Results for “As-Pd-Tl”

Materials Data on TlAsPd5 by Materials Project

Pd5TlAs crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. there are two inequivalent Pd sites. In the first Pd site, Pd is bonded in a distorted square co-planar geometry to four equivalent Tl atoms. All Pd–Tl bond lengths are 2.89 Å. In the second Pd site, Pd is bonded in a 4-coordinate geometry to two equivalent Tl and two equivalent As atoms. Both Pd–Tl bond lengths are 2.93 Å. Both Pd–As bond lengths are 2.52 Å. Tl is bonded to twelve Pd atoms to form a mixture of corner and face-sharing TlPd12 cuboctahedra. As is bonded in a body-centered cubic geometry to eight equivalent Pd atoms.