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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Stellar reddening map from DESI imaging and spectroscopy

We present new Galactic reddening maps of the high Galactic latitude sky using DESI imaging and spectroscopy. We directly measure the reddening of 2.6 million stars by comparing the observed stellar colors in $g-r$ and $r-z$ from DESI imaging with the synthetic colors derived from DESI spectra from the first two years of the survey. The reddening in the two colors is on average consistent with the Fitzpatrick (1999) extinction curve with $R_\mathrm{V}=3.1$ . We find that our reddening maps differ significantly from the commonly used Schlegel et al. (1998) (SFD) reddening map (by up to 80 mmag in $E(B-V)$ ), and we attribute most of this difference to systematic errors in the SFD map. To validate the reddening map, we select a galaxy sample with extinction correction based on our reddening map, and this yields significantly better uniformity than the SFD extinction correction. Finally, we discuss the potential systematic errors in the DESI reddening measurements, including the photometric calibration errors that are the limiting factor on our accuracy. The $E(g-r)$ and $E(r-z)$ maps presented in this work, and for convenience their corresponding $E(B-V)$ maps with SFD calibration, are publicly available.

79 ASTRONOMY AND ASTROPHYSICS↗

DESI Mg II Absorbers: Extinction Characteristics and Quasar Redshift Accuracy

In this paper, we study how absorption-line systems affect the spectra and redshifts of quasi-stellar objects (QSOs), using catalogs of Mg II absorbers from the early data release and first data release of the Dark Energy Spectroscopic Instrument. We determine the reddening effect of an absorption system by fitting an unreddened template spectrum to a sample of 50,674 QSO spectra that contain Mg II absorbers. We find that reddening caused by intervening absorbers (v off > 3500 km s −1 ) has an average color excess of $\overline{E(B-V)}$ = 0.04 mag. We find that the E(B − V) tends to be greater for absorbers at low redshifts, or those having Mg II absorption lines with higher equivalent widths, but shows no clear trend with v off for intervening systems. However, the $\overline{E(B-V)}$ of associated absorbers, those at v off < 3500 km s −1 , shows a strong trend with v off , increasing rapidly with decreasing v off and peaking (∼0.15 mag) around v off = 0 km s −1 . We demonstrate that Mg II absorbers impact redshift estimation for QSOs by investigating the distributions of v off for associated absorbers. We find that at z > 1.5, these distributions broaden and bifurcate in a nonphysical manner. In an effort to mitigate this effect, we mask pixels associated with the Mg II absorption lines and recalculate the QSO redshifts. We find that we can recover voff populations in better agreement with those for z < 1.5 absorbers and in doing so typically shift background QSO redshifts by Δz ≈ ± 0.005.

79 ASTRONOMY AND ASTROPHYSICS↗

Materials Data on VB2 by Materials Project

VB2 is hexagonal omega structure structured and crystallizes in the hexagonal P6/mmm space group. The structure is three-dimensional. V is bonded to twelve equivalent B atoms to form a mixture of face and edge-sharing VB12 cuboctahedra. All V–B bond lengths are 2.30 Å. B is bonded in a 9-coordinate geometry to six equivalent V and three equivalent B atoms. All B–B bond lengths are 1.73 Å.

36 MATERIALS SCIENCE↗

Materials Data on V3B2 by Materials Project

V3B2 crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional. there are two inequivalent V2+ sites. In the first V2+ site, V2+ is bonded in a square co-planar geometry to four equivalent B3- atoms. All V–B bond lengths are 2.32 Å. In the second V2+ site, V2+ is bonded in a distorted hexagonal planar geometry to six equivalent B3- atoms. There are four shorter (2.27 Å) and two longer (2.28 Å) V–B bond lengths. B3- is bonded in a 9-coordinate geometry to eight V2+ and one B3- atom. The B–B bond length is 1.79 Å.

36 MATERIALS SCIENCE↗

Materials Data on V3B4 by Materials Project

V3B4 crystallizes in the orthorhombic Immm space group. The structure is three-dimensional. there are two inequivalent V2+ sites. In the first V2+ site, V2+ is bonded to twelve B+1.50- atoms to form a mixture of edge and face-sharing VB12 cuboctahedra. There are eight shorter (2.30 Å) and four longer (2.36 Å) V–B bond lengths. In the second V2+ site, V2+ is bonded in a 7-coordinate geometry to seven B+1.50- atoms. There are a spread of V–B bond distances ranging from 2.22–2.33 Å. There are two inequivalent B+1.50- sites. In the first B+1.50- site, B+1.50- is bonded in a 9-coordinate geometry to seven V2+ and two equivalent B+1.50- atoms. Both B–B bond lengths are 1.76 Å. In the second B+1.50- site, B+1.50- is bonded in a 9-coordinate geometry to six V2+ and three B+1.50- atoms. The B–B bond length is 1.73 Å.

36 MATERIALS SCIENCE↗

Materials Data on V2B3 by Materials Project

V2B3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. there are two inequivalent V+4.50+ sites. In the first V+4.50+ site, V+4.50+ is bonded to twelve B3- atoms to form a mixture of edge and face-sharing VB12 cuboctahedra. There are a spread of V–B bond distances ranging from 2.30–2.36 Å. In the second V+4.50+ site, V+4.50+ is bonded in a 7-coordinate geometry to seven B3- atoms. There are a spread of V–B bond distances ranging from 2.21–2.32 Å. There are three inequivalent B3- sites. In the first B3- site, B3- is bonded in a 9-coordinate geometry to six equivalent V+4.50+ and three B3- atoms. There is two shorter (1.72 Å) and one longer (1.73 Å) B–B bond length. In the second B3- site, B3- is bonded in a 9-coordinate geometry to six V+4.50+ and three B3- atoms. Both B–B bond lengths are 1.76 Å. In the third B3- site, B3- is bonded in a 9-coordinate geometry to seven V+4.50+ and two equivalent B3- atoms.

36 MATERIALS SCIENCE↗

Materials Data on VB by Materials Project

VB1 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. V3+ is bonded in a 7-coordinate geometry to seven equivalent B3- atoms. There are a spread of V–B bond distances ranging from 2.24–2.33 Å. B3- is bonded in a 9-coordinate geometry to seven equivalent V3+ and two equivalent B3- atoms. Both B–B bond lengths are 1.79 Å.

36 MATERIALS SCIENCE↗