Materials Data on RhBr3 by Materials Project
RhBr3 is Aluminum trichloride structured and crystallizes in the monoclinic C2/m space group. The structure is two-dimensional and consists of one RhBr3 sheet oriented in the (0, 0, 1) direction. Rh3+ is bonded to six Br1- atoms to form edge-sharing RhBr6 octahedra. All Rh–Br bond lengths are 2.51 Å. There are two inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in an L-shaped geometry to two equivalent Rh3+ atoms. In the second Br1- site, Br1- is bonded in an L-shaped geometry to two equivalent Rh3+ atoms.
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