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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

Transferring Heat In Conjugating Binary Liquids

Conjugating binary liquids proposed for use as phase-change heat-transfer fluids. Phase diagrams illustrate more common types of mixing and separation of conjugating binary liquids.

Grodzka, P. G.↗
NASA NTRS1982

Measuring Interdiffusion in Binary Liquids

Liquid-phase binary interdiffusion sample is prepared by enclosing wires of two metals in a capillary tube with ends touching. While sample is at elevated temperature, tube is kept oriented with lighter metal at top to prevent convection. New method is potential research tool in such areas as zone refining of metals, recycling of spent fuel rods, and improving removal of slag and inclusions from steel castings.

Gelles, S. H.↗
NASA NTRS1985

The liquid-vapor interface of a binary liquid mixture near the consolute point

The present investigation is concerned with measurements of the reflectance of polarized light by the liquid-vapor interface above liquid mixtures of a fluorocarbon and an alcohol in the vicinity of the consolute point of the liquid mixture. The denser fluorocarbon is preferentially adsorbed at the interface. The denser fluorocarbon is preferentially adsorbed at the interface. The data are consistent with a simple model of the dielectric constant vs height profile in the interface region. Liquid mixtures of isopropanol (i-C3H7OH) and perfluoromethylcyclohexane (C7F14) near their consolute point (Tc = 363 K) are utilized in the conducted experiments. The primary quantity measured is the ellipticity as a function of temperature and liquid composition. Attention is given to details regarding the experimental techniques, model dielectric constant profiles, and the calculation of the ellipticity.

Schmidt, J. W.↗
NASA NTRS1986

Universal amplitude ratios and the interfacial tension near consolute points of binary liquid mixtures

The interfacial tension of the binary liquid mixtures triethylamine/heavy water, triethylamine/water, and cyclohexane/methanol near their consolute temperatures is determined experimentally by measuring the densities of the phases and the capillary lengths. The results are presented in tables and graphs and compared with published data obtained by other methods and with theoretical predictions. The findings are shown to be in good agreement with previous experiments, confirming the discrepancy between temperature-independent universal amplitude ratios calculated from such data and those predicted by renormalization-group calculations or Monte Carlo simulations of Ising models.

Moldover, M. R.↗
NASA NTRS1972

Transport properties of gases and binary liquids near the critical point

A status report is presented on the anomalies observed in the behavior of transport properties near the critical point of gases and binary liquids. The shear viscosity exhibits a weak singularity near the critical point. An analysis is made of the experimental data for those transport properties, thermal conductivity and thermal diffusivity near the gas-liquid critical point and binary diffusion coefficient near the critical mixing point, that determine the critical slowing down of the thermodynamic fluctuations in the order parameter. The asymptotic behavior of the thermal conductivity appears to be closely related to the asymptotic behavior of the correlation length. The experimental data for the thermal conductivity and diffusivity are shown to be in substantial agreement with current theoretical predictions.

Sengers, J. V.↗
NASA NTRS1993

Evaporation Of Clustered Drops Of Binary-Liquid Fuels

Report repeats and elaborates upon information presented in "Diffusion Of Mass In Evaporating Multicomponent Drops" (NPO-18206). Presents details of mathematical model of evaporation of binary liquid from both dense and dilute clusters of drops. Interactions among evaporation, diffusion in liquids, slip velocity, and other phenomena modeled.

Bellan, Josette↗
NASA NTRS1988

Critical exponent for the viscosity of four binary liquids

The viscosity of the following binary mixtures was measured near their consolute points: (1) methanol + cyclohexane, (2) isobutyric acid + water, (3) nitroethane + 3-methylpentane, and (4) 2-butoxyethanol + water. It is shown that the multiplicative hypothesis is valid for these mixtures. It is also found that the concentration closest to critical has the largest viscosity enhancement.

Berg, Robert F.↗
NASA NTRS1999

Effects of g-Jitter on Diffusion in Binary Liquids

The microgravity environment offers the potential to measure the binary diffusion coefficients in liquids without the masking effects introduced by buoyancy-induced flows due to Earth s gravity. However, the background g-jitter (vibrations from the shuttle, onboard machinery, and crew) normally encountered in many shuttle experiments may alter the benefits of the microgravity environment and introduce vibrations that could offset its intrinsic advantages. An experiment during STS-85 (August 1997) used the Microgravity Vibration Isolation Mount (MIM) to isolate and introduce controlled vibrations to two miscible liquids inside a cavity to study the effects of g-jitter on liquid diffusion. Diffusion in a nonhomogeneous liquid system is caused by a nonequilibrium condition that results in the transport of mass (dispersion of the different kinds of liquid molecules) to approach equilibrium. The dynamic state of the system tends toward equilibrium such that the system becomes homogeneous. An everyday example is the mixing of cream and coffee (a nonhomogeneous system) via stirring. The cream diffuses into the coffee, thus forming a homogeneous system. At equilibrium the system is said to be mixed. However, during stirring, simple observations show complex flow field dynamics-stretching and folding of material interfaces, thinning of striation thickness, self-similar patterns, and so on. This example illustrates that, even though mixing occurs via mass diffusion, stirring to enhance transport plays a major role. Stirring can be induced either by mechanical means (spoon or plastic stirrer) or via buoyancy-induced forces caused by Earth s gravity. Accurate measurements of binary diffusion coefficients are often inhibited by buoyancy-induced flows. The microgravity environment minimizes the effect of buoyancy-induced flows and allows the true diffusion limit to be achieved. One goal of this experiment was to show that the microgravity environment suppresses buoyancy-induced convection, thereby mass diffusion becomes the dominant mechanism for transport. Since g-jitter transmitted by the shuttle to the experiment can potentially excite buoyancy-induced flows, we also studied the effects of controlled vibrations on the system.

Duval, Walter M. B.↗
NASA NTRS1986

An exact solution for the solidification of a liquid slab of binary mixture

The time dependent temperature and concentration profiles of a one dimensional finite slab of a binary liquid alloy is investigated during solidification. The governing equations are reduced to a set of coupled, nonlinear initial value problems using the method outlined by Meyer. Two methods will be used to solve these equations. The first method uses a Runge-Kutta-Fehlberg integrator to solve the equations numerically. The second method comprises of finding closed form solutions of the equations.

Antar, B. N.↗
NASA NTRS1990

Critical exponent for viscosity

The critical exponent y characterizing the divergence of the viscosity for carbon dioxide and xenon has been measured. The values of y for both fluids fall within the range y = 0.041 + or - 0.001 and are consistent with the range y = 0.042 + or - 0.002 spanned by earlier data for four binary liquid mixtures. This agreement is the strongest evidence that pure fluids and binary liquids are in the same dynamic universality class; however, the results for y are inconsistent with the recent theoretical value of 0.032.

Berg, Robert F.↗
NASA NTRS1990

Critical exponent for the viscosity of carbon dioxide and xenon

The viscosities of carbon dioxide and xenon have been measured near their critical points and the critical exponent y characterizing the asymptotic divergence has been determined. Both fluids yielded exponents in the range y = 0.041 + or - 0.001 and thus also fell in the range y = 0.042 + or - 0.002 from an earlier study of four binary liquids. This agreement between experiments is the first evidence that pure fluids and binary liquids are in the same dynamic universality class. A recent theoretical value for y is 0.032. The 30 percent discrepancy is much greater than the combined errors from experiment and theory. The torsion oscillator viscometer operated at low frequency and low shear rate to avoid systematic errors caused by critical slowing down. Far from T(c) the analysis accounted for the crossover from critical to noncritical temperature dependence, where the latter was obtained from previously published correlations. Corrections for gravitational stratification were included close to T(c).

Berg, R. F.↗