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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Effects of Channel Implant Variation on Radiation-Induced Edge Leakage Currents in n-Channel MOSFETs

The effects of radiation-induced defects and statistical variation in the dose and energy of MOSFET channel implants in a modern bulk CMOS technology are modeled using a process simulator in combination with analytical computations. The model integrates doping profiles obtained from process simulations and experimentally determined defect potentials into implicit surface potential equations. Solutions to these equations are then used to model radiation-induced edge leakage currents in 90-nm bulk CMOS n-channel MOSFETs. The results indicate that slight variations in the channel implant parameters can have a significant impact on the doping profile along the shallow trench isolation sidewall and thus the radiation-induced edge leakage currents.

42 ENGINEERING↗
DOE OSTI2014

A Proton Channel Allows a Hydrogen Oxidation Catalyst to Operate at a Moderate Overpotential with Water Acting as a Base

Proton channels facilitate the movement of protons over large distances and are critical in many reactions, from controlling proton delivery in metalloenzymes[1] to moving protons through PEM fuel cells.[2] Hydrogenases are enzymes that use proton channels to deliver protons to or from the enzyme active site to achieve high rates of hydrogen production and oxidation at low overpotentials.[3] The [Ni(PR2NR’2)2]2+ series of complexes, which are functional mimics of the [FeFe]-hydrogenase active site, utilize pendant amines to move the proton to or from the Ni, resulting in some of the fastest synthetic catalysts for hydrogen production and oxidation reported.[4] While intramolecular proton movement has been shown to be facile,[5] deprotonation of hydrogen oxidation catalysts can be a slow step for catalysis.[6] Additionally, a stable H2 adduct (endo-endo) is formed which, if bypassed, could contribute to an overall enhanced rate (Figure 1). A proton channel may aid in addressing these outstanding issues, and the well-studied nature of these catalysts allows them to serve as a platform to investigate the role of a proton channel in solving these problems. To this end we added a second proton relay to this complex, which we demonstrate serves two purposes: we show that the second proton relay facilitates rapid proton transfer, altering the kinetic products formed following H2 addition, and avoiding the low energy endo-endo intermediate. It also aids in lowering the overpotential at which the catalyst operates using water as a base, demonstrating the multi-functional role of a proton channel in molecular catalysts, and possibly in enzymes. This work was supported by the US Department of Energy, Early Career Research Program, Basic Energy Sciences, Chemical Sciences, Geosciences & Biosciences Division and by the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

amino acid catalysts↗
DOE OSTI2017

Measurement of the inclusive cross-sections of single top-quark and top-antiquark t-channel production in pp collisions at $ \sqrt{s}=13 $ TeV with the ATLAS detector

A measurement of the t-channel single-top-quark and single-top-antiquark production cross-sections in the lepton+jets channel is presented, using 3.2 fb –1 of proton-proton collision data at a centre-of-mass energy of 13 TeV, recorded with the ATLAS detector at the LHC in 2015. Events are selected by requiring one charged lepton (electron or muon), missing transverse momentum, and two jets with high transverse momentum, exactly one of which is required to be b-tagged. Using a binned maximum-likelihood fit to the discriminant distribution of a neural network, the cross-sections are determined to be σ(tq) = 156 ± 5 (stat.) ± 27 (syst.) ± 3 (lumi.) pb for single top-quark production and σ(t¯q)=91±4 (stat.) ± 18 (syst.) ± 2 (lumi.) pb for single top-antiquark production, assuming a top-quark mass of 172.5 GeV. The cross-section ratio is measured to be R t = σ(tq)/σ(t¯q)=1.72±0.09 (stat.) ± 0.18 (syst.). All results are in agreement with Standard Model predictions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2018

A Simple and Portable Multi-Channel Pyrometer allowing temperature measurements down to 800 K on the microsecond scale

The measurement of transient temperatures less than 1000 K for samples in laser-heated diamond anvil cells remains a challenge. Here we present a design and performance characteristics for a multi-channel pyrometer that works in the NIR from 1200 to 2000 nm. It has a relatively small footprint, is portable, only requires low voltage power supplies and can report temperatures down to 800 K on the millisecond scale or faster. A single data point without averaging can be acquired in 14 microseconds (sampling rate of 70'000 times/s). In conjunction with a diamond anvil cell, the system still works down to about 830 K. The pyrometer has been interfaced several times with the laser heating system at the High Pressure Collaborative Access Team (HPCAT) at the Advanced Photon Source in Chicago with good results.

Montgomery, Jeffrey M.↗
DOE OSTI2014

Process tomography for unitary quantum channels

We study the number of measurements required for quantum process tomography under prior information, such as a promise that the unknown channel is unitary. We introduce the notion of an interactive observable and we show that any unitary channel acting on a d-level quantum system can be uniquely identified among all other channels (unitary or otherwise) with only O(d{sup 2}) interactive observables, as opposed to the O(d{sup 4}) required for tomography of arbitrary channels. This result generalizes to the problem of identifying channels with at most q Kraus operators, and slight improvements can be obtained if we wish to identify such a channel only among unital channels or among other channels with q Kraus operators. These results are proven via explicit construction of large subspaces of Hermitian matrices with various conditions on rank, eigenvalues, and partial trace. Our constructions are built upon various forms of totally nonsingular matrices.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2019

Measurements of gluon–gluon fusion and vector-boson fusion Higgs boson production cross-sections in the H → WW ∗ → eνμν decay channel in pp collisions at s = 13 TeV with the ATLAS detector

Higgs boson production cross-sections in proton–proton collisions are measured in the H → WW ∗ → eνμν decay channel. The proton–proton collision data were produced at the Large Hadron Collider at a centre-of-mass energy of 13 TeV and recorded by the ATLAS detector in 2015 and 2016, corresponding to an integrated luminosity of 36.1fb -1 . The product of the H→WW ∗ branching fraction times the gluon–gluon fusion and vector-boson fusion cross-sections are measured to be 11.4$_{-1.1}^{+1.2}$(stat.)$_{-1.7}^{+1.8}$(syst.) pb and 0.50$_{-0.22}^{+0.24}$(stat.)±0.17(syst.) pb, respectively, in agreement with Standard Model predictions.

Aaboud, M.↗
DOE OSTI2017

Strain-free polished channel-cut crystal monochromators: a new approach and results

The use of channel-cut crystal monochromators has been traditionally limited to applications that can tolerate the rough surface quality from wet etching without polishing. We have previously presented and discussed the motivation for producing channel cut crystals with strain-free polished surfaces [1]. Afterwards, we have undertaken an effort to design and implement an automated machine for polishing channel-cut crystals. The initial effort led to inefficient results. Since then, we conceptualized, designed, and implemented a new version of the channel-cut polishing machine, now called C-CHiRP (Channel-Cut High Resolution Polisher), also known as CCPM V2.0. The new machine design no longer utilizes Figure-8 motion that mimics manual polishing. Instead, the polishing is achieved by a combination of rotary and linear functions of two coordinated motion systems. Here we present the new design of C-CHiRP, its capabilities and features. Multiple channel-cut crystals polished using the C-CHiRP have been deployed into several beamlines at the Advanced Photon Source (APS). We present the measurements of surface finish, flatness, as well as topography results obtained at 1-BM of APS, as compared with results typically achieved when polishing flat-surface monochromator crystals using conventional polishing processes. Limitations of the current machine design, capabilities and considerations for strain-free polishing of highly complex crystals are also discussed, together with an outlook for future developments and improvements.

Kasman, Elina↗
DOE OSTI2013

Control of focusing forces and emittances in plasma-based accelerators using near-hollow plasma channels

A near-hollow plasma channel, where the plasma density in the channel is much less than the plasma density in the walls, is proposed to provide independent control over the focusing and accelerating forces in a plasma accelerator. In this geometry the low density in the channel contributes to the focusing forces, while the accelerating fields are determined by the high density in the channel walls. The channel also provides guiding for intense laser pulses used for wakefield excitation. Both electron and positron beams can be accelerated in a nearly symmetric fashion. Near-hollow plasma channels can effectively mitigate emittance growth due to Coulomb scattering for high-energy physics applications.

43 PARTICLE ACCELERATORS↗
DOE OSTI2020

Kv2.1 channels play opposing roles in regulating membrane potential, Ca 2+ channel function, and myogenic tone in arterial smooth muscle

The accepted role of the protein Kv2.1 in arterial smooth muscle cells is to form K + channels in the sarcolemma. Opening of Kv2.1 channels causes membrane hyperpolarization, which decreases the activity of L-type Ca V 1.2 channels, lowering intracellular Ca 2+ ([Ca 2+ ] i ) and causing smooth muscle relaxation. A limitation of this model is that it is based exclusively on data from male arterial myocytes. Here, we used a combination of electrophysiology as well as imaging approaches to investigate the role of Kv2.1 channels in male and female arterial myocytes. We confirmed that Kv2.1 plays a canonical conductive role but found it also has a structural role in arterial myocytes to enhance clustering of Ca V 1.2 channels. Less than 1% of Kv2.1 channels are conductive and induce membrane hyperpolarization. Paradoxically, by enhancing the structural clustering and probability of Ca V 1.2–Ca V 1.2 interactions within these clusters, Kv2.1 increases Ca 2+ influx. These functional impacts of Kv2.1 depend on its level of expression, which varies with sex. In female myocytes, where expression of Kv2.1 protein is higher than in male myocytes, Kv2.1 has conductive and structural roles. Female myocytes have larger Ca V 1.2 clusters, larger [Ca 2+ ] i , and larger myogenic tone than male myocytes. In contrast, in male myocytes, Kv2.1 channels regulate membrane potential but not Ca V 1.2 channel clustering. We propose a model in which Kv2.1 function varies with sex: in males, Kv2.1 channels control membrane potential but, in female myocytes, Kv2.1 plays dual electrical and Ca V 1.2 clustering roles. This contributes to sex-specific regulation of excitability, [Ca 2+ ] i , and myogenic tone in arterial myocytes.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2014

Secondary channels in the thermal decomposition of monomethylhydrazine (CH 3 NHNH 2 )

Mass spectrometric observations in a very low pressure pyrolysis study of the decomposition of the prototypical rocket fuel monomethylhydrazine (MMH) indicated a dominant role for the molecular channels producing NH 3 and H 2 and their coproducts. In contrast, a recent ab initio transition state theory based master equation theoretical study indicated that simple N–N and C–N bond fissions dominate the kinetics. In this work, the possible role of molecular decomposition channels in MMH is explored further through additional investigations of the potential energy surface. These investigations consider the role of triplet channels, of roaming radical channels, and of some previously unexplored pathways for molecular decomposition. New ab initio transition state theory based master equation calculations provide revised predictions for the temperature and pressure dependence of the MMH decomposition kinetics that are in excellent agreement with recent shock tube measurements. These calculations continue to suggest only a very limited contribution from the molecular elimination channels. A roaming pathway is suggested to provide the dominant route for direct formation of ammonia. The possible role of secondary abstraction reactions in the very-low-pressure pyrolysis experiments is briefly discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Structure and band gap determination of irradiation-induced amorphous nano-channels in LiNbO{sub 3}

The irradiation of lithium niobate with swift heavy ions results in the creation of amorphous nano-sized channels along the incident ion path. These nano-channels are on the order of a hundred microns in length and could be useful for photonic applications. However, there are two major challenges in these nano-channels characterization: (i) it is difficult to investigate the structural characteristics of these nano-channels due to their very long length and (ii) the analytical electron microscopic analysis of individual ion track is complicated due to electron beam sensitive nature of lithium niobate. Here, we report the first high resolution microscopic characterization of these amorphous nano-channels, widely known as ion-tracks, by direct imaging them at different depths in the material, and subsequently correlating the key characteristics with electronic energy loss of ions. Energetic Kr ions ({sup 84}Kr{sup 22} with 1.98 GeV energy) are used to irradiate single crystal lithium niobate with a fluence of 2 × 10{sup 10} ions/cm{sup 2}, which results in the formation of individual ion tracks with a penetration depth of ∼180 μm. Along the ion path, electron energy loss of the ions, which is responsible for creating the ion tracks, increases with depth under these conditions in LiNbO{sub 3}, resulting in increases in track diameter of a factor of ∼2 with depth. This diameter increase with electronic energy loss is consistent with predictions of the inelastic thermal spike model. We also show a new method to measure the band gap in individual ion track by using electron energy-loss spectroscopy.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2022

Investigation of Gas Turbine Internal Cooling Using Supercritical CO 2 —Effect of Surface Roughness and Channel Aspect Ratio

In this paper, an experimental and numerical investigation of internal cooling channels with rib turbulators is presented with sCO 2 as the working fluid at process conditions (pressure-20.7 MPa and temperature up to 150 °C). The effect of channel aspect ratio up to 2:1 on thermal-hydraulic performance is explored in additively manufactured rectangular channels and square channels, both with and without 60 deg ribs on the top and bottom sides. The Wilson-plot method is employed to experimentally measure channel-averaged Nusselt number over a Reynolds number range up to 370,000. The friction factor is calculated from pressure drop and mass flow rate and additionally, the overall thermal performance factor (TPF) is reported. A companion computational fluid dynamics (CFD) simulation is performed for the rib turbulated cooling configurations reported in the experiments using the Reynolds average Navier–Stokes-based turbulence model. The objective of the numerical study is to gain insight into the local heat transfer augmentation in the ribbed channels as a result of varying the aspect ratio, channel configuration (square versus rectangular), operating conditions (Reynolds number) and the surface roughness, an inherent outcome of the additive manufacturing process. Surface roughness is simulated using sand grain roughness height (K S ) calculated from the experimental data, and a comparison is presented with the corresponding channel configuration with varying surface roughness heights starting from smooth surfaces (K S = 0). Experimental results indicate that the heat transfer augmentation is negligible in the rectangular channels with ribs on the long side compared to the square channel. However, it is enhanced by 60% in comparison to placing ribs on the shorter side. The TPF remains constant at around 1 for the entire range of Reynolds numbers consistent with prior work at the National Energy Technology Laboratory (NETL). Here, the simulation results highlight that increased surface roughness can have a favorable considerable influence on Nusselt number and overall thermal performance enhancement.

42 ENGINEERING↗
DOE OSTI2019

Fish community response to in-channel woody debris in a channelized river system

Additions of large wood (LW) have become a go-to technique for recovering altered river ecosystems. However, successful applications of this technique are generally limited to unchannelized rivers and headwater streams. Channelization of rivers, that is, engineering river channels to reduce recruitment and retention of in-channel structure, may, by definition, limit success of this restoration technique. Moreover, sufficient time has passed (a century or more) since initial channelization of many large rivers that portions of the fish community associated with LW may have become extirpated. Thus, the maxim that LW leads to a positive fish community response may not hold true. We examined fish community associations in habitats with and without LW in the channelized Missouri River to gain an understanding of the role of LW in large, channelized rivers. There were some differences between habitats with wood present compared to those without, but the differences were not evident once year, season and channel modifications intended to create aquatic habitat were taken into account. We assert that careful planning is necessary to ensure that additions of LW in channelized rivers are made to appropriate locations such that it will be retained in-channel for use as fish habitat and that LW-associated species are found in the system.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1991

Design of a communications system for multiple telemetry data channels operating simultaneously with a coherent turn-around ranging channel

This paper presents a simple technique to design a phase-modulated residual carrier communications link for optimum performance. The emphasis is on two data channels which are operated simultaneously with a ranging signal. The data channels employ PCM/PM and PCM/PSK/PM modulation schemes for high and low data rate channels, respectively. The technique proposed here selects the optimum (1) subcarrier frequency to minimize the interference between the two data channels, and (2) modulation indices for optimum balance of power between the two telemetry data channels and the coherent turn around ranging channel. The selected set of optimum modulation indices will allow for the specified bit error rate (BER) degradations in the two data channels. Although this technique is proposed to optimize the performance degradation for two data channels, generalizations can be made for more than two data channels.

Nguyen, Tien M.↗
DOE OSTI2022

The channel-source hypothesis: Empirical evidence for in-channel sourcing of dissolved organic carbon to explain hysteresis in a headwater mountain stream

Catchment hydrologists have long puzzled over the question: How can catchments rapidly generate storm flows and pulses of solutes in response to storm events? Conceptual models viewing catchments as composed of discrete source areas generating flow at unique time scales and with unique chemical characteristics have been used to explain the observed changes in flow and water chemistry. Surprisingly, those conceptual models usually do not treat the stream channel as one of the potential source areas. We propose the channel-source hypothesis in which the stream itself should be considered as a potential source with the same rigour as other contributing areas. We pose this in the spirit of the scientific use of the word: a hypothesis is not a proven idea but rather a provisional supposition serving as the basis for further study. We suggest that the channel should be considered as a potential source for dissolved organic carbon (DOC). Channels store substantial amounts of organic matter, and stream ecologists have long studied stream carbon cycling. From those studies, we know that leaching and decomposition can generate DOC from particulate organic carbon (POC). Further, POC is stored in channel ‘dead-zones’—regions of low flow velocity - that can be activated as flow velocity increases, thus releasing accumulated DOC during storms. All catchments are different; there is no reason to assume that channel sources are always important, in every catchment, in every storm. Thus, the channel-source hypothesis does not replace existing conceptual models. Instead, it adds another potential mechanism that may explain DOC dynamics observed in streams. The channel-source hypothesis has substantial implications for catchment studies examining sources of DOC in stream water or using DOC as a tracer to determine the locations of, and proportional contributions of, different source areas for streamflow generation.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2013

Arbitrarily small amounts of correlation for arbitrarily varying quantum channels

As our main result show that in order to achieve the randomness assisted message and entanglement transmission capacities of a finite arbitrarily varying quantum channel it is not necessary that sender and receiver share (asymptotically perfect) common randomness. Rather, it is sufficient that they each have access to an unlimited amount of uses of one part of a correlated bipartite source. This access might be restricted to an arbitrary small (nonzero) fraction per channel use, without changing the main result. We investigate the notion of common randomness. It turns out that this is a very costly resource – generically, it cannot be obtained just by local processing of a bipartite source. This result underlines the importance of our main result. Also, the asymptotic equivalence of the maximal- and average error criterion for classical message transmission over finite arbitrarily varying quantum channels is proven. At last, we prove a simplified symmetrizability condition for finite arbitrarily varying quantum channels.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗