Low-Cost Efficient Manufacturing of Pressurized Conformable Compressed Natural Gas Storage Tanks
The project goal was to combine welding and superplastic forming (SPF) processes to develop a conformal pressure vessel with >90% conformability, >12 MJ/kg energy density, and <$\$$1500 tank cost. PNNL investigated an extensive set of geometries and materials showing that reinforcement geometries based on the Schwarz-P minimal surface spanning a volume produced the highest flexibility in tank geometry, conformability, and nearly met the energy density target (11.9 vs. 12 MJ/kg) based on Titanium 6Al-4V material strength. The idealized geometry proved very challenging to achieve using welding and SPF of either tubing or sheet metal. PNNL demonstrated that full Schwarz-P shapes could be formed from titanium tubing using hot metal gas forming. However, that approach was discontinued because of the many components which required joining to assemble a tank structure. Superplastic blow-forming of a welded, multi-sheet pack was further developed using PNNL’s E-beam welding and SPF capabilities. Several sheet-pack designs were welded and formed, culminating in a small demonstration tank designed to withstand the design burst pressure. X-rays confirmed that the modeled internal structure was achieved during forming. During pressure tested the tank leaked (short of the required burst pressure) at thin spots in irregular E-beam welds connecting the outer pressure boundary to the inner reinforcing layers. However, the tank did not burst and the flat sides of the conformal tank were maintained, confirming the integrity of the internal reinforcements. Further refinement of the weld energy and speed plus the control of an automated welding machine would improve weld quality and increase the pressure to leak or burst.