Materials Data on Ag2Cl3 by Materials Project
Ag2Cl3 is Corundum structured and crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Ag+1.50+ is bonded to six equivalent Cl1- atoms to form a mixture of edge, corner, and face-sharing AgCl6 octahedra. The corner-sharing octahedra tilt angles range from 47–55°. There are three shorter (2.66 Å) and three longer (2.73 Å) Ag–Cl bond lengths. Cl1- is bonded to four equivalent Ag+1.50+ atoms to form a mixture of distorted edge and corner-sharing ClAg4 trigonal pyramids.
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