Materials Data on B13P by Materials Project
(B)9B4P crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of twenty-seven boron molecules and three B4P clusters. In each B4P cluster, there are two inequivalent B+0.23+ sites. In the first B+0.23+ site, B+0.23+ is bonded in a single-bond geometry to one P3- atom. The B–P bond length is 1.89 Å. In the second B+0.23+ site, B+0.23+ is bonded in a single-bond geometry to one P3- atom. The B–P bond length is 1.98 Å. P3- is bonded in a tetrahedral geometry to four B+0.23+ atoms.
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