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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Investigation of the Pressure-Loss Characteristics of the Westinghouse X24-C-2 Inlet Screen, TED No. NACA 0447

At the request of the Bureau of Aeronautics, Navy Department, investigations of the static-pressure losses and total-head distributions of the Westinghouse X24-C-2 inlet screen were made in the induction aerodynamics laboratory at Langley. The screen was investigated in two configurations, both before and after rounding the leading edges of the vanes. Investigations were conducted through air flows up to about pounds per second. The results of the investigations indicate that maximum lift coefficients of 1.36, 1.71 and 2.11 were measured on the model with flaps neutral and deflected 20 deg. and 55 deg, respectively, at a reynolds number of 8,600,000. When the duct inlet was replaced by a basic airfoil nose the flap neutral maximum lift coefficient was increased from 1.36 to 1.41. The results also showed that at maximum lift with flaps neutral or deflected 55 deg most of the area between the nacelles was stalled while only small areas on other portions of the model were stalled; when the duct inlet was replaced by the basic airfoil nose the stall was delayed to a slightly higher angle of attack but the nature of the stall was relatively unaffected.

Lankford, John L.↗

Boundary lubrication of formulated C-ethers in air to 300 C. 2: Organic acid additives

Friction and wear measurements were made on CVM M-50 steel lubricated with three C-ether (modified polyphenyl ether) formulations in dry and moist air. Results were compared to those obtained with a formulated Type 2 ester and the C-ether base fluid. A ball-on-disk sliding friction apparatus was used. Experimental conditions were a 1-kilogram load, a 17-meter/minute surface speed, and a 25 to 300 C (77 to 572 F) disk temperature range. The three C-ether formulations yielded better boundary lubricating characteristics than the Type 2 ester under most test conditions. All C-ether formulations exhibited higher friction coefficients than the ester from 150 to 300 C (302 to 572 F) and similar or lower values from 25 to 150 C (77 to 302 F).

Jones, W. R., Jr.↗

Evaluation of Low-Energy Hydrogen Separation Method Using Metal-Organic Frameworks (MOFs) for Closed-Loop ECLSS Air Revitalization (CLEAR)

The State-of-the-Art (SOA) air revitalization architecture onboard the International Space Station (ISS) recovered approximately 50% of the oxygen (O 2 ) from metabolic carbon dioxide (CO 2 ) via the Sabatier process from 2011 to 2017. O 2 recovery is currently constrained by the limited availability of reactant hydrogen (H 2 ) preventing complete conversion of CO 2 to H 2 O. Increasing O 2 recovery within Closed-Loop ECLSS is essential to reducing resupply mass for long-duration manned missions; specifically focusing on water (H 2 O) which supplies H 2 for Sabatier via water electrolysis. Past ground test endeavors at Marshall Space Flight Center (MSFC) have attempted to recover H 2 from Sabatier-produced CH 4 using technologies such as carbon vapor deposition (CVD) and plasma pyrolysis. The byproducts of these technologies can act as a catalyst poison or reactor deadload to the Sabatier reactor. Hydrogen separation techniques must be utilized to maintain the Sabatier catalyst during gas recycling and must be scalable, non-energy intensive, and safe to operate in a habitation setting. Research indicated that metal-organic frameworks (MOFs) could meet these criteria and were tested for their capability to capture the various carbon-based gaseous products of CVD and plasma pyrolysis such as acetylene (C 2 H 2 ), ethylene (C 2 H 4 ), ethane (C 2 H 6 ), and carbon monoxide (CO) which would purify the hydrogen gas stream passing through the MOF. A sub-scale adsorption column was developed by Marshall Space Flight Center to test three MOF candidates against a synthetic gas mixture comprised of process-relevant carbonous gases and hydrogen to evaluate the separation capability of the MOFs. The results of the hydrogen separation capability, isothermal desorption capability, and demonstrated cyclic reuse of the MOF are presented in this paper.

Kagen Crawford↗

Lifetimes for OH and OD electronic states with resonance transitions in the region between 1700 and 1950 A

The upper states of the OH and OD bands in the region between 1700 and 1950 A have been studied with a phase-shift radiative lifetime apparatus. Lifetimes varying from 1.8 to 2.9 ns have been found. Lifetimes for OH and OD are essentially the same, indicating that the upper states are likely to be depopulated via purely radiative processes under the present experimental conditions. Lifetimes have also been obtained for the C(2)Sigma(+) - A(2)Sigma(+) transition in OH and OD. These results are consistent with the preliminary analysis of Pryce (private communication) that the bands between 1700 and 1950 A in OH are partly due to the C(2)Sigma(+) - X(2)Pi sub i transition.

Smith, W. H.↗

Tungsten wire-nickel base alloy composite development

Further development and evaluation of refractory wire reinforced nickel-base alloy composites is described. Emphasis was placed on evaluating thermal fatigue resistance as a function of matrix alloy composition, fabrication variables and reinforcement level and distribution. Tests for up to 1,000 cycles were performed and the best system identified in this current work was 50v/o W/NiCrAlY. Improved resistance to thermal fatigue damage would be anticipated for specimens fabricated via optimized processing schedules. Other properties investigated included 1,093 C (2,000 F) stress rupture strength, impact resistance and static air oxidation. A composite consisting of 30v/o W-Hf-C alloy fibers in a NiCrAlY alloy matrix was shown to have a 100-hour stress rupture strength at 1,093 C (2,000 F) of 365 MN/square meters (53 ksi) or a specific strength advantage of about 3:1 over typical D.S. eutectics.

Brentnall, W. D.↗

Internal low Reynolds number turbulent heat transfer

The results of a semi-analytical and experimental study of adiabatic tube flow and an analytical and experimental investigation of the thermal entrance region for gas flowing through electrically heated circular tubes are presented. Emphasis is placed on the low Reynolds number turbulent flow regime--defined as fully turbulent flow at bulk Reynolds numbers from 3,000 to about 15,000. Adiabatic air velocity and friction data and localized heat transfer measurements for air and helium, at low heating rates, are presented for this range. The adiabatic data were obtained in a 1.61 inch 1D tube for flow at bulk Reynolds numbers from 3,000 to 15,000. A continuous, Reynolds number-dependent, profile is developed from the data by using a modification of Reichardts' wall and middle law eddy diffusivity expressions. The velocity profile satisfies continuity. It is valid for all Reynolds numbers in excess of 3,000 for which the flow is fully turbulent and the Blasius friction factor expression is valid. The thermal entrance problem for a fully developed velocity profile is solved analytically by the method of Sparrow, Hallman, and Siegel. The solution is based on the profile developed from the velocity study. Tabular values of the eigenvalues and normalized Nusselt numbers for gases are presented for it range of Reynolds numbers from 3,000 to 50,000. The axial variation of Nusselt number is found to be correlated by [Nu/Nu_(∞)] = 1 + 0.8 (1+ 70,000 Re^(-3/2)) ((x/D)^(-1)) to within ± 5 per cent for x/D ≥2. The fully developed value agrees with the Dittus - Boelter correlation, Nu_(∞) = 0.021 Re^(0.8) Pr^(0.4) For the eigenvalues, λ^(2)_(n), and the associated constants, A_(n), correlations of the form λ^(2)_(n) =A_(1,n) Re^(-b_(1,n) + C_(1,n) Re^(-d_(1,n)) A_(n) = -A_(2,n) Re^(-b_(2,n) + C_(2,n) Re^(-d_(2,n)) are obtained. The coefficients and powers are presented in tabular form. Heat transfer data are presented, primarily for helium, for the low Reynolds number turbulent range. A one-quarter inch, resistively heated, vertical, circular tube was used for the study. The data cover an axial range from 1.2 to 96 diameters; wall-to-bulk temperature ratios vary from 1 to 1.4. In the low Reynolds number turbulent regime, these data clearly support the present analytical solution rather than the prediction obtained by applying the eddy diffusivity distribution used by Sparrow, Hallman, and Siegel.

Harold C. Reynolds, Jr.↗

Prediction of electron density in the boundary layer on entry vehicles with ablation

A rather general computer code has been developed for the numerical solution of the laminar boundary layer and thin shock layer (stagnation point only) equations for a multi-component gas mixture with finite reaction rates. The purpose of this paper is to indicate the capabilities of this computer program by presenting solutions for pure air flows and flows with carbon ablation. At the body surface the effects of oxidation and sublimation of carbon are taken into account with the following species included in the gas model: 0 2 , N 2 , O, N, NO, NO + , C 1 , C 2 , C 3 , CN, CO, and CO 2 . Results for the boundary layer along a 10° half-angle hyperboloid with ablation of carbon are compared to pure air results. Shock layer results for several wall temperatures and altitudes are presented and compared to pure air results. Other types of problems that can be solved with this computer code are indicated.

F. G. Blottner↗

Steady-state solutions for relativistically strong electromagnetic waves in plasmas.

New steady-state solutions are derived which describe electromagnetic waves strong enough to make plasma ions and electrons relativistic. A two-fluid model is used throughout. The following solutions are studied: (1) linearly polarized waves with phase velocity much greater than c; (2) arbitrarily polarized waves with phase velocity near c, in a cold uniform plasma; (3) circularly polarized waves in a uniform plasma characterized by a scalar pressure tensor. All of these waves are capable of propagating in normally overdense plasmas, due to nonlinearities introduced by relativistic effects. The propagation of relativistically strong waves in a density gradient is examined, for the example of a circularly polarized wave strong enough to make electrons but not ions relativistic. It is shown that such a wave propagates at constant energy flux despite the nonlinearity of the system.

Max, C. E.↗

Soft X-ray bremsstrahlung and fluorescent line production in the atmosphere by low energy electrons

The effect of low energy quasi-trapped or precipitating electrons which impact on the counter windows of soft X-ray detectors are discussed. The errors caused by X-rays produced in the residual atmosphere above a rocket-borne detector because of the resemblance to X-rays of cosmic origin are examined. The design and development of counter windows which make it possible to identify the atmospherically produced X-rays are described. Curves are presented to show the following: (1) preliminary low energy electron data from Atmospheric Explorer C, (2) X-ray flux in electron-excited nitrogen and oxygen, (3) typical proportional counter response to low energy cosmic rays, and (4) proportional counter response to X-radiation produced by electrons incident upon a gas of oxygen to nitrogen number of 0.4.

Kraushaar, W. L.↗

Design and operation of a Loran-C time reference station

Some of the practical questions that arise when one decides to use Loran-C in a time reference system are explored. An extensive effort is made to provide basic, practical information on establishing and operating a reference station. Four areas were covered: (1) the design, configuration and operational concepts which should be considered prior to establishing and operating a reference station using Loran-C, (2) the options and tradeoffs available regarding capabilities, cost, size, versatility, ease of operation, etc., that are available to the designer, (3) what measurements are made, how they are made and what they mean, and (4) the experience the U.S. Naval Observatory Time Service Division has had in the design and operation of such stations.

Putkovich, K.↗

A preliminary systems-engineering study of an advanced nuclear-electrolytic hydrogen-production facility

An advanced nuclear-electrolytic hydrogen-production facility concept was synthesized at a conceptual level with the objective of minimizing estimated hydrogen-production costs. The concept is a closely-integrated, fully-dedicated (only hydrogen energy is produced) system whose components and subsystems are predicted on ''1985 technology.'' The principal components are: (1) a high-temperature gas-cooled reactor (HTGR) operating a helium-Brayton/ammonia-Rankine binary cycle with a helium reactor-core exit temperature of 980 C, (2) acyclic d-c generators, (3) high-pressure, high-current-density electrolyzers based on solid-polymer electrolyte technology. Based on an assumed 3,000 MWt HTGR the facility is capable of producing 8.7 million std cu m/day of hydrogen at pipeline conditions, 6,900 kPa. Coproduct oxygen is also available at pipeline conditions at one-half this volume. It has further been shown that the incorporation of advanced technology provides an overall efficiency of about 43 percent, as compared with 25 percent for a contemporary nuclear-electric plant powering close-coupled contemporary industrial electrolyzers.

Escher, W. J. D.↗

Photoabsorption in formaldehyde

Theoretical studies of the vertical electronic dipole excitation and ionization spectra in molecular formaldehyde are reported. The investigations relied on configuration-interaction calculations and moment-theory techniques. A double-zeta basis of contracted Gaussian-lobe functions supplemented with appropriate polarization and bond functions was used to construct Fock spectra in C(2 nu) symmetry for certain states near the ground state equilibrium geometry. The ionization energies, discrete vertical transition frequencies, and oscillator strengths for occupied and vertical Fock orbitals are in general accord with experimental determinations and other theoretical calculations. Stieltjes and Chebyshev vertical electronic photoionization profiles were calculated and found to be in good agreement with appropriately averaged photoionization-mass spectrometric measurements of the cross section for parent H2CO(+) ion production.

Langhoff, P. W.↗

Studies on color-center formation in glass utilizing measurements made during 1 to 3 MeV electron irradiation

The coloring of NBS 710 glass was studied using a facility for making optical absorption measurements during and after electron irradiation. The induced absorption contains three Gaussian shaped bands. The color center growth curves contain two saturating exponential and one linear components. After irradiation the coloring decays can be described by three decreasing exponentials. At room temperature both the coloring curve plateau and coloring rate increases with increasing dose rate. Coloring measurements made at fixed dose rate but at increasing temperature indicate: (1) The coloring curve plateau decreases with increasing temperature and coloring is barely measurable near 400 C. (2) The plateau is reached more rapidly as the temperature increases. (3) The decay occurring after irradiation cannot be described by Arrhenius kinetics. At each temperature the coloring can be explained by simple kinetics. The temperature dependence of the decay can be explained if it is assumed that the thermal untrapping is controlled by a distribution of activation energies.

Swyler, K. J.↗

Auroral recombination of N and O - A possible source for emission in the gamma and delta bands of NO

Radiative recombination of N and O provides a significant source for auroral emission in the gamma and delta bands of NO with selective population of vibrational levels in the A 2 Sigma(+) and C 2 Pi states. This mechanism may account for emissions detected near 2150 A. Models are derived for the auroral ionosphere and include estimates for the concentrations of N and NO. The concentration of NO is estimated to have a value of about 100 million per cu cm near 140 km in an IBC III aurora. The corresponding density for N is about 50 million per cu cm, and the concentration ratio NO(+)/O2(+) has a value of about 5.5.

Wofsy, S. C.↗

Quantitative absorption and fluorescence studies of NO between 1060 and 2000 A

Synchrotron radiation in the 1060 to 2000 A region was used to measure the average absorption and fluorescence cross sections of NO and to determine approximate photodissociation quantum yields. Several vibrational levels of the D(2) sigma(+), E(2) sigma(+), and B(2) delta states have high fluorescence quantum yields. The C(2) and B(2) states do not fluoresce when the excitation energies are above the first dissociation limit, in accord with previous experiments. In general, the fluorescence yields decrease with increasing photon energy. The quantitative measurements are compared with spectroscopic observations and are found to be reasonably consistent.

Guest, J. A.↗

Dissociative and double photoionization of CO from threshold to 90 A

Partial cross sections for molecular photoionization (CO(+)), dissociative photoionization (C(+) and O(+)), and dissociative double photoionization (C(2+)) in CO have been measured from their thresholds to 90 A using techniques of mass spectrometry. The results are compared with data reported previously. Several peaks observed in the cross section curves for dissociated fragments are tentatively assigned by comparing with those in the photoelectron spectra reported for CO. It is concluded that the shoulder in the total absorption cross section curve between 400 and 90 A results solely from the dissociative ionization processes.

Masuoka, T.↗

Chemiluminescence of nitric oxide

Measurements of the intensities of the delta and gamma bands of nitric oxide in the nighttime terrestrial thermosphere are presented and used to infer the rate coefficient for the transition from the C 2 Pi to the A 2 Sigma + states. The nightglow spectrum was observed between 1900 and 2300 A at a resolution of 15 A by a rocket-borne scanning 1/4-m spectrometer pointing north at an apogee of 150 km. Progressions of the delta, gamma and epsilon bands are identified on the spectra by the construction of synthetic spectra, and the contributions of resonance fluorescence to the total band intensities are calculated. Finally, the ratio of the sum of the gamma bands for v-prime = 0 to the sum of the delta bands for v-prime = 0 is used to derive a branching ratio of 0.21 + or - 0.04 to the A 2 Sigma + state, which yields a probability for the C-A transition of 5.6 + or - 1.5 x to the 6th/sec.

Sharp, W. E.↗