Materials Data on AgPF6 by Materials Project
AgPF6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Ag1+ is bonded to six equivalent F1- atoms to form AgF6 octahedra that share corners with six equivalent PF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Ag–F bond lengths are 2.49 Å. P5+ is bonded to six equivalent F1- atoms to form PF6 octahedra that share corners with six equivalent AgF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All P–F bond lengths are 1.64 Å. F1- is bonded in a distorted linear geometry to one Ag1+ and one P5+ atom.
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