Materials Data on AgHPbC2SN2O by Materials Project
AgPbC2N2HSO crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Ag1+ is bonded to one C3+ and three equivalent S2- atoms to form distorted corner-sharing AgCS3 tetrahedra. The Ag–C bond length is 2.11 Å. There are two shorter (2.62 Å) and one longer (2.86 Å) Ag–S bond lengths. Pb2+ is bonded in a 6-coordinate geometry to three N3- and three equivalent O2- atoms. There are one shorter (2.65 Å) and two longer (3.01 Å) Pb–N bond lengths. There are one shorter (2.44 Å) and two longer (2.45 Å) Pb–O bond lengths. There are two inequivalent C3+ sites. In the first C3+ site, C3+ is bonded in a distorted linear geometry to one Ag1+ and one N3- atom. The C–N bond length is 1.18 Å. In the second C3+ site, C3+ is bonded in a distorted linear geometry to one N3- and one S2- atom. The C–N bond length is 1.18 Å. The C–S bond length is 1.65 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a single-bond geometry to two equivalent Pb2+ and one C3+ atom. In the second N3- site, N3- is bonded in a single-bond geometry to one Pb2+ and one C3+ atom. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. S2- is bonded to three equivalent Ag1+ and one C3+ atom to form corner-sharing SAg3C tetrahedra. O2- is bonded in a single-bond geometry to three equivalent Pb2+ and one H1+ atom.