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DOE OSTI2019

Materials Data on Ag2IO6 by Materials Project

Ag2O4IO2 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of one hydrogen peroxide molecule and one Ag2O4I sheet oriented in the (0, -1, 1) direction. In the Ag2O4I sheet, Ag is bonded in a square co-planar geometry to four O atoms. There are a spread of Ag–O bond distances ranging from 2.04–2.08 Å. There are two inequivalent O sites. In the first O site, O is bonded in a T-shaped geometry to three equivalent Ag atoms. In the second O site, O is bonded in a bent 120 degrees geometry to one Ag and one I atom. The O–I bond length is 2.05 Å. I is bonded in a linear geometry to two equivalent O atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Ag2IO6 by Materials Project

Ag2O6I crystallizes in the trigonal R-3 space group. The structure is two-dimensional and consists of three Ag2O6I sheets oriented in the (0, 0, 1) direction. Ag is bonded in a distorted trigonal planar geometry to three equivalent O atoms. All Ag–O bond lengths are 2.18 Å. O is bonded in a bent 120 degrees geometry to one Ag and one I atom. The O–I bond length is 1.89 Å. I is bonded in an octahedral geometry to six equivalent O atoms.

36 MATERIALS SCIENCE↗