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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Peculiarities of Magnetic States of Iron-Cobalt Coatings Formed on Aluminum by Plasma Electrolytic Oxidation

Ferromagnetic oxide coatings were formed on aluminum alloy by the plasma-electrolytic oxidation technique in an electrolyte with colloidal particles of iron and cobalt hydroxides. Iron and cobalt are concentrated in the coating pores as a part of nanosized crystallites. The size of individual crystallites in the pores was ∼50–100 nm. The deficit of oxygen to form oxides in crystallites shows that the metals in the crystallites are predominantly in a reduced state. It is also possible that the metal or oxide nuclei are surrounded by oxide-hydroxide shells. The coatings obtained within 5 min have a high coercive force H{sub c} = 1300 Oe. A theoretical analysis of the magnetic properties of Fe-, Co-containing coatings has been performed using the model of clusters consisting of magnetostatically interacting particles. The theoretical value of the saturation magnetization and the experimental values of the coercive force can be explained with the presence of two phases in the nanoparticles: a large antiferromagnetic or ferromagnetic (hydroxides and/or oxides of iron and cobalt) and a small superparamagnetic (iron, cobalt, magnetite, maghemite).

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Inter-grain interaction in random magnetic anisotropy simulation in magnetic nanocrystals

Effect of inter-grain exchange interaction on the coercive forces was analyzed with a numerical simulation in magnetic materials with random magnetic anisotropy. The magnetization of an assembly of magnetically interacting grains with randomly oriented uniaxial anisotropy was calculated using the Landau-Lifshitz-Gilbert equation. We supposed a single spin model where the magnetizations in a grain were aligned in the same direction, for simplicity. Calculations were carried out for an N×N×N system, where the number of grains on a side, N ranged from 16 to 128. The relation between the coercive forces H{sub C} and the grain size D is represented by H{sub C}∝D{sup k}. With the increase of N, k decreased gradually and tended to reach a saturated value around k = 4.5–5, which dose not correspond to the primitive theory of the random anisotropy model where k = 6. The deviation was discussed in terms of the inter-grain interaction, essentially proportional to the inverse of D.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2019

Template Synthesis, Structure, and Magnetic Properties of Layered Nanowires

Nanowires (NWs) consisting of Ni/Cu and Co/Cu alternating layers with a diameter of 100 nm and layer thicknesses varying between 10 and 500 nm are prepared by template synthesis in pores of polymer track-etched membranes. Bath compositions and different regimes for pulsed electrodeposition of NWs are explored. A procedure for electrodeposition of NWs using pulses of equal charge is developed. By diminishing the amount of charge per pulse, initially we manage to lower the layer thickness to 10–15 nm, but further diminishing of charge in pulses leads to the blending of elemental composition of adjacent layers and/or formation of rod–shell nanostructures within the NWs. The coercive force (15–30 mT) and residual magnetization of our layered NWs are determined from magnetization measurements. For NWs with a layer thickness of 50–100 nm, the magnetization curves recorded in the out-of-plane and in-plane geometries are similar in shape and have similar parameters. For NWs with thicker layers (250 and 500 nm), magnetization curves are markedly different due to magnetic anisotropy (an easy magnetization axis emerges longitudinally to NWs) and interference between neighboring NWs. Magnetic force microscopy of isolated NWs identifies that the NWs comprise magnetic regions extending over ~100–150 nm. The NW can be partially remagnetized by applying an external magnetic field (+16 mT) longitudinally.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2019

Modification of Magnetic Properties of a CoPt Alloy by Ion Irradiation

The effect of ion irradiation on magnetic properties of films of the ferromagnetic CoPt alloy fabricated by electron-beam evaporation has been studied. It is found that the coercive force decreases and the lateral component of the easy-magnetization axis increases as the He{sup +} ion fluence increases from 1 × 10{sup 13} to 1 × 10{sup 16} cm{sup –2}. It is shown by magnetic-force microscopy and the Mandelstam–Brillouin spectroscopy that the formation of isolated circle domains which are magnetic skirmions in the CoPt layer is activated at certain ion-irradiation fluence (3 × 10{sup 14} cm{sup –2}).

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Control over the Magnetic Properties of Co/Pt-based Multilayered Periodical Structures

The possibility of controlling the magnetic properties of multilayered periodical structures with perpendicular magnetic anisotropy, which are based on cobalt and platinum films, have been studied. The multilayered films composed by layers with a thickness of 0.5–1.0 nm were subjected to two types of actions: vacuum annealing at different temperatures and irradiation by helium ion beams. Transmission electron microscopy has shown that the irradiation by He{sup +} ions with energy of 30 keV leads to material mixing in the layers since at vacuum annealing the layered structure of films is kept. In this case, as a result of thermal annealing, the coercive force of the structure increases significantly, and upon irradiation with helium ions, the coercivity of the films decreases to a change in the type of anisotropy from perpendicular to “easy plane” anisotropy.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Effect of calcination temperature on microstructure and magnetic properties of Ni{sub 0.5}Zn{sub 0.25}Cu{sub 0.25} Fe{sub 2}O{sub 4} nanoparticles synthesized by sol-gel method

This paper examines the effect of calcination process on the structural and magnetic properties material nanostructure composite of Ni{sub 0Ð}œ‡{sub 5}Zn{sub 0Ð}œ‡{sub 25}Cu{sub 0.25} Fe{sub 2}O{sub 4} ferrites. The samples were successfully prepared by sol-gel method at different calcination temperature, which are 600°C, 700°C, 800°C and 900°C. Morphological investigation, average crystallite size and microstructure of the material were examined by using X-ray diffraction (XRD) and confirmed by high resolution transmission electron microscope (HRTEM) and field emission scanning electron microscope (FESEM). The effects of calcination temperature on the magnetic properties were calculated by using vibrating sample magnetometer (VSM). The XRD result shows single-phase cubic spinel structure with interval average size 5.9-38 nm, and grain size microstructure of the material was increasing with temperature increases. The highest magnetization saturation was reached at a temperature 800°C with value 53.89 emu/g, and the value coercive force (Hc) was inversely with the grain size.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2017

Micromagnetism in a planar system with a random magnetic anisotropy and two-dimensional magnetic correlations

The hysteresis loops and the micromagnetic structure of a ferromagnetic nanolayer with a randomly oriented local easy magnetization axis and two-dimensional magnetization correlations are studied using a micromagnetic simulation. The properties and the micromagnetic structure of the nanolayer are determined by the competition between the anisotropy and exchange energies and by the dipole–dipole interaction energy. The magnetic microstructure can be described as an ensemble of stochastic magnetic domains and topological magnetization defects. Dipole–dipole interaction suppresses the formation of topological magnetization defects. The topological defects in the magnetic microstructure can cause a sharper change in the coercive force with the crystallite size than that predicted by the random magnetic anisotropy model.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2018

Synthesis and Magnetic Properties of Fe–Co–Ni/С Nanocomposites

Nanoparticles of the Fe–Co–Ni ternary alloy, encapsulated in the carbon matrix of nanocomposites, have been synthesized, The structure, phase composition, and magnetic properties of the obtained materials have been determined with the help of diffractometry and magnetometry. It has been established that nanoparticles of the ternary alloy are formed due to solution of cobalt in the Fe–Ni alloy. The composition of the nanoparticles of the alloy depends on the mass percent ratio of the metas in the precursor. With growth of the iron content, nanoparticles of the ternary alloy with various composition are formed with FCC and BCC crystal lattice structure. As the synthesis temperature and relative iron content are increased, the magnetization of the Fe–Co–Ni/C nanocomposites increases from 26 to 157 A·m{sup 2}/kg. The coercive force is determined by the synthesis temperature, the size of the nanoparticles, and the composition of the alloy, and its value varies from 330 to 43 Oe.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2015

Synthesis and characterization of CoFe{sub 2}O{sub 4} nanoparticles with high coercivity

Single crystalline CoFe{sub 2}O{sub 4} nanoparticles with high coercivity were prepared via a one-step hydrothermal method. The shape and size of the nanocrystals (in the range of 20–100 nm) can be controlled by varying synthesis parameters such as the concentration of NaOH and CTAB. X-ray diffraction and Raman spectra analysis confirmed that all the as-synthesized nanoparticles have a face centered cubic spinel crystal structure. HRTEM observation of particles shows interlayer spacing 0.48 nm of (111) lattice planes. A coercive force up to 5.0 kOe and saturation magnetization of 73 emu/g was achieved at room temperature for the 40 nm CoFe{sub 2}O{sub 4} nanoparticles.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Structural, magnetic, and electronic properties of iron selenide Fe{sub 6-7}Se{sub 8} nanoparticles obtained by thermal decomposition in high-temperature organic solvents

Iron selenide nanoparticles with the NiAs-like crystal structure were synthesized by thermal decomposition of iron chloride and selenium powder in a high-temperature organic solvent. Depending on the time of the compound processing at 340 °C, the nanocrystals with monoclinic (M)-Fe{sub 3}Se{sub 4} or hexagonal (H)-Fe{sub 7}Se{sub 8} structures as well as a mixture of these two phases can be obtained. The magnetic behavior of the monoclinic and hexagonal phases is very different. The applied-field and temperature dependences of magnetization reveal a complicated transformation between ferrimagnetic (FRM) and antiferromagnetic (AFM) structures, which can be related to the spin rotation process connected with the redistribution of cation vacancies. From XRD and Mössbauer data, the 3c type superstructure of vacancy ordering was found in the hexagonal Fe{sub 7}Se{sub 8}. Redistribution of vacancies in Fe{sub 7}Se{sub 8} from random to ordered leads to the transformation of the magnetic structure from FRM to AFM. The Mössbauer data indicate that vacancies in the monoclinic Fe{sub 3}Se{sub 4} prefer to appear near the Fe{sup 3+} ions and stimulate the magnetic transition with the rotation of the Fe{sup 3+} magnetic moments. Unusually high coercive force H{sub c} was found in both (H) and (M) nanocrystals with the highest (“giant”) value of about 25 kOe in monoclinic Fe{sub 3}Se{sub 4}. This is explained by the strong surface magnetic anisotropy which is essentially larger than the core anisotropy. Such a large coercivity is rare for materials without rare earth or noble metal elements, and the Fe{sub 3}Se{sub 4}-based compounds can be the low-cost, nontoxic alternative materials for advanced magnets. In addition, an unusual effect of “switching” of magnetization in a field of 10 kOe was found in the Fe{sub 3}Se{sub 4} nanoparticles below 280 K, which can be important for applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Combined Technology Fabrication of Spin-Valve Magnetoresistive Elements and Micromagnets

We present the research results of the fabrication technology of magnetoresistive (MR) elements based on the multilayer spin-valve magnetoresistive (SVMR) Ta–FeNiCo–CoFe–Cu–CoFe–FeNiCo–FeMn–Та nanostructures and CoNi micromagnets for the construction of digital galvanic interchanges and the magnetic field sensors. The results of experimental studies of test elements based on multilayer SVMR nanostructures with an MR effect from 7 to 8% and films of magnetically hard materials with a coercive force of up to 95 Oe formed on a single silicon die are presented.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2019

Characteristics of Magnetization Reversal of Magnetostatically Coupled Microwire-Based System

The magnetization reversal process of a system consisted of one Co{sub 67}Fe{sub 3.9}Ni{sub 1.5}B{sub 12.5}Si{sub 14.5}Mo{sub 0.6} and one Fe{sub 74}B{sub 13}Si{sub 11}C{sub 2} microwires was studied. The change of the magnetic characteristics of a system (slope and shape of the hysteresis loop, coercive force) under effect of the neighbor and the length of the system (in the range of 3–20 mm) was considered and analyzed in terms of effective demagnetizing field influence.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Structure and Magnetic Properties of Nanowires of Iron Group Metals Produced by Matrix Synthesis

Abstract—Samples of arrays of nanowires are produced from iron, iron–cobalt and iron–nickel alloys via matrix synthesis based on polymer track membranes with pore diameters ranging from 30 to 300 nm. The influence of stress and pore diameter on the galvanic process and structure of nanowires is studied. The arrays of nanowires are examined by microscopy and X-ray diffraction. The magnetic properties are inspected via magnetometry and Mössbauer spectroscopy. The angular dependences of hysteresis loop shape are obtained and comprehensively discussed. As shown, decreasing the growth stress and/or increasing the pore diameter make the Mössbauer spectra of nanowires similar to those of bulk materials. Furthermore, the higher the growth stress is, the larger is the coercive force of nanowires. For the studied species of nanomaterials, the ability to control the magnetic properties during the synthesis is shown, as well.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Domain Structure and Magnetization Reversal Micromechanisms in Quasi-Two-Dimensional Exchange-Biased Nanomagnetics

Abstract—The domain structure and magnetization reversal mechanisms are studied in quasi-two-dimensional exchange-biased NiFe/FeMn and NiFe/NiO nanomagnetics, using a complex method of magnetooptical indicator films and acoustic emission. The presence of the axial dispersion of unidirectional anisotropy in grains of the antiferromagnetic layer is shown to determine the statistic distribution and chirality of spin springs near the interface. The acoustic emission signals caused by the excitation of elastic Lamb waves upon the magnetization reversal of NiFe/NiO heterostructure are found. The coercive force of these systems is due to irreversible processes to overcome potential barriers that are induced by the formation of spin springs with different chirality, localized in the antiferromagnetic near the ferromagnetic–antiferromagnetic boundary.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2017

Spectral ellipsometry as a method for characterization of nanosized films with ferromagnetic layers

Nanosized films with ferromagnetic layers are widely used in nanoelectronics, sensor systems and telecommunications. Their properties may strongly differ from those of bulk materials that is on account of interfaces, intermediate layers and diffusion. In the present work, spectral ellipsometry and magnetooptical methods are adapted for characterization of the optical parameters and magnetization processes in two- and three-layer Cr/NiFe, Al/NiFe and Cr(Al)/Ge/NiFe films onto a sitall substrate for various thicknesses of Cr and Al layers. At a layer thickness below 20 nm, the complex refractive coefficients depend pronouncedly on the thickness. In two-layer films, remagnetization changes weakly over a thickness of the top layer, but the coercive force in three-layer films increases by more than twice upon remagnetization, while increasing the top layer thickness from 4 to 20 nm.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2017

Magnetic properties of BiFe{sub 0.93}Mn{sub 0.07}O{sub 3} powders obtained by ultrasonic spray pyrolysis

Samples of BiFe{sub 0.93}Mn{sub 0.07}O{sub 3} with different specific surface area were synthesized for the first time by ultrasonic spray pyrolysis. The resulting powders consist of porous particles of a spherical shape of medium size ~0.5 μm and have record values of residual magnetization and coercive force. It is found that the magnetic properties of the porous powder particles are determined by the distortion of the crystal lattice and the presence of uncompensated magnetic moments of iron ions on the surface.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

Matrix-type effect on the magnetotransport properties of Ni–AlO and Ni–NbO composite systems

The effect of the insulating-matrix material on the electronic and magnetic properties of nanocomposites is investigated in the Ni{sub x}(Al{sub 2}O{sub 3}){sub 100–x} metal–insulator system and the Ni{sub x}(Nb{sub 2}O{sub 5}){sub 100–x} metal–semiconductor system. It is established that the characteristics of composites determined by electron transport through the matrix (the electrical resistivity, the position of the electrical percolation threshold, the magnetoresistance effect) depend on the material type. Replacement of the matrix from Al{sub 2}O{sub 3} to Nb{sub 2}O{sub 5} results in a decrease in the electrical resistivity by two–three orders of magnitude, a decrease in the magnetic resistivity by more than an order of magnitude, and in displacement of the percolation threshold from 40 to 30 at % of Ni. In this case, the magnetic properties of the composites are independent of the type of matrix: the concentration of the magnetic percolation threshold is identical in the two systems (~45 at % of Ni), and the coercive force of the samples occurring beyond the percolation threshold is close in magnitude (5–8 and 12–18 Oe) in the Ni{sub x}(Nb{sub 2}O{sub 5}){sub 100–x} and Ni{sub x}(Al{sub 2}O{sub 3}){sub 100–x} composites, respectively.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Magnetic Properties of Iron-Doped Bi{sub 2}Se{sub 3}, a Topological Insulator

We study the dc magnetization of a Bi{sub 1.94}Fe{sub 0.06}Se{sub 3} single crystal in the temperature range of 1.9 to 400 K in applied magnetic fields up to 70 kOe for two sample orientations in the applied field. We register three magnetic phase transitions and observe considerable anisotropy of the magnetic properties. The coercive force varies with temperature in a nonmonotonic manner. For the sample in a paramagnetic state, we estimate its magnetic moment per iron atom; its Curie–Weiss temperature is found to be negative. Arrot–Belov plots are constructed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗