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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2013

Macrophysical Properties of Tropical Cirrus Clouds from the CALIPSO Satellite and from Ground-based Micropulse and Raman Lidars

Lidar observations of cirrus cloud macrophysical properties over the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) program Darwin, Australia site are compared from the Cloud-Aerosol Lidar and In- frared Pathfinder Satellite Observation (CALIPSO) satellite, the ground-based ARM micropulse lidar (MPL), and the ARM Raman lidar (RL). Comparisons are made using the subset of profiles where the lidar beam is not fully attenuated. Daytime measurements using the RL are shown to be relatively unaffected by the solar background and are therefore suited for checking the validity of diurnal cycles. RL and CALIPSO cloud fraction profiles show good agreement while the MPL detects significantly less cirrus, particularly during the daytime. Both MPL and CALIPSO observations show that cirrus clouds occur less frequently during the day than at night at all altitudes. In contrast, the RL diurnal cy- cle is significantly different than zero only below about 11 km; where it is the opposite sign (i.e. more clouds during the daytime). For cirrus geomet- rical thickness, the MPL and CALIPSO observations agree well and both datasets have signficantly thinner clouds during the daytime than the RL. From the examination of hourly MPL and RL cirrus cloud thickness and through the application of daytime detection limits to all CALIPSO data we find that the decreased MPL and CALIPSO cloud thickness during the daytime is very likely a result of increased daytime noise. This study highlights the vast im- provement the RL provides (compared to the MPL) in the ARM program's ability to observe tropical cirrus clouds as well as a valuable ground-based lidar dataset for the validation of CALIPSO observations and to help im- prove our understanding of tropical cirrus clouds.

Cirrus Clouds↗
DOE OSTI2019

Differences in Ice Cloud Optical Depth From CALIPSO and Ground-Based Raman Lidar at the ARM SGP and TWP Sites

Ice cloud column optical depths from the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) satellite and ground-based Raman lidars (RLs) at the Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) and Tropical Western Pacific (TWP) sites are compared for 8 and 4 years, respectively. The cloudy mean ice cloud column optical depths from CALIPSO Version 4 data product with a horizontal resolution of 5 km are 78% (63%) larger than those from the RLs with a resolution of 10 min/30 m at SGP (TWP) for collocated transparent profiles. The main difference at SGP is caused by the lidar ratio that for CALIPSO is related to its treatment of the multiple scattering factor. The main difference at TWP is caused by the averaging resolution. Large differences in the optical depth distribution between the CALIPSO and RL are found for small optical depths at both sites, which are due to optically very thin clouds only detectable by the RLs. The differences in ice cloud column optical depth distributions and their mean values between the CALIPSO and RL can largely be reconciled over both sites after accounting for the averaging resolutions, lidar ratios along with the CALIPSO multiple scattering factor treatment, sensitivity to optically very thin ice clouds, and definition of transparent profiles. This work also examines in detail the lidar ratios that are directly observed by the RLs, which does not support the temperature-dependent parameterizations of ice cloud lidar ratio and multiple scattering factor used in CALIPSO's Version 4 data product.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2011

Comparison of the CALIPSO satellite and ground-based observations of cirrus clouds at the ARM TWP sites

Statistics of ice cloud macrophysical and optical properties from the Cloud-Aerosol LIdar with Orthogonal Polarization (CALIOP) instrument on board the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) satellite are compared with those from ground-based lidar observations over a 31 month period. Ground-based lidar observations are taken from the micropulse lidars (MPL) at the three Department of Energy Atmospheric Radiation Measurement (ARM) tropical western pacific (TWP) sites: Manus, Nauru and Darwin. CALIPSO observations show a larger cloud fraction at high altitudes while the ground-based MPLs show a larger cloud fraction at low altitudes. The difference in mean ice cloud top and base heights at the Manus and Nauru sites are all within 0.51 km, although differences are statistically significant. Mean ice cloud geometrical thickness agree to within 0.05 km at the Manus and Nauru sites. Larger differences exist at Darwin due to excessive degradation of the MPL output power during our sampling period. Both sets of observations show thicker clouds during the nighttime which may be real but could also be partially an artifact of the decreased signal-to-noise ratio during the daytime. The number of ice cloud layers per profile are also shown to be consistent after accounting for the difference in spatial resolution. For cloud optical depths, four different retrieval methods are compared, two for each set of observations. All products show that the majority of ice cloud optical depths ({approx}60%) fall below an optical depth of 0.2. For most comparisons all four retrievals agree to within the uncertainty intervals. We find that both CALIPSO retrievals agree best to ground-based optical depths when the lidar ratio in the latter is retrieved instead of set to a fixed value. Also thoroughly compared is the cloud properties for the subset of ice clouds which reside in the tropical tropopause layer (TTL).

58 GEOSCIENCES↗
DOE OSTI2022

Cloud Phase Simulation at High Latitudes in EAMv2: Evaluation using CALIPSO Observations and Comparison with EAMv1

This study performs a comprehensive evaluation of the simulated cloud phase in the U.S. Department of Energy (DOE) Energy Exascale Earth System Model (E3SM) atmosphere model version 2 (EAMv2) and version 1 (EAMv1). Enabled by the CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation) simulator, EAMv2 and EAMv1 predicted cloud phase is compared against the GCM-Oriented CALIPSO Cloud Product (CALIPSO-GOCCP) at high latitudes where mixed-phase clouds are prevalent. Our results indicate that the underestimation of cloud ice in simulated high-latitude mixed-phase clouds in EAMv1 has been significantly reduced in EAMv2. The increased ice clouds in the Arctic mainly result from the modification on the WBF (Wegner-Bergeron-Findeisen) process in EAMv2. The impact of the modified WBF process is moderately compensated by the low limit of cloud droplet number concentration (CDNC) in cloud microphysics and the new dCAPE_ULL trigger used in deep convection in EAMv2. Moreover, it is found that the new trigger largely contributes to the better cloud phase simulation over the Norwegian Sea and Barents Sea in the Arctic and the Southern Ocean where large errors are found in EAMv1. However, errors in simulated cloud phase in EAMv1, such as the overestimation of supercooled liquid clouds near the surface in both hemispheres and the underestimation of ice clouds over Antarctica, persist in EAMv2. In conclusion, this study highlights the impact of deep convection parameterizations, which has received little attention, on high-latitude mixed-phase clouds, and the importance of continuous improvement of cloud microphysics in climate models for accurately representing mixed-phase clouds.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

A global gridded dataset for cloud vertical structure from combined CloudSat and CALIPSO observations

Abstract. The vertical structure of clouds has a profound effect on the global energy budget, the global circulation, and the atmospheric hydrological cycle. The CloudSat and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) missions have taken complementary, colocated observations of cloud vertical structure for over a decade. However, no globally gridded dataset is available to the public for the full length of this unique combined data record. Here we present the 3S-GEOPROF-COMB product (Bertrand et al. 2023, https://doi.org/10.5281/zenodo.8057791), a globally gridded (level 3S) community data product summarizing geometrical profiles (GEOPROF) of hydrometeor occurrence from combined (COMB) CloudSat and CALIPSO data. Our product is calculated from the latest release (R05) of per-orbit (level-2) combined cloud mask profiles. We process a set of cloud cover, vertical cloud fraction, and sampling variables at 2.5, 5, and 10° spatial resolutions and monthly and seasonal temporal resolutions. We address the 2011 reduction in CloudSat data collection with Daylight-Only Operations (DO-Op) mode by subsampling pre-2011 data to mimic DO-Op collection patterns, thereby allowing users to evaluate the impact of the reduced sampling on their analyses. We evaluate our data product against CloudSat-only and CALIPSO-only global-gridded data products as well as four comparable surface-based sites, underscoring the added value of the combined product. Interest in the product is anticipated for the study of cloud processes, cloud–climate interactions, and as a candidate baseline climate data record for comparison to follow-up satellite missions, among other uses.

Bertrand, Leah (ORCID:0009000001607558)↗
DOE OSTI2017

Climate Impacts of CALIPSO-Guided Corrections to Black Carbon Aerosol Vertical Distributions in a Global Climate Model

Here, we alleviate the bias in the tropospheric vertical distribution of black carbon aerosols (BC) in the Community Atmosphere Model (CAM4) using the Cloud-Aerosol and Infrared Pathfinder Satellite Observations (CALIPSO)-derived vertical profiles. A suite of sensitivity experiments are conducted with 1x, 5x, and 10x the present-day model estimated BC concentration climatology, with (corrected, CC) and without (uncorrected, UC) CALIPSO-corrected BC vertical distribution. The globally averaged top of the atmosphere radiative flux perturbation of CC experiments is ~8–50% smaller compared to uncorrected (UC) BC experiments largely due to an increase in low-level clouds. The global average surface temperature increases, the global average precipitation decreases, and the ITCZ moves northward with the increase in BC radiative forcing, irrespective of the vertical distribution of BC. Further, tropical expansion metrics for the poleward extent of the Northern Hemisphere Hadley cell (HC) indicate that simulated HC expansion is not sensitive to existing model biases in BC vertical distribution.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Version 4 CALIPSO Imaging Infrared Radiometer ice and liquid water cloud microphysical properties – Part I: The retrieval algorithms

Following the release of the version 4 Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) data products from the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) mission, a new version (version 4; V4) of the CALIPSO Imaging Infrared Radiometer (IIR) Level 2 data products has been developed. The IIR Level 2 data products include cloud effective emissivities and cloud microphysical properties such as effective diameter and ice or liquid water path estimates. Dedicated retrievals for water clouds were added in V4, taking advantage of the high sensitivity of the IIR retrieval technique to small particle sizes. This paper (Part I) describes the improvements in the V4 algorithms compared to those used in the version 3 (V3) release, while results will be presented in a companion (Part II) paper. The IIR Level 2 algorithm has been modified in the V4 data release to improve the accuracy of the retrievals in clouds of very small (close to 0) and very large (close to 1) effective emissivities. To reduce biases at very small emissivities that were made evident in V3, the radiative transfer model used to compute clear-sky brightness temperatures over oceans has been updated and tuned for the simulations using Modern-Era Retrospective analysis for Research and Applications version 2 (MERRA-2) data to match IIR observations in clear-sky conditions. Furthermore, the clear-sky mask has been refined compared to V3 by taking advantage of additional information now available in the V4 CALIOP 5 km layer products used as an input to the IIR algorithm. After sea surface emissivity adjustments, observed and computed brightness temperatures differ by less than ±0.2 K at night for the three IIR channels centered at 08.65, 10.6, and 12.05 µm, and inter-channel biases are reduced from several tens of Kelvin in V3 to less than 0.1 K in V4. We have also improved retrievals in ice clouds having large emissivity by refining the determination of the radiative temperature needed for emissivity computation. The initial V3 estimate, namely the cloud centroid temperature derived from CALIOP, is corrected using a parameterized function of temperature difference between cloud base and top altitudes, cloud absorption optical depth, and CALIOP multiple scattering correction factor. As shown in Part II, this improvement reduces the low biases at large optical depths that were seen in V3 and increases the number of retrievals. As in V3, the IIR microphysical retrievals use the concept of microphysical indices applied to the pairs of IIR channels at 12.05 and 10.6 µm and at 12.05 and 08.65 µm. The V4 algorithm uses ice look-up tables (LUTs) built using two ice habit models from the recent “TAMUice2016” database, namely the single-hexagonal-column model and the eight-element column aggregate model, from which bulk properties are synthesized using a gamma size distribution. Four sets of effective diameters derived from a second approach are also reported in V4. Here, the LUTs are analytical functions relating microphysical index applied to IIR channels 12.05 and 10.6 µm and effective diameter as derived from in situ measurements at tropical and midlatitudes during the Tropical Composition, Cloud, and Climate Coupling (TC4) and Small Particles in Cirrus Science and Operations Plan (SPARTICUS) field experiments.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Regime-based aerosol–cloud interactions from CALIPSO-MODIS and the Energy Exascale Earth System Model version 2 (E3SMv2) over the Eastern North Atlantic

This study investigates aerosol-cloud interactions in marine boundary layer (MBL) clouds using an advanced deep-learning-driven synoptic-regime-based framework, combining satellite data (CALIPSO vertically resolved aerosol extinction and MODIS cloud properties) with 1° nudged Energy Exascale Earth System Model version 2 (E3SMv2) simulation over the Eastern North Atlantic (ENA; ∼10°×10°, 2006–2014). The E3SMv2 captures observed seasonal variations in cloud droplet number concentrations (N d ) and liquid water path (LWP), though it systematically underestimates N d . We then partition ENA meteorology into four synoptic regimes (Pre-Trough, Post-Trough, Ridge, Trough) via a deep-learning clustering of ERA5 reanalysis fields, enabling regime-dependent aerosol-cloud interactions analyses. Both satellite and E3SMv2 exhibit an inverted-V LWP-N d relationship. In Post-Trough and Ridge regimes, the satellite shows stronger negative LWP-N d sensitivities than in Pre-Trough regime. The Trough regime displays a muted satellite LWP response. In comparison, the model predicts more exaggerated LWP responses across regimes, with LWP increasing too quickly at low N d and decreasing more sharply at high N d , especially in Pre-Trough and Trough regimes. These exaggerated model LWP sensitivities may stem from uncertainties in representing drizzle processes, entrainment, and turbulent mixing. As for N d susceptibility to aerosols, N d increases with MBL aerosol extinction in both datasets, but the simulated aerosol-cloud interactions appear oversensitive to meteorological conditions. Overall, E3SMv2 better captures aerosol effects under regimes that favor stratiform clouds (Post-Trough, Ridge), but performance deteriorates for regimes with deeper, dynamically complex clouds (Trough), highlighting the need for improved representations of those cloud processes in climate models.

Environmental sciences↗
DOE OSTI2026

Advancing the quantification of aerosol-cloud interactions with the CALIPSO-CloudSat-Aqua/MODIS record

Aerosol-cloud-precipitation interactions are assessed over the non-polar ocean using more than 11 years of combined Aqua-MODIS, CALIPSO-CALIOP, and CloudSat products. The analysis first shows the benefit of incorporating vertically resolved aerosol extinction coefficient (σext) in aerosol-cloud interactions (ACI) assessments, demonstrating that: σext vertically collocated with the cloud layer () correlates best with cloud droplet number concentration (Nd), column-integrated aerosol optical depth (AOD) cannot explain the Nd variability in the extratropics, and the S-shape of the AOD-Nd relationship reported in previous studies is not replicated when using instead of AOD, with a Nd- linearity more consistent with in-situ studies over the ocean. ACI metric, estimated as the log-scale regression between CALIOP and MODIS Nd reveals that the eastern Pacific is the region with the strongest ACI, followed by the Southern Ocean. The susceptibility of clouds to changes in their liquid water path (LWP) and frequency of precipitation followed a 2-step calculation by combining the Nd- regression (ACI) with the regression between these macrophysical variables and Nd. LWP susceptibility is negative (LWP decreases with aerosol loading) and statistically significant over the eastern Pacific, eastern Atlantic, and extratropics. In contrast, vast areas of the tropical and subtropical ocean feature negligible changes in LWP with aerosol. Precipitation frequency susceptibility is negative, but the values are only significant over the coastal eastern Pacific and Atlantic. The findings suggest that previous modeling assessments relying on AOD may need to be revisited by taking advantage of the synergy between passive and active sensors.

Li, Zhujun↗
DOE OSTI2020

Simulations of Winter Arctic Clouds and Associated Radiation Fluxes Using Different Cloud Microphysics Schemes in the Polar WRF: Comparisons With CloudSat, CALIPSO, and CERES

Clouds are important for the Arctic climate, but simulating such clouds with numerical models is still challenging. The accuracy of model clouds has not been sufficiently examined due to the harsh Arctic environment obstructing cloud observations, especially during Arctic winters experiencing polar nights. This study compares the Arctic winter clouds simulated by a weather forecast model to cloud observations from active (lidar and radar) satellite instruments. The model successfully produced cloud patterns similar to the satellite observations. However, the choice of the cloud physics module in the model can modify the amount of cloud water significantly enough to affect the simulated surface climate.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2013

Cloud Effects on Radiative Heating Rate Profiles over Darwin using ARM and A-train Radar/Lidar Observations

Observations of clouds from the ground-based U.S. Department of Energy Atmospheric Radiation Measurement program (ARM) and satellite-based A-train are used to compute cloud radiative forcing profiles over the ARM Darwin, Australia site. Cloud properties are obtained from both radar (the ARM Millimeter Cloud Radar (MMCR) and the CloudSat satellite in the A-train) and lidar (the ARM Micropulse lidar (MPL) and the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) satellite in the A-train) observations. Cloud microphysical properties are taken from combined radar and lidar retrievals for ice clouds and radar only or lidar only retrievals for liquid clouds. Large, statistically significant differences of up to 1.43 K/day exist between the mean ARM and A-train net cloud radiative forcing profiles. The majority of the difference in cloud radiative forcing profiles is shown to be due to a large difference in the cloud fraction above 12 km. Above this altitude the A-train cloud fraction is significantly larger because more clouds are detected by CALIPSO than by the ground-based MPL. It is shown that the MPL is unable to observe as many high clouds as CALIPSO due to being more frequently attenuated and a poorer sensitivity even in otherwise clear-sky conditions. After accounting for cloud fraction differences and instrument sampling differences due to viewing platform we determined that differences in cloud radiative forcing due to the retrieved ice cloud properties is relatively small. This study demonstrates that A-train observations are better suited for the calculation cloud radiative forcing profiles. In addition, we find that it is necessary to supplement CloudSat with CALIPSO observations to obtain accurate cloud radiative forcing profiles since a large portion of clouds at Darwin are detected by CALIPSO only.

A-train↗
DOE OSTI2018

An Investigation of Optically Very Thin Ice Clouds from Ground-Based ARM Raman Lidars

Optically very thin ice clouds from the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) and ground-based Raman lidars (RL) at the atmospheric radiation measurement (ARM) sites of the Southern Great Plains (SGP) and Tropical Western Pacific (TWP) are analyzed. The optically very thin ice clouds, with ice cloud column optical depths below 0.01, are about 23% of the transparent ice-cloudy profiles from the RL, compared to 4–7% from CALIPSO. The majority (66–76%) of optically very thin ice clouds from the RLs are found to be adjacent to ice clouds with ice cloud column optical depths greater than 0.01. The temporal structure of RL-observed optically very thin ice clouds indicates a clear sky–cloud continuum. Global cloudiness estimates from CALIPSO observations leveraged with high-sensitivity RL observations suggest that CALIPSO may underestimate the global cloud fraction when considering optically very thin ice clouds.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Impacts of active satellite sensors' low-level cloud detection limitations on cloud radiative forcing in the Arctic

Previous studies revealed that satellites sensors with the best detection capability identify 25 %–40 % and 0 %–25 % fewer clouds below 0.5 and between 0.5–1.0 km, respectively, over the Arctic. Quantifying the impacts of cloud detection limitations on the radiation flux are critical especially over the Arctic Ocean considering the dramatic changes in Arctic sea ice. In this study, the proxies of the space-based radar, CloudSat, and lidar, CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations), cloud masks are derived based on simulated radar reflectivity with QuickBeam and cloud optical thickness using retrieved cloud properties from surface-based radar and lidar during the Surface Heat Budget of the Arctic Ocean (SHEBA) experiment. Limitations in low-level cloud detection by the space-based active sensors, and the impact of these limitations on the radiation fluxes at the surface and the top of the atmosphere (TOA), are estimated with radiative transfer model Streamer. The results show that the combined CloudSat and CALIPSO product generally detects all clouds above 1 km, while detecting 25 % (9 %) fewer in absolute values below 600 m (600 m to 1 km) than surface observations. These detection limitations lead to uncertainties in the monthly mean cloud radiative forcing (CRF), with maximum absolute monthly mean values of 2.5 and 3.4 Wm –2 at the surface and TOA, respectively. Cloud information from only CALIPSO or CloudSat lead to larger cloud detection differences compared to the surface observations and larger CRF uncertainties with absolute monthly means larger than 10.0 Wm –2 at the surface and TOA. The uncertainties for individual cases are larger – up to 30 Wm –2 . These uncertainties need to be considered when radiation flux products from CloudSat and CALIPSO are used in climate and weather studies.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Modeling Dust in East Asia by CESM and Sources of Biases

East Asian dust has a significant impact on regional and global climate. In this study, we evaluate the spatial distributions and temporal variations of dust extinction profiles and dust optical depth (DOD) over East Asia simulated from the Community Earth System Model (CESM) with satellite retrievals from Luo, Wang, Ferrare, et al., Luo, Wang, Zhang, et al. (L15), Yu et al. (Y15), and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) level 3 products. Both L15 and Y15 are based on CALIPSO products but use different algorithms to separate dust from nondust aerosols. We find high model biases of dust extinction in the upper troposphere over the Taklamakan desert, Gobi desert, and Tibetan Plateau, especially in the summer (June-July-August). CESM with dust emission scheme of Kok, Mahowald, et al. and Kok, Albani, et al. has the best agreement with dust extinction profiles and DOD from L15 in the Taklamakan desert and Tibetan Plateau. CESM with the default dust emission scheme of Zender, Bian, and Newman underpredicts DOD in the Tibetan Plateau compared with observations from L15 due to the underestimation of local dust emission. Large uncertainties exist in observations from L15, Y15, and CALIPSO level 3 products and have significant impacts on the model evaluation of dust spatial distributions. We also assess dust surface concentrations and 10-m wind speed with meteorological records from weather stations in the Taklamakan and Gobi deserts during dust events. We note CESM underestimates dust surface concentrations at most weather stations due to the inability of CESM to capture strong surface wind events.

58 GEOSCIENCES↗
DOE OSTI2017

The impact of lidar detection sensitivity on assessing aerosol direct radiative effects: LIDAR SENSITIVITY AND AEROSOL DRE

Spaceborne lidar observations have great potential to provide accurate global estimates of the aerosol direct radiative effect (DRE) in both clear and cloudy conditions. However, comparisons between observations from the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite (CALIPSO) and multiple years of Atmospheric Radiation Measurement (ARM) program's ground-based Raman lidars (RL) show that CALIPSO does not detect all radiatively significant aerosol, i.e., aerosol that directly modifies the Earth's radiation budget. We estimated that using CALIPSO observations results in an underestimate of the magnitude of the global mean aerosol DRE by up to 54%. The ARM RL data sets along with NASA Langley airborne high spectral resolution lidar data from multiple field campaigns are used to derive the detection sensitivity required to accurately resolve the aerosol DRE. This shows that a lidar with a backscatter coefficient detection sensitivity of about 1–2 × 10 -4 km -1 sr -1 at 532 nm would resolve all the aerosol needed to derive the DRE to within 1%.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Aerosol Optical Thickness: Organic Composition, Associated Particle Water, and Aloft Extinction

Over the contiguous United States, the strongest remotely sensed aerosol optical thickness (AOT) is observed in the east, where aerosol liquid water (ALW) and extinction per unit PM 2.5 dry mass are highest. Positive associations between ALW due to sulfate and nitrate with remotely sensed AOT offer a contributing explanation for geospatial patterns in AOT seasonality. We seek here to further resolve patterns in ALW-AOT relationships by investigating organic mass (OM) fractionation, converted from organic carbon (OC) measurements using regionally specific OM:OC ratios, and the associated impacts on ALW. ALW is integrated from the surface through the boundary layer and estimated from measured particle chemical composition using ISORROPIAv2.1 and κ-Kohler theory at eight Interagency Monitoring of PROtected Visual Environments (IMPROVE) sites in areas of contrasting AOT seasonality. Two groups of four sites each, clustered by chemical climatology, are compared to AOT derived from the Moderate Resolution Imaging Spectroradiometer and vertically resolved extinction retrieved from Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) from 2007 to 2016. Estimated ALW within the planetary boundary layer differs between the regions. Spatial patterns and vertical profiles are qualitatively similar to CALIPSO patterns. However, inclusion of volatility-based organic speciation from routine surface networks and the associated ALW do not improve correlation with satellite-derived AOT. CALIPSO-measured extinction is enhanced above the PBL and may partly explain discrepancies. This work is suggestive that the effects of intrinsic physicochemical properties are remotely sensed, but approaches to link AOT to current surface measurements are limited in detail and their ability to assess aloft phenomena.

54 ENVIRONMENTAL SCIENCES↗