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AgYb is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Yb is bonded in a body-centered cubic geometry to eight equivalent Ag atoms. All Yb–Ag bond lengths are 3.16 Å. Ag is bonded in a body-centered cubic geometry to eight equivalent Yb atoms.
YbAg2 crystallizes in the orthorhombic Imma space group. The structure is three-dimensional. Yb is bonded in a 12-coordinate geometry to twelve equivalent Ag atoms. There are a spread of Yb–Ag bond distances ranging from 3.23–3.45 Å. Ag is bonded in a 10-coordinate geometry to six equivalent Yb and four equivalent Ag atoms. There are a spread of Ag–Ag bond distances ranging from 2.75–2.92 Å.
AgYb crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Yb is bonded in a 7-coordinate geometry to seven equivalent Ag atoms. There are a spread of Yb–Ag bond distances ranging from 3.15–3.18 Å. Ag is bonded in a 9-coordinate geometry to seven equivalent Yb and two equivalent Ag atoms. Both Ag–Ag bond lengths are 2.92 Å.
Yb2Ag7 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Yb is bonded in a 8-coordinate geometry to fourteen Ag atoms. There are a spread of Yb–Ag bond distances ranging from 3.20–3.40 Å. There are three inequivalent Ag sites. In the first Ag site, Ag is bonded in a 12-coordinate geometry to four equivalent Yb and eight Ag atoms. There are a spread of Ag–Ag bond distances ranging from 2.84–3.23 Å. In the second Ag site, Ag is bonded to four equivalent Yb and eight Ag atoms to form a mixture of edge, face, and corner-sharing AgYb4Ag8 cuboctahedra. There are a spread of Ag–Ag bond distances ranging from 2.75–2.77 Å. In the third Ag site, Ag is bonded to four equivalent Yb and eight Ag atoms to form a mixture of edge, face, and corner-sharing AgYb4Ag8 cuboctahedra.
Yb5Ag3 crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. there are two inequivalent Yb sites. In the first Yb site, Yb is bonded to five Ag atoms to form a mixture of distorted edge, corner, and face-sharing YbAg5 trigonal bipyramids. There are a spread of Yb–Ag bond distances ranging from 3.11–3.32 Å. In the second Yb site, Yb is bonded in a distorted square co-planar geometry to six Ag atoms. There are four shorter (3.10 Å) and two longer (3.68 Å) Yb–Ag bond lengths. There are two inequivalent Ag sites. In the first Ag site, Ag is bonded in a 10-coordinate geometry to ten Yb atoms. In the second Ag site, Ag is bonded in a 9-coordinate geometry to eight Yb and one Ag atom. The Ag–Ag bond length is 2.89 Å.
Yb3Ag2 crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional. there are two inequivalent Yb sites. In the first Yb site, Yb is bonded in a 6-coordinate geometry to six equivalent Ag atoms. There are four shorter (3.18 Å) and two longer (3.19 Å) Yb–Ag bond lengths. In the second Yb site, Yb is bonded in a square co-planar geometry to four equivalent Ag atoms. All Yb–Ag bond lengths are 3.22 Å. Ag is bonded in a 9-coordinate geometry to eight Yb and one Ag atom. The Ag–Ag bond length is 3.00 Å.
YbAg2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Yb is bonded in a distorted q6 geometry to ten equivalent Ag atoms. All Yb–Ag bond lengths are 3.09 Å. Ag is bonded in a 10-coordinate geometry to five equivalent Yb atoms.