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At least 19 records

Entanglement Throughput Measurements and Capacity Estimates for Aerial-Inground Fiber

The throughput of entangled qubit pairs per second (eqps) is a basic performance metric of quantum networks that provide the entanglement distribution capability. Over fiber connections, it is measured using specialized instruments, including photonic entanglement sources and single-photon detectors. Extensive theory has been developed to estimate the capacity of a generic quantum channel, which in turn is applied to estimate the maximum achievable eqps over a fiber connection. However, there is a gap in relating these two performance metrics, in part due to their disparate nature, namely, mathematical formulae of the channel capacity and specialized instrumentation for eqps measurements. We describe eqps measurements collected over testbed connections composed of aerial and inground fiber of lengths up to 45 km. We estimate the normalized capacity using the transmissivity parameter derived from single photon detector measurements. These estimates are then converted to capacity bounds on the connection's eqps using the source eqps rate derived from co-located detector measurements. The results indicate a consistency between eqps measurements and their capacity estimates, and provide insights into relating the parameters of analytic capacity estimates to physical measurements.

Rao, Nageswara [ORNL] (ORCID:0000000234085941)

Proposal for superconducting quantum networks using multioctave transduction to lower frequencies

We propose networking superconducting quantum circuits by transducing their excitations (typically 4–8 GHz) to 200–500 MHz photons for transmission via superconducting cryogenic coaxial cables. This frequency down-conversion reduces transmission losses and, counterintuitively, reduces noise. We introduce a multioctave asymmetrically threaded superconducting quantum interference device circuit capable of the required efficient, high-rate transduction. For a 100-meter cable with 𝑄 𝑖 = 10 5 at 10 mK, we theoretically show that our approach achieves single-photon fidelities of 0.962 at 200 MHz versus 0.772 at 8 GHz, and triples the lower bound on quantum channel capacity. In conclusion, this method enables highly efficient networking of superconducting qubits while maintaining high fidelities, combining improved performance with the practical advantages of flexible, compact coaxial cables.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND

What exactly does Bekenstein bound?

The Bekenstein bound posits a maximum entropy for matter with finite energy confined to a spatial region. It is often interpreted as a fundamental limit on the information that can be stored by physical objects. In this work, we test this interpretation by asking whether the Bekenstein bound imposes constraints on a channel's communication capacity, a context in which information can be given a mathematically rigorous and operationally meaningful definition. We study specifically the Unruh channel that describes a stationary Alice exciting different species of free scalar fields to send information to an accelerating Bob, who is confined to a Rindler wedge and exposed to the noise of Unruh radiation. We show that the classical and quantum capacities of the Unruh channel obey the Bekenstein bound that pertains to the decoder Bob. In contrast, even at high temperatures, the Unruh channel can transmit a significant number of zero-bits , which are quantum communication resources that can be used for quantum identification and many other primitive protocols. Therefore, unlike classical bits and qubits, zero-bits and their associated information processing capability are generally not constrained by the Bekenstein bound. However, we further show that when both the encoder and the decoder are restricted, the Bekenstein bound does constrain the channel capacities, including the zero-bit capacity.

Hayden, Patrick [Stanford University, CA (United S

Entanglement Capacity Estimates and Throughput Measurements of Quantum Channels

The throughput is an important performance metric of entangled qubit distribution quantum networks, and may be characterized by the number of distributed entangled qubit pairs per second (ebps). It is measured over physical quantum network connections using specialized instruments, including photonic entanglement sources and single photon detectors. Extensive theory has been developed to estimate the entangled qubit capacity of quantum channels using abstractions of physical connections. These two quantities both characterize the throughput performance but in different ways, and typically have been hard to relate to each other in concrete terms, in part due to the lack of precise measurements with matching analytical models and derivations. We describe measurements on a physical testbed with fiber connections of lengths 0-75 kilometers. We obtain the normalized analytic capacity estimates using the transmissivity approximations derived using single photon coincidence measurements, and convert them to bounds on throughput (measured in ebps) using a multiplier derived from co-located detector measurements. The results indicate consistent throughput measurements upper-bounded by their analytical capacity estimates across all connections. We show that previous capacity estimates using light measurements are below ebps measurements for some connections, due to the inclusion of non-representative decrease of light levels outside C-band with distance.

Rao, Nageswara

Passive Environment-Assisted Quantum Communication with GKP States

Bosonic pure-loss channel, which represents the process of photons decaying into a vacuum environment, has zero quantum capacity when the channel’s transmissivity is less than 50%. Modeled as a beam splitter interaction between the system and its environment, the performance of bosonic pure-loss channel can be enhanced by controlling the environment state. We show that by choosing the ideal Gottesman-Kitaev-Preskill (GKP) states for the system and its environment, perfect transmission of quantum information through a beam splitter is achievable at arbitrarily low transmissivities. Our explicit constructions allow for experimental demonstration of the improved performance of a quantum channel through passive environment assistance, which is potentially useful for quantum transduction where the environment state can be naturally controlled. In practice, it is crucial to consider finite-energy constraints, and high-fidelity quantum communication through a beam splitter remains achievable with GKP states at the few-photon level.

Wang, Zhaoyou [Univ. of Chicago, IL (United States

Efficiently Computable Limits on EPR Pair Generation in Quantum Broadcast Channels

We investigate the generation of EPR pairs between three observers in a general causally structured setting, where communication occurs via a noisy quantum broadcast channel. The most general quantum codes for this setup take the form of tripartite quantum channels. Since the receivers are constrained by causal ordering, additional temporal relationships naturally emerge between the parties. These causal constraints enforce intrinsic no-signalling conditions on any tripartite operation, ensuring that it constitutes a physically realizable quantum code for a quantum broadcast channel. We analyze these constraints and, more broadly, characterize the most general quantum codes for communication over such channels. We examine the capabilities of codes that are fully no-signalling among the three parties, positive partial transpose (PPT)-preserving, or both, and derive simple semidefinite programs to compute the achievable entanglement fidelity. We then establish a hierarchy of semidefinite programming converse bounds -- both weak and strong -- for the capacity of quantum broadcast channels for EPR pair generation, in both one-shot and asymptotic regimes. Notably, in the special case of a point-to-point channel, our strong converse bound recovers and strengthens existing results. Finally, we demonstrate how the PPT-preserving codes we develop can be leveraged to construct PPT-preserving entanglement combing schemes, and vice versa.

FOS: Physical sciences

Capacities of Entanglement Distribution From a Central Source

Distribution of entanglement is an essential task in quantum information processing and the realization of quantum networks. In our work, we theoretically investigate the scenario where a central source prepares an N -partite entangled state and transmits each entangled subsystem to one of N receivers through noisy quantum channels. The receivers are then able to perform local operations assisted by unlimited classical communication to distill target entangled states from the noisy channel output. In this operational context, we define the EPR distribution capacity and the GHZ distribution capacity of a quantum channel as the largest rates at which Einstein-Podolsky-Rosen (EPR) states and Greenberger-Horne-Zeilinger (GHZ) states can be faithfully distributed through the channel, respectively. We establish lower and upper bounds on the EPR distribution capacity by connecting it with the task of assisted entanglement distillation. We also construct an explicit protocol consisting of a combination of a quantum communication code and a classical-post-processing-assisted entanglement generation code, which yields a simple achievable lower bound for generic channels. As applications of these results, we give an exact expression for the EPR distribution capacity over two erasure channels and bounds on the EPR distribution capacity over two generalized amplitude damping channels. We also bound the GHZ distribution capacity, which results in an exact characterization of the GHZ distribution capacity when the most noisy channel is a dephasing channel.

42 ENGINEERING

Achievable Rates for Concatenated Square Gottesman-Kitaev-Preskill Codes

The Gottesman-Kitaev-Preskill (GKP) codes are known to achieve optimal rates under displacement noise and pure-loss channels, which establishes theoretical foundations for its optimality. However, such optimal rates are only known to be achieved at a discrete set of noise strengths with the current self-dual symplectic lattice construction. In this work, we develop a new coding strategy using concatenated continuous variable-discrete variable encodings to go beyond past results and establish GKP’s optimal rate over all noise strengths. In particular, for displacement noise, the rate is obtained through a constructive approach by concatenating GKP codes with a quantum polar code and analog decoding. For a pure-loss channel, we prove the existence of capacity-achieving GKP codes through a random coding approach. These results highlight the capability of concatenation-based GKP codes and provides new methods for constructing good GKP lattices.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC

Application of a Physics-Informed Convolutional Neural Network for Monitoring the Temperature Fields in High-Temperature Gas Reactors

Here, this work presents current advances in applying a physics-informed convolutional neural network (CNN) to evaluate temperature distributions in advanced reactors. Our goal is to demonstrate that the CNN can reconstruct temperature fields within the solid region of a prismatic fuel assembly in a high-temperature gas reactor (HTGR) with sensor data available in only a few cooling channels. Before that, we showcase the superior performance of the physics-informed CNN in comparison to a purely data-driven multilayer perceptron (MLP), considering a canonical heated channel setup. This analysis shows the advantages of our approach and justifies its choice. The datasets employed here are obtained upon numerical simulations performed with codes under the Nuclear Energy Advanced Modeling and Simulation program. This work is important, as industry experience indicates that the assembly material in HTGR concepts is prone to large thermal-mechanical loads nearing operational limits. This makes it crucial to characterize peak temperatures and their distributions near hot spots. Modern thermocouples are unreliable in these types of harsh environments because of the high neutron fluxes and elevated temperatures involved. The CNN-based field reconstruction represents an attractive solution, enabling sensor arrays in less aggressive locations and augmenting indirect predictions for less accessible regions. The results show that the CNN reduces prediction errors by orders of magnitude in comparison to the MLP, considering the simple yet well-representative heated channel case. In the case of the HTGR fuel assembly, the CNN can successfully reconstruct temperature fields over various cooling regimes. Furthermore, we also explore the algorithm’s ability to detect abnormalities. Interestingly, the CNN proves it has the capacity to detect blockage in one of the noninstrumented cooling channels.

Machine learning

Refractory-based thermal energy storage for industrial process heat: one-dimensional modeling, control, and optimization

The variable and weather-dependent output of wind and solar power plants present a substantial challenge for planning and operating electricity-systems, particularly in the absence of cost-effective and dispatchable energy storage technologies. This study investigates a high-temperature, electrically heated, refractory-based thermal energy storage (RTES) system that stores electrical energy as sensible heat in dense ceramic bricks over the 950–1800 °C range. The stored heat can be discharged as a controlled hot-gas stream for industrial heating, fuel substitution in high-temperature processes, or electricity generation. The main novelty is a comprehensive modelling, control, mapping, and optimization framework that integrates one-dimensional transient gas–solid heat transfer, fan-assisted discharge, bypass-flow regulation, reheating logic, fan-power evaluation, insulation-loss assessment, and genetic-algorithm-based design optimization. The model uses feedback from outlet temperature and delivered power to regulate discharge, while a two-stage genetic algorithm optimizes brick-channel geometry, gas-flow operation, and multilayer insulation thicknesses. Storage capacities below 50 MWh and discharge powers of 5–30 MW are analyzed to evaluate hold time, thermal delivery, fan-power penalty, heat loss, state-of-charge evolution, and indicative capital cost. Results demonstrate that optimized and well-insulated refractory-based thermal energy storage units can provide stable, efficient, and repeatable heat delivery over multiple discharge cycles. The generated performance and cost maps support modular refractory thermal energy storage as a practical option for large-scale integration of wind and solar generation and for high-temperature industrial process heat.

25 ENERGY STORAGE

Optimizing Transportation Networks for E-Waste Reverse Logistics: A Multi-Modal Cost Allocation and Pricing Strategy

The exponential growth of electronic waste (e-waste) poses critical challenges for sustainable reverse logistics and transportation network optimization. This study develops a dual-channel transportation framework for e-waste logistics that integrates dynamic freight pricing, cost allocation mechanisms, and game-theoretic coordination. The model captures interactions between centralized hubs and distributed processing networks, accounting for freight rate elasticity, volume allocation, and capacity constraints. Using Stackelberg game theory and cost-sharing strategies, the framework optimizes transportation efficiency and profit distribution across logistics channels. Numerical simulations show that the dual-channel structure increases centralized hub profit by 226.8% compared to baseline single-channel operations, while boosting total transported volume by 1.2% and nearly doubling freight collector profit under cost-sharing. Scenario analyses across regional infrastructures reveal that network density, policy incentives, and logistics costs shape routing efficiency and profit allocation. These findings suggest that coordinated strategies combining dynamic pricing, targeted infrastructure investment, and strategic cost allocation are needed to design efficient, resilient, and regionally adaptable e-waste transportation systems.

29 ENERGY PLANNING, POLICY, AND ECONOMY

Testbed and Experiments for Quantum-Conventional Networking

The realization of quantum networks requires the development of devices and methods unprecedented in conventional networks, and yet they critically depend on the latter for implementing foundational blocks and essential operations. We describe a testbed to support the development and testing of their functionality and performance by providing quantum and conventional data planes and devices, together with a secure conventional control plane. It incorporates a variety of entangled photon sources, qubit technologies, detector technologies, photonic components, and supporting conventional switches and workstations. It implements a novel fiber telescoping scheme that provides suites of connections using fiber spools and inground-aerial fiber loops. We briefly summarize a variety of experiments conducted over this testbed including: (i) flex-grid quantum connection experiments, (ii) quantum state and channel tomography, (iii) utilization of quantum key distribution keys to secure conventional encryption and firewall devices, (iv) comparative study of analytical capacity estimates and entanglement throughput, (v) deployed squeezing coexisting with conventional communications, and (iv) measurement of polarization time variation.

Rao, Nageswara [ORNL] (ORCID:0000000234085941)

Tuning Cation (Dis)Order in Cr‐Based Li‐Excess Oxide Cathode Materials to Improve Li+ Transport Properties

Abstract Li‐excess disordered rocksalts (DRXs) hold promise as next‐generation cathodes for Li‐ion batteries due to their high capacity and energy density, along with the potential to eliminate the need for Co and Ni. However, due to their low Li + diffusivity, DRXs need to be pulverized into nanoparticles to achieve high performance. Herein, a new strategy for overcoming this limitation is demonstrated, involving the design of as‐synthesized partially disordered oxides with a structure that lies between ordered layered and fully disordered, exhibiting a varying degree of local (dis)order. This unique structure activates new Li + diffusion channels, improving percolation and transport properties. This strategy allows a large content of Li + to be accessed in material with large, micron‐sized particles through highly reversible Cr 3+/6+ and O redox, yielding a first discharge capacity of 286 mAh g −1 (881 Wh kg −1 ). The Li + percolation network is further improved by substituting Ti with a mixture of multiple metals, which appears to locally decrease the migration barrier through lattice distortion. Proper tuning of the chemical composition, especially the content of metals with empty d orbitals, is established as a crucial factor for controlling the degree of disorder and mitigating voltage fade and hysteresis growth upon cycling.

Moździerz, Maciej

Disordered Rocksalts as High‐Energy and Earth‐Abundant Li‐Ion Cathodes

To address the growing demand for energy and support the shift toward transportation electrification and intermittent renewable energy, there is an urgent need for low‐cost, energy‐dense electrical storage. Research on Li‐ion electrode materials has predominantly focused on ordered materials with well‐defined lithium diffusion channels, limiting cathode design to resource‐constrained Ni‐ and Co‐based oxides and lower‐energy polyanion compounds. Recently, disordered rocksalts with lithium excess (DRX) have demonstrated high capacity and energy density when lithium excess and/or local ordering allow statistical percolation of lithium sites through the structure. This cation disorder can be induced by high temperature synthesis or mechanochemical synthesis methods for a broad range of compositions. DRX oxides and oxyfluorides containing Earth‐abundant transition metals have been prepared using various synthesis routes, including solid‐state, molten‐salt, and sol‐gel reactions. This review outlines DRX design principles and explains the effect of synthesis conditions on cation disorder and short‐range cation ordering (SRO), which determines the cycling stability and rate capability. In addition, strategies to enhance Li transport and capacity retention with Mn‐rich DRX possessing partial spinel‐like ordering are discussed. Finally, the review considers the optimization of carbon and electrolyte in DRX materials and addresses key challenges and opportunities for commercializing DRX cathodes.

Li-ion batteries

Catalytic disproportionation on carbon superstructures enables long-life, high-loading Li–S batteries

Electrocatalysis has been widely explored as an effective strategy to accelerate polysulfide (PS) conversion and suppress the shuttle effect in lithium–sulfur (Li–S) batteries. However, the underlying mechanisms remain elusive, and electrocatalytic reactions are inactive during cell resting. In this work, we reveal and quantitatively analyze a previously unrecognized sulfur reduction route (SRR) driven by catalytic disproportionation at the carbon cathode surface—fundamentally distinct from conventional electrocatalysis. Unlike conventional stepwise pathways, this SRR enables high-order polysulfides (Sₓ²⁻, x = 5–8) to directly convert into S₈ and Li₂S₂, bypassing low-order intermediates. This sulfur-reduction shortcut is systematically elucidated through high-performance liquid chromatography, revealing the intrinsic catalytic contribution of carbon frameworks and the dynamic evolution of PS species. We demonstrate that carbon superstructures (CSS-0.5), assembled from nanosheet subunits with abundant N/O functionalities and interconnected charge-migration channels, synergistically promote this catalytic process. Benefiting from these features, CSS-0.5 delivers superior electrochemical performance under practical conditions, enabling high sulfur loading (6.0 mg cm⁻²) pouch cells with 80.5% capacity retention over 210 cycles. This study provides the first quantitative evidence of electrocatalytic disproportionation in Li–S batteries, offering mechanistic insights and design principles for advanced sulfur cathodes.

25 ENERGY STORAGE

Effect of Sulfonation Level on the Percolated Morphology and Proton Conductivity of Hydrated Fluorine-Free Copolymers: Experiments and Simulations

Using all-atom molecular dynamics simulations and a variety of experimental methods, we previously reported on a linear polyethylene with pendant phenyl sulfonated groups precisely on every fifth carbon along the backbone. With increasing relative humidity this fluorine-free polymer self-assembled to form nanoscale water channels and exhibited exceptional proton conductivity. Expanding upon those findings, here we explore partially sulfonated random copolymers, referred to as p 5PhSH-Y. Using either acetyl sulfate or sulfuric acid, a wide range of sulfonation levels were prepared ( Y = 34−98%) corresponding to ion-exchange capacities (IEC) of 2.0−4.4 mmol/g. Combining experimental techniques and all-atom molecular dynamics simulations, we study the effect of Y on water uptake, nanoscale morphology, and the proton/water transport properties of p5PhSH- Y . The proton conductivity of p 5PhSH- Y increases with relative humidity and with Y and achieves values in excess of 0.1 S/cm. These high conductivities are attributed to high IEC and welldeveloped nanoscale percolated hydrophilic domains made possible by the flexible backbone. We quantitatively describe the nature of the water channels using the characteristic distance, channel width distribution, the area per sulfonate group at the hydrophilic/ hydrophobic interface, and the fractal dimension. Notably, the channel widths and the areas per sulfonate group are nominally independent of the level of sulfonation, while depending significantly on the level of hydration. The fractal dimension of the water channels correlates strongly with the water diffusion coefficients calculated from the molecular dynamics (MD) simulations. These findings demonstrate that the p 5PhSH- Y hydrocarbon copolymers can be modified to tune properties, particularly proton conductivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Kinetic Monte Carlo Framework for Coupled Degradation and Dehydration of Anion Exchange Membranes

Kinetic Monte Carlo (kMC) simulations, augmented with temporal-acceleration schemes, can efficiently handle stiff reaction-transport networks when fast processes rapidly relax to quasi-equilibrium on a fixed lattice. However, in glassy anion-exchange membranes (AEM), rare and irreversible chemical degradation events continuously reshape the nanoscale morphology, and the associated hydration and transport degrees of freedom remain far from a well-defined local equilibrium. This combination of evolving state space and nonequilibrated fast dynamics lies outside the scope of existing kMC acceleration frameworks. Here, to address this challenge, we introduce an auxiliary-particle kinetic Monte Carlo (AP-kMC) scheme. In AP-kMC, short-lived mobile particles spawned at degradation sites execute hop, water-elimination, and decay moves, enforcing rapid local relaxation of the hydration structure while preserving the stochastic rules of kMC. Parameterized with molecular-dynamics morphologies and experimental solution degradation kinetics, AP-kMC reproduces the evolution of ion-exchange capacity, water uptake, and conductivity, and reveals a feedback loop in which poorly hydrated sites degrade first and each degradation event induces further local dehydration. The resulting thinning and fragmentation of water channels cause loss of hydrophilic percolation and abrupt conductivity collapse well before complete charge loss. AP-kMC thus reframes AEM durability as a coupled degradation–drying–percolation problem and provides a transferable strategy to simulate reactive, out-of-equilibrium polymer electrolytes where local solvation controls reactivity.

organic

Optimizing Non-Terrestrial Hybrid RF/FSO Links With Reinforcement Learning: Navigating Through Clouds

In the pursuit of ubiquitous broadband connectivity, there has been a significant shift towards the vertical expansion of communication networks into space, particularly through the exploitation of low Earth orbit (LEO) satellite constellations, which are favored for their relatively low latency. However, this approach faces many challenges that need to be addressed, including atmospheric turbulence, high path loss, and dynamic cloud formations. High-altitude pseudo-satellites (HAPS) have emerged as promising relaying layers between LEO satellites and ground stations, enhancing coverage, latency, and direct terrestrial user connectivity. While radio frequency (RF) bands suffer from congestion and limited bandwidth, free space optical (FSO) communications offer higher data rates, but are susceptible to misalignment and weather-induced signal degradation. To address these challenges, a hybrid RF/FSO approach has been proposed to take advantage of both technologies by dynamic switching between RF and FSO based on propagation channel conditions. This paper introduces a reinforcement learning-based algorithm designed to optimize the trajectory of HAPS, maneuver around cloudy areas, and seamlessly switch between the RF and FSO communication modes to maximize the achievable capacity. The proposed approach aims to maximize system performance by intelligently adapting to environmental conditions and offering a promising solution for next-generation space communication networks.

actor-critic algorithm