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Magnetotransport properties of the topological nodal-line semimetal CaCdSn

Topological nodal-line semimetals support protected band crossings, which form nodal lines or nodal loops between the valence and conduction bands and exhibit novel transport phenomena. Here we address the topological state of the nodal-line semimetal candidate material CaCdSn, and report magnetotransport properties of its single crystals grown by the self-flux method. In this work, our first-principles calculations show that the electronic structure of CaCdSn harbors a single nodal loop around the Γ point in the absence of spin-orbit coupling effects. The nodal crossings in CaCdSn are found to lie above the Fermi level and yield a Fermi surface that consists of both electron and hole pockets. CaCdSn exhibits high mobility (μ ≈ 3.44 × 10 4 cm 2 V –1 s –1 ) and displays a field-induced metal-semiconductor-like crossover with a plateau in resistivity at low temperature. We observe an extremely large and quasilinear nonsaturating transverse as well as longitudinal magnetoresistance (MR) at low temperatures (≈ 7.44 × 10 3 % and ≈ 1.71 × 10 3 %, respectively, at 4 K). We also briefly discuss possible reasons behind such a large quasilinear magnetoresistance and its connection with the nontrivial band structure of CaCdSn.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Materials Data on CaCdSn by Materials Project

CaCdSn crystallizes in the hexagonal P-62m space group. The structure is three-dimensional. Ca is bonded in a 5-coordinate geometry to six equivalent Cd and five Sn atoms. There are two shorter (3.45 Å) and four longer (3.70 Å) Ca–Cd bond lengths. There are one shorter (3.26 Å) and four longer (3.30 Å) Ca–Sn bond lengths. Cd is bonded in a 12-coordinate geometry to six equivalent Ca, two equivalent Cd, and four Sn atoms. Both Cd–Cd bond lengths are 3.39 Å. There are two shorter (2.94 Å) and two longer (3.07 Å) Cd–Sn bond lengths. There are two inequivalent Sn sites. In the first Sn site, Sn is bonded in a 9-coordinate geometry to three equivalent Ca and six equivalent Cd atoms. In the second Sn site, Sn is bonded in a 9-coordinate geometry to six equivalent Ca and three equivalent Cd atoms.

36 MATERIALS SCIENCE↗

Materials Data on CaCdSn by Materials Project

CaCdSn is half-Heusler structured and crystallizes in the cubic F-43m space group. The structure is three-dimensional. Ca is bonded in a 4-coordinate geometry to four equivalent Cd and six equivalent Sn atoms. All Ca–Cd bond lengths are 3.04 Å. All Ca–Sn bond lengths are 3.51 Å. Cd is bonded in a body-centered cubic geometry to four equivalent Ca and four equivalent Sn atoms. All Cd–Sn bond lengths are 3.04 Å. Sn is bonded in a 10-coordinate geometry to six equivalent Ca and four equivalent Cd atoms.

36 MATERIALS SCIENCE↗