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Results for “CROSS COUPLING”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1961

Effects of Gyroscopic Cross Coupling Between Pitch and Yaw on the Handling Qualities of VTOL Aircraft

Gyroscopic cross coupling between pitch and yaw was simulated with a variable-stability helicopter while hovering in a yawing maneuver to ascertain the effect of cross coupling on handling qualities. Pilot ratings of the controllability of cross coupling were obtained for various combinations of longitudinal control power, angular velocity about the yaw axis, and simulated engine angular momentum. A theoretical investigation, supplemented by simulator data, was undertaken to determine the effect of longitudinal damping on the coupling controllability. Also, a comparison was made between flight and simulator data. The results indicated that for an aircraft with otherwise satisfactory longitudinal handling qualities, the level of cross coupling is satisfactory when less than 30 percent of the available longitudinal control will trim out the largest gyroscopic coupling moment which might be encountered. Increased longitudinal damping resulted in a significant increase in the controllability of pitch-yaw gyroscopic cross coupling.

Garren, John F., Jr.↗
NASA NTRS1985

Cross coupling in pilot/vehicle systems

Multiloop pilot/vehicle analysis is applied to the problem of determining crossfeed techniques which may be employed by pilots in minimizing the effects of vehicle cross coupling. As used here, cross coupling refers to unwanted vehicle motion which occurs in one control axis or loop as the result of pilot control actuation in another control axis or loop. The minimization or elimination of such cross coupling can contribute significantly to the 'workload' associated with tasks like nap-of-the-earth helicopter flight. In contrast, situations arise in which pilot's may use vehicle cross coupling to improve performance by coordinating two control actuations in the control of a single response variable. A crossfeed model is developed based upon simple control system design principles and configured in a manner amenable to pilot pursuit or precognitive control activity. A handling qualities theory developed to analyze single loop tasks is applied to the multiloop problem. The crossfeed model is applied to five different vehicles/configurations ranging from helicopters to fighter aircraft. Results indicate relatively simple crossfeed commands can significantly reduce cross coupling and, in some improve handling qualities as predicted by the single loop theory.

Hess, R. A.↗
NASA NTRS1996

Cross Coupling Between Attenuators In A Docking Mechanism

Cross coupling between motion attenuators on opposite sides of docking mechanism proposed as means of increasing capture envelope. Prototype system for application of cross-coupling concept is one used for docking of Apollo and Soyuz spacecraft; however, given widespread use of docking mechanisms, concept may prove useful in many terrestrial applications as well.

Holmberg, Arthur↗
NASA NTRS1961

Effects of Gyroscopic Cross Coupling between Pitch and Roll on the Handling Qualities of VTOL Aircraft

In order to provide information relative to the effects of gyroscopic cross coupling between pitch and roll on the handling qualities of VTOL aircraft, a flight investigation has been conducted during which cross coupling was simulated. Generality is achieved by presenting the results of the flight investigation in the form of a criterion which may be used t o predict the acceptability of the level of cross coupling in VTOL aircraft as a function of the aircraft design parameters. The criterion is based on pilot's opinions of the acceptability of the motions for the range of cross coupling which was simulated during a maneuver in which cross coupling is particularly objectionable. is used to provide a basis for application of the criterion. The theory which i s developed is shown to predict accurately the aircraft motions.

Garren, John F., Jr.↗
DOE OSTI2025

Development, Application, and Mechanistic Interrogation of a Dual Ni Catalysis Approach to Photoredox-Based C(sp 3 )–C(sp 3 ) Cross-Coupling

The installation of alkyl substituents such as methyl groups is a crucial tactic for the synthesis and diversification of medicinal compounds with improved pharmacological profiles. However, strategies that leverage methyl radical for C(sp 3 ) methylation remain underdeveloped due to the challenge of obtaining cross-selectivity between fleeting aliphatic radicals and alkyl electrophiles. Here, we report the development, application, and interrogation of a conceptually novel mechanistic framework for C(sp 3 )–Me bond formation using two distinct Ni catalysts capable of cross-coupling sterically and electronically diverse alkyl halides (chlorides and bromides) with methyl radical generated photocatalytically from benzaldehyde dimethyl acetal. Furthermore, by modifying the alkyl substituents on the acetal coupling partner, we demonstrate cross-couplings beyond methylation to access an array of 1°–1° and 1°–2° alkyl–alkyl bonds. Experimental and computational mechanistic studies provide support for cooperativity between an in situ-generated (bpy)Ni I (X) catalyst that facilitates XAT and inner-sphere C–C bond formation and a (Tp*)Ni II (acac) cocatalyst that captures methyl radical and engages in concurrent outer-sphere S H 2 coupling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1973

Effects of visual reference on adaptation to motion sickness and subjective responses evoked by graded cross-coupled angular accelerations

Three groups of 10 subjects each were exposed to stepwise increments of cross coupled angular accelerations in three visual modes: internal visual reference (IVR), external visual reference (EVR), and vision absent (VA). The subjects in the IVR condition required significantly greater amounts of stimulus exposure to neutralize their illusory subjective reactions. They also suffered a greater loss of well-being and a more marked incidence of motion sickness than did subjects in the EVR and VA conditions. The same 30 subjects were reexposed to the same graded cross coupled stimulation 1 week later. This time, however, all the subjects were tested under only the IVR condition. All three groups showed some positive transfer of adaptation, but only the IVR-IVR combination required significantly fewer head motions to achieve the same level of adaptation on the second occasion. Taken overall, however, the most efficient and least disturbing route to adaptation at the completion of the second test was via the VA-IVR combination.

Reason, J. T.↗
NASA NTRS1988

In-flight simulation investigation of rotorcraft pitch-roll cross coupling

An in-flight simulation experiment investigating the handling qualities effects of the pitch-roll cross-coupling characteristic of single-main-rotor helicopters is described. The experiment was conducted using the NASA/Army CH-47B variable stability helicopter with an explicit-model-following control system. The research is an extension of an earlier ground-based investigation conducted on the NASA Ames Research Center's Vertical Motion Simulator. The model developed for the experiment is for an unaugmented helicopter with cross-coupling implemented using physical rotor parameters. The details of converting the model from the simulation to use in flight are described. A frequency-domain comparison of the model and actual aircraft responses showing the fidelity of the in-flight simulation is described. The evaluation task was representative of nap-of-the-Earth maneuvering flight. The results indicate that task demands are important in determining allowable levels of coupling. In addition, on-axis damping characteristics influence the frequency-dependent characteristics of coupling and affect the handling qualities. Pilot technique, in terms of learned control crossfeeds, can improve performance and lower workload for particular types of coupling. The results obtained in flight corroborated the simulation results.

Watson, Douglas C.↗
DOE OSTI2025

Binding the Power of Cycloaddition and Cross-Coupling in a Single Mechanism: An Unexpected Bending Journey to Radical Chemistry of Butadiynyl with Conjugated Dienes

What if an experiment could combine the power of cycloaddition and cross-coupling with the in situ formation of an aromatic molecule in a single collision? Crossed molecular beam experiments augmented with electronic structure and statistical calculations provided compelling evidence on a novel radical route involving 1,3-butadiynyl (HCCCC; X 2 Σ + ) radicals synthesizing (substituted) arylacetylenes in the gas phase upon reactions with 1,3-butadiene (CH 2 CHCHCH 2 ; X 1 Ag) and 2-methyl-1,3-butadiene (isoprene; CH 2 C(CH 3 )CHCH 2 ; X 1 A'). Furthermore, this elegant mechanism de facto merges two previously disconnected concepts of cross-coupling and cycloaddition–aromatization in a single collision event via the formation of two new C(sp 2 )–C(sp 2 ) bonds and bending the 180° moiety of the linear 1,3-butadiynyl radical out of the ordinary by 60° to 120°. In addition to its importance to fundamental organic chemistry, this unconventional mechanism links two previously separated routes of gas-phase molecular mass growth processes of polyacetylenes and polycyclic aromatic hydrocarbons (PAHs), respectively, in low-temperature environments such as in cold molecular clouds like the Taurus Molecular Cloud (TMC-1) and in hydrocarbon-rich atmospheres of planets and their moons such as Titan, what revises the established understanding of low-temperature molecular mass growth processes in the Universe.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Multiconfigurational Electronic Structure of Nickel Cross-Coupling Catalysts Revealed by X-ray Absorption Spectroscopy

Ni II 2,2'-bipyridine complexes are commonly invoked intermediates in metallaphotoredox cross-coupling reactions. Despite their ubiquity, design principles targeting improved catalytic performance remain underdetermined. A series of Ni( R bpy)( R 'Ar)Cl (R = MeOOC, t-Bu, R' = CH 3 , CF 3 ) complexes were proposed to have multiconfigurational electronic structures on the basis of multiconfigurational/multireference calculations, with significant mixing of Ni → bpy metal-to-ligand charge transfer (MLCT) configurations into the ground-state wave function. Here, Ni K-edge and L 2,3 -edge X-ray absorption spectroscopies provide experimental support for the highly covalent and multiconfigurational electronic structures of these complexes. The pre-edge intensity in the K-edge spectrum reflects highly covalent Ni–aryl bonding. The L 3 -edge spectral shape is dependent on ligand functionalization, and a feature reflecting the MLCT character is assigned using prior ab initio and new semiempirical calculations. The results suggest the push/pull effects of the aryl/bpy ligands moderate the changes in electron density on Ni during the multiredox cross-coupling reaction cycle.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1982

Conditioned feeding suppression in rats produced by cross-coupled and simple motions

Results are presented of an experiment on the induction of motion sickness in rats by the use of cross-coupled accelerations of magnitudes similar to those used in human experiments. Accelerations were produced in a seesaw apparatus with rotating disks supporting the animal cages mounted on each seesaw arm, and motion sickness was assessed according to the consumption of a sweet food previously offered to the animals immediately before the motion treatment. During a 1-hour test session 72 h after motion treatment and after a 24-h fast, rats having undergone cross-coupled vertical sinusoidal and rotational motion are observed to consume less food than those having experienced either type of motion alone, or no motion. The ordering of the conditioned suppressive feeding effects is consistent with the amounts of vestibular stimulation produced by the respective motions. The results support the existence of motion sickness effects in rats, even though they are unable to vomit.

Fox, R. A.↗
NASA NTRS1984

Quantification of Cross-coupling and Motion Feedthrough for Multiaxis Controllers Used in an Air Combat Flying Task

A real-time piloted simulation of an air-to-air combat flying task using a wings-level-turn aircraft and various novel controllers was conducted. One objective is to quantify how the pilot interacts with the controllers and control modes, including: (1) controller versus aircraft response; (2) proprioceptive cross-coupling among axes of the controllers; and (3) biodynamic cross-coupling between the aircraft motions and the controllers. In order to aid in identifying the items listed above, both the target aircraft and the large amplitude multimode aerospace research simulator (LAMARS) motion system were distributed with quasi-random sums-of-sinusoids. Since the disturbances were separated in frequency, spectral analysis techniques were used to identify the three items listed. The results of the spectral analysis of controller motions from the two-axis side stick, a twist grip mounted on the side stick, a thumb button mounted on the side stick, and conventional rudder pedals are presented. Conclusions and recommendations for further research are also presented.

Jewell, W. E.↗
NASA NTRS2011

Implementation of CAPIO for Composite Adaptive Control of Cross-Coupled Unstable Aircraft

This paper presents an implementation of a recently developed control allocation algorithm CAPIO (a Control Allocation technique to recover from Pilot Induced Oscillations) for composite adaptive control of an inertially cross coupled unstable aircraft. When actuators are rate-saturated due to either an aggressive pilot command, high gain of the flight control system or some anomaly in the system, the effective delay in the control loop may increase due to the phase shifting between the desired and the achieved system states. This effective time delay may deteriorate the performance or even destabilize the system in some cases, depending on the severity of rate saturation. CAPIO reduces the effective time delay by minimizing the phase shift between the commanded and the actual attitude accelerations. We present simulation results for an unstable aircraft with cross-coupling controlled with a composite adaptive controller in the presence of rate saturation. The simulations demonstrate the potential of CAPIO serving as an effective rate saturation compensator in adverse conditions.

Yildiz, Yildiray↗
DOE OSTI2024

Precision Synthesis of Conjugated Polymer Films by Surface-Confined Stepwise Sonogashira Cross-Coupling

Thin films of poly(arylene ethynylene)-conjugated polymers, including low-energy-gap donor–acceptor polymers, can be prepared via stepwise polymerization utilizing surface-confined Sonogashira cross-coupling. This robust and efficient polymerization protocol yields conjugated polymers with a precise molecular structure and with nanometer-level control of the organization and the uniform alignment of the macromolecular chains in the densely packed film. In addition to high stability and predictable and well-defined molecular organization and morphology, the surface-confined conjugated polymer chains experience significant interchain electronic interactions, resulting in dominating intermolecular π-electron delocalization which is primarily responsible for the electronic and spectroscopic properties of polymer films. The fluorescent films demonstrate remarkable performance in chemosensing applications, showing a turn-off fluorescent response on the sub-ppt (part per trillion) level of nitroaromatic explosives in water. This unique sensitivity is likely related to the enhanced exciton mobility in the uniformly aligned and structurally monodisperse polymer films.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Formation of a Decanuclear Organometallic Dysprosium Complex via a Radical–Radical Cross–Coupling Reaction

Over the years, polynuclear cyclic or torus complexes have attracted increasing interest due to their unique metal topologies and properties. However, the isolation of polynuclear cyclic organometallic complexes is extremely challenging due to their inherent reactivity, which stems from the labile and reactive metal-carbon bonds. In this study, the pyrazine ligand undergoes a radical-radical cross-coupling reaction leading to the formation of a decanuclear [(Cp*) 20 Dy 10 (L1) 10 ] ⋅ 12(C 7 H 8 ) ( 1 ; where L1 = anion of 2-prop-2-enyl-2 H -pyrazine; Cp* = pentamethylcyclopentadienyl) complex, where all Dy III metal centres are bridged by the anionic L1 ligand. Amongst the family of polynuclear Ln organometallic complexes bearing Cp R 2 Ln x units (Cp R = substituted cyclopentadienyl), 1 features the highest nuclearity obtained to date. In-depth computational studies were conducted to elucidate the proposed reaction mechanism and formation of L1, while probing of the magnetic properties of 1 , revealed slow magnetic relaxation upon application of a static dc field.

cross-coupling↗