Materials Data on AgH3CN2 by Materials Project
AgCN2H3 crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four AgCN2H3 clusters. Ag1+ is bonded in a linear geometry to one C2+ and one N3- atom. The Ag–C bond length is 2.03 Å. The Ag–N bond length is 2.14 Å. C2+ is bonded in a linear geometry to one Ag1+ and one N3- atom. The C–N bond length is 1.17 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a single-bond geometry to one C2+ atom. In the second N3- site, N3- is bonded in a distorted trigonal non-coplanar geometry to one Ag1+ and three H1+ atoms. There is two shorter (1.02 Å) and one longer (1.03 Å) N–H bond length. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom.