Materials Data on AlH36C12S6(ClO2)3 by Materials Project
(CH3)24(Al(SO)6)2(Cl2)3 crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of nine hydrochloric acid molecules, thirty-six methane molecules, and three Al(SO)6 clusters. In each Al(SO)6 cluster, Al3+ is bonded in an octahedral geometry to six equivalent O2- atoms. All Al–O bond lengths are 1.92 Å. S2- is bonded in a distorted single-bond geometry to one O2- atom. The S–O bond length is 1.55 Å. O2- is bonded in a bent 120 degrees geometry to one Al3+ and one S2- atom.
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