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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

COMPUTATIONAL MODELING OF THE CLASS I LOW-MASS PROTOSTAR ELIAS 29 APPLYING OPTICAL CONSTANTS OF ICES PROCESSED BY HIGH ENERGY COSMIC RAY ANALOGS

We present a study of the effects of high energy cosmic rays (CRs) over the astrophysical ices, observed toward the embedded class I protostar Elias 29, by using computational modeling and laboratory data. Its spectrum was observed with the Infrared Space Observatory (ISO) covering 2.3–190 μm. The modeling employed the three-dimensional Monte Carlo radiative transfer code RADMC-3D and laboratory data of bombarded ice grains by CR analogs and unprocessed ices (not bombarded). We are assuming that Elias 29 has a self-irradiated disk with inclination i = 60.°0, surrounded by an envelope with a bipolar cavity. The results show that absorption features toward Elias 29 are better reproduced by assuming a combination between unprocessed astrophysical ices at low temperature (H{sub 2}O, CO, CO{sub 2}) and bombarded ices (H{sub 2}O:CO{sub 2}) by high energy CRs. Evidences of the ice processing around Elias 29 can be observed by the good fitting around 5.5–8.0 μm, by polar and apolar ice segregation in 15.15–15.25 μm, and by the presence of the CH{sub 4} and HCOOH ices. Given that non-nitrogen compounds were employed in this work, we assume that absorption around 5.5–8.0 μm should not be associated with the NH{sub 4}{sup +} ion (see the 2003 work of Shutte and Khanna ), but more probably with aliphatic ethers (e.g., R1-OCH{sub 2}-R2), CH{sub 3}CHO, and related species. The results obtained in this paper are important because they show that the environment around protostars is better modeled considering processed samples and, consequently, demonstrate the chemical evolution of the astrophysical ices.

79 ASTRONOMY AND ASTROPHYSICS↗

Applying Optical Diagnostics to Study Aircraft Gas Turbine Combustor Performance

This is for an invited lecture at Cleveland State University for a combustion course. The presentation gives an overview of some of the optical diagnostic techniques the Combustion Branch uses to characterize research fuel injection concepts to reduce emissions. Examples are provided that come from previously presented conference papers

Hicks, Yolanda R.↗

Velocity filtering applied to optical flow calculations

Optical flow is a method by which a stream of two-dimensional images obtained from a forward-looking passive sensor is used to map the three-dimensional volume in front of a moving vehicle. Passive ranging via optical flow is applied here to the helicopter obstacle-avoidance problem. Velocity filtering is used as a field-based method to determine range to all pixels in the initial image. The theoretical understanding and performance analysis of velocity filtering as applied to optical flow is expanded and experimental results are presented.

Barniv, Yair↗

Grain optical properties

The optical properties of small grains provide the link between the infrared observations presented in Chapter 1 and the dust composition described in Chapter 3. In this session, the optical properties were discussed from the viewpoint of modeling the emission from the dust coma and the scattering in order to draw inference about the dust size distribution and composition. The optical properties are applied to the analysis of the infrared data in several ways, and these different uses should be kept in mind when judging the validity of the methods for applying optical constants to real grains.

Hanner, Martha↗

Efficient and interpretable graph network representation for angle-dependent properties applied to optical spectroscopy

Abstract Graph neural networks are attractive for learning properties of atomic structures thanks to their intuitive graph encoding of atoms and bonds. However, conventional encoding does not include angular information, which is critical for describing atomic arrangements in disordered systems. In this work, we extend the recently proposed ALIGNN (Atomistic Line Graph Neural Network) encoding, which incorporates bond angles, to also include dihedral angles (ALIGNN-d). This simple extension leads to a memory-efficient graph representation that captures the complete geometry of atomic structures. ALIGNN-d is applied to predict the infrared optical response of dynamically disordered Cu(II) aqua complexes, leveraging the intrinsic interpretability to elucidate the relative contributions of individual structural components. Bond and dihedral angles are found to be critical contributors to the fine structure of the absorption response, with distortions that represent transitions between more common geometries exhibiting the strongest absorption intensity. Future directions for further development of ALIGNN-d are discussed.

36 MATERIALS SCIENCE↗

Device Applies Films to Optical Elements

Clamping device applies protective or antireflective dielectric coating to lenses or other optical elements. Alternative version of device applies thin sheet of dielectric film to ring or stretches it for clamping in holder to form pellicle or beam splitter. Defects avoided by new apparatus, which uniformly stretches dielectric films in radial direction and creates vacuum between them before thermally bonded to optical element.

Augason, Gordon C.↗

Applying Improved Optical Recognition with Machine Learning on Sorting Cu Impurities in Steel Scrap

Annually, 20–55 million tons of electronic waste (e-waste) is produced worldwide (5% of all municipal solid waste). Although e-waste embodies only 2% of America’s municipal waste, it accounts for a significantly larger proportion of the heavy metals and flame retardants present in the waste stream. Currently, less than 20% of all e-waste is recycled in the United States because the heterogeneity of the feedstock limits the opportunity for reuse in high value products and processing of the waste itself is often too costly to justify handling. To address this concern, the aims of this study are: 1) to identify the major plastic and metal compositions within electronic shredder residue (ESR), 2) to formulate solvents and processing conditions to separate 90% of the plastics targeted from consumer shred ESR, and 3) to develop a process design model to estimate the cost and energy efficiency of the proposed solvent-based processing. In this study, a pre-sorted heterogeneous ESR feedstock (one where aluminum, magnetic components, and hazardous battery materials removed by an e-waste recycling facility) was used, with the major compositions of the ESR characterized. It was found that 25 wt.% of the feedstock was composed of plastics, 6 wt.% rubber, 27 wt.% printed circuit boards, 23% wire, and the remainder metals and capacitors. Within the plastic portion, polystyrene (PS, 40 wt.%), acrylonitrile butadiene styrene (ABS, 25 wt.%), and styrene-acrylonitrile (SAN, 9wt.%) were identified to compose the majority of the screened plastics using Fourier transform infrared spectroscopy (FTIR). Next, selective solvents were screened using Hansen Solubility Parameter Theory (HSP) for dissolving PS and ABS. The pre-screening results show that methylene chloride (dichloromethane, DCM) and tetrahydrofuran (THF) are capable of dissolving the most PS and ABS, while methanol (MeOH) and ethylene glycol (EG) are capable of precipitating the most PS and ABS. These solvents were subsequently used to recover polymers and remove. flame retardants within the ESR feedstock. By optimizing the dissolution time and the solvents used, the highest polymer dissolution yield (99 wt.%%) was achieved using DCM for 48 hr. Both pre-screened anti-solvents (MeOH and EG) showed the highest polymer precipitation yield (71 wt.%). In terms of flame retardant removal rate, EG was found to have a high phosphorus-containing flame retardant removal rate (up to 98%). Characterization shows that the proposed solvent-based processing can preserve a high molecular weight fraction of the polymers and effectively remove flame retardants. Cost analysis indicates that the amount of the solvent/anti-solvent recovered after the reaction would play a critical role in reducing the operating costs. The energy analysis shows that the proposed solvent-based processes can save up to 60% of the embodied energy used to manufacture plastics used in electronics (PS and ABS were used for calculations). The results from this project prove the potential of solvent-based processing to produce secondary materials (plastics and metals) from e-waste for cross-industry reuse.

36 MATERIALS SCIENCE↗

Applied nonlinear optics in the journal 'Quantum Electronics'

A brief historical review of the experimental and theoretical works on nonlinear optical frequency conversion (generation of harmonics, up- and down-conversion, parametric oscillation), which have been published in the journal 'Quantum Electronics' for the last 40 years, is presented.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Applying Linear Optics from Closed Orbits Modulation for finding beam-based alignment of harmonic sextupoles

A fast and accurate beam-based alignment (BBA) method for harmonic sextupoles has been devel oped at NSLS-II using Linear Optics from Closed Orbit Modulation (LOCOM). The approach excites the beam with simultaneous sine-wave signals at two fast correctors, chosen with an appropriate phase advance to span the full betatron phase space. This strategy suppresses systematic errors from hysteresis, while additional errors from orbit drift and power-supply calibration are minimized by the short measurement time (a few minutes) and reliance solely on beam-based current-to-field conver sion of the sextupoles, with hysteresis explicitly included. Simulations indicate that Linear Optics from Closed Orbits (LOCO) combined with 0.5 mm local orbit bumps can resolve relative sextupole field offsets (∆k₂) with precision better than 10% of k₂, reflecting to beam-based alignment (BBA) accuracy finer than 50 µm. Moreover, employing machine-learning-optimized local orbit bumps en hances sextupole-induced quadrupole signals in a deterministic manner and maintains orbit stability under large sextupole strength variations (±40%). The proposed method is experimentally validated through proof-of-principle measurements at NSLS-II, demonstrating its potential as a fast, precise, and robust tool for harmonic sextupole alignment.

43 PARTICLE ACCELERATORS↗

Laser-electron beam interaction applied to optical amplifiers and oscillators

Momentum modulation of a relativistic electron beam by a Nd:YAG laser is demonstrated. The electrons, at 100 MeV energy, interact with the laser light in helium gas at standard temperature and pressure. At an angle of 6.55 mrad between the two wavevectors, corresponding to the Cerenkov angle, a given electron remains in a field of constant phase as it passes through the light beam. The experimental arrangement is illustrated showing the trajectories of the electron and light. The particle momentum is measured by a mass spectrometer, and the angle between the wavevectors is controlled by a rotatable mirror. Experimental results indicate that momentum modulation of an electron beam may be used for amplification. A possible configuration for an optical klystron is illustrated.

Pantell, R. H.↗

Directed assembly of hybrid nanostructures using optically resonant nanotweezers

This represents the final report for this project. Over the course of the project we have made significant progress in photonically driven nano-assembly including: (1) demonstrating the first direct optical tweezer based manipulation of proteins, (2) the ability to apply optical angular torques to microtubuals and other rod-shaped microparticles, (3) direct assembly of hybrid nanostructures comprising of polymeric nanoparticles and carbon nanotubes and, (4) the ability to drive biological reactions (specifically protein aggregation) that are thermodynamically unfavorable by applying localized optical work. These advancements are described in the list of papers provided in section 2.0 of the below. Summary details are provided in prior year annual reports. We have two additional papers which will be submitted shortly based on the work done under this award. An updated publication list will be provided to the program manager when those are accepted. In this report, we report on a new advancement made in the final project year, which uses the nanotweezer technology to perform direct measurements of particle-surface interactions. Briefly, these measurements are important for characterizing the stability and behavior of colloidal and nanoparticle suspensions and current techniques are limited in their ability to measure piconewton scale interaction forces on sub-micrometer particles due to signal detection limits and thermal noise. In this project year we developed a new technique called “Nanophotonic Force Microscopy” which uses the localized region of exponentially decaying, near-field, light to confine small particles close to a surface. From the statistical distribution of the light intensity scattered by the particle the technique maps out the potential well of the trap and directly quantify the repulsive force between the nanoparticle and the surface. The major advantage of the technique is that it can measure forces and energy wells below the thermal noise limit, resolving interaction forces smaller than 1 pN on dielectric particles as small as 100 nm in diameter.

36 MATERIALS SCIENCE↗

Diffraction Effects in a Grating Spectrometer

This paper describes a numerical study of diffraction effects in the AIRES optical system using GLAD by Applied Optics Research. AIRES (or Airborne Infrared Echelle Spectrometer) employs two gratings in series. The small, first-order (i.e., predisperser) grating sorts orders for the large, high-order echelle grating, thus providing moderately high spectral resolution over 3.6 octaves in wavelength. The AIRES' optical design includes three field stops (i.e., a circular aperture and two long, narrow slits) and four pupil stops. A detailed diffraction analysis is required to evaluate critical trade-offs between spectral resolution, optical throughput, detector background, scattered light, and system size and weight. Such an analysis must consider diffraction effects at the pupil stops (edge diffraction), at the field stops (spatial filtering), and at intermediate positions where other optical elements are located. The effects of slit width, slit length, oversizing of the second slit relative to the first, baffling at the Lyot stop and subsequent pupil stops, and the necessity for oversizing other optical elements are presented and discussed. It is found that for narrow slits, the downstream energy distribution is significantly broadened relative to that for large slits, where telescope diffraction dominates, leading to significantly more light loss than anticipated, unless other key optical elements are oversized. The importance of performing a proper diffraction analysis is emphasized and the suitability of GLAD for this task is discussed.

Haas, Michael R.↗

Development and Optical Testing of the Camera, Hand Lens, and Microscope Probe with Scannable Laser Spectroscopy (CHAMP-SLS)

Conducting high resolution field microscopy with coupled laser spectroscopy that can be used to selectively analyze the surface chemistry of individual pixels in a scene is an enabling capability for next generation robotic and manned spaceflight missions, civil, and military applications. In the laboratory, we use a range of imaging and surface preparation tools that provide us with in-focus images, context imaging for identifying features that we want to investigate at high magnification, and surface-optical coupling that allows us to apply optical spectroscopic analysis techniques for analyzing surface chemistry particularly at high magnifications. The camera, hand lens, and microscope probe with scannable laser spectroscopy (CHAMP-SLS) is an imaging/spectroscopy instrument capable of imaging continuously from infinity down to high resolution microscopy (resolution of approx. 1 micron/pixel in a final camera format), the closer CHAMP-SLS is placed to a feature, the higher the resultant magnification. At hand lens to microscopic magnifications, the imaged scene can be selectively interrogated with point spectroscopic techniques such as Raman spectroscopy, microscopic Laser Induced Breakdown Spectroscopy (micro-LIBS), laser ablation mass-spectrometry, Fluorescence spectroscopy, and/or Reflectance spectroscopy. This paper summarizes the optical design, development, and testing of the CHAMP-SLS optics.

Fluorescence↗

Synthetic Hyperspectral Data for Global Water Quality Algorithm Development

Eutrophication and increasing prevalence of potentially toxic algal blooms (cyanoHABs) among global inland water bodies have become a major ecological concern and require direct attention. There is now a growing necessity to develop pragmatic approaches that allow timely and effective extrapolation of local aquatic processes, to spatially resolved global products. Planned aquatic biogeochemistry remote sensing data products from hyperspectral imagers such as NASA’s Surface Biology and Geology (SBG) mission and relevant aquatic sensor sensitivity precursor airborne imaging spectrometer data provide unprecedented radiometric resolution and sensor sensitivity for characterizing complex aquatic ecosystems. However, scarcity of high-quality freshwater in-situ optical data hinders our capability to develop and validate robust retrieval algorithms. A state-of-the-art synthetic dataset of paired top-of-atmosphere, bottom-of-atmosphere, and optical and biogeophysical data was developed through radiative transfer modeling to simulate natural freshwater ecosystems. A synthetic or precursor dataset for SBG is being used to train robust machine learning models to derive water quality products pertinent to SBG mission objectives. The dataset is also used to show the potential of performing vigorous aquatic sensitivity studies and explored pathways for how best to optimize hyperspectral data for machine learning development. A processing pipeline and resultant global synthetic/precursor dataset for inland waters is presented to establish the innovation for water quality studies of inland waters globally. Optical Society of America Imaging and Applied Optics Congress, Hyperspectral Imaging and Sounding of the Environment (OSA HISE) Meeting, 19-23 July 2021, Virtual Meeting, https://www.osa.org/enus/meetings/osa_meetings/optical_sensors_and_sensing_congress/program/hyperspectral_imaging_and_sounding_of_the_environm/

Synthetic↗

Interference effects in laser-induced plasma emission from surface-bound metal micro-particles

Here, the light-matter interaction of an optical beam and metal micro-particulates at the vicinity of an optical substrate surface is critical to the many fields of applied optics. Examples of impacted fields are laser-induced damage in high power laser systems, sub-wavelength laser machining of transmissive materials, and laser-target interaction in directed energy applications. We present a full-wave-based model that predicts the laser-induced plasma pressure exerted on a substrate surface as a result of light absorption in surface-bound micron-scale metal particles. The model predictions agree with experimental observation of laser-induced shallow pits, formed by plasma emission and etching from surface-bound metal micro-particulates. It provides an explanation for the prototypical side lobes observed along the pit profile, as well as for the dependence of the pit shape on the incident laser and particle parameters. Furthermore, the model highlights the significance of the interference of the incident light in the open cavity geometry formed between the micro-particle and the substrate in the resulting pit shape.

42 ENGINEERING↗

SXI Prototype mirror mount

This final report describes the work performed from June 1993 to January 1995. The purpose of this contract was to provide optomechanical engineering and fabrication support to the Solar X-ray Imager (SXI) program in the areas of mirror, optical bench and camera assemblies of the telescope. The Center for Applied Optics (CAO) worked closely with the Optics and S&E technical staff of MSFC to develop and investigate the most viable and economical options for the design and fabrication of a number of parts for the various telescope assemblies. All the tasks under this delivery order have been successfully completed within budget and schedule.

Source record↗