Materials Data on Ag2F3 by Materials Project
Ag2F3 is Corundum structured and crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Ag+1.50+ is bonded to six equivalent F1- atoms to form a mixture of edge, face, and corner-sharing AgF6 octahedra. The corner-sharing octahedra tilt angles range from 47–58°. There are three shorter (2.32 Å) and three longer (2.41 Å) Ag–F bond lengths. F1- is bonded to four equivalent Ag+1.50+ atoms to form a mixture of distorted edge and corner-sharing FAg4 trigonal pyramids.
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