplished through the use of tunnel-boring-machines (TBM) in the case of the stony-irons. The metals within the story-iron asteroids occur as dispersed granules, which can be separated from the stony fraction through magnetic and gaseous digestion separation techniques. The metal asteroids are processes by drilling and gaseous digestion or by gaseous digestion alone. Manufacturing of structures, housings, framing networks, pressure vessels, mirrors, and other products is accomplished through the chemical vapor deposition (CVD) of metal coating on advanced composites and on the inside of contour-defining inflatables (CDI). Metal coatings on advanced composites provide: resistance to degradation in the hostile environments of space; superior optical properties; superior heat dissipation; service as wear coatings; and service as evidential coatings. Metal coatings on the inside of CDI produce metal load-bearing products. Fibers such as graphite, kevlar, glass, ceramic, metal, etc., can be incorporated in the metal coatings on the inside of CDI producing metal matrix products which exhibit high strength and resist crack propagation.

Westfall, Richard↗
NASA NTRS1991

End products of cometary evolution - Cometary origin of earth-crossing bodies of asteroidal appearance

The present state of the understanding of the dynamic mechanisms under which the orbits of some comets evolve into those observed for Apollo-Amor objects is reviewed. Observed Jupiter-family objects of asteroidal appearance, e.g., 1983SA, are much more likely to be of cometary rather than asteroidal origin. 'Decoupling' is facilitated by several mechanisms: perturbations by terrestrial planets, perturbations by Jupiter and the other giant planets, and nongravitational orbital changes caused by the loss of gas and dust from the comet. The dynamical time scale for decoupling is argued to be 100,000-1,000,000 yr, and almost all decoupled comets are likely to be of asteroidal appearance. Estimates can be made of the number of cometary Apollo-Amor 'asteroids', the observed number of earth-crossing active and inactive short-period comets, and the production rate of short-period comets. These estimates are compatible with other theoretical and observational inferences that suggest the presence of a significant population of Apollo objects that formerly were active comets.

Wetherill, G. W.↗