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Despite the computational efficiency of conventional normal mode techniques for the analysis of rotational-vibrational spectra, the overtone bands of small symmetrical hydrides have certain features that favour an alternative local mode interpretation.
The map of the coseismic displacement field generated by interferometric processing of synthetic aperture radar (SAR) images taken before and after the June 28, 1992, Landers earthquake sequence brings new insights into the nature of deformation caused by these earthquakes. We use the interferometric map generated by Massonnet et al. (1993) to analyze the surface displacement field in the vicinity of the fault trace. Complexities in the fringe pattern near the fault reflect short-wavelength variations of the surface rupture and slip distribution, and attest to large displacement gradients. Along two sections of the fault, characteristic fringe patterns can be recognized, contrasting in density and direction with patterns observed away from the rupture. In order to understand the observed fringe patterns, we compute synthetic interferograms in three simple cases: (1) rigid-body rotations about a vertical axis, (2) about a horizontal axis (tilt), and (3) distributed, simple shear. The orientation and spatial separation of interferometric fringes predicted by these models help constrain near-field deformation and rupture parameters. Where the Kickapoo fault connects with the Homestead Valley fault, the interferogram shows a clear pattern of parallel N20 deg W fringes separated by about 160 m. This pattern and vertical offsets measured along the Kickapoo fault suggest that the block between this fault and the Johnson Valley fault may have been tilted, down to the west. A 5-km block lifted by 1 m on one side would be tilted by an angle of 0.01 deg (190 microrad), producing fringes separated by about 160 m, parallel to the tilt axis. Such a tilt, parallel to a N20 deg W direction, would account for the gradual, northward increase of the vertical slip component observed along the Kickapoo fault. This tilt may also explain the 1 m of reverse slip observed along the 'slip gap' section of the Homestead Valley break. Between the southern end of the Johnson Valley fault and the Eureka Peak fault, where no surface rupture has been mapped, the dense pattern of fringes implies distributed shear, probably resulting from fault slip at depth. The density and direction of the fringes in the gap are consistent with a right-lateral slip of 1.2-3.8 m on a blind fault locked above the depth of 1.5-2 km. Such observations of small wavelength features in the SAR interferogram bring new insights into the near-field displacement gradient and thus on response of the uppermost crust to seismic rupture.
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Abstract Grain boundaries are critical in determining the properties of materials, including mechanical stability, conductivity, and corrosion resistance. The specific properties of materials depend not only on the misorientation of the crystals, the three most commonly characterized parameters, but also on the angle of the grain boundary plane between the two crystals, the final two parameters in the five-parameter macroscopic description of the grain boundary. The method presented here allows for the direct measurement of all five parameters of the grain boundary in a transmission electron microscopy specimen of various morphologies. This is especially applicable to atom probe specimens, where only a single-tilt axis is generally available, allowing the crystallographic description to be matched to the detailed chemical data available in the atom probe tomography. This method provides a platform for efficient grain boundary analysis in unique samples, saving operator time and allowing for ease of acquisition and interpretation in comparison with traditional electron diffraction methods.
The negative-parity band structure built on the proton h 9/2 state in 199 Tl has been established up to an excitation energy of 7 MeV and spin of (51/2) ℏ. The level scheme has been extended with the inclusion of fourteen new transitions de-exciting levels at high spin. The ΔI = 1 γ rays are found to be more prominently visible in the spectra when comparing to Δ I = 2 transitions. Rotation alignments are evident at frequencies of 0.22 and 0.30 MeV with both being attributed to the breaking of pairs of neutrons in the i 13/2 subshell. Since 199 Tl is expected to have weak oblate deformation, and lies in a transitional region where competing contributions to the spin are expected from collective rotation and the angular momentum of high-j nucleons, calculations using both the principal axis cranking (PAC) and tilted axis cranking (TAC) formalisms have been performed to understand its structure. Both the PAC and TAC calculations are found to provide a satisfactory description of the evolution of excitation energies with spin. The PAC calculations give a good account of the experimental crossing frequencies and associated spins. Furthermore, the structure of the yrast, negative-parity band in 199 Tl may be primarily understood in terms of the collective rotation of a moderately deformed oblate nucleus, along with contributions to the angular momentum from two pairs of rotation-aligned i 13/2 neutrons.
Several large (1500 kW) horizontal rotor configurations were analyzed to determine the effects on dynamic loads of upwind downwind rotor locations, coned and radial blade positions, and tilted and horizontal rotor axis positions. Loads were calculated for a range of wind velocities at three locations in the structure: (1) the blade shank; (2) the hub shaft; and (3) the yaw drive. Blade axis coning and rotor axis tilt were found to have minor effects on loads. However, locating the rotor upwind of the tower significantly reduced loads at all locations analyzed.
Three large (1500 kW) horizontal rotor configurations were analyzed to determine the effects on dynamic loads of upwind and downwind rotor locations, coned and radial blade positions, and tilted and horizontal rotor axis positions. Loads were calculated for a range of wind velocities at three locations in the structure: the blade shank, the hub shaft, and the yaw drive. Blade axis coning and rotor axis tilt were found to have little effect on loads. However, locating the rotor upwind of the tower significantly reduced loads at all locations analyzed.
Three-dimensional time-dependent convection in a plane layer of fluid, uniformly heated from below and subject to vertical shear and to rotation about an axis tilted from the vertical, was simulated by the numerical solution of the Boussinesq equations, including all Coriolis terms. Rotation about a vertical axis produces smaller convection cells with diminished heat fluxes and considerable vorticity. When the rotation axis is tilted from the vertical to represent tropical latitudes, the convection cells become elongated in a N-S direction. Imposed flows with constant vertical shear produce convective rolls aligned with the mean flow. When the rotation vector is tilted from the vertical, the competing effects due to rotation and shear can stabilize the convective motions.
Magnetic field data obtained by Mariner 10 during the third and final encounter with the planet Mercury on 16 March 1975 were studied. A well developed bow shock and modest magnetosphere, previously observed at first encounter on 29 March 1974, were again observed. In addition, a much stronger magnetic field near closest approach, 400 gamma versus 98 gamma, was observed at an altitude of 327 km and approximately 70 deg north Mercurian latitude. Spherical harmonic analysis of the data provide an estimate of the centered planetary magnetic dipole of 4.7 x 10 to the 22nd power Gauss/cu cm with the axis tilted 12 deg to the rotation axis and in the same sense as Earth's. The interplanetary field was sufficiently different between first and third encounters that in addition to the very large field magnitude observed, it argues strongly against a complex induction process generating the observed planetary field. While a possibility exists that Mercury possesses a remanent field due to magnetization early in its formation, a present day active dynamo seems to be a more likely candidate for its origin.
The high-field magnetic properties and magnetic order of the gem mineral green dioptase Cu 6 [Si 6 O 18 ] .6 H 2 O have been studied by means of single-crystal neutron diffraction in magnetic fields up to 21 T and magnetization measurements up to 30 T. In zero field, the Cu 2+ moments in the antiferromagnetic chains are oriented along the c axis with a small off-axis tilt. For a field applied parallel to the c axis, the magnetization shows a spin-flop-like transition at B*=12.2 T at 1.5 K. Neutron diffraction experiments show a smooth behavior in the intensities of the magnetic reflections without any change in the periodicity of the magnetic structure. Bulk and microscopic observations are well described by a model of ferromagnetically coupled antiferromagnetic X X Z spin-$\frac{1}{2}$ chains, taking into account a change of the local easy-axis direction. We demonstrate that the magnetic structure evolves smoothly from a deformed Néel state at low fields to a deformed spin-flop state in a high field via a strong crossover around B*. The results are generalized for different values of interchain coupling and spin anisotropy.
It is well established that the head and eye velocity axes do not always align during compensatory vestibular slow phases. It has been shown that the eye velocity axis systematically tilts away from the head velocity axis in a manner that is dependent on eye-in-head position. The mechanisms responsible for producing these axis tilts are unclear. In this model-based study, we aimed to determine whether muscle pulleys could be involved in bringing about these phenomena. The model presented incorporates semicircular canals, central vestibular pathways, and an ocular motor plant with pulleys. The pulleys were modeled so that they brought about a rotation of the torque axes of the extraocular muscles that was a fraction of the angle of eye deviation from primary position. The degree to which the pulleys rotated the torque axes was altered by means of a pulley coefficient. Model input was head velocity and initial eye position data from passive and active yaw head impulses with fixation at 0 degrees, 20 degrees up and 20 degrees down, obtained from a previous experiment. The optimal pulley coefficient required to fit the data was determined by calculating the mean square error between data and model predictions of torsional eye velocity. For active head impulses, the optimal pulley coefficient varied considerably between subjects. The median optimal pulley coefficient was found to be 0.5, the pulley coefficient required for producing saccades that perfectly obey Listing's law when using a two-dimensional saccadic pulse signal. The model predicted the direction of the axis tilts observed in response to passive head impulses from 50 ms after onset. During passive head impulses, the median optimal pulley coefficient was found to be 0.21, when roll gain was fixed at 0.7. The model did not accurately predict the alignment of the eye and head velocity axes that was observed early in the response to passive head impulses. We found that this alignment could be well predicted if the roll gain of the angular vestibuloocular reflex was modified during the initial period of the response, while pulley coefficient was maintained at 0.5. Hence a roll gain modification allows stabilization of the retinal image without requiring a change in the pulley effect. Our results therefore indicate that the eye position-dependent velocity axis tilts could arise due to the effects of the pulleys and that a roll gain modification in the central vestibular structures may be responsible for countering the pulley effect.
Motion sickness susceptibility of four normal subjects was measured in terms of duration of exposure necessary to evoke moderate malaise (MIIA) as a function of velocity in a chair rotated about a central axis tilted 10 deg with respect to gravitational upright. The subjects had little or no susceptibility to this type of rotation at 2.5 and 5.0 rpm, but with further increases in rate, the MIIA endpoint was always reached and with ever shorter test durations. Minimal provocative periods for all subjects were found at 15 or 20 rpm. Higher rotational rates dramatically reversed the vestibular stressor effect, and the subjects as a group tended to reach a plateau of relatively low susceptibility at 40 and 45 rpm. At these higher velocities, furthermore, the subjects essentially lost their sensation of being tilted off vertical. In the second half of the study, the effect of tilt angle was varied while the rotation rate was maintained at a constant 17.5 rpm. Two subjects were completely resistant to symptoms of motion sickness when rotated at 2.5 deg off vertical; with greater off-vertical angles, the susceptibility of all subjects increased sharply at first, then tapered off in a manner reflecting a Fechnerian function.
A brief description for a proposed new pointing mechanism which requires no mechanical gimbals, is virtually friction free, and is vibration isolated from a ground support system or vehicle is presented. The device uses electromagnetic forces for support levitation and pointing, both being accomplished from a ground reference thereby leaving the payload virtually free from a remotely located command center. Solid pointing angles of almost 2(pi) steradians are achievable, limited only by structural interference. A third degree-of-freedom tilt axis can be added at will, but will not be elaborated. Although the system is primarily intended for space vehicles in a micro-gravity environment, earth-ground support is possible with superconducting electromagnets.
Néel-type magnetic skyrmions in multilayers are promising candidates for ultra-low power spintronic devices. To image the Néel-type skyrmions using Lorentz transmission electron microscopy (L-TEM), the samples must be tilted. Thus, the external magnetic field consists of both in-plane and out-of-plane components. To date, it is still not well known on the effect of the in-plane magnetic field on the L-TEM images, leading to ambiguities in retrieving the structure of Néel-type skyrmions. Here, Néel-type skyrmions in three [Pt/Co/Ta]$_{20}$ multilayer samples, with the easy magnetization axis being tuned from the out-of-plane to the in-plane direction by increasing the Co thickness from 1.8 to 2.2 nm, are imaged. When using a smaller defocus value (-2 mm) and a higher magnification (×9100) of L-TEM, a surprising dark-bright-dark-bright double contrasted pattern, instead of the previously reported dark-bright contrasted pattern, is observed. The additional dark-bright contrasted pattern becomes more evident for thicker Co layer samples in which the magnetization axis tilts more toward the in-plane direction. Further analysis, via a combination of magnetic force microscopy experiments, micromagnetic simulations, and micromagnetic analysis to Lorentz TEM simulation, shows that the additional dark-bright features originate from the deformation of the Néel-type skyrmions within an in-plane magnetic field.
Solid-state batteries featuring fast ion-conducting solid electrolytes are promising next-generation energy storage technologies, yet challenges remain for practical deployment due to electro-chemo-mechanical instabilities at solid-solid interfaces. These interfaces, which include homogeneous/internal interfaces such as grain boundaries (GBs) and heterogeneous/external interfaces between solid-electrolyte and electrode materials, can impede Li-ion transport, deteriorate performance, and eventually lead to cell failure. Here, in this study, we leverage large-scale molecular simulations, enabled by validated machine-learning interatomic potentials, to directly probe the onset of interfacial degradation at the garnet Li 7 La 3 Zr 2 O 12 (LLZO) solid-electrolyte/LiCoO 2 (LCO) cathode interface. By surveying different interfacial geometries and compositions, it is found that Li-deficient interfaces can lead to severe interfacial disordering with cation mixing and Co interdiffusion from LCO into LLZO. By contrast, Li-sufficient interfaces are less disordered, although elemental segregation with local ordering is observed. As a consequence of Co interdiffusion, Co-rich regions are formed at the GBs of LLZO due to cation segregation and trapping effects. This behavior is independent of the GB tilting axis, degree of disorder at the GBs, and Co concentration, which implies Co clustering at GBs is a general phenomenon in polycrystalline LLZO and can dictate its overall transport and mechanical properties. Our findings elucidate the underlying fundamental mechanisms that give rise to experimentally observed physicochemical properties and provide guidelines for interface design that can mitigate interfacial degradation and improve cycling performance.
We introduce a novel composite holey gold support that prevents cryo-crinkling and reduces beam-induced motion of soft specimens, building on the previously introduced all-gold support. The composite holey gold support for high-resolution cryogenic electron microscopy of soft crystalline membranes was fabricated in two steps. In the first step, a holey gold film was transferred on top of a molybdenum grid. In the second step, a continuous thin carbon film was transferred onto the holey gold film. This support (Au/Mo grid) was used to image crystalline synthetic polymer membranes. The low thermal expansion of Mo is not only expected to avoid cryo-crinkling of the membrane when the grids are cooled to cryogenic temperatures, but it may also act to reduce whatever crinkling existed even before cooling. Here, the Au/Mo grid exhibits excellent performance with specimens tilted to 45°. This is demonstrated by quantifying beam-induced motion and differences in local defocus values. In addition, images of specimens on the Au/Mo grids that are tilted at 45° show high-resolution information of the crystalline membranes that, after lattice-unbending, extends beyond 1.5 Å in the direction perpendicular to the tilt axis.
The lifetime of the 2 + and 9 – , 11 – , 13 – , 15 – states in the neutron-deficient 110 Te was measured for the first time using the recoil distance Doppler shift technique. The reported value of the reduced transition probability B(E2; $0$$^{+}_{g.s}$ → 2 + ) = 4.3(8) × 10 3 e 2 fm 4 supports the systematic for even-mass Te isotopes and was interpreted in the framework of the large-scale shell model and cranked shell model calculations. The measured reduced transition probabilities in the negative-parity yrast band revealed the upward trend towards the high spins. Furthermore, the enhanced collectivity is discussed in terms of the tilted axis cranking approach and the symmetry configuration mixing method with the Gogny D1S interaction.
Short segments of RNA displace one strand of a DNA duplex during diverse processes including transcription and CRISPR-mediated immunity and genome editing. These strand exchange events involve the intersection of two geometrically distinct helix types—an RNA:DNA hybrid (A-form) and a DNA:DNA homoduplex (B-form). Although previous evidence suggests that these two helices can stack on each other, it is unknown what local geometric adjustments could enable A-on-B stacking. Here we report the X-ray crystal structure of an RNA-5′/DNA-3′ strand exchange junction at an anisotropic resolution of 1.6 to 2.2 Å. The structure reveals that the A-to-B helical transition involves a combination of helical axis misalignment, helical axis tilting and compression of the DNA strand within the RNA:DNA helix, where nucleotides exhibit a mixture of A- and B-form geometry. These structural principles explain previous observations of conformational stability in RNA/DNA exchange junctions, enabling a nucleic acid architecture that is repeatedly populated during biological strand exchange events.