Materials Data on Bi2OF2 by Materials Project
Bi2OF2 crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one Bi2OF2 cluster. Bi2+ is bonded in a linear geometry to one O2- and one F1- atom. The Bi–O bond length is 2.16 Å. The Bi–F bond length is 2.09 Å. O2- is bonded in a linear geometry to two equivalent Bi2+ atoms. F1- is bonded in a single-bond geometry to one Bi2+ atom.
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