Materials Data on AgIO4 by Materials Project
AgIO4 is Zircon-like structured and crystallizes in the tetragonal I4_1/a space group. The structure is three-dimensional. Ag3+ is bonded in a 8-coordinate geometry to eight equivalent O2- atoms. There are four shorter (2.59 Å) and four longer (2.62 Å) Ag–O bond lengths. O2- is bonded in a 3-coordinate geometry to two equivalent Ag3+ and one I5+ atom. The O–I bond length is 1.82 Å. I5+ is bonded in a tetrahedral geometry to four equivalent O2- atoms.
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