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At least 19 records

Identification of acetylene /C2H2/ in infrared atmospheric absorption spectra

Infrared atmospheric absorption spectra at 0.02/cm resolution were obtained during a balloon flight on March 23, 1981 from the Holloman AFB, New Mexico. The absorption features, attributed to C2H2, were used to derive a preliminary mixing ratio of about 25 pptv near 9 km, accurate to + or - 40%. This mixing ratio falls into the range of values calculated for the upper troposphere C2H2 in a photochemical/transport model. However, previous measurements from aircraft grab sampling (Cronn and Robinson, 1979) show four to twelve times this C2H2 concentration 1.5 km below the tropopause.

Goldman, A.

Atmospheric absorption near 2400 kayser

Theoretical atmospheric absorption spectra between 2385 and 2425 kayser are shown to give excellent agreement with high resolution observations. Most of the atmospheric absorption in this region arises from continuum features due to absorption of N2 and the wings of distant CO2 lines. The treatment of each of these factors is discussed.

Susskind, J.

Impact of Nonabsorbing Anthropogenic Aerosols on Clear-Sky Atmospheric Absorption

Absorption of solar radiation by atmospheric aerosol has become recognized as important in regional and global climate. Nonabsorbing, hydrophilic aerosols, such as sulfate, potentially affect atmospheric absorption in opposing ways: first, decreasing absorption through aging initially hydrophobic black carbon (BC) to a hydrophilic state, enhancing its removal by wet scavenging, and consequently decreasing BC lifetime and abundance, and second, increasing absorption through enhancement of the BC absorption efficiency by internal mixing as well as through increasing the amount of diffuse solar radiation in the atmosphere. On the basis of General Circulation Model studies with an embedded microphysical aerosol module we systematically demonstrate the significance of these mechanisms both on the global and regional scales. In remote transport regions, the first mechanism prevails, reducing atmospheric absorption, whereas in the vicinity of source regions, despite enhanced wet scavenging, absorption is enhanced owing to the prevalence of the second mechanisms. Our findings imply that the sulfur to BC emission ratio plays a key role in aerosol absorption.

Stier, Philip

The experimental determination of atmospheric absorption from aircraft acoustic flight tests

A method for determining atmospheric absorption coefficients from acoustic flight test data is presented. Measurements from five series of acoustic flight tests were included in the study. The number of individual flights totaled 24: six Boeing 707 flights performed in May 1969 in connection with the turbofan nacelle modification program, eight flights from Boeing tests conducted during the same period, and 10 flights of the Boeing 747 airplane. The effects of errors in acoustic, meteorological, and aircraft performance and position measurements are discussed. Tabular data of the estimated sample variance of the data for each test are given for source directivity angles from 75 deg to 120 deg and each 1/3-octave frequency band. Graphic comparisons are made of absorption coefficients derived from ARP 866, using atmospheric profile data, with absorption coefficients determined by the experimental method described in the report.

Miller, R. L.

Microwave Resonator Measurements of Atmospheric Absorption Coefficients: A Preliminary Design Study

A preliminary design study examined the feasibility of using microwave resonator measurements to improve the accuracy of atmospheric absorption coefficients and refractivity between 18 and 35 GHz. Increased accuracies would improve the capability of water vapor radiometers to correct for radio signal delays caused by Earth's atmosphere. Calibration of delays incurred by radio signals traversing the atmosphere has applications to both deep space tracking and planetary radio science experiments. Currently, the Cassini gravity wave search requires 0.8-1.0% absorption coefficient accuracy. This study examined current atmospheric absorption models and estimated that current model accuracy ranges from 5% to 7%. The refractivity of water vapor is known to 1% accuracy, while the refractivity of many dry gases (oxygen, nitrogen, etc.) are known to better than 0.1%. Improvements to the current generation of models will require that both the functional form and absolute absorption of the water vapor spectrum be calibrated and validated. Several laboratory techniques for measuring atmospheric absorption and refractivity were investigated, including absorption cells, single and multimode rectangular cavity resonators, and Fabry-Perot resonators. Semi-confocal Fabry-Perot resonators were shown to provide the most cost-effective and accurate method of measuring atmospheric gas refractivity. The need for accurate environmental measurement and control was also addressed. A preliminary design for the environmental control and measurement system was developed to aid in identifying significant design issues. The analysis indicated that overall measurement accuracy will be limited by measurement errors and imprecise control of the gas sample's thermodynamic state, thermal expansion and vibration- induced deformation of the resonator structure, and electronic measurement error. The central problem is to identify systematic errors because random errors can be reduced by averaging. Calibrating the resonator measurements by checking the refractivity of dry gases which are known to better than 0.1% provides a method of controlling the systematic errors to 0.1%. The primary source of error in absorptivity and refractivity measurements is thus the ability to measure the concentration of water vapor in the resonator path. Over the whole thermodynamic range of interest the accuracy of water vapor measurement is 1.5%. However, over the range responsible for most of the radio delay (i.e. conditions in the bottom two kilometers of the atmosphere) the accuracy of water vapor measurements ranges from 0.5% to 1.0%. Therefore the precision of the resonator measurements could be held to 0.3% and the overall absolute accuracy of resonator-based absorption and refractivity measurements will range from 0.6% to 1.

Walter, Steven J.

Atmospheric absorption spectra near 2200 kayser and 2400 kayser

Quantitative interpretation of radiometric measurements for temperature profiling requires the ability to accurately calculate the average transmittance across the sounding channel. Therefore, an accurate calculation of atmospheric absorption due to broad banded or continuum absorption features is as significant as one of features due to individual lines. The important broad banded features affecting atmospheric absorption in the 4.3 micrometer region are due to the pressure induced N2 fundamental (called the N2 continuum) and to wings of relatively nearby very saturated CO2 lines. Attention is given to the N2 continuum, the CO2 line shape, and calculated and observed line spectra.

Susskind, J.

Real-time atmospheric absorption spectra for in-flight tuning of an airborne dial system

Real-time measurements of atmospheric absorption spectra are displayed and used to precisely calibrate and fix the frequency of an Alexandrite laser to specific oxygen absorption features for airborne Differential Absorption Lidar (DIAL) measurements of atmospheric pressure and temperature. The DIAL system used contains two narrowband tunable Alexandrite lasers: one is electronically scanned to tune to oxygen absorption features for on-line signals while the second is used to obtain off-line (nonabsorbed) atmospheric return signals. The lidar operator may select the number of shots to be averaged, the altitude, and altitude interval over which the signals are averaged using single key stroke commands. The operator also determines exactly which oxygen absorption lines are scanned by comparing the line spacings and relative strengths with known line parameters, thus calibrating the laser wavelength readout. The system was used successfully to measure the atmospheric pressure profile on the first flights of this lidar, November 20, and December 9, 1985, aboard the NASA Wallops Electra aircraft.

Dombrowski, M.

AFGL atmospheric absorption line parameters compilation - 1982 edition

The latest edition of the AFGL atmospheric absorption line parameters compilation for the seven most active infrared terrestrial absorbers is described. Major modifications to the atlas for this edition include updating of water-vapor parameters from 0 to 4300 per cm, improvements to line positions for carbon dioxide, substantial modifications to the ozone bands in the middle to far infrared, and improvements to the 7- and 2.3-micron bands of methane. The atlas now contains about 181,000 rotation and vibration-rotation transitions between 0 and 17,900 per cm. The sources of the absorption parameters are summarized.

Rothman, L. S.

Determination of The Inflight Spectral Calibration of AVIRIS Using Atmospheric Absorption Features

Both the surface and atmospheric characteistics were measured for a calibration target during an inflight calibration experiment held at Lunar Lake, Nevada on April 5, 1994 (Green, et al., 1995). This paper uses upwelling spectral radiance predicted for the calibration target with the MODTRAN radiative transfer code (Berk, et al., 1986) to validage the spectral calibration of AVIRIS inflight.

Atmospheric Absorption

An Updated Model for the Effect of Atmospheric Absorption on Sounding Rockets

A very high-resolution R > 20,000 Far Ultraviolet full-disk, solar spectrograph will be launched in the Spring of 2023. This paper describes the in-flight wavelength calibration techniques and the fortuitous retrieval of Earth’s thermospheric information during the flight. Building and calibration of the Full-sun Ultraviolet Rocket Spectrograph (FURST) is currently underway. The purpose of this instrument is to obtain the highest resolution and most complete Far Ultra-Violet (FUV) spectra of the full disk Sun. This so-called "Sun-as-a-star" spectra will allow direct comparisons between our Sun and other stars measured by the Hubble Space Telescope(HST) and the upcoming James Webb Space Telescope (JWST). The Solar Physics groups at NASA Marshall Space Flight Center (MSFC) and Montana State University (MSU) have been developing the tools and procedures necessary to achieve the high spectral resolution goal. These include, among other things, improved tracking of error propagation, in-situ monitoring of the camera gain with a radioactive Fe-55 source, and the development of a simulated spectral calibration map under a noisy diagnostic-lamp signal. This mapping introduces a clocked CCD in order to obtain sub-pixel spectral resolution and overcome the Nyquist limit by about a factor of 2. Aside from the main purpose of FURST, we have been investigating the effect of absorption in the upper atmosphere at sounding-rocket altitudes (about 100-300 km). We present here an improved model of the optical depth caused by the thermospheric Oxygen cross-section and H and O self-absorption. This data-based model uses concentric spherical shells to account for the curvature of the Earth’s atmosphere and refraction. Using these calculations, we present the anticipated effect on the signal received by FURST, how that signal changes over the course of the flight-path These absorption peaks would provide wavelength fiducials at line-center that might add to in-flight calibration of the instrument. Many studies have found ways to correct for these so-called "Telluric" lines. However, it may be that these lines can in fact be a useful tool to further improve our calibration, rather than simply a nuisance to be corrected for! Finally, we discuss the inversion problem: how we could take actual flight data and back-out the atmospheric data (such as density and temperature) from any such sounding rocket flight that shows evidence of atmospheric absorption.

Nicolas Donders

Development of solar cycle 21 observed in EUV spectrum and atmospheric absorption

The results of AE-C and AE-E satellite observations of solar EUV irradiance and atmospheric absorption at wavelengths from 140 to 1850 A, which reflect unexpectedly large differences between the past solar cycle (20) and the present one (21), are discussed. While observations of the oxygen-dissociating solar UV flux above 1230 A show at most a 10% change between the two periods, the EUV minimum at other wavelengths was found to occur 14 months before the sunspot minimum, with a magnitude considerably greater in cycle 21 than in developing cycle 20. During the period of cycle transition, observed irradiance values did not correlate with conventional activity indices. Measurements of UV attenuation reveal no increase of optical depths around 300 km, indicating no corresponding rises in atmospheric density or temperature. The results are considered to present a major challenge to aeronomical models.

Hinteregger, H. E.

Aerosol Forcing of Climate Change and "Anomalous" Atmospheric Absorption

The forcings that drive long-term climate change are not known with an accuracy sufficient to define future climate change. Anthropogenic greenhouse gases (GHGs), which are well-measured, cause a strong positive (warming) forcing. But other, poorly measured, anthropogenic forcings, especially changes of atmospheric aerosols, clouds, and land-use patterns, cause a negative forcing that tends to offset greenhouse warming. We will focus on the role of aerosols as a climate forcing mechanism and the contribution that aerosols might make to the so- called "anomalous" atmospheric absorption that has been inferred from some atmospheric measurements.

Hansen, James E.

Aerosol Forcing of Climate Change and Anomalous Atmospheric Absorption

The forcings that drive long-term climate change are not known with an accuracy sufficient to define future climate change, Anthropogenic greenhouse gases (GHGs), which are well-measured, cause a strong positive (warming) forcing. But other, poorly measured, anthropogenic forcings, especially changes of atmospheric aerosols, clouds, and land-use patterns, cause a negative forcing that tends to offset greenhouse warming. We will focus on the role of aerosols as a climate forcing mechanism and the contribution that aerosols might make to the so-called "anomalous" atmospheric absorption that has been inferred from some atmospheric measurements.

Hansen, James E.

An Updated Model for the Effect of Atmospheric Absorption on Sounding Rockets

Our team is working on building and calibrating the FURST sounding rocket, with an expected launch in mid-2023. The goal is to image the most complete and highest resolution UV spectra to date. To do this, precise radiometric and wavelength calibration techniques have been developed. We describe below our model of O2 atmospheric absorption and couple that with simulated FURST images. With a high-enough SNR, we can estimate our ability to use absorption peaks for calibration, or for back-calculating atmospheric properties. If data is available, this method could be applied to older sounding rocket data to find hidden science.

MSFC, NASA, UAH, CSPAR, SPA, FURST, MSU

Understanding Atmospheric Absorption Effects on UV Spectra from Sounding Rockets using a Spherical-Shells Model

Our team is working on building and calibrating the FURST sounding rocket, with an expected launch in mid-2023. The goal is to image the most complete and highest resolution UV spectra to date. To do this, preciseradiometric and wavelength calibration techniques have been developed. We describe below our model of O2 atmospheric absorption and couple that with simulated FURST images. With a high-enough SNR, we canestimate our ability to use absorption peaks for calibration, or for back-calculating atmospheric properties. If data is available, this method could be applied to older sounding rocket data to find hidden science.

MSFC, NASA, UAH, CSPAR, FURST, MSU, SHINE, Aeronom