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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Determination of cosmogenic Ca-41 in a meteorite with tandem accelerator mass spectrometry

The first use of tandem accelerator mass spectrometry (TAMS) to measure the content of Ca-41 in a natural sample, the iron Bogou meteorite, is reported. Ca in the samples was extracted by hydroxide precipitation and purified by means of a caution exchange resin (AG 50W-X8). After adding 4 percent ammonium oxide, the precipitate was ignited to CaO in a quartz vial at about 1100 C. The Ca-41/Ca ratios were determined following acceleration by alternate measurements of the Ca-40 beam current in an image Faraday cup. Ca-41 particles were also measured using a gas counter. The measured Ca-41/Ca ratio was 3.8 + or -0.6 x 10 to the 12th, which corresponds to a Ca-41 activity of 6.9 + or -1.1 d.p.m. per kg. Calculation of the half-life of Ca-41 in the Bogou meteorite yielded an age of 103,000 years.

Kubik, P. W.↗
NASA NTRS1986

Radionuclide measurements by accelerator mass spectrometry at Arizona

Over the past years, Tandem Accelerator Mass Spectrometry (TAMS) has become established as an important method for radionuclide analysis. In the Arizona system the accelerator is operated at a thermal voltage of 1.8MV for C-14 analysis, and 1.6 to 2MV for Be-10. Samples are inserted into a cesium sputter ion source in solid form. Negative ions sputtered from the target are accelerated to about 25kV, and the injection magnet selects ions of a particular mass. Ions of the 3+ charge state, having an energy of about 9MeV are selected by an electrostatic deflector, surviving ions pass through two magnets, where only ions of the desired mass-energy product are selected. The final detector is a combination ionization chamber to measure energy loss (and hence, Z), and a silicon surface-barrier detector which measures residual energy. After counting the trace iosotope for a fixed time, the injected ions are switched to the major isotope used for normalization. These ions are deflected into a Faraday cup after the first high-energy magnet. Repeated measurements of the isotope ratio of both sample and standards results in a measurement of the concentration of the radionuclide. Recent improvements in sample preparation for C-14 make preparation of high-beam current graphite targets directly from CO2 feasible. Except for some measurements of standards and backgrounds for Be-10 measurements to date have been on C-14. Although most results have been in archaeology and quaternary geology, studies have been expanded to include cosmogenic C-14 in meteorites. The data obtained so far tend to confirm the antiquity of Antarctic meteorites from the Allan Hills site. Data on three samples of Yamato meteorites gave terrestrial ages of between about 3 and 22 thousand years.

Jull, A. J. T.↗
NASA NTRS1980

Half-life of Si-32 from tandem-accelerator mass spectrometry

A newly developed mass-spectrometry technique employing a tandem Van de Graaff accelerator together with a special beam-transport system and heavy-ion detector has been used to determine the half-life of Si-32. The result obtained, 108 plus or minus 18 yr, disagrees with the accepted value of 330 plus or minus 40 yr. The implications of the new half-life of Si-32, which is used for dating studies, are discussed.

Elmore, D.↗
NASA NTRS1984

C-14 content of ten meteorites measured by tandem accelerator mass spectrometry

Measurements of C-14 in three North American and seven Antarctic meteorites show in most cases that this cosmogenic isotope, which is tightly bound, was separated from absorbed atmospheric radiocarbon by stepwise heating extractions. The present upper limit to age determination by the accelerator method varies from 50,000 to 70,000 years, depending on the mass and carbon content of the sample. The natural limit caused by cosmic ray production of C-14 in silicate rocks at 2000 m elevation is estimated to be 55,000 + or - 5000 years. An estimation is also made of the 'weathering ages' of the Antarctic meteorites from the specific activity of loosely bound CO2 which is thought to be absorbed from the terrestrial atmosphere. Accelerator measurements are found to agree with previous low level counting measurements, but are more sensitive and precise.

Brown, R. M.↗
NASA NTRS1983

Measurements of I-129 in meteorites and lunar rock by tandem accelerator mass spectrometry

Precise measurements of the half-life of I-129 in three different meteorites and one lunar surface rock are reported. The meteorite source of I-129 was produced by cosmic ray secondary neutron reactions on Te, while the source in lunar materials in spallation on barium and rare earth elements. The Abee, Allende, and Dhajala meteorites were examined, together with the lunar rock 14310. Details of the process used to extract the iodine are provided. The Abee and Allende samples exhibited a production of 0.5 atom/min per gm of Te from the (n,2n) reaction and 0.05 atom/min/gm for the (n,gamma) reaction. The I-129 is concluded to be a viable tool for long-lived cosmogenic nuclide studies. Further work to extend the data to include the constancy of the cosmic ray flux, the meteorite bombardment history, and the cosmic exposure age dating by means of the I-129 and Xe-129 method is indicated.

Nizhiizumi, K.↗
NASA NTRS1991

Determination of the isotopic composition of atmospheric methane and its application in the Antarctic

A procedure for establishing the C-13/C-12 ratio and the C-14 abundance in the atmospheric methane is discussed. The method involves air sample collection, measurement of the methane mixing ratio by gas chromotography followed by quantitative conversion of the methane in the air samples to CO2 and H2O, and analysis of the resulting CO2 for the C-13/C-12 ratio by stable isotope ratio mass spectrometry and measurement of C-14 content by accelerator mass spectrometry. The carbon isotropic composition of methane in air collected at Baring Head, New Zealand, and in air collected on aircraft flights between New Zealand and Antarctica is determined by the method, and no gradient in the composition between Baring Head and the South Pole station is found. As the technique is refined, and more data is gathered, small seasonal and long-term variations in C-13 are expected to be resolved.

Lowe, David C.↗
NASA NTRS1984

Radioactivities in returned lunar materials and in meteorites

Carbon 14 terrestial ages were determined with low level minicomputers and accelerator mass spectrometry on 1 Yamato and 18 Allan Hills and nearby sited meteorites. Techniques for an accelerator mass spectrometer which make C(14) measurements on small samples were developed. Also Be(10) concentrations were measured in Byrd core and Allan Hills ice samples.

Fireman, E. L.↗
NASA NTRS1992

Cosmogenic radioisotopes on LDEF surfaces

The radioisotope Be-7 was discovered in early 1990 on the front surface, and the front surface only, of the LDEF. A working hypothesis is that the isotope, which is known to be mainly produced in the stratosphere by spallation of nitrogen and oxygen nuclei with cosmic ray protons or secondary neutrons, diffuses upward and is absorbed onto metal surfaces of spacecraft. The upward transport must be rapid, that is, its characteristic time scale is similar to, or shorter than, the 53 day half-life of the isotope. It is probably by analogy with meteoritic metal atmospheric chemistry, that the form of the Be at a few 100 km altitude is as the positive ion Be(+) which is efficiently incorporated into the ionic lattice of oxides, such as Al2O3, Cr2O3, Fe2O3, etc., naturally occurring on surfaces of Al and stainless steel. Other radioisotopes of Be, Cl, and C are also produced in the atmosphere, and a search was begun to discover these. Of interest are Be-10 and C-14 for which the production cross sections are well known. The method of analysis is accelerator mass spectrometry. Samples from LDEF clamp plates are being chemically extracted, purified, and prepared for an accelerator run.

Gregory, J. C.↗
NASA NTRS1997

Measuring excitation functions needed to interpret cosmogenic nuclide production in lunar rocks

Radionuclides produced in lunar rocks by cosmic ray interactions are measured using Accelerator Mass Spectrometry or gamma-ray spectroscopy. From these measurements, estimates of the solar proton flux over time periods characterized by the half-life of the isotope under study can be made, if all the cross sections for all the reactions of all cosmic ray particles with all elements found in lunar rocks are known. Proton production cross sections are very important because (approximately) 98% of solar cosmic rays and (approximately) 87% of galactic cosmic rays are protons in the lunar environment. Many of the needed cross sections have never been measured. Targets of C, Al, Si, SiO2, mg, K, Ca, Fe and Ni have been irradiated using three accelerators to cover a proton energy range of 25-500 MeV. Excitation functions for Be-7, Be-10, Na-22, and Al-26 production from Mg and Al will be reported, and the consequences of using these new cross section values to estimate solar proton fluxes discussed.

Radiation Flux↗
NASA NTRS2020

A New Glacial Varve Chronology Along the Southern Laurentide Ice Sheet That Spans the Younger Dryas–Holocene Boundary

Glacial varves can detail ice-margin positions and provide a proxy for meltwater discharge at resolutions comparable to those of the Greenland ice core archives, and thus they can be critical paleorecords for assessing the response of both ancient and modern ice sheets to climate change. Here we provide an ~1500 yr varve chronology straddling the Younger Dryas (YD)–Holocene boundary (11.65 cal. kyr B.P.), the first such chronology in North America. The varves are from glacial Lake Agassiz (central North America). The chronology is pinned on accelerator mass spectrometry radiocarbon-dated terrestrial macrofossils at the base of a widespread red-clay bed deposited during flooding from the Lake Superior basin. We illustrate the utility of this record by examining ice-margin retreat and melting through the late Younger Dryas and across the Holocene boundary. The ice margin receded at a constant rate, not only during the late YD, but for at least 300 yr after the onset of the Holocene. In contrast, varve thicknesses increased at the boundary, and a moraine formed over a 50 yr period, perhaps in response to the warming climate. Our expectation is that this time series will continue to be developed, expanded, and refined because it promises to be the longest and most geographically extensive glacial varve data set in North America.

Glacial varves↗
NASA NTRS1981

Cosmic-ray-produced Cl-36 and Mn-53 in Allan Hills-77 meteorites

Cosmic-ray-produced Mn-53 has been determined by neutron activation in nine Allan Hills-77 meteorites. Additionally, Cl-36 has been measured in seven of these objects using tandem accelerator mass spectrometry. These results, along with C-14 and Al-26 concentrations determined elsewhere, yield terrestrial ages ranging from 10,000 to 700,000 years. Weathering was not found to result in Mn-53 loss.

Nishiizumi, K.↗
NASA NTRS1984

Be-10 and Cl-36 depth profiles in an Apollo 15 drill core

The present study of galactic cosmic ray production profiles by means of tandem accelerator mass spectrometry has measured cosmic ray-produced Be-10 and Cl-36, whose half-attenuation lengths are respectively calculated to be 120 and 132 g/sq cm. The measured half-attenuation lengths for Be-10 are noted to be slightly longer than predicted by the Reedy-Arnold (1972) theoretical model. Secondary thermal neutron production from Cl-35 is invoked as an explanation for the flatter and deeper maximum seen in the Cl-36 profile.

Nishiizumi, K.↗
NASA NTRS1984

Al-26 depth profile in Apollo 15 drill core

Accelerator mass spectrometry is used in a study of galactic cosmic ray production profiles based on cosmic ray-produced Al-26 in the Apollo 15 long core. The results, which are in general agreement with earlier nondestructive counting data, are of significantly higher precision, yet systematically lower. The half-attenuation length for Al-26 production is presently calculated to be 122 g/sq cm, after normalizing the data to average chemical composition.

Nishiizumi, K.↗
NASA NTRS1986

The 10Be contents of SNC meteorites

Several authors have explored the possibility that the Shergottites, Nakhlites, and Chassigny (SNC) came from Mars. The spallogenic gas contents of the SNC meteorites have been used to: constrain the sizes of the SNC's during the last few million years; to establish groupings independent of the geochemical ones; and to estimate the likelihood of certain entries in the catalog of all conceivable passages from Mars to Earth. The particular shielding dependence of Be-10 makes the isotope a good probe of the irradiation conditions experienced by the SNC meteorites. The Be-10 contents of nine members of the group were measured using the technique of accelerator mass spectrometry. The Be-10 contents of Nakhla, Governador Valadares, Chassigny, and probably Lafayette, about 20 dpm/kg, exceed the values expected from irradiation of the surface of a large body. The Be-10 data therfore do not support scenario III of Bogard et al., one in which most of the Be-10 in the SNC meteorites would have formed on the Martian surface; they resemble rather the Be-10 contents found in many ordinary chondrites subjected to 4 Pi exposures. The uncertainties of the Be-10 contents lead to appreciable errors in the Be-10 ages, t(1) = -1/lambda ln(1 Be-10/Be-10). Nonetheless, the Be-10 ages are consistent with the Ne-21 ages calculated assuming conventional, small-body production rates and short terrestrial ages for the finds. It is believed that this concordance strengthens the case for at least 3 different irradiation ages for the SNC meteorites. Given the similar half-thicknesses of the Be-10 and Ne-21 production rates, the ratios of the Be-10 and Ne-21 contents do not appear consistent with common ages for any of the groups. In view of the general agreement between the Be-10 and Ne-21 ages it does not seem useful at this time to construct multiple-stage irradiation histories for the SNC meteorites.

Pal, D. K.↗
NASA NTRS1986

Studies on cosmogenic nuclides in meteorites with regard to an application as potential depth indicators

Measurements of stable and radioactive spallation products in meteorites allow to investigate their histories, especially with respect to the exposure to galactic cosmic ray particles and the pre-atmospheric size of the object. While the concentrations of spallation products lead to the determination of exposure and terrestrial ages, production rate ratios are characteristic for the location of the sample in the meteorite. So, one of the aims of this investigation on meteorites is to obtain depth indicators from suitable pairs of cosmogenic nuclides. Because of the different depth profiles for nuclide productions it is necessary to determine the concentrations of a larger number of spallation products in aliquots of a single small sample. Such same sample measurements of Be-10 and light noble gases were performed on 15 ordinary chondrites (7 H- and 8 L-chondrites. Be-10 was determined by accelerator mass spectrometry and the noble gases were measured by static mass spectrometry. The results are summarized and discussed.

Sarafin, R.↗
NASA NTRS1986

Exposure history of shergottites

The cosmogenic nuclides Cl-36, Al-26, Be-10, and Mn-53 were analyzed in Shergotty, ALHA 77005, and EETA 79001 shergottites by means of accelerator mass spectrometry and neutron activation. The cosmogenic radionuclide data were combined with noble gas data and cosmic ray track data to obtain the exposure ages, terrestrial ages, preatmospheric radii, and ablation depths for the three shergottites. The results indicate that none of the three meteorites was irradiated measurably by cosmic rays on its parent body, and that all three objects were ejected from greater than a 3-m depth in their parent bodies. The EETA 79001 meteorite was ejected in an event distinct from that of ALHA 77005 and Shergotty. All three shergottites show a very small amount of ablation, suggesting low velocities on entry into the earth's atmosphere.

Nishizumi, K.↗
NASA NTRS1986

Beryllium-10 contents of shergottites, nakhlites, and Chassigny

Accelerator mass spectrometry gives the following Be-10 contents (dpm/kg) for the SNC meteorites: Shergotty, 13.0 + or - 1.5 and 17.3 + or - 2.7; Zagami, 18.6 + or - 2.5 and 20.0 + or - 3.2; ALHA 77005, 15 + or - 3; EETA 79001A, 7.8 + or - 1.1 and 6.3 + or - 0.5; EETA 79001B, 8.5 + or - 1.1; Nakhla, 19.7 + or - 3.3; Lafayette, 18.1 + or - 2.5; Governador Valadares, 25.6 + or - 3.6; Chassigny, 20.5 + or - 3.1. The Be-10 contents of the NC meteorites indicate that significant accumulation of cosmogenic nuclides occurred in decimeter rather than planetary-size bodies. The agreement of the He-3, Ne-21, and Be-10 exposure ages of the shergottites also supports small-body irradiation. A long terrestrial age for EETA 79001 appears unlikely.

Pal, D. K.↗
NASA NTRS1988

Al-26 and Be-10 production in iron meteorites

To compare the Al-26/Ne-21 ages with K-40/K-41 ages, the contents of Al-26 were determined in seven iron meteorites using accelerator mass spectrometry and the light noble gas contents were determined using conventional mass spectrometry, for samples for which these values were not available. In addition, contents of Be-10 were measured. Due to the presence of boron in the samples, the values of Al-26 were found to be at least 30 percent lower than the literature values obtained by low-level counting techniques, while the Be-10 values were 10-15 percent lower. The production rates of these nuclides at different He-4/Ne-21 ratios were estimated, showing that the increase in He-4/Ne-21 ratios corresponded with decreases in Al-26 and Be-10. It was shown that the exposure ages calculated from the Ne-21/Al-26 ratio cannot be calibrated so as to agree with both the K-40/K-41 ages and ages based on the shorter-lived nuclides Ar-39 and Cl-36.

Aylmer, D.↗