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Airborne laser induced fluorescence system for measuring OH and other trace gases in the parts-per-quadrillion to parts-per-trillion range

Described in detail is a laser induced fluorescence system which has been successfully interfaced with two aircraft sampling platforms (i.e., Sabreliner jet and an L-188C Electra). This system, which has been under development for four years, presently consists of the following major components: (1) a Nd-Yag laser driven oscillator-amplifier dye laser; (2) a sampling manifold with associated fluorescence detection optics; (3) an OH calibration chamber; (4) a laser beam steering assembly; and (5) sampling electronics and data processing hardware. During the last three years, this system has been flown some 50,000 air miles making tropospheric OH radical measurements over the latitude range of 70 N to 57 S. OH concentrations measured during these flights have ranged from 30 parts-per-quadrillion (3.7 x 10 to the 5th molecules/sq cm) at altitudes of 6 km to 0.8 parts-per-trillion (2.0 x 10 to the 7th molecules/sq cm) at 0.5 km. Computations have been completed which indicate that the existing aircraft system with modest modifications should also be capable of detecting natural tropospheric levels of NO, SO2, CH2O, NO2, HNO2, NO3, H2O2 and CS2 by using both conventional laser-induced fluorescence methodology and multiphoton techniques.

Davis, D. D.↗

High-Spatial-Resolution OH and CH2O PLIF Visualization in a Dual-Mode Scramjet Combustor

A high-spatial-resolution planar laser-induced fluorescence (PLIF) imaging system was constructed and used to image a cavity-stabilized, premixed ethylene-air flame. The flame was created within a continuous flow, electrically-heated supersonic combustion facility consisting of a Mach 2 nozzle, an isolator with flush-wall fuel injectors, a combustor with a cavity flameholder of height 9 mm and optical access, and an extender. Tests were conducted at total temperature 1200 K, total pressure 300 kPa, equivalence ratio near 0.4 in the combustor, and Mach number near 0.6 in the combustor. A frequency-doubled Nd:YAG laser pumped a dye laser, which produced light at 283.55 nm. The beam was shaped into a light sheet with full width half-maximum 25 microns, which illuminated a streamwise plane that bisected the cavity. An intensified camera system imaged OH in this plane with a square 6.67 mm field of view and in-plane resolution 39 microns. Images were taken between the backward-facing step and 120 mm downstream of the step. OH structures as small as 110 microns were observed. CH2O was excited using 352.48 nm light; the smallest observed CH2O structures were approximately 200 microns wide. Approximately 15,000 images per species were processed and used to compute composite images.

Geipel, Clayton M.↗

High-Resolution OH and CH2O Visualization in a Premixed Cavity-Anchored Ethylene-Air Flame in a M = 0.6 Flowfield

OH and CH2O were imaged in a premixed, cavity-anchored, ethylene-air turbulent flame using a high resolution planar laser-induced fluorescence (PLIF) system. The electrically-heated, continuous flow facility (UVa Supersonic Combustion Facility, Configuration E) consisted of a Mach 2 nozzle, an isolator with fuel injectors, a test section with a cavity flame holder and optical access, and an extender. Standard test conditions comprised total temperature 1200 K, total pressure 300 kPa, local equivalence ratio near 0.4, and local Mach number near 0.6. OH PLIF data was also collected for a case with reduced total temperature and another with reduced equivalence ratio. OH and CH2O were excited in separate experiments with light sheets at 283.55 nm and 352.48 nm, respectively. A light sheet of approximate thickness 25 ?m illuminated the stream-wise midplane. This plane was imaged for 120 mm downstream of the backward-facing step. The intensified camera system imaged OH with magnification 1.97, a square 6.67 mm field of view, and in-plane resolution of 39 ?m. The smallest observed OH structures observed were approximately 100 ?m wide. The CH2O PLIF image signal was much weaker; the smallest observed structures were approximately 200 ?m wide. Composite fluorescence images were computed for the observed area.

Geipel, Clayton M.↗

An aircraft compatible laser induced fluorescence system - In situ and remote measurements of trace gases

The laser-induced fluorescence technique for obtaining direct measurements of atmospheric OH and other gases is described. A narrow-band UV laser is tuned to one or more of the electronic absorption bands of a specified molecule so as to cause fluorescence from a bonding excited electronic state. The monitored wavelength is longer than the laser wavelength. Equipment, specifics for OH detection, data processing, and interference are discussed, and application of the technique to the detection of NO, SO2, and CH2O is considered.

Davis, D. D.↗