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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on Bi2PdO4 by Materials Project

PdBi2O4 crystallizes in the tetragonal P4/ncc space group. The structure is three-dimensional. Pd2+ is bonded in a rectangular see-saw-like geometry to four equivalent O2- atoms. All Pd–O bond lengths are 2.05 Å. Bi3+ is bonded to six equivalent O2- atoms to form a mixture of distorted edge and corner-sharing BiO6 pentagonal pyramids. There are a spread of Bi–O bond distances ranging from 2.21–2.74 Å. O2- is bonded in a 4-coordinate geometry to one Pd2+ and three equivalent Bi3+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Bi2PdO4 by Materials Project

PdBi2O4 crystallizes in the tetragonal I4cm space group. The structure is three-dimensional. Pd2+ is bonded in a rectangular see-saw-like geometry to four equivalent O2- atoms. All Pd–O bond lengths are 2.04 Å. Bi3+ is bonded in a 4-coordinate geometry to four equivalent O2- atoms. There are two shorter (2.24 Å) and two longer (2.26 Å) Bi–O bond lengths. O2- is bonded in a 3-coordinate geometry to one Pd2+ and two equivalent Bi3+ atoms.

36 MATERIALS SCIENCE↗